Patents Represented by Attorney, Agent or Law Firm Shlomo R. Frieman
  • Patent number: 5634984
    Abstract: A method for cleaning oil-contaminated substrates employing a composition composed of a diluent oil, a first surfactant having a HLB value of at least 10, and a second surfactant having a higher HLB value. The difference in the HLB values of the first and second surfactants is at least 3 and a mixture of the surfactants would have a HLB value of at least 11.
    Type: Grant
    Filed: March 17, 1994
    Date of Patent: June 3, 1997
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 5629270
    Abstract: Oil-base drilling fluids containing a non-sulfonated polymer and/or a non-organophilic clay maintain desirable rheological properties at elevated temperatures.
    Type: Grant
    Filed: June 30, 1994
    Date of Patent: May 13, 1997
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 5617920
    Abstract: Enhanced gel properties (e.g., faster gel time, higher attainable gel strengths) are achieved by reducing the pH and/or increasing the salt of a monovalent and/or divalent cation concentration of an aqueous reaction medium in which a polymer is reacted with an organic crosslinking agent. In addition, the gelation time of an aqueous composition comprising a polymer and an organic crosslinking agent is reduced by heating the composition above about 48.9.degree. C. (120.degree. F.) prior to injecting the composition into a subterranean formation. Alternatively, the gelation time of the aqueous composition is increased by incorporating a pH increasing agent into the composition.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: April 8, 1997
    Assignee: Union Oil Company of California
    Inventors: Hoai T. Dovan, Burton B. Sandiford, Richard D. Hutchins
  • Patent number: 5614476
    Abstract: Compounds selected from the group consisting of ammonia, ammonium-containing compounds, urea, urea homologues and analogues, and mixtures thereof surprisingly lower the crystallization temperature of aqueous, carbon disulfide precursor (e.g., thiocarbonate)-containing solutions.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: March 25, 1997
    Assignee: Entek Corporation
    Inventor: Donald C. Young
  • Patent number: 5601721
    Abstract: Selenium exists in oil refinery stripped sour water as selenocyanate and can be effectively removed using an acrylic, strong base, anion exchange column or stannous chloride. The acrylic, strong base, anion exchange column can also be employed to remove arsenic, iron, and vanadium from an aqueous fluid.
    Type: Grant
    Filed: April 29, 1994
    Date of Patent: February 11, 1997
    Assignee: Union Oil Company of California
    Inventors: Ronald J. Lukasiewicz, Darrel L. Gallup, Brian J. Kelly
  • Patent number: 5593955
    Abstract: Compounds selected from the group consisting of urea, urea homologues and analogues, and mixtures thereof are employed to synergistically increase the dewaxing efficacy of aqueous, carbon disulfide precursor (e.g., thiocarbonate)-containing solutions.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: January 14, 1997
    Assignee: Entek Corporation
    Inventor: Charles L. Kissel
  • Patent number: 5556832
    Abstract: A solids-free, essentially all-oil wellbore fluid comprises (a) an organic fluid having (i) a melting point less than about 20.degree. C. (about 68.degree. F.), (ii) a flash point greater than about 54.4.degree. C. (about 130.degree. F.), and (iii) a dipole moment greater than 0 debye (D), and (b) a salt dissolved in the organic fluid. The wellbore fluid is employed in well drilling, completion, and work-over operations.
    Type: Grant
    Filed: September 21, 1992
    Date of Patent: September 17, 1996
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 5541149
    Abstract: A composition exhibiting increased defoliation and growth inhibition efficacy comprises the mixture of an amide-sulfuric acid adduct and a phosphonic acid and/or phosphonic acid derivative or salt.
    Type: Grant
    Filed: November 7, 1994
    Date of Patent: July 30, 1996
    Assignee: Union Oil Company of California
    Inventor: Mark L. Atwater
  • Patent number: 5494498
    Abstract: Urea increases the solute content of a fertilizer comprising water and at least two different nitrate-containing compounds selected from the group consisting of ammonium nitrate, alkali metal nitrates, and alkaline earth metal nitrates. In addition, urea enhances plant uptake of alkaline earth metals. Particularly favored are quaternary aqueous solutions containing urea, calcium nitrate, and ammonium nitrate.
    Type: Grant
    Filed: March 7, 1995
    Date of Patent: February 27, 1996
    Assignee: Union Oil Company of California
    Inventor: Donald C. Young
  • Patent number: 5486312
    Abstract: Gels stable in a subterranean formation at a temperature greater than about 175.degree. F. are formed using, inter alia, a stabilizing agent (e.g., a buffer having a buffering capacity at a pH of at least about 8 and/or a chelating agent).
    Type: Grant
    Filed: September 10, 1993
    Date of Patent: January 23, 1996
    Assignee: Union Oil Company of California
    Inventors: Burton B. Sandiford, Hoai T. Dovan, Richard D. Hutchins
  • Patent number: 5472050
    Abstract: Hydrocarbon production from a low permeability formation is increased by fracturing a production interval in the formation and restricting the release of pressure from the fracture to lengthen the time that the reservoir pressure remains above the fracture collapse pressure.
    Type: Grant
    Filed: September 13, 1994
    Date of Patent: December 5, 1995
    Assignee: Union Oil Company of California
    Inventors: Aaron T. Rhoten, Matthew A. Norris, Gregory S. Craley, Paul E. Crossman, Anthonius W. Vervloet
  • Patent number: 5418217
    Abstract: Visible gels are formed by mixing an inorganic crosslinking agent with a low viscosity aqueous solution having a low polyacrylamide concentration and devoid of polymers containing a vicinal diol pendant group. The visible gels are employed to reduce the water/hydrocarbon permeability ratio of subterranean formations.
    Type: Grant
    Filed: January 28, 1993
    Date of Patent: May 23, 1995
    Assignee: Union Oil Company of California
    Inventors: Richard D. Hutchins, Hoai T. Dovan
  • Patent number: 5417737
    Abstract: Urea increases the solute content of a fertilizer comprising water and at least two different nitrate-containing compounds selected from the group consisting of ammonium nitrate, alkali metal nitrates, and alkaline earth metal nitrates. In addition, urea enhances plant uptake of alkaline earth metals. Particularly favored are quaternary aqueous solutions containing urea, calcium nitrate, and ammonium nitrate.
    Type: Grant
    Filed: March 9, 1993
    Date of Patent: May 23, 1995
    Assignee: Union Oil Company of California
    Inventor: Donald C. Young
  • Patent number: 5397557
    Abstract: Salts of tetrathiocarbonic acid are produced by a batch process in which a hydroxide, hydrogen sulfide, sulfur and carbon disulfide are reacted sequentially. The salts are produced as aqueous solutions having concentrations of upwards of 30 percent by weight.
    Type: Grant
    Filed: June 10, 1993
    Date of Patent: March 14, 1995
    Assignee: Union Oil Company of California
    Inventors: Marjorie M. Hatter, Charles F. Wong
  • Patent number: 5393778
    Abstract: Oligomeric thiocarbonates such as hexathiodicarbonate salts and thioesters are used as pesticides and preservatives. Certain oligomeric thiocarbonate salts, notably quaternary ammonium hexathiodicarbonates, are prepared. The compounds are stabilized with added base and/or sulfide.
    Type: Grant
    Filed: November 30, 1993
    Date of Patent: February 28, 1995
    Assignee: Union Oil Company of California
    Inventors: James A. Green, II, Donald C. Young
  • Patent number: 5384329
    Abstract: Oligomeric thiocarbonates such as hexathiodicarbonate salts and thioesters are used as pesticides and preservatives. Certain oligomeric thiocarbonate salts, notably quaternary ammonium hexathiodicarbonates, are prepared. The compounds are stabilized with added base and/or sulfide.
    Type: Grant
    Filed: December 30, 1993
    Date of Patent: January 24, 1995
    Assignee: Union Oil Company of California
    Inventors: James A. Green, II, Donald C. Young
  • Patent number: 5360782
    Abstract: Aqueous thiocarbonate solutions are stabilized by the addition of base, sulfide and/or polysulfide, and the stability and safety of the more concentrated solutions containing 1 weight percent or more equivalent CS.sub.2 as a thiocarbonate are achieved as reflected by significant reduction of CS.sub.2 partial pressure in such solutions. Also, deposit formation in irrigation systems delivering such thiocarbonates, such as drip emitters and sprinkler heads, is reduced or eliminated with minor amounts of sodium hexametaphosphate.
    Type: Grant
    Filed: October 22, 1993
    Date of Patent: November 1, 1994
    Assignee: Union Oil Company of California
    Inventors: Donald C. Young, James A. Green, II
  • Patent number: 5353869
    Abstract: A method and system, for reducing the temperature of a hydrogeothermal fluid, entails directly or indirectly contacting a self-rising, heated hydrogeothermal fluid with a cooling fluid to cool the hydrogeothermal fluid before it enters and/or as it rises in the production tube.
    Type: Grant
    Filed: March 12, 1993
    Date of Patent: October 11, 1994
    Assignee: Union Oil Company of California
    Inventor: William C. Allen
  • Patent number: 5346614
    Abstract: A method and system for removing hydrogen sulfide from a continuous aqueous phase-containing fluid without forming a sulfur sludge. Oil is either initially present in the fluid or added thereto.
    Type: Grant
    Filed: November 10, 1992
    Date of Patent: September 13, 1994
    Assignee: Union Oil Company of California
    Inventors: Christohper R. Culver, Clifford D. Juengst
  • Patent number: 5340593
    Abstract: Aqueous thiocarbonate solutions are stabilized by the addition of base, sulfide and/or polysulfide, and the stability and safety of the more concentrated solutions containing 1 weight percent or more equivalent CS.sub.2 as a thiocarbonate are achieved as reflected by significant reduction of CS.sub.2 partial pressure in such solutions.
    Type: Grant
    Filed: March 15, 1993
    Date of Patent: August 23, 1994
    Assignee: Union Oil Company of California
    Inventors: James A. Green, II, Donald C. Young