Abstract: The applicants have provided laminates prepared by (a) impregnating a glass fabric with an N-methyl-2-pyrrolidone solution of a compound having the structure of Formula A shown in FIG. 1 of the drawings, (b) heating the impregnated glass fabric to remove solvent therefrom and to covert the amic acid groups to imide groups, and (c) assembling a plurality of the impregnated glass fabrics from (b) and heating the assembly under pressure to a temperature in the range of 177.degree.-260.degree. C.
Type:
Grant
Filed:
April 27, 1978
Date of Patent:
June 29, 1982
Assignee:
Gulf Oil Corporation
Inventors:
Patricia A. Antonoplos, William J. Heilman
Abstract: Blends of thermoplastic polymers which may be coextruded to form bonding layers in film laminates contain (a) a copolymer of ethylene with a lower alkyl acrylate or methacrylate or vinyl acetate, (b) a chlorinated ethylene polymer and optionally (c) a tackifying resin.
Abstract: Compatible blends of polymers are disclosed which contain (a) a low density ethylene polymer, (b) a copolymer of ethylene and an alkyl ester of acrylic or methacrylic acid or vinyl acetate, (c) an ionomer resin, and (4) optionally a tackifying resin such as a glyceryl ester of a rosin acid.
Type:
Grant
Filed:
August 5, 1981
Date of Patent:
June 29, 1982
Assignee:
Gulf Oil Corporation
Inventors:
Khalid A. Karim, Pallavoor R. Lakshmanan, James H. Rea
Abstract: Propylene is polymerized with an improved titanium chloride catalyst. The improved titanium chloride catalyst is prepared by treating TiCl.sub.4 with an aluminum alkyl and treating the resulting titanium chloride catalyst with carbon dioxide and a Lewis base, such as di(n-butyl) ether in a hydrocarbon medium at an elevated temperature.
Abstract: Hot melt adhesive compositions are provided which contain (a) about 10-30 weight % of an alkenyl succinic anhydride, (b) about 20-60 weight % of an ethylene copolymer, and (c) about 10-40 weight % of a tackifying resin which is a rosin ester.
Type:
Grant
Filed:
January 29, 1981
Date of Patent:
April 20, 1982
Assignee:
Gulf Oil Corporation
Inventors:
Vikramkumar Acharya, Pallavoor R. Lakshmanan
Abstract: Intimate fusion blends of 100 parts of an ionomer resin and about 5 to 900 parts of an alkenyl succinic anhydride (the alkenyl group containing about 16 to 52 carbon atoms) are provided. The compositions can be heated with aqueous alkaline solutions to form stable dispersions useful as coating compositions.
Abstract: Hot melt adhesive compositions are provided which contain (a) about 10-30 weight % of an alkenyl succinic anhydride, (b) abut 20-60 weight % of an ethylene copolymer, and (c) about 10-40 weight % of a tackifying resin which is a terpene-phenolic resin.
Type:
Grant
Filed:
January 28, 1981
Date of Patent:
April 13, 1982
Assignee:
Gulf Oil Corporation
Inventors:
Vikramkumar Acharya, Pallavoor R. Lakshmanan
Abstract: Ethylene or propylene polymers are dyed by dispersing a small quantity of a copolymer of a C-14 or higher alpha-olefin and maleic anhydride therein and subsequently treating the composition with an aqueous solution of a basic dye stuff such as Malachite Green.
Abstract: Improved ethylene polymer fibrils are provided which are characterized in having:(a) a melt temperature of at least about 137.degree. C.,(b) a molecular weight of at least 250,000,(c) at least about 1.2 weight % of polyvinyl alcohol sorbed thereon, and(d) a zero-span breaking length of at least about 25,000.
Type:
Grant
Filed:
December 12, 1980
Date of Patent:
March 16, 1982
Assignee:
Gulf Oil Corporation
Inventors:
Jin K. Kim, Clarence R. Murphy, Edward W. Smith
Abstract: Hot melt adhesive compositions are provided which contain (a) about 10-30 weight % of an alkenyl succinic anhydride, (b) about 20-60 weight % of an ethylene copolymer, and (c) about 10-40 weight % of a tackifying resin which is a terpene-urethane resin.
Type:
Grant
Filed:
January 28, 1981
Date of Patent:
March 16, 1982
Assignee:
Gulf Oil Corporation
Inventors:
Vikramkumar Acharya, Pallavoor R. Lakshmanan
Abstract: Acrylate monomers useful as a component of U.V. curable resin compositions and anaerobic adhesive compositions are provided and have the structure: ##STR1## where the phenanthrene ring contains up to three (3) double bonds, where R.sub.1 is a divalent radical, where R.sub.2 is a divalent radical, and where R.sub.3 is a hydrogen atom or an alkyl group.
Type:
Grant
Filed:
June 20, 1980
Date of Patent:
January 5, 1982
Assignee:
Gulf Oil Corporation
Inventors:
Thomas F. Huemmer, Pallavoor R. Lakshmanan
Abstract: Improved anaerobic adhesives are provided which contain two monomer types. The first is a polyacrylate terminated ester of 3,4,3',4'-benzophenone tetracarboxylic acid. The second is an acrylate terminated urethane prepolymer that is prepared in part from abietyl alcohol.
Type:
Grant
Filed:
June 20, 1980
Date of Patent:
January 5, 1982
Assignee:
Gulf Oil Corporation
Inventors:
Thomas F. Huemmer, Pallavoor R. Lakshmanan
Abstract: A group of heat curable resins are provided which have good physical properties, which properties are retained to a surprising degree after prolonged exposure to temperatures as high as 300.degree. C. The products are acetylene end-capped esterimides having the structure: ##STR1## where R is an arylene group or a group having the structure: ##STR2## where X is ##STR3## R.sub.1 is an alkyl group containing 1 or 2 carbon atoms and R.sub.2 is hydrogen or an alkyl group containing 1 or 2 carbon atoms; and where R' is a phenylene group.
Abstract: The products of the invention are partial acetylene end-capped oligomers which have the structure as shown in FIG. 3 in which terminal R" group is derived from a mixture consisting of about 14-40 mol % of an aromatic monoamine and the balance an acetylene substituted aromatic monoamine. The products are prepared from either of two (2) precursors. The first precursor has the structure shown in FIG. 2. The second precursor is a complex amine salt having the structure shown in FIG. 5.
Type:
Grant
Filed:
May 3, 1979
Date of Patent:
November 10, 1981
Assignee:
Gulf Oil Corporation
Inventors:
Patricia A. Antonoplos, William J. Heilman
Abstract: Novel catalysts are provided for the polymerization of olefins such as ethylene. The catalysts consist essentially of a chromium compound supported upon an inorganic carrier containing aluminum and phosphorus moieties, at least a portion of the chromium having a valence of less than 6. The inorganic carrier is an amorphous precipitate of aluminum phosphate or an amorphous precipitate containing aluminum and phosphorus moieties in an atomic ratio in the range of about 5:1 to 1:1. The catalysts are particularly useful for polymerizing ethylene in a Particle Form Process in that the catalyst has essentially no polymerization induction period and provides ethylene polymers having a desirably broad molecular weight distribution and a desirably high melt flow shear ratio.
Type:
Grant
Filed:
April 4, 1980
Date of Patent:
September 15, 1981
Assignee:
Gulf Oil Corporation
Inventors:
Robert W. Hill, William L. Kehl, Thomas J. Lynch
Abstract: Alkali-soluble hot melt adhesive compositions are provided which contain (a) about 10-40 weight % of an alkenyl succinic anhydride, (b) a carboxyl group containing ethylene copolymer, and (c) about 10-50 weight % of rosin.
Abstract: A compatible blend of polymers is disclosed and consists essentially of 100 parts by weight of an ethylene-alkyl acrylate copolymer and about 0.2 to 3 parts by weight of either poly(ethylene adipate) or poly(trimethylene adipate). The polymer blends have a lower sealing temperature than the ethylene-alkyl acrylate copolymer contained therein.
Abstract: A compatible blend of polymers is disclosed and consists essentially of 100 parts by weight of a low density ethylene polymer and about 0.2 to 3 parts by weight of either poly(ethylene adipate) or poly(trimethylene adipate). The polymer blends have a lower sealing temperature than the low density ethylene polymer contained therein.
Abstract: The products of the invention are vinyl end-capped oligomers which are prepared from 2,4-bis (p-aminobenzyl) aniline and a vinyl substituted aromatic monoamine, the principal component of which is the compound whose structure is shown in FIG. 3. The products are prepared from either of two (2) precursors. The first precursor is a compound whose structure is shown in FIG. 2 and which is prepared from 2,4-bis (p-aminobenzyl) aniline, a dianhydride of an aromatic tetracarboxylic acid such as 3,3'4,4'-benzophenonetetracarboxylic acid (BTDA) and a vinyl substituted aromatic monoamine, such as 3-aminophenyl-ethylene (APE). The second precursor is a complex amine salt having the structure shown in FIG. 6 and which is prepared from 2,4-bis-(p-aminobenzyl) aniline, a dialkyl ester of BTDA and APE.