Patents Assigned to Chemische Fabrik Stockhausen GmbH
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Patent number: 5575939Abstract: The invention relates to a process for the fat liquoring/softening of leathers and furs by treatment with an aqueous dispersion of a copolymer obtainable by polymerization of a) maleic anhydride, b) C.sub.12 -C.sub.30 alpha-olefins, esters of (meth)acrylic acid and/or maleic acid with C.sub.12 -C.sub.30 alcohols and c) optionally, further hydrophilic, ethylenically unsaturated monomers which are copolymerizable with a) and b), reaction of the anhydride groups with monovalent alcohols comprising at least one ether functionality, and partial neutralization or hydrolysis of the residual acid or anhydride groups and manufacture of a flowable dispersion having an active substance content of at least 40%-wt.Type: GrantFiled: June 9, 1995Date of Patent: November 19, 1996Assignee: Chemische Fabrik Stockhausen GmbHInventors: Kurt Dahmen, Richard Mertens, Thomas Muller, Helmut Lohmann
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Patent number: 5575946Abstract: Water-softening formulations which comprise:(a) a biodegradable copolymer;(b) an inorganic water-softening silicate; and, optionally,(c) another inorganic salt;(d) a dispersing and complexing agent; and(e) a surfactant and also additional customary additives have improved biodegradability.Type: GrantFiled: April 28, 1994Date of Patent: November 19, 1996Assignee: Chemische Fabrik Stockhausen GmbHInventors: Rudolf Beck, Frank Krause, Udo Schoenkaes
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Patent number: 5574120Abstract: The preparation of terpolymers by free radical polymerization of an unsaturated dicarboxylic acid with an unsaturated monocarxylic acid and a further saturated monomer which contains no free carboxyl groups, in an aqueous medium, is carried out, according to the invention, in the presence of surfactant compounds.Type: GrantFiled: November 6, 1995Date of Patent: November 12, 1996Assignee: Chemische Fabrik Stockhausen GmbHInventors: Klaus Heidel, Wulf Ruback, Frank Krause
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Patent number: 5569408Abstract: Water-soluble, biologically decomposable carbonic acid polyesters having the general formula (I): ##STR1## in which R.sub.1 represents a straight- or branched-chain, saturated or monounsaturated alkyl residue having from 6 to 22 carbon atoms;R.sub.2 represents a hydrogen or methyl group;R.sub.3 represents hydrogen or the group: ##STR2## n is an integer between 0 and 10; m is an integer between 5 and 16, andz is an integer between 1 and 3 are disclosed.The use of these compounds for preparation and lubricating agents for synthetic fibers is also disclosed.Type: GrantFiled: October 27, 1993Date of Patent: October 29, 1996Assignee: Chemische Fabrik Stockhausen GmbHInventors: Reinmar Peppmoller, Bernhard Goossens, Karl Winck
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Patent number: 5567478Abstract: The present invention relates to a process for producing water-absorbing sheet-like materials which consist of a water-absorbent polymer and a prefabricated nonwoven fabric, wherein the prefabricated nonwoven fabric is impregnated with a solution comprising partially neutralized acrylic acid and at least one cross-linking agent and is squeezed to a certain coating amount, and the monomer solution thus applied is characterized in that the polymerization is carried out in the presence of radical initiators which cannot be activated thermally and at least one thermally activatable radical former used in addition. The additional use of a thermally activatable radical former in the polymerization results in products having a low residual monomer content, an improved water absorption under load, and a higher retention, with a production method being employed which is technically simple and economically efficient at the same time.Type: GrantFiled: May 31, 1995Date of Patent: October 22, 1996Assignee: Chemische Fabrik Stockhausen GmbHInventors: Jochen Houben, Edgar Herrmann, Kurt Dahmen
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Patent number: 5556930Abstract: The present invention relates to copolymers built up of a) 20-60%-wt. ethylenically unsaturated acid-groups-comprising monomers, b) 40-80%-wt. ethylenically unsaturated glycerol derivatives in which one hydroxyl group of the glycerol is unsubstituted, one hydroxyl group is etherified with (meth)-allyl alcohol and the third hydroxyl group is etherified with a C.sub.12 -C.sub.24 -alcohol or C.sub.12 -C.sub.24 -alkyl phenol or esterified with a C.sub.12 -C.sub.40 -monocarboxylic acid and c) 0-30%-wt. other ethylenically unsaturated monomers copolymerizable with the monomers a) and b), whereby the sum of the monomers a+b+c=100. The present invention further relates to the use of said copolymers for the softening of leather. The copolymers according to the present invention result in an improved exhaustion during the leather treatment.Type: GrantFiled: June 12, 1995Date of Patent: September 17, 1996Assignee: Chemische Fabrik Stockhausen GmbHInventors: Helmut Brehm, Leonardus Strijbos, Hans-Bernhard Eikmeier
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Patent number: 5512646Abstract: A water-soluble, powdered, cationic polyelectrolyte comprising a copolymer of acrylamide and dimethylaminopropylacrylamide in whicha) the dimethylaminopropylacrylamide is neutralized with mineral acids;b) the quotient of the intrinsic viscosity of the copolymers divided by the molar ratio of acrylamide to dimethylaminopropylacrylamide is greater than 200; andc) the proportion of the cationic monomers in the polymer is between 4 and 80 mol-%,the copolymer having been obtained by copolymerization of acrylamide and dimethylaminopropylacrylamide that is essentially free of bifunctional compounds.Type: GrantFiled: September 13, 1993Date of Patent: April 30, 1996Assignee: Chemische Fabrik Stockhausen GmbHInventors: Hans-Georg Hartan, Alfons Landscheidt
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Patent number: 5496495Abstract: The present invention relates to detergent formulations which contain(a) 3 to 70% by weight of one or more surfactants;(b) 1 to 60% by weight of a readily biodegradable copolymer which comprises monomer units obtained from(A) monoethylenically unsaturated dicarboxylic acids, anhydrides, salts thereof or mixtures thereof,(B) monoethylenically unsaturated monocarboxylic acids, salts thereof or mixtures thereof,(C) monounsaturated monomers which aqueous polymerization, after hydrolysis or saponification, give monomer units which have one or more free hydroxyl groups on a carbon chain of the copolymer, and(D) 0 to 15% by weight of one or more further monomers capable of free radical copolymerization;(c) 0 to 60% by weight of washing alkalis; and(d) 0 to 70% by weight of standardizing agents,and their use in inhibiting incrustation of textiles and in removing alkaline earth metals from textiles during laundering.Type: GrantFiled: August 3, 1994Date of Patent: March 5, 1996Assignee: Chemische Fabrik Stockhausen GmbHInventors: Rudolf Beck, Frank Krause, Udo Schoenkaes
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Patent number: 5496933Abstract: Chitosan absorbent is prepared by reacting pulverized chitosan suspended as a powder in an organic solvent with an acid and then isolating solid chitosan-acid reaction product.Type: GrantFiled: May 17, 1994Date of Patent: March 5, 1996Assignee: Chemische Fabrik Stockhausen GmbHInventor: Heike Kelkenberg
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Patent number: 5455284Abstract: The present invention relates to a process for the production of water-swellable products, using very fine particles of water-swellable polymers, characterized by the following steps: a) the very fine particles of water-swellable polymer are dispersed in a monomer which is liquid at room temperature and does not cause the polymeric superfines to swell, b) the dispersion obtained in step a) is mixed with an aqueous monomer solution, c) the mixture obtained in step b) is polymerized by the addition of catalysts and/or by exposure, and d) the polymer gel is comminuted and dried. The present invention further relates to a water-insoluble, water-swellable polymer which absorbs aqueous and serous liquids and blood, and is obtained by the process described above.Type: GrantFiled: June 7, 1993Date of Patent: October 3, 1995Assignee: Chemische Fabrik Stockhausen GmbHInventors: Kurt Dahmen, Richard Mertens, Helmut Brehm
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Patent number: 5433753Abstract: The present invention discloses the use of polymers which have built-in by polymerization 20 to 70%-wt. of a hydrophobic monomer selected from long-chain alpha-olefins, long-chain alkyl(meth)acrylates, vinyl esters of long-chain carboxylic acids, long-chain vinyl ethers, or mixtures of these monomers, 1 to 60%-wt. of a monomer with a specific polysiloxane group, and 20 to 35%-wt. water-soluble, unsaturated acids, unsaturated C.sub.4 -C.sub.6 dicarboxylic anhydrides, semi-esters or semi-amides of unsaturated C.sub.4 -C.sub.6 dicarboxylic acids, or mixtures of these monomers, in partially neutralized form as aqueous solution or dispersion, for softening, fat-liquoring and greasing, or hydrophobing leathers and furs.Type: GrantFiled: May 25, 1994Date of Patent: July 18, 1995Assignee: Chemische Fabrik Stockhausen GmbHInventors: Kurt Dahmen, Richard Mertens, Manfred Kaussen, Helmut Lohmann, Horst Kilian
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Patent number: 5409771Abstract: The present invention relates to a powdery, water-insoluble, cross-linked resin which absorbs aqueous or serous liquids as well as blood and is composed of a) 55 to 99.9%-wt. polymerized, unsaturated, polymerizable, acid-groups-containing monomers which are neutralized to the extent of at least 25 mol-%, b) 0 to 40%-wt. polymerized, unsaturated monomers copolymerizable with a), c) 0.1 to 5.0%-wt. of a cross-linking agent, and d) 0 to 30%-wt. of a water-soluble polymer, whereby the weight amounts a) to d) relate to anhydrous polymer. The polymer is characterized by the fact that the resin powder has been coated with 0.1 to 5%-wt. of an alkylene carbonate, relative to resin powder, and heated to a temperature of 150.degree. to 300.degree. C. The present invention further relates to a method of producing said polymer and to the use thereof in sanitary articles, such as diapers and the like, and in absorbent constructions consisting of hydrophilic fibers and absorbing resin.Type: GrantFiled: December 29, 1992Date of Patent: April 25, 1995Assignee: Chemische Fabrik Stockhausen GmbHInventors: Kurt Dahmen, Richard Mertens
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Patent number: 5408019Abstract: The invention relates to a cross-linked, water-absorbent polymer obtainable by the polymerization of a mixture consisting of a) 60-99%-wt. unsaturated, polymerizable monomers with acid groups which are neutralized to the extent of at least 30 mol-%, b) 0-37%-wt. monomers copolymerizable with a), c) 0.1-3.0%-wt. of a cross-linking agent and d) 0-10%-wt. of a water-soluble polymer, in which polymerization is conducted with a redox catalyst system containing formamidine sulfinic acid as reducing agent. The polymer is distinguished by a retention of greater than or equal to 28 g 0.9% aqueous NaCl-solution per 1 g of polymer, an absorption of greater than or equal to 26 g 0.9% aqueous NaCl-solution per 1 g of polymer at a load of 20 g/cm.sup.2 and a residual monomer content of less than 700 ppm, and preferably less than 500 ppm. The invention also relates to the use of this polymer in the production of hygiene articles.Type: GrantFiled: February 1, 1994Date of Patent: April 18, 1995Assignee: Chemische Fabrik Stockhausen GmbHInventors: Richard Mertens, Kurt Dahmen, Helmut Brehm
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Liquid or flowable derivatives of natural fats and oils a process for their production and their use
Patent number: 5391784Abstract: The present invention relates to derivatives of natural fats and oils that are liquid or flowable, respectively, and to a process for the production of said derivatives, in which oxalkylation is carried out at elevated temperatures in the presence of basic catalysts with at least one compound containing an epoxide group, and sulfation is carried out in a manner known per se, in which a starting material containingA) at least one C.sub.8 -C.sub.24 -fatty acid ester of an aliphatic C.sub.1 -C.sub.5 -monoalcoholThe present invention furthermore relates to the use of said derivatives, optionally in combination with other greasing substances and anionic and/or non-ionic emulsifiers, for the fatliquoring and greasing of leather.Type: GrantFiled: December 6, 1993Date of Patent: February 21, 1995Assignee: Chemische Fabrik Stockhausen GmbHInventors: Helmut Brehn, Helmut Klimmek, Leonhard Strijbos -
Patent number: 5340853Abstract: The present invention relates to an absorbing and swelling agent for water, aqueous solutions and body liquids, which consists of a mixture of at least two components, whereby component A is at least a water-swellable, synthetic polymer or copolymer cross-linked with a polyfunctional compound, and component B is at least a polysaccharide selected from the group consisting of galactomannans or polygalactomannans, as well as galactomannan derivatives or mixtures thereof with other natural or synthetic polymers which at normal temperature are present as pourable powders or as fibrous materials and are only partially soluble or insoluble in water.Type: GrantFiled: September 17, 1991Date of Patent: August 23, 1994Assignee: Chemische Fabrik Stockhausen GmbHInventors: Miroslav Chmelir, Helmut Klimmek
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Patent number: 5304664Abstract: To obtain highly sulfated fatty acids, hydroxy fatty acids or oxalkylated hydroxy fatty acids, the reaction mixture obtained from the sulfatation of unsaturated fatty acid esters and/or saturated hydroxy fatty acid ester and/or oxalkylated hydroxy fatty acid esters is neutralized, optionally separated from the brine, diluted with water and hydrolyzed at a temperature between 20.degree. C. and 160.degree. C. after addition of lye the amount of which at maximum is equivalent to the organically bonded sulfuric acid content. After phase separation from the non-sulfated starting products, the highly sulfated fatty acids are isolated from the aqueous phase.Type: GrantFiled: April 5, 1991Date of Patent: April 19, 1994Assignee: Chemische Fabrik Stockhausen GmbHInventors: Reinmar Peppmoller, Kurt Dahmen
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Patent number: 5292404Abstract: The present invention relates to a process for trash removal or pitch control in the paper manufacture, in which process as agent for the trash removal or pitch control cationic groups containing polymers of 50 to 100%-wt. quaternized dimethylaminopropylmethacrylamide or dimethylaminopropylmethacrylamide and 0 to 50%-wt acrylamide, acrylic acid, methacrylic acid, acrylamidomethylpropanesulfonic acid, are used, which polymers have an intrinsic viscosity of smaller than 150 ml/g. The trash removal or pitch control agent is added to the pulp flow and/or the circuit water in amounts of up to 1%-wt., relative to the dry weight of the paper manufactured.Type: GrantFiled: March 27, 1992Date of Patent: March 8, 1994Assignee: Chemische Fabrik Stockhausen GmbHInventors: Hans-Georg Hartan, Alfons Landscheidt
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Patent number: 5264471Abstract: The invention relates to a process for the production of absorbers for water, aqueous solutions and body liquids, the absorbers consisting of at least two components A and B, whereby component A is at least a water-swellable synthetic polymer or copolymer, and component B is at least a natural or synthetic compound being present at normal temperature as a pourable powder which is highly or at least partially soluble, in water, or as a liquid. The present invention is characterized by the fact that component B is added in the form of a powder, a liquid or as a solution to component A during the end phase of the production process thereof after a polymer reaction degree of 90%, preferably 95% is attained, that is is mixed with the polymer gel of component A and, in order to obtain a powdery, pourable end product, is dried, if necessary, and ground.Type: GrantFiled: September 17, 1991Date of Patent: November 23, 1993Assignee: Chemische Fabrik Stockhausen GmbHInventor: Miroslav Chmelir
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Patent number: 5248709Abstract: The present invention relates to granular materials of water-swellable polymers having a content of water-swellable polymer and agglomeration auxiliary agent as main component, and optionally further additional non-agglomerating components, the invention further relates to the method for the manufacture of said material, to its use as absorbents, and to disposable articles comprising these granular materials.Type: GrantFiled: August 3, 1990Date of Patent: September 28, 1993Assignee: Chemische Fabrik Stockhausen GmbHInventor: Helmut Brehm
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Patent number: 5229466Abstract: The present invention relates to a powdery absorbing material for aqueous liquids based on a water-swellable powdery polymer having at least 0.2 equivalents carboxyl groups per 100 parts by weight which are neutralized by 50 to 99, advantageously by at least 80 mole %. The powdery absorbing material is obtained by treating the water-swellable carboxyl-groups-containing polymer with a solution of an N-(hydroxyalkyl).beta.-(meth)-alanine ester or with the polycondensation products thereof. As a solvent for the powdery absorbing material, water is used which either contains water-miscible organic diluents which evaporate on heating, or non-evaporative water-miscible organic diluents, i.e., diluents remaining in the polymer.Type: GrantFiled: May 18, 1992Date of Patent: July 20, 1993Assignee: Chemische Fabrik Stockhausen GmbHInventors: Helmut Brehm, Richard Mertens