Abstract: A coupler containing in the coupling position a carbamoyloxy group ##STR1## upon oxidative coupling, releases a carbamic acid fragment that, in turn, is capable of thermally releasing ammonia or an amine. Such a carbamoyloxy substituted coupler and carbamic acid fragment are useful in imaging such as in photothermography and thermography. Ammonia or an amine released from the carbamic acid fragment enables imaging in imaging materials that are responsive to ammonia or an amine. The carbamoyloxy substituted coupler also generally is a dye-forming coupler that reacts with the oxidized form of a color developing agent to form a dye. An image is produced in an exposed photothermographic material comprising the carbamoyloxy substituted coupler by thermal development. An image is produced in a thermographic material comprising the carbamoyloxy substituted coupler and a color developing agent by imagewise heating the thermographic material.
Type:
Grant
Filed:
June 15, 1983
Date of Patent:
September 4, 1984
Assignee:
Eastman Kodak Company
Inventors:
Anthony Adin, Csaba A. Kovacs, Delwyn E. Machiele
Abstract: A 6-substituted-2,4-bis(trichloromethyl)-s-triazine stabilizer precursor which has a maximum absorption wavelength greater than 320 nanometers and is thermally stable at temperatures up to 150.degree. C. provides improved post-processing stability in a photothermographic silver halide material designed for dry physical development. Such a photothermographic material comprises photographic silver halide and an image forming combination comprising (i) an organic silver salt oxidizing agent, with (ii) a reducing agent for the organic silver salt oxidizing agent. A developed visible image is provided after imagewise exposure by uniformly heating the photothermographic material to moderately elevated temperatures.
Abstract: A redox release compound that is capable upon oxidation of releasing a silver ion complexing heterocyclic thio moiety enables reduction of the concentration of silver required in a photographic silver halide material comprising a combination of (i) photographic silver halide capable of forming a surface latent image, and (ii) a photographic silver halide capable of forming an internal latent image. The silver halide capable of forming an internal latent image preferably has lower photosensitivity than the silver halide capable of forming a surface latent image. The redox release compound preferably comprises a silver ion complexing 1,2,4-triazolium-3-thio moiety. An image is developed in such an exposed photographic silver halide element by means of a surface type silver halide developer.
Abstract: Useful scavengers for oxidized developing agents in photographic elements are 2,4-disulfonamidophenols, or alkali labile precursors of such phenols.
Abstract: Photographic couplers comprising a coupler moiety and a ballast moiety have advantageous properties when the ballast moiety is terminated with a hydroxyphenylsulfonyl or hydroxyphenylsulfinyl group. The couplers are useful in photographic emulsions and element.
Abstract: An electrically activatable recording (EAR) element capable of producing a positive image comprises an electrically activatable recording layer comprising a transition metal complex selected from the group consisting of Group VIIIB and Group IB metal complexes in a film forming ionic polymer that is capable of undergoing an imagewise reorientation upon exposure to electric current and, upon such exposure, development of an image in the exposed areas of the recording layer is restricted. The recording element is light handleable and provides a non-silver positive image upon exposure and processing.
Abstract: Photosensitive silver halide grains that are thin tabular grains having an average grain thickness of less than 0.3 microns provide advantages, including improved spectral sensitization and image tone, in a photothermographic material comprising photosensitive silver halide and a photosensitive silver halide processing agent. An image is developed in such an exposed photothermographic material by heating the material, such as to a temperature within the range of about 90.degree. C. to about 180.degree. C.
Abstract: A heat erasable photographic material comprises, in reactive association, in a suitable binder:(a) photographic silver halide;(b) a mild oxidizing agent which consists essentially of a cobalt(III) amine salt which, upon heating of the photographic material, will oxidize any latent image silver present in the photographic material; and(c) a weak complexing agent for the oxidized silver.Any latent image silver in the photographic material is erased upon brief uniform heating of the photographic material. The photographic material is light handleable prior to uniform heating. After uniform heating, the photographic material is capable of being imagewise exposed and processed to produce a developed silver image. The photographic material may comprise a selected silver halide developing agent.
Abstract: In a photothermographic silver halide material and process for preparing an enhanced silver image, an aminosulfonylhydrazone that is capable of developing an image in the photothermographic material and that is capable, upon oxidation, of releasing an aminosulfinic acid, which, in turn, thermally releases ammonia or amine provides a silver image in the photothermographic material and provides ammonia or amine for activation of an ammonia or amine responsive imaging material. After imagewise exposure of the photothermographic material, a silver image enhanced by an image in the ammonia or amine responsive imaging material is produced by heating the photothermographic material.
Abstract: In a dye-forming imaging material comprising (a) a dye-forming coupler, and (b) an organic reducing agent that is capable in its oxidized form of reacting with the dye-forming coupler to form a dye, improvements are provided by a reducing agent that is a ureidoaniline silver halide developing agent free of strong electron withdrawing groups. Such an imaging material can be a photographic silver halide material. The imaging material can be a photothermographic material for producing a dye image comprising, in reactive association, (a) photographic silver halide, (b) a dye-forming coupler, and (c) an oxidation-reduction image forming combination comprising (1) an organic silver salt oxidizing agent, and (2) an organic reducing agent for the organic silver salt oxidizing agent, wherein the reducing agent is a ureidoaniline which is capable in its oxidized form of reacting with the dye-forming coupler to form a dye.
Abstract: A new color-forming 4-(4'-secondary or tertiary-amino)anilino-1-carboxamidonaphthalene dye precursor in a photographic material and process enables formation of a dye image by means of cross-oxidation without the need for a coupling reaction. The color-forming 4-(4'-secondary or tertiary-amino)anilino-1-carboxamidonaphthalene dye precursor is useful in a photographic silver halide material for producing (i) a dye image, or (ii) a dye image and silver image. The exposed photographic material is processed to produce (a) a positive dye image, (b) a negative dye and negative silver image, (c) a negative dye image or (d) a positive dye image and a positive silver image. New naphthoquinoneimide dyes are also described.
Abstract: Light sensitive layers in photographic elements are protected against exposure to radiation in the blue region of the visible spectrum by a yellow filter dye having the structure: ##STR1## where: R.sup.1 is alkyl of 1 to 3 carbon atoms;R.sup.2 is hydrogen or alkyl of 1 to 3 carbon atoms;R.sup.3 and R.sup.4 are each individually alkyl of 1 to 3 carbon atoms, at least one of which is terminated with ##STR2## and R.sup.5 is alkyl of 1 to 3 carbon atoms or fluoroalkyl of 1 to 3 carbon atoms.
Type:
Grant
Filed:
July 19, 1982
Date of Patent:
December 13, 1983
Assignee:
Eastman Kodak Company
Inventors:
Spencer M. Krueger, James W. Brown, III
Abstract: A diphenylamine compound that is a precursor for a phenazine dye comprises, in an ortho position to the amine of the diphenylamine, a sulfonyldiamido group (--NHSO.sub.2 NHR) that is capable of releasing a sulfonylamine fragment upon oxidation. The diphenylamine compound upon oxidation intramolecularly cyclizes to a phenazine dye. The sulfonylamine fragment is capable of thermally releasing ammonia or an amine. The diphenylamine compound and sulfonylamine fragment are useful in imaging such as in photothermography. Ammonia or an amine thermally released from the sulfonylamine fragment enables imaging in imaging materials that are responsive to ammonia or an amine. The diphenylamine compound also generally is a silver halide developing agent.
Abstract: Stabilizer precursors which comprise triarylphosphines and triarylphosphoranes and which, upon being heated to a temperature above about 100.degree. C., release a phosphorous compound silver halide stabilizer that is useful in a heat stabilizable photographic silver halide material comprising photographic silver halide. A stabilized image is produced in the photographic material following exposure and development by heating the material to processing temperature. The triarylphosphines and triarylphosphoranes are useful in a dry physical development photographic material and process. Alternatively, the triarylphosphines and triarylphosphoranes are useful in a dry chemical photographic material and process.
Abstract: In an electrically activatable recording element and process comprising a polymeric electrically active conductive layer improvements are provided wherein the polymeric electrically active conductive layer comprises a polymer that has recurring units represented by the structure: ##STR1## wherein R is hydrogen or alkyl containing 1 to 20 carbon atoms;R.sup.1 and R.sup.3 are individually hydrogen or methyl;R.sup.2 is alkyl containing 2 to 20 carbon atoms;x is 0 or 1;y is 0 to 4;R.sup.4 is C.sub.6 H.sub.5-z X.sub.z ; wherein z is 1 to 5;X is chlorine, bromine or iodine;n is 40 to 100 weight percent;and the polymer has a glass transition temperature within the range of 20.degree. C. to 40.degree. C.
Abstract: In an electrically activatable recording (EAR) element comprising an electrically conductive support bearing (a) a first layer, and, contiguous to the first layer, (b) an electrically activatable recording layer, image formation in the electrically activatable recording layer is aided when the first layer (a) consists essentially of a compound selected from the group consisting of silver chlorides, silver bromides, silver iodides, transition metal bromides, transition metal chlorides, alkali metal chlorides, alkali metal bromides, alkali metal iodides, mixed chlorides, bromides and iodides of such metals and combinations of such compounds. The EAR element is light handleable when free of photosensitive silver halide and provides an image, after electrically activated exposure by dry development processing or by processing in a processing solution or bath.
Type:
Grant
Filed:
August 26, 1982
Date of Patent:
October 11, 1983
Assignee:
Eastman Kodak Company
Inventors:
Mark Lelental, Arthur A. Rasch, David P. Sullivan
Abstract: Mesoionic 1,2,4-triazolium-3-thiolate silver halide stabilizer precursors are novel compounds useful in a heat developable and heat stabilizable photographic silver halide materials and processes. After imagewise exposure of the photographic material, a developed and stabilized silver image is produced by heating the element. Mesoionic stabilizer precursors are also useful in photographic silver halide processing compositions.
Abstract: Couplers of good reactivity contain an aryloxy coupling-off group having in an ortho position a polarizable carbonyl, sulfonyl or phosphinyl substituent group which is free of photographic dye groups and photographic reagent groups.
Abstract: A color-forming para-sulfonamidodiphenylamine dye precursor in a photographic material and process enables formation of a sulfonimide dye image by means of cross-oxidation without the need for a coupling reaction. The color-forming para-sulfonamidodiphenylamine dye precursor is useful in a photographic silver halide material for producing (i) a dye image, or (ii) a dye image and silver image. The exposed photographic material is processed to produce (a) a positive dye image, (b) a negative dye and negative silver image, (c) a negative dye image or (d) a positive dye image and a positive silver image.
Type:
Grant
Filed:
July 1, 1982
Date of Patent:
June 28, 1983
Assignee:
Eastman Kodak Company
Inventors:
Rolf S. Gabrielsen, Patricia A. Graham, James E. Klijanowicz, Max H. Stern
Abstract: A color-forming para sulfonamidodiphenylamine dye precursor has one or two sulfonamido groups in positions ortho to the amine --NH-- moiety separating the two phenyl rings of the para sulfonamidodiphenylamine and, in oxidized form, intramolecularly reacts to produce a sulfonamido-substituted phenazine dye. Such color-forming para sulfonamidodiphenylamine dye precursors are useful to produce a dye image by cross-oxidation in an imaging material.
Type:
Grant
Filed:
July 6, 1981
Date of Patent:
April 19, 1983
Assignee:
Eastman Kodak Company
Inventors:
Rolf S. Gabrielsen, Patricia A. Graham, James E. Klijanowicz