Patents Assigned to Dow Toray Co., Ltd.
  • Patent number: 10731009
    Abstract: Cured silicone particles are disclosed. The cured silicone particles are obtained by curing a curable silicone composition comprising at least components (A) through (C), wherein components (A) and (B) are polyorganosiloxanes having certain average formulas, and component (C) is a catalyst. The average particle size of the cured silicone particles is from 0.1 to 500 ?m. Related methods and a cosmetic material comprising the cured silicone particles are also disclosed.
    Type: Grant
    Filed: July 22, 2016
    Date of Patent: August 4, 2020
    Assignee: DOW TORAY CO., LTD.
    Inventors: Seiji Hori, Yasue Kanzaki, Yoshitsugu Morita, Mari Wakita
  • Patent number: 10717872
    Abstract: A polyether-polysiloxane block copolymer composition is disclosed. The copolymer composition comprises (A) a polyether-polysiloxane block copolymer having in a molecule structural units as expressed by General Formula (1) below: where a terminal group thereof is an alkenyl group or the like bonded to a polyether portion. The copolymer composition further comprises (B) a liquid monool organic compound, which is (B1) a glycol ether compound having a low degree of polymerization, a terminal hydrogen substituted with a hydrocarbon group, and a secondary alcoholic hydroxyl group provided on another terminal, or (B2) a higher alcohol compound having a branched alkyl group with 12 or more carbon atoms. The copolymer composition generally does not contain a dimethyl polysiloxane at more than the mass of component (A). A manufacturing method, foam stabilizer or the like containing the copolymer composition, and a polyurethane foam are also disclosed.
    Type: Grant
    Filed: April 13, 2016
    Date of Patent: July 21, 2020
    Assignee: DOW TORAY CO., LTD.
    Inventors: Hiroyuki Inagaki, Ikutaro Morikawa, Son Thanh Phan, Seiki Tamura
  • Patent number: 10618255
    Abstract: A flexible laminate for which increased flexibility and improved durability can coexist, and a flexible display provided with same, are disclosed. The flexible laminate has at least one unit of a laminated structure in which two hard layers closely adhere to each other with at least one intermediate layer therebetween. When the flexible laminate is bent, neutral planes are formed inside each of the hard layers that closely adhere to each other with the intermediate layer therebetween. The flexible laminate satisfies the following expression: a×ln(tan ?×ET/0.01)?100. In the expression, a is any value ranging from 200 to 2,000, tan ? represents a loss factor for a substance configuring the intermediate layer, and ET represents an elastic modulus (MPa) of the substance configuring the intermediate layer.
    Type: Grant
    Filed: April 26, 2017
    Date of Patent: April 14, 2020
    Assignees: Dow Toray Co., Ltd., Dow Silicones Corporation
    Inventors: Hojin Choi, Haruhiko Furukawa, Maki Itoh, Jeonggi Kim, Sunny Kim, Haruna Mizuno, Michitaka Suto, Takeaki Tsuda
  • Patent number: 10611877
    Abstract: A curable organopolysiloxane composition comprises: (A) an epoxy group-containing organopolysiloxane represented by the average composition formula: XaR1bSiO(4?a?b)/2 wherein X represents at least one type of epoxy group selected from a glycidoxyalky group, an epoxycycloalkyl alkyl group, and an epoxyalkyl group; R1 represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an aralkyl group, a hydroxyl group, or an alkoxy group; provided at least two X groups are present in a molecule; and “a” and “b” are numbers satisfying: 0<a<1, 0<b<3, and 0.8<(a+b)<3; (B) a compound having at least two mercapto groups in a molecule; and (C) an amine compound not having a N—H bond and/or a phosphine compound not having a P—H bond. The composition has favorable curability even at a relatively low temperature, and forms a cured film having excellent bonding with regard to an object to be coated.
    Type: Grant
    Filed: December 4, 2015
    Date of Patent: April 7, 2020
    Assignee: Dow Toray Co., Ltd.
    Inventors: Takuya Ogawa, Satoshi Onodera
  • Patent number: 10604658
    Abstract: An organic silicon compound is disclosed which is represented by a formula: (R13SiO)3SiR2—[SiR32O]y[SiR32]w—R4—R5, wherein each of R1 and R3 is a group independently selected from the group consisting of alkyl groups, alkenyl groups, aryl groups, aralkyl groups and alkoxy groups having 1 to 20 carbon atoms, R2 is a divalent hydrocarbon group or an oxygen atom, R4 is a divalent hydrocarbon group, or a direct bond to a silicon (Si) atom, R5 is a monovalent group represented by (R6O)qR7(3-q)Si or a monovalent hydrocarbon group having 1 to 20 carbon atoms, and each of R6 and R7 is a group independently selected from the group consisting of alkyl groups, alkenyl groups, aryl groups, aralkyl groups and alkoxy groups having 1 to 20 carbon atoms, and q is an integer between 1 and 3, y is an integer between 0 and 200, and w is 0 or 1.
    Type: Grant
    Filed: August 11, 2014
    Date of Patent: March 31, 2020
    Assignee: Dow Toray Co., Ltd.
    Inventors: Haruhiko Furukawa, Makoto Iwai, Kousei Iwakawa, Eiji Kitaura, Kazuhiro Nishijima, Tadashi Okawa
  • Patent number: 10604612
    Abstract: Disclosed is a curable organopolysiloxane composition, comprising: (A) a curing reactive organopolysiloxane component formed by curing or semi-curing and reacting at least two or more types of organopolysiloxanes in the presence of one or more types of catalysts; and (B) a peroxide. The composition is a non-fluid at 25° C., and the melt viscosity at 100° C. is 8000 Pa·s or lower. A sealing agent comprising the curable organopolysiloxane composition and a cured product of the curable organopolysiloxane composition are also disclosed, along with a method of molding a cured product and a semiconductor device comprising the cured product.
    Type: Grant
    Filed: December 17, 2015
    Date of Patent: March 31, 2020
    Assignee: Dow Toray Co., Ltd.
    Inventors: Toyohiko Fujisawa, Nohno Toda, Ryosuke Yamazaki
  • Patent number: 10604653
    Abstract: Disclosed is an active energy ray curable hot melt silicone composition that is non-flowable at 25° C. and has a viscosity of 1,000 Pa·s or less at 100° C. The active energy ray curable hot melt silicone composition comprises: (A) a mixture of (A1) an organopolysiloxane having an aliphatic unsaturated bond-containing organic group and (A2) an organopolysiloxane optionally having an aliphatic unsaturated bond-containing organic group, (B) a compound having at least two mercapto groups in a molecule, and (C) a photoradical initiator. A cured product and a method of making a film are also disclosed.
    Type: Grant
    Filed: October 12, 2016
    Date of Patent: March 31, 2020
    Assignee: Dow Toray Co., Ltd.
    Inventors: Ryota Dogen, Haruna Yamazaki, Shin Yoshida, Makoto Yoshitake
  • Patent number: 10584223
    Abstract: The present invention provides an optical member comprising a silicone material having excellent antifouling property while having good light transmittance, heat resistance, and strength, and an optical semiconductor device and illumination apparatus having excellent antifouling property. The present invention is an optical member comprising a silicone material containing a fluorinated surface, the proportion of F atoms being from 0.1 to 45 at % and/or the ratio of F atoms relative to C atoms being from 0.01 to 1.00 in the atomic composition percentage according to X-ray photoelectron spectroscopy (XPS) of the fluorinated surface.
    Type: Grant
    Filed: October 16, 2015
    Date of Patent: March 10, 2020
    Assignees: Dow Toray Co., Ltd., Dow Silicones Corporation
    Inventors: Christopher S. McMillan, Kazutaka Mori, Hiroaki Yoshida, Shin Yoshida
  • Publication number: 20190375908
    Abstract: A sponge-forming liquid silicone rubber composition is provided. The composition generally maintains a stable emulsified state, can form a low-density silicone rubber sponge having a uniform and fine open-cell foam structure even when a coating or molding method involving shearing force and thin layer formation is used, is less likely to contract during curing, and that forms a silicone rubber sponge having a density close to the density designed on the basis of water content. A low-density silicone rubber sponge material using the sponge-forming liquid silicone rubber composition is also provided. The sponge-forming liquid silicone rubber composition comprises (A) an alkenyl group-containing organopolysiloxane, (B) an organopolysiloxane having a silicon atom-bonded hydrogen atom, (C) a mixture of water and an inorganic thickener, (D) an emulsifier, and (E) a hydrosilylation reaction catalyst. The contained amount of the component (C) in the entire composition is 70 mass % or more.
    Type: Application
    Filed: November 21, 2017
    Publication date: December 12, 2019
    Applicant: DOW TORAY CO., LTD.
    Inventors: Shuji ENDO, Takatoshi TOYAMA, Tsugio NOZOE
  • Patent number: 10494484
    Abstract: The present invention provides a release control agent for producing a release agent composition that has sufficient releasability from a silicone-based adhesive agent and that exhibits excellent releasability even when pressure is applied to a cured product; a silicone release agent composition containing such a release control agent; a release sheet having a cured layer formed from the cured product of the silicone release agent composition; and a laminated body having the release sheet and an adhesive layer. The present invention includes a release control agent containing from 15 to 29 mol % of a fluorine atom-containing organic group in each molecule, and an organopolysiloxane having no hydrosilylation reactive group; a silicone release agent composition containing such a release control agent; a release sheet; and a laminated body.
    Type: Grant
    Filed: July 9, 2015
    Date of Patent: December 3, 2019
    Assignee: Dow Toray Co., Ltd.
    Inventors: Seiji Hori, Haruna Mizuno, Akihiro Nakamura, Hidefumi Tanaka
  • Patent number: 10479910
    Abstract: A primer composition is provided. The primer composition comprises: (A) an organosiloxane block copolymer represented by the average unit formula: (R12SiO2/2)a(R2SiO3/2)b, wherein each R1 and R2 is independently an alkyl group having 1 to 12 carbon atoms, an aryl group having 6 to 20 carbon atoms, or an aralkyl group having 7 to 20 carbon atoms, “a” is a number in the range of 0.40 to 0.90, “b” is a number in the range of 0.10 to 0.60, and “a+b”=1.00, and having 0.5 to 35.0 mol % of silicon atom-bonded hydroxyl groups or silicon atom-bonded alkoxy groups, in which resinous siloxane blocks are connected by linear siloxane blocks; (B) a curing catalyst; and (C) an organic solvent. The primer composition improves the adhesion of silicone-cured products to base materials of optical semiconductor elements, package materials, substrates etc., and can suppress peeling or cracking caused by heat cycles.
    Type: Grant
    Filed: February 23, 2016
    Date of Patent: November 19, 2019
    Assignee: Dow Toray Co., Ltd.
    Inventors: Ryosuke Yamazaki, Hiroaki Yoshida, Shin Yoshida
  • Patent number: 10472511
    Abstract: Provided are a novel composite material in which a fluoropolymer and a fluorine-containing organopolysiloxane are dispersed in a mutually inseparable state, a method for producing the same, use of the same, and a precursor composition. The fluoropolymer-fluorine-containing organopolysiloxane composite material comprises: (A) one or more fluoropolymers selected from the group comprising polyvinylidene fluoride and polyvinylidene fluoride copolymers; (B) an organopolysiloxane crosslinking reaction product having a fluorine atom-containing organic group, obtained by subjecting to a crosslinking reaction a reactive organopolysiloxane having a fluorine atom-containing organic group and one or more reactive functional groups in the molecule capable of crosslinking between molecules by the reaction of these reactive functional groups; and optionally (X) fillers and/or other additives besides component (A) and component (B).
    Type: Grant
    Filed: August 26, 2015
    Date of Patent: November 12, 2019
    Assignee: DOW TORAY CO., LTD.
    Inventors: Hiroshi Fukui, Takuya Ogawa
  • Patent number: 10385233
    Abstract: The present disclosure relates to a primer composition. The primer composition comprises: a tert butyl acetate solvent; an organometallic reagent selected from organotitanates, organozirconates, aluminum organometallic compounds, and any combination thereof; an organotin compound; a silane with at least 3 hydrolyzable groups; and a polyorganosiloxane resin. Optionally, the primer composition further comprises a second solvent different from the tert butyl acetate solvent.
    Type: Grant
    Filed: October 11, 2013
    Date of Patent: August 20, 2019
    Assignees: Dow Silicones Corporation, Dow Toray Co., Ltd.
    Inventors: Hiroshi Adachi, Brent D. Dull, Thomas W. Galbraith, Kenji Ota
  • Patent number: 10370565
    Abstract: A curable organopolysiloxane composition containing a fluoroalkyl group, the curable organopolysiloxane composition containing: (A) (R13SiO1/2)a(R22SiO)b(R3SiO3/2)c(SiO2)d where 10 mol % or more of substitution groups are fluoroalkyl groups, other substitution groups are alkyl groups or the like, and a, b, c, and d represent a number satisfying 0?a?0.5, 0?b?0.7, 0?c?1, 0?d?0.7, 0.3?c+d?1, and a+b+c+d=1; (B) R43Si(OSiR42)eOSiR43 where 5 mol % or more of substitution groups are fluoroalkyl groups, and of other R4s, at least two are alkenyl groups; (C) is an organohydrogen polysiloxane; (D) is an effective amount of a hydrosilylation reaction catalyst; and (E) is a solvent. The curable composition provides a high dielectric constant and favorable transparency. A pressure-sensitive adhesive as a cured product thereof, and a display device, are also provided.
    Type: Grant
    Filed: December 11, 2015
    Date of Patent: August 6, 2019
    Assignee: Dow Toray Co., Ltd.
    Inventors: Hiroshi Fukui, Toru Masatomi, Takuya Ogawa
  • Patent number: 10357947
    Abstract: A curable organopolysiloxane composition containing a fluoroalkyl group is disclosed. The composition comprises: (A) an organopolysiloxane containing a fluoroalkyl group, having at least two alkenyl groups in a molecule, where 10 mol % or more of all substitution groups on the silicon atoms is a fluoroalkyl group, and the average degree of polymerization is less than 150; (B) an organohydrogen polysiloxane having at least two silicon-bonded hydrogen atoms in a molecule at an amount where the silicon-bonded hydrogen atoms in the component is 0.1 to 1.0 mol with regard to a total of 1 mol of the alkenyl groups in component (A); (C) an effective amount of a hydrosilylation reaction catalyst; and optionally, (D) a solvent. The composition generally has a high dielectric constant and favorable transparency. A cured product and applications of the composition and the cured product thereof are also disclosed.
    Type: Grant
    Filed: March 9, 2016
    Date of Patent: July 23, 2019
    Assignee: DOW TORAY CO., LTD.
    Inventors: Hiroshi Fukui, Toru Masatomi, Takuya Ogawa
  • Patent number: 10358542
    Abstract: An adhesion promoter that can achieve excellent initial adhesion improvement effects towards various types of substrates, a curable organopolysiloxane composition containing the adhesion promoter, and a protective agent or adhesive composition for electric and electronic components, are provided. The adhesion promoter comprises the following components (A) to (C) in a specific weight ratio: (A) a reaction mixture of an organoalkoxysilane having an amino group and an organoalkoxysilane having an epoxy group; (B) an organic compound having at least two alkoxysilyl groups in a molecule and having a bond other than a silicone-oxygen bond between these silyl groups; and (C) a silane containing an epoxy group or a partially hydrolyzed condensate thereof.
    Type: Grant
    Filed: March 26, 2015
    Date of Patent: July 23, 2019
    Assignee: DOW TORAY CO., LTD.
    Inventors: Toyohiko Fujisawa, Harumi Kodama
  • Patent number: 10316148
    Abstract: An organopolysiloxane represented by the following average unit formula: (R1SiO3/2)a(XR22SiO1/2)b(O1/2SiR22—Y—R22SiO1/2)c is provided. R1 and R2 each individually represent a C1-C20 alkyl group, C6-C20 aryl group, or C7-C20 aralkyl group. X represents a C2-C12 alkenyl group or a siloxane residue and Y represents a siloxane linking group. Alternatively X represents a C2-C12 alkenyl group or a silphenylene residue and Y represents a silphenylene linking group. Subscript “a” is a number in a range of 0.65 to 0.90, “b” is a number in a range of 0.10 to 0.35, “c” is a number in a range of 0 to 0.10, and “a”+“b”+“c”=1.00. The organopolysiloxane has a siloxane residue or silphenylene residue having a silicon atom-bonded hydrogen atom in an organopolysiloxane resin block. The organopolysiloxane generally exhibits high refractive index and high transparency as well as excellent handleability.
    Type: Grant
    Filed: March 11, 2016
    Date of Patent: June 11, 2019
    Assignee: Dow Toray Co., Ltd.
    Inventor: Yoshitsugu Morita