Patents Assigned to Celgard LLC
-
Patent number: 10601012Abstract: A multi-layered battery separator for a lithium secondary battery includes a first layer of a dry processed membrane bonded to a second layer of a wet processed membrane. The first layer may be made of a polypropylene based resin. The second layer may be made of a polyethylene based resin. The separator may have more than two layers. The separator may have a ratio of TD/MD tensile strength in the range of about 1.5-3.0. The separator may have a thickness of about 35.0 microns or less. The separator may have a puncture strength of greater than about 630 gf. The separator may have a dielectric breakdown of at least about 2000V.Type: GrantFiled: September 2, 2016Date of Patent: March 24, 2020Assignee: Celgard, LLCInventors: Lie Shi, Jill V. Watson, Ronald W. Call, Ronnie E. Smith
-
Patent number: 10559802Abstract: A battery separator for a secondary lithium battery includes a microporous/porous membrane with a ceramic coating of one or more layers, a layer may include one or more particles having an average particle size ranging from 0.01 ?m to 5 ?m and/or binders that include poly (sodium acrylate-acrylamide-acrylonitrile) copolymer.Type: GrantFiled: August 7, 2013Date of Patent: February 11, 2020Assignee: Celgard, LLCInventors: Zhengming Zhang, Xuefa Li, Lie Shi, Premanand Ramadass, Paul M. Halmo, Xiaomin Zhang
-
Patent number: 10544521Abstract: In accordance with at least selected embodiments, the present invention is directed to novel, improved, or modified porous membranes, fibers, porous fibers, products made from such membranes, fibers or porous fibers, and/or related methods of production, use, and/or the like. In accordance with at least certain embodiments, the present invention is directed to novel, improved, or modified microporous membranes or films, fibers, microporous fibers, materials or layers made from such membranes, fibers or porous fibers, and the like for use in textile materials, garments, products, and/or textile related applications. Microporous membranes, fibers, and/or microporous fibers are made of one or more copolymers, such as block or impact copolymers, or of at least one polyolefin combined with at least one copolymer as a means of improving the hand, drape, and/or surface coefficient of friction performance properties for use in textile garments, textile materials or textile related applications.Type: GrantFiled: September 5, 2017Date of Patent: January 28, 2020Assignee: Celgard, LLCInventors: Kristoffer K. Stokes, Xiaomin Zhang, Karl F. Humiston
-
Patent number: 10461293Abstract: In accordance with at least selected embodiments, novel or improved separator membranes, separators, batteries including such separators, methods of making such membranes and/or separators, and/or methods of using such membranes and/or separators are disclosed or provided. In accordance with at least certain embodiments, an ionized radiation treated microporous polyolefin, polyethylene (PE), copolymer, and/or polymer blend (e.g., a copolymer or blend comprising PE and another polymer, such as polypropylene (PP)) battery separator for a secondary or rechargeable lithium battery and/or a method of making an ionized radiation treated microporous battery separator is disclosed.Type: GrantFiled: April 8, 2016Date of Patent: October 29, 2019Assignee: Celgard, LLCInventors: Changqing Wang Adams, Michael Bielmann, Zhengming Zhang
-
Patent number: 10347890Abstract: Disclosed herein are novel or improved microporous battery separator membranes, separators, batteries including such separators, methods of making such membranes, separators, and/or batteries, and/or methods of using such membranes, separators and/or batteries. Further disclosed are laminated multilayer polyolefin membranes with exterior layers comprising one or more polyethylenes, which exterior layers are designed to provide an exterior surface that has a low pin removal force. Further disclosed are battery separator membranes having increased electrolyte absorption capacity at the separator/electrode interface region, which may improve cycling. Further disclosed are battery separator membranes having improved adhesion to any number of coatings. Also described are battery separator membranes having a tunable thermal shutdown where the onset temperature of thermal shutdown may be raised or lowered and the rate of thermal shutdown may be changed or increased.Type: GrantFiled: July 29, 2016Date of Patent: July 9, 2019Assignee: Celgard, LLCInventors: Xiaomin Zhang, Eric Robert White, Kang Karen Xiao, Robert A. Nark, Insik Jeon, Kristoffer K. Stokes, Paul Vido, Zhengming Zhang
-
Patent number: 10347951Abstract: In accordance with at least selected aspects, objects or embodiments, optimized, novel or improved membranes, battery separators, batteries, and/or systems and/or related methods of manufacture, use and/or optimization are provided. In accordance with at least selected embodiments, the present invention is related to novel or improved battery separators that prevent dendrite growth, prevent internal shorts due to dendrite growth, or both, batteries incorporating such separators, systems incorporating such batteries, and/or related methods of manufacture, use and/or optimization thereof. In accordance with at least certain embodiments, the present invention is related to novel or improved ultra thin or super thin membranes or battery separators, and/or lithium primary batteries, cells or packs incorporating such separators, and/or systems incorporating such batteries, cells or packs.Type: GrantFiled: April 20, 2017Date of Patent: July 9, 2019Assignee: Celgard, LLCInventors: Paul M. Halmo, Xiaomin Zhang, Paul D. Vido, Zhengming Zhang, Lie Shi, Daniel R. Alexander, Jill V. Watson
-
Patent number: 10333125Abstract: An improved multilayer laminated microporous battery separator for a lithium ion secondary battery, and/or a method of making or using this separator is provided. The preferred inventive dry process separator is a tri-layer laminated Polypropylene/Polyethylene/Polypropylene microporous membrane with a thickness range of 12 ?m to 30 ?m having improved puncture strength and low electrical resistance for improved cycling and charge performance in a lithium ion battery. In addition, the preferred inventive separator's or membrane's low Electrical Resistance and high porosity provides superior charge rate performance in a lithium battery for high power applications.Type: GrantFiled: November 24, 2015Date of Patent: June 25, 2019Assignee: Celgard, LLCInventors: Xiaomin Zhang, Lie Shi, William John Paulus
-
Patent number: 10326121Abstract: A method for preventing oxidation of a polyolefin separator in a lithium ion secondary battery includes the steps of: providing a lithium ion secondary battery having a positive electrode and a polyolefin separator film; and positioning an antioxidative barrier coating between the positive electrode and the polyolefin separator film, the antioxidative barrier coating being made of a polymer having a resistance to oxidation greater than polyethylene.Type: GrantFiled: April 10, 2017Date of Patent: June 18, 2019Assignee: Celgard, LLCInventors: Zhengming Zhang, Pankaj Arora
-
Patent number: 10256447Abstract: Microporous battery separators, batteries including such separators, and/or methods of making such separators, and/or methods of using such separators. In accordance with at least certain embodiments, an improved or novel battery separator for a secondary or rechargeable lithium battery may have low electrical resistance of less than 0.95 ohm-cm2, or in some cases, less than 0.8 ohm-cm2. Furthermore, the inventive battery separator membrane may provide a means to achieve an improved level of battery performance in a rechargeable or secondary lithium battery based on a possibly synergistic combination of low electrical resistance, low Gurley, low tortuosity, and/or a unique trapezoid shaped pore. In accordance with at least certain multilayer embodiments (by way of example only, a trilayer membrane made of two polypropylene layers with a polyethylene layer in between), the inventive microporous membrane or battery separator may have excellent onset and rate of thermal shutdown performance.Type: GrantFiled: June 3, 2016Date of Patent: April 9, 2019Assignee: Celgard, LLCInventors: Xiaomin Zhang, Lie Shi
-
Patent number: 10249862Abstract: A membrane includes a porous membrane or layer made of a polymeric material having a plurality of surface treated (or coated) particles (or ceramic particles) having an average particle size of less than about 1 micron dispersed therein. The polymeric material may be selected from the group consisting of polyolefins, polyamides, polyesters, co-polymers thereof, and combinations thereof. The particles may be selected from the group consisting of boehmite (AlOOH), SiO2, TiO2, Al2O3, BaSO4, CaCO3, BN, and combinations thereof, or the particles may be boehmite. The surface treatment (or coating) may be a molecule having a reactive end and a non-polar end. The particles may be pre-mixed in a low molecular weight wax before mixing with the polymeric material. The membrane may be used as a battery separator.Type: GrantFiled: May 8, 2017Date of Patent: April 2, 2019Assignee: Celgard, LLCInventors: C. Glen Wensley, Lie Shi
-
Patent number: 10240031Abstract: The present invention relates to surface modifying agents for polymeric and/or textile materials, methods of making and/or using a surface modifying agent to modify and functionalize polymeric and/or textile materials, and/or methods of using surface modified or functionalized polymeric and textile materials, and/or products using or incorporating surface modified or functionalized polymeric and textile materials. For example, the surface modifying agent in precursor form can be styrene sulfonyl azide monomer, polymer or copolymer capable of undergoing a chemical reaction in the presence of heat or light to form one or more styrene sulfonated nitrene monomers, polymers or copolymers, which are capable of chemically reacting with the surface of a polymeric or textile material to endow a specific or desired chemical surface functionality to the surface of a polymeric or textile material.Type: GrantFiled: January 17, 2014Date of Patent: March 26, 2019Assignee: Celgard, LLCInventor: Kristoffer K. Stokes
-
Patent number: 10196495Abstract: A functionalized microporous, mesoporous, or nanoporous membrane, material, textile, composite, laminate, or the like, and/or a method of making or using such functionalized membranes. The functionalized porous membrane may be a functionalized microporous, mesoporous, or nanoporous membrane that has a functional molecule attached, such as a functional polymer, to the surface and/or internal fibrillar structure of the membrane.Type: GrantFiled: May 13, 2015Date of Patent: February 5, 2019Assignee: Celgard, LLCInventors: Kristoffer K. Stokes, Karl F. Humiston
-
Patent number: 10069126Abstract: The present invention relates to new, improved or modified polymer materials, membranes, substrates, and the like and to new, improved or modified methods for permanently modifying the physical and/or chemical nature of surfaces of the polymer materials, membranes, or substrates for a variety of end uses or applications. For example, one improved method uses a carbene and/or nitrene modifier to chemically modify a functionalized polymer to form a chemical species which can chemically react with the surface of a polymer substrate and alter its chemical reactivity. Furthermore, this invention can be used to produce chemically modified membranes, fibers, hollow fibers, textiles, and the like.Type: GrantFiled: July 18, 2012Date of Patent: September 4, 2018Assignee: Celgard, LLCInventors: Kristoffer K. Stokes, Karl F. Humiston
-
Patent number: 10046537Abstract: The present invention is directed to novel, improved, modified or treated microporous membranes for use in textile related applications and which are preferably composed of two or more dissimilar porous membrane or material layers laminated together using heat, compression and/or adhesives. The preferred inventive laminated composite microporous membrane is modified using a technique or treatment such as microcreping to introduce permanent small, regularly spaced, crepes, profiles, compactions, pleats, or wrinkles into the laminated composite microporous membrane for the purpose of improving mechanical strength, elasticity and/or resiliency. In addition, the inventive microcreped microporous laminated membrane more preferably has significantly improved ‘hand’ or softness, has ‘next-to-the-skin’ softness, and/or is quiet without crinkling noises during movement, which may be desired performance properties or characteristics of or in textile garments, materials or applications.Type: GrantFiled: September 26, 2013Date of Patent: August 14, 2018Assignee: Celgard, LLCInventors: Karl F. Humiston, Gerald P. Rumierz, Dickie J. Brewer
-
Patent number: 10030157Abstract: In one aspect, microporous membranes are described herein demonstrating composite architectures and properties suitable for electronic and/or optical applications. In some embodiments, a composite membrane described herein includes a microporous polymeric matrix or substrate having an interconnected pore structure and an index of refraction and an electrically conductive coating deposited over one or more surfaces of the microporous polymeric matrix. In other embodiments, the pores are filled and the membranes are substantially transparent.Type: GrantFiled: April 15, 2015Date of Patent: July 24, 2018Assignee: Celgard, LLCInventors: Karl F. Humiston, Kristoffer K. Stokes
-
Patent number: 10003058Abstract: A battery separator comprises a co-extruded, microporous membrane having at least two layers made of extrudable polymers and having: a uniform thickness defined by a standard deviation of <0.80 microns (?m); or an interply adhesion as defined by a peel strength >60 grams.Type: GrantFiled: November 17, 2006Date of Patent: June 19, 2018Assignee: Celgard, LLCInventors: Ronald W. Call, C. William Fulk, Jr., Lie Shi, Xiaomin Zhang, Khuy V. Nguyen
-
Patent number: 9985263Abstract: The present invention is preferably directed to a polylactam ceramic coating for a microporous battery separator for a lithium ion secondary battery and a method of making this formulation and application of this formulation to make a coated microporous battery separator. The preferred inventive coating has excellent thermal and chemical stability, excellent adhesion to microporous base substrate, membrane, and/or electrode, improved binding properties to ceramic particles and/or has improved or excellent resistance to thermal shrinkage, dimensional integrity, and/or oxidation stability when used in a rechargeable lithium ion battery.Type: GrantFiled: December 29, 2015Date of Patent: May 29, 2018Assignee: Celgard, LLCInventor: Insik Jeon
-
Patent number: 9908317Abstract: A microporous battery separator is provided having a first co-extruded multilayered portion and a second co-extruded multilayered portion. The two portions are bonded together. In a preferred embodiment, the battery separator has two substantially identical multilayered portions bonded together face-to-face. Each of the two multilayered portions has at least one strength layer and at least one shutdown layer. Methods for making the battery separators are also provided. Preferably, a tubular multilayered film is extruded, and collapsed onto itself to form a multilayered battery separator precursor. The precursor is then bonded and annealed before it is stretched to form a microporous multilayer battery separator.Type: GrantFiled: May 7, 2007Date of Patent: March 6, 2018Assignee: Celgard, LLCInventors: Ronald W. Call, Donald K. Simmons, Ta-Hua Yu
-
Patent number: 9790337Abstract: Provided herein are seam tapes and related methods. The seam tapes can be compatible with polyolefin-based waterproof/breathable (w/b) membranes, including polypropylene (PP) w/b membranes and/or polyethylene (PE) w/b membranes. Also provided are seams sealed by means of these seam tapes, as well as materials, fabrics, and garments including one or more of these sealed seams.Type: GrantFiled: March 23, 2015Date of Patent: October 17, 2017Assignee: Celgard, LLCInventors: Karl F. Humiston, Kristoffer K. Stokes, Perry K. Hancock
-
Patent number: RE47520Abstract: The instant invention is directed to a separator for a high energy rechargeable lithium battery and the corresponding battery. The separator includes a ceramic composite layer and a polymeric microporous layer. The ceramic layers includes a mixture of inorganic particles and a matrix material. The ceramic layer is adapted, at least, to block dendrite growth and to prevent electronic shorting. The polymeric layer is adapted, at least, to block ionic flow between the anode and the cathode in the event of thermal runaway.Type: GrantFiled: October 5, 2015Date of Patent: July 16, 2019Assignee: Celgard, LLCInventor: Zhengming Zhang