Patents Represented by Attorney W. G. Muller
  • Patent number: 4780228
    Abstract: Hydrocarbon polymers such as ethylene copolymers may be reacted with unsaturated nitrogen-containing monomers or unsaturated carboxylic acids in the presence of a free radical catalyst such as a peroxide or azo free radical initiator and a chain stopping agent, e.g. a mercaptan to inhibit excessive cross-linking and branching. The copolymer grafted directly with the nitrogen-containing monomers may be utilized as an additive for oil and fuel compositions, particularly lubricating oil compositions as a V.I.-dispersant additive. The polymer reacted with carboxylic acid may be further reacted with amines, polyols, amino-alcohols, etc. to also form a V.I.-dispersant additive.
    Type: Grant
    Filed: June 18, 1987
    Date of Patent: October 25, 1988
    Assignee: Exxon Chemical Patents Inc.
    Inventors: John B. Gardiner, Martyn N. Dick
  • Patent number: 4772406
    Abstract: Hydrocarbon compositions, including oligomers and polymers, for use in improving the thermo-oxidative stability and the dispersancy and viscosity index improvement (for high molecular weight) properties of fuels and lubricating oils are disclosed. These compositions are adducts of sulfur mono- and diimides having one of the following formulae: ##STR1## wherein r is a hydrocarbyl containing at least 18 carbon atoms, in which X.dbd. can be O.dbd., S.dbd., Y'--N.dbd., i is 0 or 1, --Y and Y'-- can be ##STR2## wherein R' is hydrocarbyl or hydrocarbyloxy, R" is hydrocarbyl, R'" and R"" are hydrocarbyloxy, and each of R', R", R'", and R"" is from 1 to 20 carbon atoms.
    Type: Grant
    Filed: April 8, 1987
    Date of Patent: September 20, 1988
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Stanley J. Brois
  • Patent number: 4749505
    Abstract: Olefin polymers are degraded in molecular weight in the presence of a free radical initiator under an inert blanket. The degradation preferably is carried out under high shearing stress and/or a high temperature in order to increase the degradation. The degradation may be separate from, overlap, or occur simultaneously with further derivatization of the polymer.
    Type: Grant
    Filed: July 8, 1985
    Date of Patent: June 7, 1988
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, John E. Johnston
  • Patent number: 4734213
    Abstract: Solutions of ethylene-propylene copolymers grafted with vinyl containing monomers, maleic anhydride or ethylenically unsaturated acids including functionalized derivatives thereof, reacted with polyols, polyamines and hydroxamines, as well as hydrogenated butadiene or isoprene copolymers, which solutions have haze-forming tendencies in mineral oil and are generally useful as multifunctional lubricating oil additives, are reduced in haze-forming tendencies by treatment with 0.5 to 25 wt. % of an alkyl hydroxy benzene compound, such as nonyl or dodecyl phenol.
    Type: Grant
    Filed: May 19, 1987
    Date of Patent: March 29, 1988
    Assignee: Exxon Research & Engineering Co.
    Inventors: Phillip W. Brewster, Clinton R. Smith
  • Patent number: 4707285
    Abstract: Solutions of ethylene-propylene copolymers grafted with vinyl containing monomers, maleic anhydride or ethylenically unsaturated acids including functionalized derivatives thereof, reacted with polyols, polyamines and hydroxamines, as well as hydrogenated butadiene or isoprene copolymers, which solutions have haze-forming tendencies in mineral oil and are generally useful as multifunctional lubricating oil additives, are reduced in haze-forming tendencies by treatment with 0.5 to 25 wt. % of an alkyl hydroxy benzene compound, such as nonyl or dodecyl phenol.
    Type: Grant
    Filed: January 16, 1987
    Date of Patent: November 17, 1987
    Assignee: Exxon Research & Engineering Co.
    Inventors: Phillip W. Brewster, Clinton R. Smith
  • Patent number: 4693838
    Abstract: Hydrocarbon polymers such as ethylene copolymers may be reacted with unsaturated nitrogen-containing monomers or unsaturated carboxylic acids in a synthetic hydrocarbon lubricating oil in the presence of a free radical initiator such as a peroxide. The copolymer grafted directly with the nitrogen-containing monomers may be utilized as an additive for oil compositions, particularly lubricating oil compositions as a V.I.-dispersant additive. The polymer reacted with carboxylic acid may be further reacted with amines or amino-alcohols to also form a multifunctional V.I.-dispersant additive.
    Type: Grant
    Filed: October 29, 1985
    Date of Patent: September 15, 1987
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Vijaya K. Varma, Esther D. Winans, Rosemary O'Halloran, Phillip W. Brewster