Abstract: Improvements in the retardation of water evaporation from benzyl alcohol containing water-in-oil emulsions by incorporating in the organic phase thereof an effective amount of a terpene.

Abstract: A process for the fluorination of 1230za is provided, wherein 1230za is contacted with HF in the gas phase in the presence of an aluminum fluoride or chromium-based fluorination catalyst under conditions sufficient to produce a reaction mixture containing 1233zd, 1234ze and 245fa. 245fa is a known foam blowing agent and refrigerant, while 1233zd and 1234ze are known intermediates useful for preparing 245fa.

Abstract: The inventors disclose a process for producing semi-bright to bright electrogalvanic coatings at high current densities, comprising electroplating a cathodic conductive substrate in a coating bath based on:a) a zinc sulfur-acid salt;b) a low molecular weight polyoxyalkylene glycol based on 2 to about 4 carbon atom alkylene oxides;c) an aromatic sulfonate; andd) a conductivity enhancing salt.The process includes maintaining the coating composition at a pH from about 2 to about 5 and the current density on the substrate at from about 1,000 to about 3,700 ASF. The zinc sulfur-acid salt includes zinc sulfate or a zinc organosulfonate, and the conductivity enhancing salt, a potassium salt. In one embodiment, the aromatic sulfonate comprises a condensation product of an aromatic sulfonate and formaldehyde. The inventors also describes coating bath compositions.

Abstract: Compounds of formula (I) are disclosed: ##STR1## wherein L.sup.1 is a main group atom, L.sup.2 is a neutral ligand, M is a transition element or a metal element of Group 13, 14, 15, or 16 of the Periodic Table, x is the number of coordination sites of M, R.sup.1 is a polymerizable group, R.sup.2, R.sup.3, and R.sup.4 are ligands, and R.sup.5 is an anionic ligand. The compounds or monomers of formula (I) are capable of conversion to polymers by combination with one or more other known monomers, such as methyl methacrylate. Such polymers can then be added as a binder in a paint formulation to make marine antifouling coating compositions. Also described is a method to prevent fouling on surfaces wherein a composition containing a metal complex compound of formula (II): ##STR2## wherein M, x, L.sup.2, n, and R.sup.4 have the same meaning as in formula (I), is applied to the surface susceptible to fouling.

Abstract: Natural or synthetic wax dissolved in the continuous organic phase of an water-in-oil emulsion retards evaporation of water from a dispersed aqueous phase. An in situ prepared equilibrium mixture of benzyl alcohol, formic acid and benzyl formate emulsified with oleic hydroxyethyl imidazoline or similar oil soluble emulsifying agent is thickened with hydroxypropyl cellulose or hydroxypropyl methylcellulose and contains 0.1 to 1.0% by weight paraffin wax with a melting point of 47.degree. to 65.degree. C. Wax dissolved in the organic phase retards evaporation of water, and formic acid or ammonia which are very volatile in comparison with benzyl alcohol forming the major component of the organic phase. A petroleum distillate is used to pre-wet a hydroxypropyl cellulose thickener and dissolve the wax.

Abstract: Active Rhodium catalyst and impurities are separated from a hydroformylation process stream containing both active and inactive organo-rhodium catalyst by binding active catalyst and impurities to an acidic ion exchange resin containing an acidic group. The purified hydroformylation stream can be returned to the hydroformylation reactor. All or a portion of inactive rhodium can be reactivated before recycling purified hydroformylation process stream to the reactor. During regeneration of the resin, a neutral solvent is used first to remove impurities which are discarded, then an acidic solvent is used to remove active organic rhodium catalyst from the resin. Such active catalyst can be rehydrided and returned to the hydroformylation reactor. An ion exchange resin having at least one acid group disposed on a silica backbone and an active organo-rhodium complex from a hydroformylation process stream bound to the resin can be produced.

Abstract: The present invention comprises a polystannoxane catalyst, a curable composition containing the catalyst and a method of using the catalyst and curing the composition. The curable composition comprises:(i) a blocked isocyanate;(ii) a functional component containing reactive hydrogen;(iii) a polystannoxane catalyst for promoting the reaction of the blocked isocyanate with the functional component.A co-catalyst may also be employed based on Cu, Zn, Ni, Zr, Ce, Fe, Co, V, Sb and Bi and especially oxides, salts or chelates of said metals. The invention also relates to a method for curing a blocked isocyanate at a low reaction temperature which comprises combining the catalyst with the blocked isocyanate and functional component and heating to a temperature less than about 180.degree. C. to obtain a cured urethane.

Abstract: Poly(monoperoxycarbonates) of the structure: ##STR1## where R, R.sup.1 and n are defined in the summary of the invention such as 1,1,1-tris(t-butylperoxycarbonyloxymethyl)ethane, intermediates for their preparation as well as processes for their preparation and use are disclosed. The monoperoxycarbonate compounds are useful in initiating the polymerization of ethylenically unsaturated monomers, particularly styrene, curing of unsaturated polyester resins, and in modifying the molecular weight of polymers such as by crosslinking or controlled chain degradation.

Abstract: A process is disclosed for the preparation of primary mercaptans by reacting hydrogen sulfide with an alpha-olefin in the presence of a reaction initiating amount of a borane represented by the formula R.sub.2 BH or R.sub.3 B where R is a linear or cyclic aliphatic or aryl group.

Abstract: Natural or synthetic wax dissolved in the continuous organic phase of an water-in-oil emulsion retards evaporation of water from a dispersed aqueous phase. An in situ prepared equilibrium mixture of benzyl alcohol, formic acid and benzyl formate emulsified with oleic hydroxyethyl imidazoline or similar oil soluble emulsifying agent is thickened with hydroxypropyl cellulose or hydroxypropyl methylcellulose and contains 0.1 to 1.0% by weight paraffin wax with a melting point of 47.degree. to 65.degree. C. Wax dissolved in the organic phase retards evaporation of water, and formic acid or ammonia which are very volatile in comparison with benzyl alcohol forming the major component of the organic phase. A petroleum distillate is used to pre-wet a hydroxypropyl cellulose thickener and dissolve the wax.

Abstract: Liquid methyltin halide compositions and their use as intermediates in chemical synthesis and as precursors for forming tin oxide coatings on substrates are disclosed.

Abstract: This invention relates to novel peroxide blends which are liquid at 25.degree. C. and lower, their method of preparation and their use in curing peroxide crosslinkable polymers.The blend is a mixture of the meta isomers or the meta and para isomers of the compounds of Formulae I, II and III and optionally Formula IV (all as defined herein) in such proportions that the composition provides a liquid mixture at 25.degree. C. or below which has a high crosslinking efficiency for polymeric materials.

Abstract: Anionic waterborne polyurethane dispersions made using hydroxyl terminated polybutadiene resins and use of the dispersions to make films and adhesives.

Abstract: A novel and safe ethylenically unsaturated peroxyester composition derived from an ethylenically unsaturated dicarboxylic acid is provided, as well as processes for making and using the composition. The peroxyester composition comprises about 0.04 to about 0.70 mole fraction of a first component compound having a formula I: ##STR1## about 0.32 to about 0.50 mole fraction of a second component compound having a formula II: ##STR2## about 0.04 to about 0.70 mole fraction of a third component compound having a formula III: ##STR3## wherein Q is an unsaturated ethylene divalent radical and R.sup.1 and R.sup.2 are organic substituents. Polymeric-peroxides are prepared via polymerizing the peroxyester compositions. The peroxyester compositions are also used for curing unsaturated polyester resins and for initiating polymerization of ethylenically unsaturated monomers.

Abstract: An apparatus for removing polymer particles from the stripping solution used in the treatment of printed wireboards comprises passing a solution having resist particles dispersed therein over a screen having openings of 100 microns, where the screen is maintained at an angle of from 40 to 70.degree. to the horizontal. The apparatus comprises a curtain tube consisting of an inner concentric tube with a plurality of holes and an outer concentric tube with a slot wherein the position of the slot is adjustable, a filter comprising a screen, and a pump for circulating the solution. In one embodiment, the filter comprises a cylindrical screen.The stripping solution comprises an aqueous solution of an organoamine, ionic nitrogen compound or alkali or alkaline-earth hydroxide, or mixtures thereof.

Abstract: Shaped, dust-free dry wire drawing compound lubricants having at least one reproducibly controlled dimension and methods for their preparation comprising the steps of conglutinating and pressure forming the lubricant composition.

Abstract: Apparatus and method for coating hot glass bottles are improved by providing a controlled non-turbulent air supply directed downward across the coating material stream. The apparatus has a relocated blower for delivering process fluid (e.g. air) into an end of a plenum upper chamber, passing the air first through an permeable attenuator, then into a lower plenum chamber and finally through a diffuser plate to provide a uniform stream of process air directed downward across the coating-material stream into the finish region of the bottle. In the method, process air is blown to a plenum, through an angled attenuator plate with small holes to distribute the process air evenly and to avoid standing waves and regions of high or low air velocity. Several attenuator plates can be juxtaposed to permit removal of particulates by movement of the plates relative to each other. An iris or throttle valve after the blower can be used as an additional method of controlling the force and velocity of process air.

Abstract: Inhibition of the formation of unsaturated carbon compounds during the heating of 141b involving the addition of various inhibitors such as butylene oxide and/or the use of a vessel made of a nickel alloy.

Abstract: Radiation resistant, gadolinium oxide modified, thermoplastic polymers which may be used for containing nuclear waste.

Abstract: Nonazeotropic solvent blends useful for cold cleaning applications in an open environment containing an HCFC, HFC or PFC component having no flash point (such as 141b), a higher boiling nonflammable chlorinated solvent (such as perchloroethylene), and a moderately flammable, intermediate boiling, oxygenated organic solvent (such as n-butanol).