Abstract: An article is described herein that includes: a substrate having a glass, glass-ceramic or a ceramic composition and comprising a primary surface; and a protective film disposed on the primary surface. The protective film comprises a thickness of greater than 1.5 microns and a maximum hardness of greater than 15 GPa at a depth of 500 nanometers, as measured on the film disposed on the substrate. Further, the protective film comprises a metal oxynitride that is graded such that an oxygen concentration in the film varies by 1.3 or more atomic %. In addition, the substrate comprises an elastic modulus less than an elastic modulus of the film.
Type:
Grant
Filed:
January 26, 2023
Date of Patent:
February 20, 2024
Assignee:
Corning Incorporated
Inventors:
Kaveh Adib, Guangli Hu, William Joseph Hurley, Dana Ianson, Lin Lin, Santona Pal, James Joseph Price
Abstract: An article includes a carrier including a carrier bonding surface, a sheet including a sheet bonding surface, and a surface modification layer disposed on at least one of the carrier bonding surface and the sheet bonding surface. The surface modification layer includes a plasma polymerized material. The plasma polymerized material planarizes the at least one of the carrier bonding surface and the sheet bonding surface. The carrier bonding surface and the sheet bonding surface are bonded with the surface modification layer so that the carrier is temporarily bonded with the sheet. A method of making an article includes depositing a surface modification layer on at least one of a carrier bonding surface and a sheet bonding surface. The method further includes bonding the carrier bonding surface and the sheet bonding surface with the surface modification layer to temporarily bond the carrier with the sheet.
Type:
Grant
Filed:
June 22, 2016
Date of Patent:
February 20, 2024
Assignee:
CORNING INCORPORATED
Inventors:
Robert Alan Bellman, Robert George Manley, Prantik Mazumder
Abstract: An apparatus for testing a sheet of brittle material is disclosed. The apparatus can include a plurality of assemblies configured for selectively applying a 3-point bending load on an edge of the sheet of material in a test region of the apparatus, a detection mechanism that optically measures strain in the sheet of material in the region, and a processor that determines the stress in the sheet based on the measured strain by calculating the stress that would be required to produce the measured strain in the sheet of material.
Type:
Grant
Filed:
May 6, 2020
Date of Patent:
February 20, 2024
Assignee:
Corning Incorporated
Inventors:
Gabriel Pierce Agnello, Chong Pyung An, Zhenxing Hu, Bosun Jang, Peter Knowles, Balamurugan Meenakshi Sundaram, Douglas Miles Noni, Jr., Richard Sean Priestley, Jamie Todd Westbrook
Abstract: A composition includes: 30 mol % to 60 mol % SiO2; 15 mol % to 35 mol % Al2O3; 5 mol % to 25 mol % Y2O3; 0 mol % to 20 mol % TiO2; and 0 mol % to 25 mol % R2O, such that R2O is the sum of Na2O, K2O, Li2O, Rb2O, and Cs2O.
Type:
Grant
Filed:
May 13, 2021
Date of Patent:
February 20, 2024
Assignee:
Corning Incorporated
Inventors:
Alexandra Lai Ching Kao Andrews Mitchell, Steven Alvin Tietje
Abstract: Apparatus and methods are disclosed which apply inorganic particles to a plugged honeycomb body comprising porous walls, an inlet end and an outlet end. The apparatus comprises a particle counter and the method comprises counting a selected portion of the inorganic particles from a first sampling port upstream from the plugged honeycomb body and a second sampling port downstream from the plugged honeycomb body. The selected portion of the inorganic particles are in a preselected inorganic particle size range. Filtration efficiency can be determined while inorganic particles are being deposited, for example to increase filtration efficiency.
Type:
Grant
Filed:
July 8, 2020
Date of Patent:
February 13, 2024
Assignee:
Corning Incorporated
Inventors:
Pavel Boyuk, Joseph Henry Citriniti, Stefan Wolfgang Kramel, Cai Liu
Abstract: A laminate includes a first glass article having a first thickness, a first annealing point, and a first softening point, a second glass article having a second thickness, a second annealing point, and a second softening point, and an interlayer disposed between the first glass article and the second glass article. The first thickness is greater than the second thickness, the second annealing point is less than or equal to the first annealing point, and the second softening point is greater than the first softening point.
Type:
Grant
Filed:
April 12, 2019
Date of Patent:
February 13, 2024
Assignee:
Corning Incorporated
Inventors:
Douglas Dale Bressler, Rebecca Marie Connors, Sinue Gomez, Timothy Michael Gross, Shane David Seyler, Jason Scott Stewart, Zhongzhi Tang, Lisa Anne Tietz Moore
Abstract: Embodiments of a vehicle interior system are disclosed. In one or more embodiments, the system includes a base with a curved surface, and a display or touch panel disposed on the curved surface. The display includes a cold-bent glass substrate with a thickness of 1.5 mm or less and a first radius of curvature of 20 mm or greater, and a display module and/or touch panel attached to the glass substrate having a second radius of curvature that is within 10% of the first radius of curvature. Methods for forming such systems are also disclosed.
Type:
Grant
Filed:
March 31, 2021
Date of Patent:
February 13, 2024
Assignee:
Corning Incorporated
Inventors:
Thomas Michael Cleary, Steven Edward DeMartino, Timothy Michael Gross, Atul Kumar, Cheng-Chung Li, Torsten Nath, Fabio Lopes Brandao Salgado, Wendell Porter Weeks
Abstract: Disclosed herein is a method and apparatus for automatic extrudate loading and alignment. An extrudate handling system includes a head end assembly and an imaging device (which may be part of the head end assembly). The imaging device is configured to image an end face of an extrudate, and generate, during translation of the extrudate, an imaging output signal indicative of a rotational position of the end face of the extrudate. The head end assembly includes a rotational effector to rotate the extrudate during translation thereof and a fixed effector rotationally fixed relative to a track. The extrudate handling system is able to determine the rotational position of the web angle of the extrudate and precisely adjust the rotational position while linearly translating the extrudate along the track. The extrudate handling system provides greater accuracy, reduced costs, and improved results.
Type:
Grant
Filed:
February 12, 2020
Date of Patent:
February 13, 2024
Assignee:
Corning Incorporated
Inventors:
Colby William Audinwood, Brian Stephen Banks, Stephen Andrew Campbell, John Christian Duroe, Dustin Andrew Jochum, Anthony Nicholas Rodbourn, Gary Yaw
Abstract: A glass composition includes: greater than or equal to 24 mol % and less than or equal to 60 mol % SiO2; greater than or equal to 23 mol % and less than or equal to 35 mol % Al2O3; greater than or equal to 3.5 mol % and less than or equal to 35 mol % B2O3; greater than 0 mol % and less than or equal to 20 mol % Li2O; greater than or equal to 0 mol % and less than or equal to 10 mol % Na2O; and greater than or equal to 0 mol % and less than or equal to 3 mol % K2O. The sum of Li2O, Na2O, and K2O (i.e., R2O) in the glass composition may be greater than or equal to 12 mol % and less than or equal to 20 mol %.
Type:
Grant
Filed:
August 26, 2021
Date of Patent:
February 13, 2024
Assignee:
Corning Incorporated
Inventors:
Xiaoju Guo, Peter Joseph Lezzi, Jian Luo
Abstract: Methods for limiting bleed-through of aqueous catalyst solutions in ceramic articles are described herein. The methods include applying a hydrophobic cellulose derivative, such as ethylcellulose, to an exterior surface of a fired porous ceramic article. The aqueous catalyst solution is applied to the fired porous ceramic article, such that the hydrophobic cellulose derivative limits bleed-through of the aqueous catalyst solution through at least a portion of the ceramic article. Ceramic articles with skins that limit bleed-through of aqueous catalyst solutions are also described herein.
Abstract: A laminate glass-ceramic article is provided that includes: a core glass layer having a first coefficient of thermal expansion (CTE); and a plurality of clad glass-ceramic layers, each having a CTE that is lower than or equal to the first CTE of the core glass layer. A first of the clad glass-ceramic layers is laminated to a first surface of core glass layer and a second of the clad glass-ceramic layers is laminated to a second surface of the core glass layer. Further, a total thickness of the plurality of clad glass-ceramic layers is from about 0.05 mm to about 0.5 mm. In addition, each of the glass-ceramic layers includes: an alumino-boro-silicate glass, 0 mol %?MoO3?15 mol %, and 0 mol %?WO3?15 mol %, the WO3 (mol %) plus the MoO3 (mol %) is from 0.7 mol % to 19 mol %.
Abstract: A system and method for nitridizing a glass article includes supplying a source of a nitridizing gas including gaseous NH3 to a glass article supported within a furnace assembly and heating the glass article. In some embodiments, the system includes a handle assembly configured to support the glass article within the furnace assembly and a gas supply conduit carried by the handle and configured to supply the nitridizing gas to the glass article. In some embodiments, a method of nitridizing a glass article includes supplying the nitridizing gas such that a residence time of the nitridizing gas at temperatures greater than 500° C. corresponds to a predetermined time period. In some embodiments, a method of nitridizing a glass article includes supplying the nitridizing gas such that the glass articles is exposed to the nitridizing gas within a contact time tc.
Type:
Grant
Filed:
April 23, 2021
Date of Patent:
February 6, 2024
Assignee:
Corning Incorporated
Inventors:
Kenneth Edward Hrdina, Ming-Jun Li, Haitao Zhang
Abstract: A method is provided for manufacturing an article comprising a transparent conductive material, wherein a transparent conductive material (e.g., indium tin oxide) is deposited onto a substrate (e.g., fused silica) by physical vapor deposition, then annealed at high temperature (i.e., at least 450° C.) in a nitrogen atmosphere. The resulting article comprises a transparent conductive material that reduces the trade-off between low resistivity (or sheet resistance) and high near infrared transmission. For example, the transparent conductive material thus obtained may possess a transmission of at least 80% at 1550 nm while having a resistivity of less than or equal to about 5×10?4 Ohm-cm and a Haacke figure of merit of at least about 40×10?4??1. Also provided is a method for modulating the resistivity and/or the near infrared transmission of a transparent conductive material by annealing the transparent conductive material at a high temperature under nitrogen atmosphere.
Abstract: The system and methods for marking an optical fiber with color-coded marks disclosed herein include forming closely spaced multiple ink streams, with at least two of the ink streams having different colors. The optical fiber moves over a fiber path that resides adjacent the ink streams. The fiber path and the ink streams are made to briefly intersect so that the ink streams form on the outer surface of the optical fiber a group of spaced apart individual marks, wherein the group of individual marks constitute a color-coded mark. Repeating this marking process at different times as the fiber moves over the fiber path forms spaced apart color-coded marks along the length of the fiber. Subsequent drying and overcoating of the marks fixes and protects the color-coded marks.
Type:
Grant
Filed:
December 31, 2020
Date of Patent:
February 6, 2024
Assignee:
Corning Incorporated
Inventors:
Aditya Kaimal, Kelvin Nguyen, Darren Andrew Stainer
Abstract: A colored glass article includes greater than or equal to 50 mol % and less than or equal to 80 mol % SiO2; greater than or equal to 7 mol % and less than or equal to 25 mol % Al2O3; greater than or equal to 1 mol % and less than or equal to 15 mol % B2O3; greater than or equal to 5 mol % and less than or equal to 20 mol % Li2O; greater than or equal to 0.5 mol % and less than or equal to 15 mol % Na2O; greater than 0 mol % and less than or equal to 1 mol % K2O; and greater than or equal to 1×10?6 mol % and less than or equal to 1 mol % Au. R2O—Al2O3 is greater than or equal to ?5 mol % and less than or equal to 7 mol %, R2O being the sum of Li2O, Na2O, and K2O.
Type:
Grant
Filed:
January 5, 2023
Date of Patent:
February 6, 2024
Assignee:
Corning Incorporated
Inventors:
Xiaoju Guo, Jill Marie Hall, Karl William Koch, III, Jesse Kohl, Jian Luo, Liping Xiong Smith, Nicole Taylor Wiles
Abstract: A strengthened cover glass or glass-ceramic sheet or article as well as processes and systems for making the strengthened glass or glass-ceramic sheet or article is provided for use in consumer electronic devices. The process comprises cooling the cover glass sheet by non-contact thermal conduction for sufficiently long to fix a surface compression and central tension of the sheet. The process results in thermally strengthened cover glass sheets for use in or on consumer electronic products.
Type:
Grant
Filed:
July 20, 2021
Date of Patent:
February 6, 2024
Assignee:
CORNING INCORPORATED
Inventors:
Peter Joseph Lezzi, Richard Orr Maschmeyer, John Christopher Thomas, Kevin Lee Wasson
Abstract: Honeycomb bodies and methods for treating a honeycomb bodies that include a skin surrounding a matrix of cells, the skin and the matrix of cells comprising a porous inorganic material. Methods include applying a buffer solution to only the porous inorganic material of the skin and coating the porous inorganic material of the skin with an oxide slurry. The oxide slurry includes an oxide or a precursor of the oxide configured to increase the isostatic strength of the honeycomb body. After treatment, the honeycomb body may be dried.
Type:
Grant
Filed:
September 11, 2020
Date of Patent:
February 6, 2024
Assignee:
Corning Incorporated
Inventors:
Jacob George, Mallanagouda Dyamanagouda Patil, Elizabeth Margaret Wheeler
Abstract: A ceramic body exhibiting % P?50%, df?0.36, and a combined weight percentage of crystalline phases containing cordierite and indialite of at least 85 wt %, and up to 10 wt % of a crystalline pseudobrookite structured phase, such as armalcolite. The ceramic body contains, as expressed on an oxide basis, either: 1% wt % to 11% wt % titania and 89% wt % to 99% wt % MgO, Al2O3, and SiO2 that have relative weight ratios of MgO:Al2O3:SiO2 within the field defined by 15.6:34.0:50.4, 12.6:34.0:53.4, 13.9:30.7:55.4, and 16.9:30.7:52.4, or 2.5% to 11% titania and 89% wt % to 97.5% wt % MgO, Al2O3, and SiO2 that have relative weight ratios of MgO:Al2O3:SiO2 within the field defined by 15.6:34.0:50.4, 12.6:34.0:53.4, 12.0:35.7:52.3, and 15.0:35.7:49.3. Batch composition mixtures and methods of manufacturing ceramic bodies using the batch compositions are provided, as are other aspects.
Type:
Grant
Filed:
August 29, 2019
Date of Patent:
February 6, 2024
Assignee:
Corning Incorporated
Inventors:
Huthavahana Kuchibhotla Sarma, Cameron Wayne Tanner
Abstract: A method for plugging a subset of cells of a honeycomb structure that includes: covering a first end face of the honeycomb structure with a mask that comprises a body and a plurality of openings, wherein the plurality of openings of the mask is coincident with a plurality of cells of the honeycomb structure; providing a plug of material upon a film material; applying a force to the film material to push the plug of material through the plurality of openings of the mask and into the plurality of cells of the honeycomb structure; and measuring a pressure within the plurality of cells during the applying step, wherein the applying step further comprises adjusting the force applied to the film material based at least in part on the pressure within the plurality of cells to push the plug of material to a predetermined depth within the plurality of cells.
Type:
Grant
Filed:
July 15, 2019
Date of Patent:
February 6, 2024
Assignee:
Corning Incorporated
Inventors:
Philip Robert LeBlanc, Robert Arthur Mcintosh, Richard Henry Weachock
Abstract: A display backlight unit is disclosed including a glass substrate with a first major surface and a second major surface opposite the first major surface, the first major surface coated with at least one of 3-mercaptopropyl trimethoxysilane, aminopropyl triethoxysilane, or silanated PMMA, and a plurality of PMMA-containing light extraction dots deposited on the coated first major surface.
Type:
Grant
Filed:
February 1, 2021
Date of Patent:
January 30, 2024
Assignee:
CORNING INCORPORATED
Inventors:
Joy Banerjee, Indrani Bhattacharyya, Prantik Mazumder, Wanda Janina Walczak