Abstract: A system and method for removing organic carboxylates from a mono ethylene glycol (“MEG”) stream includes a reaction vessel; means for cooling and diluting the MEG stream being routed to the reaction vessel; means for acidifying the cooled and diluted MEG stream during its residence time within the reaction vessel; and means for removing an acetic-rich overhead stream from the reaction vessel. The acidification of the cooled and diluted MEG stream occurs under a vacuum. The reaction vessel may be located downstream of a calcium removal vessel and receive a filtered bottom stream from that vessel, or it may be a single reaction vessel that cycles between a calcium removal mode and an acetate removal mode, with the pressure of the single vessel being greater during the calcium removal mode than during the acetate removal mode.

Abstract: A method to remove oil from an oily water stream includes the step of pressure controlling a release of dissolved gases from the stream as the stream passes through two or more stages of gas flotation treatment. The operating pressure of the first stage of flotation treatment is purposefully reduced relative to that of an upstream unit so that a certain controlled percent volume of dissolved gases is released. The operating pressure of the second stage of flotation treatment is then purposefully reduced relative to that of the first stage so that another controlled percent volume of dissolved gases is released. Any subsequent flotation treatment stage is at a lower operating pressure than that of the previous stage so that the subsequent treatment stage releases a controlled percent volume of dissolved gases. By controlling the operating pressure in this way, overall separation performance is improved.

Abstract: A process train for a floating production storage and offloading installation includes a crude oil storage tank that is equipped with at least one electrostatic separator configured to subject the produced stream that enters the tank to an electric field. The electrostatic separator may include two inclined vessels containing electrostatic internals and in fluid communication with one another. Employing electrostatic separators within the tank can permit an allowable inlet water content into the tank of up to 80%, significantly reducing the required topside processing equipment.

Abstract: Systems and methods for removing solids from a process stream being fed into a flash separator include a solids fluidization device and a solids removal device. The solids fluidization device at the bottom end of the fluid column of the flash separator introduces a swirling motive fluid within the fluid column, while the solids removal device located above the solids fluidization device removes the slurry created by the swirling motive fluid. Systems and methods for fluidizing solids in the fluid column of a flash separator include a solids fluidization device that introduces a swirling motive fluid within the fluid column, means to limit the upward movement of the swirling motive fluid, such as a valve, and removing the solid slurry produced by the swirling motive fluid.

Abstract: A MEG stream having a first pH level is contacted with a CO2-rich gas stream to yield a MEG product having a second different and lower pH level. The system and method can be readily incorporated into a slipstream MEG recovery package, with a source of the MEG stream being a MEG regeneration section of the package. The CO2-rich gas could be a vented CO2 stream from the MEG reclamation section of the package. Unlike hydrochloric and acetic acid overdosing, CO2 overdosing of the lean MEG stream does not lead to rapid acidification of the MEG product to be stored or injected.

Abstract: An apparatus and method for separating water from an oil-water influx are provided. The apparatus includes a separation vessel having an inlet, an oil collection portion at its upper end, and a water collection portion at its lower end. Multiple high voltage tubes, each containing an electrode, are located within the oil collection portion. These high voltage tubes are staggered in length and held in place by perforated plates. The oil-water influx flows through the inlet of the vessel into the high voltage tubes, where it is subjected to an electrostatic field. The electrostatic field causes water droplets in the influx to coalesce and form a water out-flux which flows downwardly into the water collection portion of the vessel. The remaining stream of dehydrated oil flows upwardly to the upper outlet end. The oil collection portion of the separation vessel may be oriented vertically or at an angle.

Abstract: A system and method for removing acetic acid and other short chain fatty acids described as organic acid from a rich mono-ethylene glycol (“MEG”) solution does so by stripping the organic acid from the rich MEG solution by contacting the solution with a gas, the gas being nitrogen or a fuel gas such as methane; and stripping the organic acid from the gas by contacting the gas with a caustic solution such as a dilute sodium hydroxide solution. The stripping steps take place in respective stripping columns. A portion of the gas exiting the gas/organic acid stripping column can be recycled to the MEG/organic acid stripping column to reduce total gas usage. A portion of the waste stream exiting the gas/organic acid stripping column can be recycled back to the gas/organic acid stripping column to reduce the amount of caustic solution used as well as the amount of waste.

Abstract: A system for separating the components of an incoming oil-water mixture includes two electrode sets, one set arranged to apply an electrostatic field to an oil layer residing within a separator vessel and the other set arranged to apply an electrostatic field to the interface emulsion layer residing within the separator vessel. The first set of electrodes is in communication with a high voltage power source that ranges from 1 to 60 kV; the second set of electrodes is in communication with a low voltage power source that is no greater than 5 kV. Each set of electrodes may also be in communication with a second voltage source to provide increased power to promote effective coalescence. The system may also include power electronics to produce a variable amplitude and a variable frequency voltage supply to one or both electrode sets.

Abstract: A system and method for removing organic carboxylates from a mono ethylene glycol (“MEG”) stream includes a reaction vessel; means for cooling and diluting the MEG stream being routed to the reaction vessel; means for acidifying the cooled and diluted MEG stream during its residence time within the reaction vessel; and means for removing an acetic-rich overhead stream from the reaction vessel. The acidification of the cooled and diluted MEG stream occurs under a vacuum. The reaction vessel may be located downstream of a calcium removal vessel and receive a filtered bottom stream from that vessel, or it may be a single reaction vessel that cycles between a calcium removal mode and an acetate removal mode, with the pressure of the single vessel being greater during the calcium removal mode than during the acetate removal mode.

Abstract: A process train for a floating production storage and offloading installation includes a crude oil storage tank equipped with at least one set of electrostatic internals. The set of electrostatic internals are arranged to provide a treatment flow path within the crude oil storage tank oblique to a longitudinal centerline of the crude oil storage tank and through an electric field provided by the set of electrostatic internals. Employing these electrostatic internals within the tank permits an allowable inlet water content into the tank of up to 80%, significantly reducing the required topside processing equipment. The process and system also includes, upstream of the tank, two separator vessels arranged in parallel so each receives a portion of an incoming oil-and-water stream, a flash vessel arranged downstream of the two separator vessels, and a degasser vessel. Downstream of the crude oil storage tank is an electrostatic treater.

Abstract: A system and method for dehydrating crude oil on a floating production storage and offloading installation include a separator vessel to receive an incoming produced water stream, followed by a flash vessel, a treatment block, a crude oil storage tank, and an electrostatic treater. The treatment block includes a low pressure degasser followed by a compact electrostatic separator pre-treater or a compact electrostatic separator pre-treater followed by a low pressure degasser. The flash vessel and/or the low pressure degasser may employ an inlet cyclonic distributor and demisting cyclones, while the electrostatic treater may employ DUAL FREQUENCY® technology. The separator vessel may be a single horizontal two-phase separator/degasser or two vertical two-phase separator/degassers that operate in parallel with each receiving approximately 50 percent of the incoming produced water stream. The final outlet stream preferably contains no more than 0.5 BS&W and 285 milligrams per liter salt.

Abstract: A system for desalting a crude oil stream includes vessel that has an interior piping structure that releases wash water into a crude oil flow within the vessel. The piping structure, which may have more than one level, has a plurality of spray nozzles for dispersing or releasing the wash water into the flowing crude oil stream. The spray nozzles may be located on a same side or opposite sides of the piping structure. Where multiple levels are used, the number of spray nozzles on each level may be the same as or different than the number of spray nozzles on other levels. The pressure drop through each spray nozzle is no greater than 300 psi and the nozzles deliver a dilution water droplet no larger than 300 microns in diameter. A mixing valve, static mixer, or both can be placed downstream of the vessel.

Abstract: A system for, and method of, recovering salt from fluid stream in a recycle loop of a flash separator has a desanding hydrocyclone located in the hot recycle loop of the flash separator; a first solids fluidization device located at the bottom end of the flash separator's brine column; a second desanding hydrocyclone arranged to receive a salt slurry stream created by the first solids fluidization device; and an accumulator located downstream of the second desanding hydrocyclone and having a second solids fluidization device located at its bottom end. Each solids fluidization device causes a motive fluid to exit the device in a swirling motion to fluidize the salt components contained in the resident fluid. The overflow from the second desanding hydrocyclone is the motive fluid for the brine column and a produced water, condensate water, or seawater stream is the motive fluid for the accumulator.

Abstract: A process train for a floating production storage and offloading installation includes a crude oil storage tank that is equipped with at least one set of electrostatic internals arranged to provide a treatment flow path isolated from a surrounding volume of the electrostatic separator section of the tank. An oil-and-water stream or mixture entering the set of electrostatic internals travels along the treatment flow path and is subjected to an electric field. The treatment flow path is in an upwardly direction toward the oil outlet section and in a downwardly opposite direction toward the water outlet section of the tank. Employing electrostatic internals within the tank permits an allowable inlet water content into the tank of up to 80%, significantly reducing the required topside processing equipment.

Abstract: A method of removing entrained salt containing water from an inlet crude oil stream includes the steps of applying an electrical energy to at least one electrode of a plurality of horizontally oriented, spaced-apart electrodes (12, 14, 16) housed within an elongated desalting vessel (10) and distributing an inlet crude oil stream between the electrodes. Each electrode in the plurality of electrodes is housed in an upper portion of the desalting vessel and may be in communication with a first, second and third transformer (42, 44, 46), respectively. The electrical energy may be at a single frequency and voltage or at a modulated voltage. Or, the electrical energy may be a modulated frequency at a single or modulated voltage. Fresh water may be mixed with the inlet crude oil stream either exteriorly or interiorly of the vessel.

Abstract: An apparatus for separating water from a water-in-oil mixture having an elongated inlet vessel with a lower outlet end and an upper inlet end, the length thereof being a multiple of the largest vessel cross-sectional dimension. A separation vessel having an oil outlet and a divergent water outlet has an inlet passageway in communication with the inlet vessel lower outlet end. At least one electrode is positioned within the inlet vessel by which a mixture flowing therethrough is subjected to an electric field.

Abstract: A lean MEG stream having a first pH level is contacted with a CO2-rich gas stream to yield a lean MEG product having a second different and lower pH level preferably in a range of 6.5 to 7.0. The system and method can be readily incorporated into a slipstream MEG recovery package, with a source of the lean MEG stream being a MEG regeneration section of the package. The CO2-rich gas could be a vented CO2 stream from the MEG reclamation section of the package. Unlike hydrochloric and acetic acid overdosing, CO2 overdosing of the lean MEG stream does not lead to rapid acidification of the lean MEG product to be stored or injected.

Abstract: A system and method for removing acetic acid and other short chain fatty acids described as organic acid from a rich mono-ethylene glycol (“MEG”) solution does so by stripping the organic acid from the rich MEG solution by contacting the solution with a gas, the gas being nitrogen or a fuel gas such as methane; and stripping the organic acid from the gas by contacting the gas with a caustic solution such as a dilute sodium hydroxide solution. The stripping takes place in respective stripping columns. A portion of the gas exiting the gas/organic acid stripping column can be recycled to the MEG/organic acid stripping column to reduce total gas usage. A portion of the waste stream exiting the gas/organic acid stripping column can be recycled back to the gas/organic acid stripping column to reduce the amount of caustic solution used as well as the amount of waste.

Abstract: A system and process for intermittently venting combustible gas (c-gas) from a continuous source to the atmosphere are presented. The system includes a primary c-gas storage tank, at least one primary admission valve located upstream of the primary c-gas storage tank for regulating the flow of c-gas from the continuous source to the storage tank, a primary valve for atmospheric venting located downstream of the primary c-gas storage tank, and a primary PIC that opens the primary valve for atmospheric venting when pressure in the primary c-gas storage tank reaches a pre-determined PIC vent point. The system may include an auxiliary system to receive and vent c-gas while the primary admission valve is closed. The primary and auxiliary systems may also include an inert gas storage tank and inert gas valve for diluting the c-gas before it is vented to the atmosphere.

Abstract: A system and process for removing divalent ions from a MEG feed stream is presented. Embodiments of the system include a chemical treatment tank where chemicals are mixed with the feed stream to form insoluble carbonate and hydroxide salts. The system also includes a solid-liquid separation unit that receives the feed stream from the chemical treatment tank and separates it into a liquids portion containing MEG and a insoluble salts portion. The system may also include washing the insoluble salts portion to remove additional MEG, which is then recycled to a MEG regeneration or reclamation process. The system may also include a dryer that receives waste slurry from the solid-liquid separation unit and dries it to form a solid waste, thereby facilitating its handling, storage, and disposal.