Patents Assigned to Dow Toray Co., Ltd.
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Patent number: 10731009Abstract: Cured silicone particles are disclosed. The cured silicone particles are obtained by curing a curable silicone composition comprising at least components (A) through (C), wherein components (A) and (B) are polyorganosiloxanes having certain average formulas, and component (C) is a catalyst. The average particle size of the cured silicone particles is from 0.1 to 500 ?m. Related methods and a cosmetic material comprising the cured silicone particles are also disclosed.Type: GrantFiled: July 22, 2016Date of Patent: August 4, 2020Assignee: DOW TORAY CO., LTD.Inventors: Seiji Hori, Yasue Kanzaki, Yoshitsugu Morita, Mari Wakita
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Patent number: 10717872Abstract: A polyether-polysiloxane block copolymer composition is disclosed. The copolymer composition comprises (A) a polyether-polysiloxane block copolymer having in a molecule structural units as expressed by General Formula (1) below: where a terminal group thereof is an alkenyl group or the like bonded to a polyether portion. The copolymer composition further comprises (B) a liquid monool organic compound, which is (B1) a glycol ether compound having a low degree of polymerization, a terminal hydrogen substituted with a hydrocarbon group, and a secondary alcoholic hydroxyl group provided on another terminal, or (B2) a higher alcohol compound having a branched alkyl group with 12 or more carbon atoms. The copolymer composition generally does not contain a dimethyl polysiloxane at more than the mass of component (A). A manufacturing method, foam stabilizer or the like containing the copolymer composition, and a polyurethane foam are also disclosed.Type: GrantFiled: April 13, 2016Date of Patent: July 21, 2020Assignee: DOW TORAY CO., LTD.Inventors: Hiroyuki Inagaki, Ikutaro Morikawa, Son Thanh Phan, Seiki Tamura
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Patent number: 10618255Abstract: A flexible laminate for which increased flexibility and improved durability can coexist, and a flexible display provided with same, are disclosed. The flexible laminate has at least one unit of a laminated structure in which two hard layers closely adhere to each other with at least one intermediate layer therebetween. When the flexible laminate is bent, neutral planes are formed inside each of the hard layers that closely adhere to each other with the intermediate layer therebetween. The flexible laminate satisfies the following expression: a×ln(tan ?×ET/0.01)?100. In the expression, a is any value ranging from 200 to 2,000, tan ? represents a loss factor for a substance configuring the intermediate layer, and ET represents an elastic modulus (MPa) of the substance configuring the intermediate layer.Type: GrantFiled: April 26, 2017Date of Patent: April 14, 2020Assignees: Dow Toray Co., Ltd., Dow Silicones CorporationInventors: Hojin Choi, Haruhiko Furukawa, Maki Itoh, Jeonggi Kim, Sunny Kim, Haruna Mizuno, Michitaka Suto, Takeaki Tsuda
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Patent number: 10611877Abstract: A curable organopolysiloxane composition comprises: (A) an epoxy group-containing organopolysiloxane represented by the average composition formula: XaR1bSiO(4?a?b)/2 wherein X represents at least one type of epoxy group selected from a glycidoxyalky group, an epoxycycloalkyl alkyl group, and an epoxyalkyl group; R1 represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an aralkyl group, a hydroxyl group, or an alkoxy group; provided at least two X groups are present in a molecule; and “a” and “b” are numbers satisfying: 0<a<1, 0<b<3, and 0.8<(a+b)<3; (B) a compound having at least two mercapto groups in a molecule; and (C) an amine compound not having a N—H bond and/or a phosphine compound not having a P—H bond. The composition has favorable curability even at a relatively low temperature, and forms a cured film having excellent bonding with regard to an object to be coated.Type: GrantFiled: December 4, 2015Date of Patent: April 7, 2020Assignee: Dow Toray Co., Ltd.Inventors: Takuya Ogawa, Satoshi Onodera
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Patent number: 10604658Abstract: An organic silicon compound is disclosed which is represented by a formula: (R13SiO)3SiR2—[SiR32O]y[SiR32]w—R4—R5, wherein each of R1 and R3 is a group independently selected from the group consisting of alkyl groups, alkenyl groups, aryl groups, aralkyl groups and alkoxy groups having 1 to 20 carbon atoms, R2 is a divalent hydrocarbon group or an oxygen atom, R4 is a divalent hydrocarbon group, or a direct bond to a silicon (Si) atom, R5 is a monovalent group represented by (R6O)qR7(3-q)Si or a monovalent hydrocarbon group having 1 to 20 carbon atoms, and each of R6 and R7 is a group independently selected from the group consisting of alkyl groups, alkenyl groups, aryl groups, aralkyl groups and alkoxy groups having 1 to 20 carbon atoms, and q is an integer between 1 and 3, y is an integer between 0 and 200, and w is 0 or 1.Type: GrantFiled: August 11, 2014Date of Patent: March 31, 2020Assignee: Dow Toray Co., Ltd.Inventors: Haruhiko Furukawa, Makoto Iwai, Kousei Iwakawa, Eiji Kitaura, Kazuhiro Nishijima, Tadashi Okawa
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Patent number: 10604612Abstract: Disclosed is a curable organopolysiloxane composition, comprising: (A) a curing reactive organopolysiloxane component formed by curing or semi-curing and reacting at least two or more types of organopolysiloxanes in the presence of one or more types of catalysts; and (B) a peroxide. The composition is a non-fluid at 25° C., and the melt viscosity at 100° C. is 8000 Pa·s or lower. A sealing agent comprising the curable organopolysiloxane composition and a cured product of the curable organopolysiloxane composition are also disclosed, along with a method of molding a cured product and a semiconductor device comprising the cured product.Type: GrantFiled: December 17, 2015Date of Patent: March 31, 2020Assignee: Dow Toray Co., Ltd.Inventors: Toyohiko Fujisawa, Nohno Toda, Ryosuke Yamazaki
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Patent number: 10604653Abstract: Disclosed is an active energy ray curable hot melt silicone composition that is non-flowable at 25° C. and has a viscosity of 1,000 Pa·s or less at 100° C. The active energy ray curable hot melt silicone composition comprises: (A) a mixture of (A1) an organopolysiloxane having an aliphatic unsaturated bond-containing organic group and (A2) an organopolysiloxane optionally having an aliphatic unsaturated bond-containing organic group, (B) a compound having at least two mercapto groups in a molecule, and (C) a photoradical initiator. A cured product and a method of making a film are also disclosed.Type: GrantFiled: October 12, 2016Date of Patent: March 31, 2020Assignee: Dow Toray Co., Ltd.Inventors: Ryota Dogen, Haruna Yamazaki, Shin Yoshida, Makoto Yoshitake
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Patent number: 10584223Abstract: The present invention provides an optical member comprising a silicone material having excellent antifouling property while having good light transmittance, heat resistance, and strength, and an optical semiconductor device and illumination apparatus having excellent antifouling property. The present invention is an optical member comprising a silicone material containing a fluorinated surface, the proportion of F atoms being from 0.1 to 45 at % and/or the ratio of F atoms relative to C atoms being from 0.01 to 1.00 in the atomic composition percentage according to X-ray photoelectron spectroscopy (XPS) of the fluorinated surface.Type: GrantFiled: October 16, 2015Date of Patent: March 10, 2020Assignees: Dow Toray Co., Ltd., Dow Silicones CorporationInventors: Christopher S. McMillan, Kazutaka Mori, Hiroaki Yoshida, Shin Yoshida
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Publication number: 20190375908Abstract: A sponge-forming liquid silicone rubber composition is provided. The composition generally maintains a stable emulsified state, can form a low-density silicone rubber sponge having a uniform and fine open-cell foam structure even when a coating or molding method involving shearing force and thin layer formation is used, is less likely to contract during curing, and that forms a silicone rubber sponge having a density close to the density designed on the basis of water content. A low-density silicone rubber sponge material using the sponge-forming liquid silicone rubber composition is also provided. The sponge-forming liquid silicone rubber composition comprises (A) an alkenyl group-containing organopolysiloxane, (B) an organopolysiloxane having a silicon atom-bonded hydrogen atom, (C) a mixture of water and an inorganic thickener, (D) an emulsifier, and (E) a hydrosilylation reaction catalyst. The contained amount of the component (C) in the entire composition is 70 mass % or more.Type: ApplicationFiled: November 21, 2017Publication date: December 12, 2019Applicant: DOW TORAY CO., LTD.Inventors: Shuji ENDO, Takatoshi TOYAMA, Tsugio NOZOE
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Patent number: 10494484Abstract: The present invention provides a release control agent for producing a release agent composition that has sufficient releasability from a silicone-based adhesive agent and that exhibits excellent releasability even when pressure is applied to a cured product; a silicone release agent composition containing such a release control agent; a release sheet having a cured layer formed from the cured product of the silicone release agent composition; and a laminated body having the release sheet and an adhesive layer. The present invention includes a release control agent containing from 15 to 29 mol % of a fluorine atom-containing organic group in each molecule, and an organopolysiloxane having no hydrosilylation reactive group; a silicone release agent composition containing such a release control agent; a release sheet; and a laminated body.Type: GrantFiled: July 9, 2015Date of Patent: December 3, 2019Assignee: Dow Toray Co., Ltd.Inventors: Seiji Hori, Haruna Mizuno, Akihiro Nakamura, Hidefumi Tanaka
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Patent number: 10479910Abstract: A primer composition is provided. The primer composition comprises: (A) an organosiloxane block copolymer represented by the average unit formula: (R12SiO2/2)a(R2SiO3/2)b, wherein each R1 and R2 is independently an alkyl group having 1 to 12 carbon atoms, an aryl group having 6 to 20 carbon atoms, or an aralkyl group having 7 to 20 carbon atoms, “a” is a number in the range of 0.40 to 0.90, “b” is a number in the range of 0.10 to 0.60, and “a+b”=1.00, and having 0.5 to 35.0 mol % of silicon atom-bonded hydroxyl groups or silicon atom-bonded alkoxy groups, in which resinous siloxane blocks are connected by linear siloxane blocks; (B) a curing catalyst; and (C) an organic solvent. The primer composition improves the adhesion of silicone-cured products to base materials of optical semiconductor elements, package materials, substrates etc., and can suppress peeling or cracking caused by heat cycles.Type: GrantFiled: February 23, 2016Date of Patent: November 19, 2019Assignee: Dow Toray Co., Ltd.Inventors: Ryosuke Yamazaki, Hiroaki Yoshida, Shin Yoshida
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Patent number: 10472511Abstract: Provided are a novel composite material in which a fluoropolymer and a fluorine-containing organopolysiloxane are dispersed in a mutually inseparable state, a method for producing the same, use of the same, and a precursor composition. The fluoropolymer-fluorine-containing organopolysiloxane composite material comprises: (A) one or more fluoropolymers selected from the group comprising polyvinylidene fluoride and polyvinylidene fluoride copolymers; (B) an organopolysiloxane crosslinking reaction product having a fluorine atom-containing organic group, obtained by subjecting to a crosslinking reaction a reactive organopolysiloxane having a fluorine atom-containing organic group and one or more reactive functional groups in the molecule capable of crosslinking between molecules by the reaction of these reactive functional groups; and optionally (X) fillers and/or other additives besides component (A) and component (B).Type: GrantFiled: August 26, 2015Date of Patent: November 12, 2019Assignee: DOW TORAY CO., LTD.Inventors: Hiroshi Fukui, Takuya Ogawa
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Patent number: 10385233Abstract: The present disclosure relates to a primer composition. The primer composition comprises: a tert butyl acetate solvent; an organometallic reagent selected from organotitanates, organozirconates, aluminum organometallic compounds, and any combination thereof; an organotin compound; a silane with at least 3 hydrolyzable groups; and a polyorganosiloxane resin. Optionally, the primer composition further comprises a second solvent different from the tert butyl acetate solvent.Type: GrantFiled: October 11, 2013Date of Patent: August 20, 2019Assignees: Dow Silicones Corporation, Dow Toray Co., Ltd.Inventors: Hiroshi Adachi, Brent D. Dull, Thomas W. Galbraith, Kenji Ota
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Patent number: 10370565Abstract: A curable organopolysiloxane composition containing a fluoroalkyl group, the curable organopolysiloxane composition containing: (A) (R13SiO1/2)a(R22SiO)b(R3SiO3/2)c(SiO2)d where 10 mol % or more of substitution groups are fluoroalkyl groups, other substitution groups are alkyl groups or the like, and a, b, c, and d represent a number satisfying 0?a?0.5, 0?b?0.7, 0?c?1, 0?d?0.7, 0.3?c+d?1, and a+b+c+d=1; (B) R43Si(OSiR42)eOSiR43 where 5 mol % or more of substitution groups are fluoroalkyl groups, and of other R4s, at least two are alkenyl groups; (C) is an organohydrogen polysiloxane; (D) is an effective amount of a hydrosilylation reaction catalyst; and (E) is a solvent. The curable composition provides a high dielectric constant and favorable transparency. A pressure-sensitive adhesive as a cured product thereof, and a display device, are also provided.Type: GrantFiled: December 11, 2015Date of Patent: August 6, 2019Assignee: Dow Toray Co., Ltd.Inventors: Hiroshi Fukui, Toru Masatomi, Takuya Ogawa
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Patent number: 10357947Abstract: A curable organopolysiloxane composition containing a fluoroalkyl group is disclosed. The composition comprises: (A) an organopolysiloxane containing a fluoroalkyl group, having at least two alkenyl groups in a molecule, where 10 mol % or more of all substitution groups on the silicon atoms is a fluoroalkyl group, and the average degree of polymerization is less than 150; (B) an organohydrogen polysiloxane having at least two silicon-bonded hydrogen atoms in a molecule at an amount where the silicon-bonded hydrogen atoms in the component is 0.1 to 1.0 mol with regard to a total of 1 mol of the alkenyl groups in component (A); (C) an effective amount of a hydrosilylation reaction catalyst; and optionally, (D) a solvent. The composition generally has a high dielectric constant and favorable transparency. A cured product and applications of the composition and the cured product thereof are also disclosed.Type: GrantFiled: March 9, 2016Date of Patent: July 23, 2019Assignee: DOW TORAY CO., LTD.Inventors: Hiroshi Fukui, Toru Masatomi, Takuya Ogawa
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Patent number: 10358542Abstract: An adhesion promoter that can achieve excellent initial adhesion improvement effects towards various types of substrates, a curable organopolysiloxane composition containing the adhesion promoter, and a protective agent or adhesive composition for electric and electronic components, are provided. The adhesion promoter comprises the following components (A) to (C) in a specific weight ratio: (A) a reaction mixture of an organoalkoxysilane having an amino group and an organoalkoxysilane having an epoxy group; (B) an organic compound having at least two alkoxysilyl groups in a molecule and having a bond other than a silicone-oxygen bond between these silyl groups; and (C) a silane containing an epoxy group or a partially hydrolyzed condensate thereof.Type: GrantFiled: March 26, 2015Date of Patent: July 23, 2019Assignee: DOW TORAY CO., LTD.Inventors: Toyohiko Fujisawa, Harumi Kodama
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Patent number: 10316148Abstract: An organopolysiloxane represented by the following average unit formula: (R1SiO3/2)a(XR22SiO1/2)b(O1/2SiR22—Y—R22SiO1/2)c is provided. R1 and R2 each individually represent a C1-C20 alkyl group, C6-C20 aryl group, or C7-C20 aralkyl group. X represents a C2-C12 alkenyl group or a siloxane residue and Y represents a siloxane linking group. Alternatively X represents a C2-C12 alkenyl group or a silphenylene residue and Y represents a silphenylene linking group. Subscript “a” is a number in a range of 0.65 to 0.90, “b” is a number in a range of 0.10 to 0.35, “c” is a number in a range of 0 to 0.10, and “a”+“b”+“c”=1.00. The organopolysiloxane has a siloxane residue or silphenylene residue having a silicon atom-bonded hydrogen atom in an organopolysiloxane resin block. The organopolysiloxane generally exhibits high refractive index and high transparency as well as excellent handleability.Type: GrantFiled: March 11, 2016Date of Patent: June 11, 2019Assignee: Dow Toray Co., Ltd.Inventor: Yoshitsugu Morita