Patents Assigned to Chiyoda Corporation
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Patent number: 9388096Abstract: A producing method of monocyclic aromatic hydrocarbons in which reaction products including monocyclic aromatic hydrocarbons are produced by bringing an oil feedstock and an aromatic production catalyst into contact with each other, the oil feedstock having a 10 volume % distillation temperature of more than or equal to 140° C. and a 90 volume % distillation temperature of less than or equal to 380° C., the method including the steps of: introducing the oil feedstock into a fluidized-bed reaction apparatus housing the aromatic production catalyst; bringing the oil feedstock and the aromatic production catalyst into contact with each other in the fluidized-bed reaction apparatus; and introducing steam into the fluidized-bed reaction apparatus based on the introducing amount of the oil feedstock per hour.Type: GrantFiled: May 24, 2012Date of Patent: July 12, 2016Assignees: JX Nippon Oil & Energy Corporation, CHIYODA CORPORATIONInventors: Shinichiro Yanagawa, Yasuyuki Iwasa, Susumu Yasui, Yoshishige Sugi, Atsushi Fukui, Atsuro Nagumo, Osamu Hirohata
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Patent number: 9382173Abstract: Provided is a method for producing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms, the method including a cracking reforming reaction step of bringing feedstock oil into contact with a catalyst to effect a reaction; a step of purifying and recovering monocyclic aromatic hydrocarbons separated from the reaction step; and (1) a step of hydrogenating a heavy fraction separated from the reaction step; a dilution step of returning a portion of the hydrogenation product as a diluent oil to the hydrogenation step; and a step of returning the hydrogenation product to the reaction step; or (2) a step of adding a diluent to the heavy fraction separated from the reaction step; a step of hydrogenating the mixture; and a step of returning the hydrogenation product to the reaction step.Type: GrantFiled: March 23, 2012Date of Patent: July 5, 2016Assignees: JX Nippon Oil & Energy Corporation, CHIYODA CORPORATIONInventors: Shinichiro Yanagawa, Ryoji Ida, Yasuyuki Iwasa, Masahide Kobayashi, Susumu Yasui, Yoshishige Sugi, Atsushi Fukui, Atsuro Nagumo
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Publication number: 20160130207Abstract: To provide a production method for suppressing the reduction in production rate of a carbonyl compound due to transferring a noble metal component into liquid phase. A method for producing a carbonyl compound, including: a reaction step of reacting a carbonylation raw material with CO in liquid phase including a solid catalyst having noble metal complex on a resin carrier containing quaternized nitrogen to produce a carbonyl compound; a distillation step of distilling a reaction product liquid to recover gas phase distillate including the carbonyl compound; and a circulation step of circulating a bottom product from the distillation to reaction step. After part of the bottom product contacts with an acidic cation-exchange resin to remove nitrogen compound, liquid having higher moisture concentration than the bottom product contacts with the resin to extract noble metal complex captured by oligomer adsorbing the resin, and the complex is returned to the reaction step.Type: ApplicationFiled: June 3, 2014Publication date: May 12, 2016Applicant: CHIYODA CORPORATIONInventors: Zhixiong You, Yoichi Umehara, Tetsuro Matsumura, Takeshi Minami
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Publication number: 20160121320Abstract: An aldehyde adsorbent that can adsorb and remove aldehyde from a carboxylic acid-containing liquid is provided. The aldehyde adsorbent is an aldehyde adsorbent for adsorbing aldehyde in a carboxylic acid-containing liquid containing aldehyde, including a cation exchange resin ion-exchanged with a polyvalent amine in 1 to 99% by mol of the total exchange capacity.Type: ApplicationFiled: June 3, 2014Publication date: May 5, 2016Applicant: CHIYODA CORPORATIONInventors: Zhixiong You, Yoichi Umehara, Tetsuro Matsumura, Takeshi Minami
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Patent number: 9255042Abstract: A producing method of monocyclic aromatic hydrocarbons from the oil feedstock having a 10 volume % distillation temperature of more than or equal to 140° C. and a 90 volume % distillation temperature of less than or equal to 380° C. by bringing into contact with an aromatic production catalyst includes the steps of: introducing the oil feedstock into a cracking and reforming reaction apparatus housing the aromatic production catalyst; bringing the oil feedstock and the aromatic production catalyst into contact with each other at the inside of the cracking and reforming reaction apparatus; heating the oil feedstock in advance before introducing the oil feedstock into the cracking and reforming reaction apparatus and forming a two-phase gas-liquid stream; separating the two-phase gas-liquid stream into a gas fraction and a liquid fraction; and introducing the gas fraction and the liquid fraction at different positions of the cracking and reforming reaction apparatus.Type: GrantFiled: May 24, 2012Date of Patent: February 9, 2016Assignees: JX Nippon Oil & Energy Corporation, CHIYODA CORPORATIONInventors: Shinichiro Yanagawa, Yasuyuki Iwasa, Susumu Yasui, Yoshishige Sugi, Atsushi Fukui, Atsuro Nagumo
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Patent number: 9233892Abstract: A method for producing monocyclic aromatic hydrocarbons includes a step of introducing a feedstock oil into a cracking/reforming reactor, bringing the feedstock oil into contact with a catalyst, and causing the feedstock oil to react, a step of purifying and recovering the monocyclic aromatic hydrocarbons separated from the product produced in the reaction step, a step of hydrogenating a heavy fraction separated from the product, and a recycling step of returning a hydrogenation reactant of the heavy fraction to the cracking/reforming reaction step. In the recycling step, the hydrogenation reactant is introduced at a location different from an introduction location of the feedstock oil into the reactor so that a time during which the hydrogenation reactant is in contact with the catalyst in the reactor becomes shorter than a time during which the feedstock oil is in contact with the catalyst in the reactor.Type: GrantFiled: March 23, 2012Date of Patent: January 12, 2016Assignees: JX Nippon Oil & Energy Corporation, CHIYODA CORPORATIONInventors: Shinichiro Yanagawa, Masahide Kobayashi, Ryoji Ida, Susumu Yasui, Yoshishige Sugi, Atsushi Fukui, Atsuro Nagumo
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Publication number: 20150252792Abstract: A solar-thermal collector includes a shaft supported by stands, a plurality of plate-like arms, which are secured to the shaft and arranged at intervals in the direction of length of the shaft, a reflector, which is supported by two adjacent arms and which reflects and concentrates the sunlight, and a spacer, which defines the spacing between the two adjacent arms and which is provided between the two adjacent arms.Type: ApplicationFiled: May 15, 2015Publication date: September 10, 2015Applicant: CHIYODA CORPORATIONInventors: Hirokazu SAITO, Toshihisa SUZUKI
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Publication number: 20150247490Abstract: A solar-thermal collector includes a shaft supported by stands, arms, which are fixed to the shaft and are arranged at intervals along the length of the shaft, and a flexible reflector supported by the arms. Each arm has reflection-surface forming faces such that the vertical cross section thereof relative to the shaft is parabolic. Ends of the reflector are firmly attached to the reflection-surface forming faces of the arms, so that the reflection surface of the reflector is formed into a parabolic-cylindrical surface suited to the concentration of the sunlight.Type: ApplicationFiled: May 15, 2015Publication date: September 3, 2015Applicant: CHIYODA CORPORATIONInventors: Hirokazu SAITO, Toshihisa SUZUKI
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Publication number: 20150233651Abstract: In an air-cooled heat exchanger system, the stress in the pipe connecting the upstream main pipe of the upstream manifold and each heat exchanger is minimized by using a simple structure. The air-cooled heat exchanger system (1) comprises an upstream manifold (6) including a plurality of upstream branch pipes (18) extending therefrom, a heat exchanger (4) connected to the downstream end of each branch pipe, and including an inlet header (31) placed on a base frame in a moveable manner, an outlet header and a plurality of heat transfer tubes (34) connecting the two headers, and a connecting member (41, 75) connecting each adjacent pair of the inlet headers.Type: ApplicationFiled: August 14, 2013Publication date: August 20, 2015Applicant: CHIYODA CORPORATIONInventors: Masao Ueno, Yoshiaki Sakomoto, Fumiaki Sakai, Kensaku Suzuki, Atsumasa Ishikiawa
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Publication number: 20150202614Abstract: Provided is a method of reactivating a used titania catalyst for hydrogenation treatment, capable of improving the catalytic activity of the used titania catalyst for hydrogenation treatment that is obtained by supporting a catalyst component on a titania support and exhibits reduced catalytic activity after having been used for hydrogenation treatment of a hydrocarbon oil, to a level comparable to that of a newly prepared fresh titania catalyst before use.Type: ApplicationFiled: May 16, 2013Publication date: July 23, 2015Applicant: CHIYODA CORPORATIONInventors: Shinichi Inoue, Yukitaka Wada, Akihiro Mutou
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Publication number: 20150174525Abstract: To provide a method for predicting a deactivation phenomenon in a flue-gas desulfurization unit to prevent the occurrence of the deactivation phenomenon before it happens. There is provided a method for preventing the occurrence of a deactivation phenomenon in a flue-gas desulfurization unit that treats flue gas of a coal-fired boiler, the method includes calculating a deactivation potential as an index of the deactivation phenomenon based on alkaline components such as Na, Ca, Mg, and K contained in ash in the flue gas, and performing an operation management, such as adjustment of set value of a pH control system, on the flue-gas desulfurization unit depending on change of the deactivation potential.Type: ApplicationFiled: August 22, 2012Publication date: June 25, 2015Applicant: CHIYODA CORPORATIONInventors: Noboru Takei, Chisa Nishizaki
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Publication number: 20150174565Abstract: Provided are zeolite catalysts that allow reactions to proceed at temperatures as low as possible when lower olefins are produced from hydrocarbon feedstocks with low boiling points such as light naphtha, make it possible to make propylene yield higher than ethylene yield in the production of lower olefins, and have long lifetime. The zeolite catalysts are used in the production of lower olefins from hydrocarbon feedstocks with low boiling points such as light naphtha. The zeolite catalysts are MFI-type crystalline aluminosilicates containing iron atoms and have molar ratios of iron atoms to total moles of iron atoms and aluminum atoms in the range from 0.4 to 0.7. The use of the zeolite catalysts make it possible to increase propylene yield, to lower reaction temperatures, and to extend catalyst lifetime.Type: ApplicationFiled: June 7, 2013Publication date: June 25, 2015Applicant: CHIYODA CORPORATIONInventors: Shinya Hodoshima, Fuyuki Yagi, Azusa Motomiya, Shuhei Wakamatsu, Sachio Asaoka
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Patent number: 9056772Abstract: It is avoided that the sulfur compounds originating from the castable is mixed into produced synthesis gas, the mixed sulfur compounds are separated and collected with carbon dioxide, the collected carbon dioxide is recycled as raw material gas and then the sulfur compounds is directly supplied to the reformer to consequently degrade the reforming catalyst in the reformer by sulfur poisoning. The carbon dioxide separated and collected in the carbon dioxide removal step is introduced into the desulfurization apparatus of the desulfurization step or the sulfur compounds adsorption apparatus before being recycled to the reformer to remove the sulfur compounds.Type: GrantFiled: February 21, 2011Date of Patent: June 16, 2015Assignees: JAPAN OIL GAS AND METALS NATIONAL CORPORATION, INPEX CORPORATION, JX NIPPON OIL & ENERGY CORPORATION, JAPAN PETROLEUM EXPLORATION CO., LTD., COSMO OIL CO., LTD., NIPPON STEEL ENGINEERING CO., LTD., CHIYODA CORPORATIONInventors: Shinya Hodoshima, Fuyuki Yagi, Shuhei Wakamatsu, Kenichi Kawazuishi
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Patent number: 9045336Abstract: There is provided a method for producing synthesis gas without CO2 emissions. In the method for producing synthesis gas by reforming a hydrocarbon gas, a reforming reaction is caused by supplying a light hydrocarbon gas containing steam and/or carbon dioxide added thereto to a catalyst-filled tube side of a shell-and-tube heat exchanger-type reformer and circulating a heating medium, such as a molten salt, heated by a heat source such as solar heat or nuclear heat in a shell side of the shell-and-tube heat exchanger-type reformer. Carbon dioxide is removed from a produced gas discharged from the tube side and is supplied to the upstream side of the tube side and recycled.Type: GrantFiled: March 21, 2012Date of Patent: June 2, 2015Assignee: Chiyoda CorporationInventor: Junichi Sakaguchi
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Publication number: 20150147816Abstract: Provided is a method of evaluating a resin capable of quantitatively evaluating a deterioration degree of the resin with high accuracy and ease. The method includes evaluating the resin based on a shift of a characteristic peak representing a deterioration degree of the resin, the peak being observed in thermal analysis of the resin by a temperature increase, to lower temperatures.Type: ApplicationFiled: November 19, 2014Publication date: May 28, 2015Applicant: CHIYODA CORPORATIONInventors: Zhixiong You, Ryuichi Kanai, Yoichi Umehara, Takeshi Minami
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Patent number: 9039813Abstract: The exhaust gas treatment apparatus has a sealed vessel which is vertically partitioned into two spaces by a partition. A portion of the sealed vessel lower than the partition is an absorbing liquid storage portion, and a portion of the sealed vessel upper than the partition is an exhaust gas introducing portion. The partition is provided with a large number of sparger pipes so that the sparger pipes reach inside an absorbing liquid stored in the absorbing liquid storage portion. The partition is provided with a single gas riser in communication with a space upper than the absorbing liquid in the absorbing liquid storage portion. An upper end of the gas riser passes through a top plate portion of the sealed vessel and protrudes upward.Type: GrantFiled: October 21, 2010Date of Patent: May 26, 2015Assignee: CHIYODA CORPORATIONInventors: Noboru Takei, Sohsuke Kido, Naohiro Kaji, Akira Kumagai
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Patent number: 8961666Abstract: The exhaust gas treatment apparatus has a sealed vessel which is vertically partitioned into two spaces by a partition. The partition is provided with a gas riser for deriving treated exhaust gas from an upper space of the absorbing liquid storage portion. A large number of sparger pipes are provided in a effective region, so as to reach inside an absorbing liquid stored in the absorbing liquid storage portion. A non-jet region is provided in the effective region. The froth layer is not formed in the non-jet region, and the absorbing liquid in a foamed state flows down from the froth layer therearound to circulate the absorbing liquid.Type: GrantFiled: October 21, 2010Date of Patent: February 24, 2015Assignee: Chiyoda CorporationInventors: Noboru Takei, Sohsuke Kido, Naohiro Kaji, Akira Kumagai
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Publication number: 20150021264Abstract: A plant effluent treatment method includes a mixing treatment step that mixes a microorganism activating agent into plant effluent containing organic compounds as discharged from a chemical plant, petroleum plant or petrochemical plant and discharges it as mixing treatment effluent, and an aerobic treatment step that subjects the mixing treatment effluent to aerobic biological treatment and solid-liquid separation treatment in a membrane bioreactor tank.Type: ApplicationFiled: January 10, 2013Publication date: January 22, 2015Applicants: Chiyoda Corporation, Toray Industries, Inc.Inventors: Kanako Tsuda, Yusuke Shinoda, Masayo Shinohara, Kazuyuki Tejima, Atsushi Kitanaka, Masahide Taniguchi
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Patent number: 8900456Abstract: A method of treating wastewater containing an organic compound includes feeding wastewater to an anoxic tank, adding compounds containing nitrogen and phosphorus components to wastewater, performing anaerobic treatment on wastewater, and discharging treated wastewater as pre-treated water; introducing pre-treated water into an anaerobic treatment tank, performing anaerobic treatment on pre-treated water, thereby decomposing the organic compound into organic compounds of smaller molecular size and a mixture gas containing methane and carbon dioxide, and discharging treated water as primary water; introducing primary water into an aerobic treatment tank, performing aerobic treatment on primary water, and discharging treated water through a solid-liquid separator as secondary water; and introducing at least a part of secondary water into a reverse osmosis membrane separation unit, and separating part of secondary water into RO permeated water and RO concentrated brine, wherein at least a part of RO concentratedType: GrantFiled: September 1, 2010Date of Patent: December 2, 2014Assignees: Chiyoda Corporation, Toray Industries, Inc.Inventors: Masayo Shinohara, Kazuhige Kawamura, Hiromi Satoh, Toshinobu Imahama, Atsushi Kitanaka, Masahide Taniguchi
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Publication number: 20140316071Abstract: According to a method for producing acetic acid by carbonylation of methanol characterized in that an acid having an acid dissociation constant (pKa) smaller than the constant of acetic acid is allowed to be present in the reaction system, acetic acid can be produced by the reaction of methanol and carbon monoxide in a reaction liquid in the presence of a solid catalyst containing rhodium and alkyl iodide, to achieve an enhanced reaction rate of carbonylation of methanol in producing acetic acid in the region at a high carbonylation degree (Ca>0.8 mol/mol) for more efficient production of acetic acid.Type: ApplicationFiled: July 3, 2014Publication date: October 23, 2014Applicant: CHIYODA CORPORATIONInventors: Zhixiong You, Takeshi Minami, Chunji Yin, Yoichi Umehara, Tetsuro Matsumura, Chikako Hashimoto, Yasuo Hosono