Abstract: This invention relates to an improved composition of matter for and method of desiccating plants such as, for example, cotton. More particularly, this invention relates to an improved desiccating composition comprising a solution of endothall, an ammonium salt, a glutamine synthetase inhibitor, and optionally, a surface active agent, and a method of using the composition.
Abstract: A supported Lewis acid catalyst such as antimony V on a fluorine-treated moisture-free activated carbon support is provided, as are fluorination processes using such a catalyst.
Abstract: A crosslinkable composition of a polymeric thermoplastic and/or elastomeric material which is susceptible to scorching when processed at elevated temperatures, prior to crosslinking, in the presence of a free radical initiator, is protected against such scorching by the incorporation therein of a mixture of at least one hydroquinone compound and a sulfur accelerator. This mixture may also contain at least one monomeric allylic, methacrylic, acrylic or diene type coagent. The mixture exhibits a synergistic effect resulting in improved scorch protection for peroxide cured systems when compared with the protection afforded by the components singly.
Type:
Grant
Filed:
June 7, 1995
Date of Patent:
May 30, 2000
Assignee:
ELF Atochem N.A., Inc.
Inventors:
Michael Fred Novits, Chester Joseph Kmiec, Edward Phillip Hibbard
Abstract: A process is disclosed for the efficient production of high purity alkane sulfonic acid and/or alkane sulfonyl chloride product wherein a compound of the formula RSX, where X is hydrogen or --SR.sup.1 and R and R.sup.1 are alkyl radicals is continuously reacted with chlorine in aqueous hydrochloric acid to produce a turbulent evolution of hydrochloride gas, passing the reactants through stationary mixing elements to promote plug-flow, and separately withdrawing a product. Apparatus for this process is also disclosed.
Abstract: A process for the preparation of 142 is provided, wherein 1130 is fluorinated in the gas phase in the presence of a catalyst which is a supported or unsupported fluorinated salt of one or more of chromium, iron, niobium, nickel, antimony, tin, tantalum or titanium. 142 is a known foam blowing agent.
Abstract: Orthophosphite ions produced by oxidation of hypophosphite in an electroless nickel plating bath can be removed by precipitation with an alkali metal or alkaline earth metal cation such as calcium. In order to avoid the precipitation of calcium sulfate and the generation of large amounts of particulates in the bath, nickel sulfate can be replaced by a nickel salt of an alkylsulfonic acid or hypophosphorous acid, whose anion forms a soluble salt with an alkali metal or alkaline earth metal cation.
Abstract: Novel peroxyoxalate compositions of Structure A, ##STR1## and use of the novel monoperoxyoxalates of Structure A as initiators for polymerizing ethylenically unsaturated monomers and for curing of unsaturated polyester resins are disclosed.
Abstract: Dual cure organotin salts of strong organic acids, the use of such salts as catalysts and an improved process for producing the catalysts are provided. The catalysts are capable of effectively catalyzing esterification and transesterification reactions and urethane, silicone, melamine, ester and acrylic forming reactions and can simultaneously catalyze more than one reaction in a mixture of urethane, silicone, amino, ester and acrylic polymer forming reactants to produce a polymer mixture.
Type:
Grant
Filed:
June 9, 1998
Date of Patent:
November 9, 1999
Assignee:
ELF Atochem North America, Inc.
Inventors:
Sri R. Seshadri, William D. Honnick, Melvin H. Gitlitz
Abstract: Partially epoxidized compounds obtained from Diels Alder adducts of dicyclopentadiene with fatty oils having a iodine number of 70 or greater and their transesterification products with C.sub.1 to C.sub.10 alkanols are disclosed. 100% solids radiation and heat curable coating compositions containing the epoxidized compounds and/or their transesterification products are also disclosed.
Type:
Grant
Filed:
October 23, 1997
Date of Patent:
September 7, 1999
Assignee:
Elf Atochem North America, Inc.
Inventors:
Fred Budde, Mohammed R. Kazemizadeh, Walter P. Kosar, Jr.
Abstract: This invention relates to aqueous solutions containing Ni cation and hypophosphite anion which have a Ni cation concentration greater than 36 grams/liter. Such solutions have utility in electroless nickel plating baths and processes as make-up solutions and replenishing solutions. The increased concentration of Ni cation results from the addition of the nickel salt of an alkyl sulfonic acid to the solution.
Abstract: A crosslinkable composition of a polymeric thermoplastic and/or elastomeric material which is susceptible to scorching when processed at elevated temperatures, prior to crosslinking, in the presence of a free radical initiator, is protected against such scorching by the incorporation therein of a mixture of at least one hydroquinone compound and a sulfur accelerator. This mixture may also contain at least one monomeric allylic, methacrylic, acrylic or diene type coagent. The mixture exhibits a synergistic effect resulting in improved scorch protection for peroxide cured systems when compared with the protection afforded by the components singly.
Type:
Grant
Filed:
June 7, 1995
Date of Patent:
June 15, 1999
Assignee:
Elf Atochem North America, Inc.
Inventors:
Michael Fred Novits, Chester Joseph Kmiec, Edward Phillip Hibbard
Abstract: A crosslinkable composition of a polymeric thermoplastic and/or elastomeric material which is susceptible to scorching when processed at elevated temperatures, prior to crosslinking, in the presence of a free radical initiator, is protected against such scorching by the incorporation therein of a mixture of at least one hydroquinone compound and a sulfur accelerator. This mixture may also contain at least one monomeric allylic, methacrylic, acrylic or diene type coagent. The mixture exhibits a synergistic effect resulting in improved scorch protection for peroxide cured systems when compared with the protection afforded by the components singly.
Type:
Grant
Filed:
June 7, 1995
Date of Patent:
March 2, 1999
Assignee:
Elf Atochem North America, Inc.
Inventors:
Michael Fred Novits, Chester Joseph Kmiec, Edward Phillip Hibbard
Abstract: An uncatalyzed liquid phase process is provided for the preparation of oligomer free 1233zd via the fluorination of 1230za with a high molar excess of HF. The 1233zd is a known intermediate useful for preparing 245fa.
Abstract: A crosslinkable composition of a polymeric thermoplastic and/or elastomeric material which is susceptible to scorching when processed at elevated temperatures, prior to crosslinking, in the presence of a free radical initiator, is protected against such scorching by the incorporation therein of a mixture of at least one hydroquinone compound and a sulfur accelerator. This mixture may also contain at least one monomeric allylic, methacrylic, acrylic or diene type coagent. The mixture exhibits a synergistic effect resulting in improved scorch protection for peroxide cured systems when compared with the protection afforded by the components singly.
Type:
Grant
Filed:
June 7, 1995
Date of Patent:
February 9, 1999
Assignee:
Elf Atochem North America, Inc
Inventors:
Michael Fred Novits, Chester Joseph Kmiec, Edward Phillip Hibbard
Abstract: A novel peroxide composition of Structure A, ##STR1## and use of the novel oxalic acid peroxide composition of Structure A as an initiator; a) for curing of unsaturated polyester resins, b) for polymerizing ethylenically unsaturated monomers, c) for crosslinking of polyolefins, d) for curing of elastomers, e) for modifying polyolefins, f) for grafting of vinyl monomers onto polymer backbones and g) for compatibilizing blends of two or more incompatible polymers are disclosed.
Abstract: Liquid methyltin halide compositions and their use as intermediates in chemical synthesis and as precursors for forming tin oxide coatings on substrates are disclosed.
Abstract: A process is disclosed for the eradication of and subsequent inhibition of bivalve mollusk settlement on solid surfaces immersed in water inhabited by said mollusk comprising introducing into said water, a specified tertiary amine salt at a rate and for a time at least sufficient to inhibit settlement of said mollusk.
Abstract: A crosslinkable composition of a polymeric thermoplastic and/or elastomeric material which is susceptible to scorching when processed at elevated temperatures, prior to crosslinking, in the presence of a free radical initiator, is protected against such scorching by the incorporation therein of a mixture of at least one hydroquinone compound and a sulfur accelerator. This mixture may also contain at least one monomeric allylic, methacrylic, acrylic or diene type coagent. The mixture exhibits a synergistic effect resulting in improved scorch protection for peroxide cured systems when compared with the protection afforded by the components singly.
Type:
Grant
Filed:
June 7, 1995
Date of Patent:
December 15, 1998
Assignee:
ELF ATOChem North America, Inc.
Inventors:
Michael Fred Novits, Chester Joseph Kmiec, Edward Phillip Hibbard
Abstract: A novel bis(mono- or diperoxyoxalate) composition of Structure A, ##STR1## and use of the novel bis(mono- or diperoxyoxalate) composition as an initiators for curing of unsaturated polyester resins and for polymerizing ethylenically unsaturated monomers are disclosed.