Patents Represented by Attorney, Agent or Law Firm Shlomo R. Frieman
  • Patent number: 5335733
    Abstract: The gelation of a gelable composition is delayed by using, inter alia, a crosslinking rate retardant selected from the group consisting of epoxides, ethers, and mixtures thereof.
    Type: Grant
    Filed: June 25, 1993
    Date of Patent: August 9, 1994
    Assignee: Union Oil Company of California
    Inventors: Burton B. Sandiford, Hoai T. Dovan, Richard D. Hutchins
  • Patent number: 5333698
    Abstract: A wellbore fluid (e.g., a drilling, completion, packer, or fracturing fluid) comprises (a) at least one additive selected from the group consisting of emulsifiers, wetting agents, viscosifiers, weighting agents, fluid loss control agents, proppants for use in hydraulically fracturing subterranean formations, and particulate agents for use in forming a gravel pack; and (b) a non-toxic white mineral oil having (i) an API gravity at 15.6.degree. C. (60.degree. F.) greater than 35, (ii) a content of compounds containing 14 or more carbon atoms of at least about 95 weight percent, and (iii) a pour point of at least about -30.degree. C. (-22.degree. F.).
    Type: Grant
    Filed: May 21, 1993
    Date of Patent: August 2, 1994
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 5332580
    Abstract: Aqueous thiocarbonate solutions are stabilized by the addition of base, sulfide and/or polysulfide, and the stability and safety of the more concentrated solutions containing 1 weight percent or more equivalent CS.sub.2 as a thiocarbonate are achieved as reflected by significant reduction of CS.sub.2 partial pressure in such solutions. Also, deposit formation in irrigation systems delivering such thiocarbonates, such as drip emitters and sprinkler heads, is reduced or eliminated with minor amounts of sodium hexametaphosphate.
    Type: Grant
    Filed: November 25, 1992
    Date of Patent: July 26, 1994
    Assignee: Union Oil Company of California
    Inventors: Donald C. Young, James A. Green, II
  • Patent number: 5322121
    Abstract: A fracturing fluid comprises (a) a carrier, (b) a nucleating agent capable of reducing the concentration of scale-forming ingredients and/or natural occurring radioactive materials (NORMs) present in an aqueous subterranean fluid, and optionally (c) an ingredient selected from the group consisting of proppants, friction-reducing additives, fluid-loss-control additives, gelling agents, bactericides, and scale stabilizers. The fracturing fluid is employed in hydraulic fracturing procedures to, among other things, reduce the concentration of the scale-forming ingredients and/or NORMs present in produced aqueous subterranean fluids.
    Type: Grant
    Filed: September 23, 1992
    Date of Patent: June 21, 1994
    Assignee: Union Oil Company of California
    Inventor: Marty J. Hrachovy
  • Patent number: 5291949
    Abstract: Polymers (and especially hydroxyethylcellulose) are crosslinked using a lanthanide as a crosslinking agent. The crosslinked polymers have utility in well completion, well stimulation, enhanced oil recovery, and subterranean fluid containment operations.
    Type: Grant
    Filed: February 26, 1992
    Date of Patent: March 8, 1994
    Assignee: Union Oil Company of California
    Inventors: Hoai T. Dovan, Richard D. Hutchins
  • Patent number: 5290339
    Abstract: Geothermal brine and other platinum-containing solutions are passed through a carbon-containing zone to recover platinum from the aqueous medium.
    Type: Grant
    Filed: December 17, 1992
    Date of Patent: March 1, 1994
    Assignee: Union Oil Company of California
    Inventors: Darrell L. Gallup, G. Todd Ririe
  • Patent number: 5288495
    Abstract: Aqueous thiocarbonate solutions are stabilized by the addition of base, sulfide and/or polysulfide, and the stability and safety of the more concentrated solutions containing 1 weight percent or more equivalent CS.sub.2 as a thiocarbonate are achieved as reflected by significant reduction of CS.sub.2 partial pressure in such solutions. The stabilized thiocarbonate solutions are employed to control pests in soil.
    Type: Grant
    Filed: September 8, 1992
    Date of Patent: February 22, 1994
    Assignee: Union Oil Company of California
    Inventors: James A. Green, II, Donald C. Young
  • Patent number: 5277886
    Abstract: The addition of a nucleating or coalescing agent (e.g., urea) to liquid ammonia reduces the size and persistence of a deadly, fog-like cloud of ammonia droplets that tend to form when liquid ammonia is accidentally released to the atmosphere. In addition, high purity ammonia is obtained by evaporating ammonia from the ammonia- and nucleating agent-containing composition.
    Type: Grant
    Filed: March 31, 1992
    Date of Patent: January 11, 1994
    Assignee: Union Oil Company of California
    Inventor: Donald C. Young
  • Patent number: 5268112
    Abstract: Gels containing gas precursors and/or pathways are used to selectively reduce the flow of aqueous fluids with respect to the flow of nonaqueous fluids to enhance the recovery of the nonaqueous fluids from subterranean formations. The gels, while stable at reservoir conditions, are also readily degraded by gel degrading agents such as acids and therefore are also employed as fail-safe gels in subterranean gel treatments. In another embodiment, selective permeability is restored to a previously treated well by injecting a gas into the previous treated portions of the subterranean formation to displace any aqueous fluid obstructing the passage of the nonaqueous fluid through the polymer-coated pores or gel.
    Type: Grant
    Filed: April 16, 1992
    Date of Patent: December 7, 1993
    Assignee: Union Oil Company of California
    Inventors: Richard D. Hutchins, Burton B. Sandiford, Hoai T. Dovan
  • Patent number: 5263540
    Abstract: Polymers (and especially hydroxyethylcellulose) are crosslinked using a lanthanide as a crosslinking agent. The crosslinked polymers have utility in well completion, well stimulation, enhanced oil recovery, and subterranean fluid containment operations.
    Type: Grant
    Filed: February 26, 1992
    Date of Patent: November 23, 1993
    Assignee: Union Oil Company of California
    Inventors: Hoai T. Dovan, Richard D. Hutchins
  • Patent number: 5256424
    Abstract: Aqueous thiocarbonate solutions are stabilized by the addition of base, sulfide and/or polysulfide, and the stability and safety of the more concentrated solutions containing 1 weight percent or more equivalent CS.sub.2 as a thiocarbonate are achieved as reflected by significant reduction of CS.sub.2 partial pressure in such solutions.
    Type: Grant
    Filed: May 31, 1991
    Date of Patent: October 26, 1993
    Assignee: Union Oil Company of California
    Inventors: James A. Green, II, Donald C. Young
  • Patent number: 5247993
    Abstract: Oil production from a fractured, oil-bearing subterranean formation is enhanced by sequentially injecting (i) a wettability reversal agent-containing fluid and (ii) an overflush fluid through a well and into the formation. The well is then place into production after allowing a sufficient period of time for (a) the matrix face of the formation to change from preferentially oil wet to preferentially water wet and (b) a displacing fluid (e.g., hot water, steam) to imbibe into the fractured matrix and displace the oil from the matrix into the fracture cracks.
    Type: Grant
    Filed: June 16, 1992
    Date of Patent: September 28, 1993
    Assignee: Union Oil Company of California
    Inventors: A. M. Sam Sarem, Richard D. Hutchins, Shlomo R. Frieman
  • Patent number: 5246860
    Abstract: Organic tracers are employed to monitor the movement of subterranean fluids. These organic tracers are (a) stable at elevated temperatures, (b) capable of being detected at low concentrations, and/or (c) not adversely affected by the make-up of at least one subterranean formation. In addition, a plurality of these tracers can be measured by a single analytical technique.
    Type: Grant
    Filed: January 31, 1992
    Date of Patent: September 21, 1993
    Assignee: Union Oil Company of California
    Inventors: Richard D. Hutchins, Dennis L. Saunders
  • Patent number: 5246073
    Abstract: Gels stable in a subterranean formation at a temperature greater than about 175.degree. F. are formed using, inter alia, a stabilizing agent (e.g., a buffer having a buffering capacity at a pH of at least about 8 and/or a chelating agent).
    Type: Grant
    Filed: August 31, 1992
    Date of Patent: September 21, 1993
    Assignee: Union Oil Company of California
    Inventors: Burton B. Sandiford, Hoai T. Dovan, Richard D. Hutchins
  • Patent number: 5244042
    Abstract: Polymers (and especially hydroxyethylcellulose) are crosslinked using a lanthanide as a crosslinking agent. The crosslinked polymers have utility in well completion, well stimulation, enhanced oil recovery, and subterranean fluid containment operations.
    Type: Grant
    Filed: February 26, 1992
    Date of Patent: September 14, 1993
    Assignee: Union Oil Company of California
    Inventors: Hoai T. Dovan, Richard D. Hutchins
  • Patent number: 5238905
    Abstract: Compositions and methods for vegetation control comprise synergistic combinations of a thiazol-urea abscission agent and an adduct formed by the reaction of sulfuric acid with an amide. The synergistic combinations are particularly useful for the defoliation of cotton.
    Type: Grant
    Filed: January 31, 1992
    Date of Patent: August 24, 1993
    Assignee: Union Oil Company of California
    Inventor: Mark L. Atwater
  • Patent number: 5234577
    Abstract: Drill cuttings are cleaned of oil-based drilling mud and oil using a cleansing agent, such as a C6-C10 carboxylic acid, that is preferentially oil soluble at one pH and preferentially water soluble at another pH. The oily cuttings are treated with the carboxylic acid and then washed with an aqueous, alkaline washing solution, which converts the carboxylic acid to its water soluble salt and, with vigorous agitation, lifts most of the oil from the cuttings. In other embodiments, the process is used for cleaning oil-contaminated soil, sand, and gravel, and for separating the oils from the solids in oily sludges.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: August 10, 1993
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 5226480
    Abstract: Polymers (and especially hydroxyethylcellulose) are crosslinked using a lanthanide as a crosslinking agent. The crosslinked polymers have utility in well completion, well stimulation, enhanced oil recovery, and subterranean fluid containment operations.
    Type: Grant
    Filed: February 26, 1992
    Date of Patent: July 13, 1993
    Assignee: Union Oil Company of California
    Inventors: Hoai T. Dovan, Richard D. Hutchins
  • Patent number: 5225090
    Abstract: Visible gels are formed by mixing an inorganic crosslinking agent with a low viscosity aqueous solution having a low polyacrylamide content. The visible gels are employed to reduce the water/hydrocarbon permeability ratio of subterranean formations.
    Type: Grant
    Filed: April 14, 1992
    Date of Patent: July 6, 1993
    Assignee: Union Oil Company of California
    Inventors: Richard D. Hutchins, Hoai T. Dovan
  • Patent number: 5221659
    Abstract: Compositions and methods for vegetation control comprise synergistic combinations of a thiazol-urea abscission agent and an adduct formed by the reaction of sulfuric acid with an amide. The synergistic combinations are particularly useful for the defoliation of cotton.
    Type: Grant
    Filed: October 28, 1991
    Date of Patent: June 22, 1993
    Assignee: Union Oil Company of California
    Inventor: Mark L. Atwater