Patents Assigned to Ethox Chemicals LLC
  • Patent number: 9518212
    Abstract: Liquid hydrocarbons are gelled by the introduction of a phosphate ester and a crosslinking agent for use in oil recovery. Generally a proppant, delayed gel breaker and other modifiers are added to the gelled hydrocarbon to improve the oil recovery process. The phosphate ester used in this method and composition for oil recovery has low volatility and good stability during hydrocarbon distillation resulting in improved distillation efficiency in a refinery.
    Type: Grant
    Filed: February 18, 2013
    Date of Patent: December 13, 2016
    Assignee: Ethox Chemicals, LLC
    Inventors: Emil Delgado, Bradley Keown
  • Patent number: 9487698
    Abstract: The invention provides compounds having the general structure: wherein R and R? are independently selected from the group consisting of H, C1-24 alkyl, aryl, C1-24 alkylaryl, aryl(C1-24)alkyl, —C(?O)—R1 (esters), C(?O)—NHR1 (urethanes), or C(?O)—O—R1 (carbonates) wherein R1 is selected from the group consisting of C1-24 alkyl, aryl, C1-24 alkylaryl, C1-24 arylalkyl; A is an organic moiety derived from the group consisting of alkylene oxides having 4-12 carbon atoms and aryl epoxides having 8-12 carbon atoms; x=1-300; y=0-200; z=0-200; and with the proviso that R and R? can not be H or ether functionality at the same time. The compounds are useful for improving the water transport characteristics of hydrophobic surfaces.
    Type: Grant
    Filed: January 23, 2008
    Date of Patent: November 8, 2016
    Assignee: Ethox Chemicals, LLC
    Inventors: Charles Francis Palmer, Jr., Calvin M. Wicker, Jr.
  • Patent number: 9441089
    Abstract: The present invention relates to novel dispersants based on reaction products of two and one moles respectively of the branched ester alcohol or alkokylated ester alcohol with maleic anhydride that has been subjected to a further sulfonation reaction. The compounds are useful as dispersing and wetting agents. The invention further relates to the use of the dispersants of the invention to produce stable aqueous dispersions of high performance thermoplastic polymers.
    Type: Grant
    Filed: March 17, 2014
    Date of Patent: September 13, 2016
    Assignee: Ethox Chemicals, LLC
    Inventor: James T. Tanner
  • Patent number: 9409852
    Abstract: The invention provides a compound of the formula: wherein Ar is selected from the group consisting of aryl, monosubstituted aryl and polysubstituted aryl, heteroaryl, monosubstituted heteroaryl and polysubstituted heteroaryl; Ar? is selected from the group consisting of aryl, monosubstituted aryl and polysubstituted aryl, heteroaryl, monosubstituted heteroaryl and polysubstituted heteroaryl; R is an alkylene radical having 2-20 carbon atoms; and n=1-20. The compounds of the invention are used with polymer resins to enhance their gas barrier properties.
    Type: Grant
    Filed: September 27, 2013
    Date of Patent: August 9, 2016
    Assignee: ETHOX CHEMICALS, LLC
    Inventor: James T Tanner
  • Patent number: 9376647
    Abstract: The present invention relates to novel non-aqueous gels of natural oils and their derivatives and provides a novel process for the gelation of natural oils and their derivatives that does not require the addition of gellants or the irreversible heat bodying of the oil. The gels and method of the present invention are applicable to a wide range of natural oils, and the method is easily tailored to provide thermoreversible gels of any desired viscosity. The natural oil based gels of the present invention and the method of their preparation have many advantages over the prior art. The natural oil based gels provided have exemplary properties and find use in a variety of applications.
    Type: Grant
    Filed: February 25, 2013
    Date of Patent: June 28, 2016
    Assignee: Ethox Chemicals, LLC
    Inventor: James T. Tanner
  • Patent number: 9371435
    Abstract: The invention provides a composition comprising: (a) about 0% to 99% by weight of at least one resin wherein the resin is selected from the group consisting of epoxy, latex, polyurethane, polyurea, polyspartic, or alkyd resins; (b) about 1%-99% by weight of tristyrenated phenol or distyrenated phenol; and (c) optionally about 2% to 98% by weight of an additional solvent.
    Type: Grant
    Filed: April 22, 2014
    Date of Patent: June 21, 2016
    Assignee: Ethox Chemicals, LLC
    Inventors: Charles Francis Palmer, Jr., Gerald Vandezande
  • Patent number: 9309376
    Abstract: Waterborne coatings are described having an acceptable balance of properties both during the storage of coating, application and drying. The period in which irregularities in a freshly applied coating can be repaired without resulting in brush marks is referred to as the open time. Aqueous coatings generally employ dispersed high molecular weight polymers as binders. These binders often provide short open times when the coating is dried since the dispersed polymer particles tend to be immobilized quickly in the edge region of an applied coating. As a result, the viscosity of the coating increases rapidly, which leads to a limited window of workability. The instant invention provides additives that are not volatile but that will extend the time that the film is malleable after after it is applied without interfering with other attributes, such as the resistance of the coating to freezing while in the can prior to application.
    Type: Grant
    Filed: March 10, 2013
    Date of Patent: April 12, 2016
    Assignee: Ethox Chemicals, LLC
    Inventors: Charles Francis Palmer, Jr., Lester Arnold Haney, II, Calvin M. Wicker, Jr.
  • Patent number: 9255206
    Abstract: An aqueous alkyd resin coating composition, comprising (a) at least one alkyd resin as a dispersed phase; (b) an emulsifier based on styrenated phenols that have been converted into reactive surfactants by first reaction with one or more equivalents of an allyl glycidyl ether to provide pendant allyl groups and then oxyalkylated and (c) water. The invention also provides a method for preparing these aqueous alkyd resin coating compositions from solvent borne alkyd compositions.
    Type: Grant
    Filed: March 17, 2014
    Date of Patent: February 9, 2016
    Assignee: Ethox Chemicals LLC
    Inventors: Charles Francis Palmer, Jr., Lester A Haney, II
  • Patent number: 9051341
    Abstract: The present invention provides reactive surfactants of the formula R1O—(CH2CHR2O)x—(CH2CH2O)y—(CH2CHR3O)z—R4 where R1 is either alkyl, aryl, alkylaryl, or aralkylaryl of 8-30 carbon atoms, R2 is —CH2OCH2CH?CH2 (AGE); R3 is either H, CH3, or CH2CH3; R4 is H or —SO3M or —PO3M where M is H or K, Na, NH4, NR4, alkanolamine, or other cationic species and x=2-100; y=4-200 and z=0-50.
    Type: Grant
    Filed: August 29, 2012
    Date of Patent: June 9, 2015
    Assignee: ETHOX CHEMICALS LLC
    Inventor: Charles Francis Palmer, Jr.
  • Patent number: 9023943
    Abstract: The present invention relates to the use of Styrenated Phenol Ethoxylates as surfactants in emulsion polymerization. The present invention further relates to the use of both anionic and nonionic Styrenated Phenol Ethoxylates in emulsion polymerization. Latexes with small average particle and narrow particle size distributions are obtained. Prepared latexes also have low coagulum levels and exhibit excellent mechanical and chemical stability.
    Type: Grant
    Filed: November 28, 2011
    Date of Patent: May 5, 2015
    Assignee: Ethox Chemicals LLC
    Inventors: Lawrence C. Davis, Edward R. Godwin, Charles V. Hinton, James T. Tanner
  • Publication number: 20140329935
    Abstract: The invention provides a method for forming a TiO2-latex composite particle dispersion comprising combining an aqueous TiO2 dispersion with a latex manufactured with a phosphate-containing ethylenically unsaturated reactive surfactant. The dispersions have improved opacity or hiding.
    Type: Application
    Filed: May 6, 2013
    Publication date: November 6, 2014
    Applicant: ETHOX CHEMICALS, LLC
    Inventors: Charles Francis Palmer, JR., Gerald Vandezande
  • Patent number: 8815007
    Abstract: This invention relates to novel compounds derived from the reaction of diamines or polyamines with alkylene oxides. The invention also relates to novel compounds derived from the reaction of amine terminated polyethers with epoxide functional compounds. The novel compounds of the invention are particularly useful as wetting and foam control agents. The disclosed compounds exhibit exceptional antifoaming and defoaming activity while simultaneously reducing the dynamic surface tension when incorporated at low levels in water-based systems.
    Type: Grant
    Filed: June 4, 2012
    Date of Patent: August 26, 2014
    Assignee: Ethox Chemicals, LLC
    Inventors: James T. Tanner, Charles F. Palmer, Jr., Calvin M. Wicker, Jr.
  • Publication number: 20140235512
    Abstract: Liquid hydrocarbons are gelled by the introduction of a phosphate ester and a crosslinking agent for use in oil recovery. Generally a proppant, delayed gel breaker and other modifiers are added to the gelled hydrocarbon to improve the oil recovery process. The phosphate ester used in this method and composition for oil recovery has low volatility and good stability during hydrocarbon distillation resulting in improved distillation efficiency in a refinery.
    Type: Application
    Filed: February 18, 2013
    Publication date: August 21, 2014
    Applicant: Ethox Chemicals, LLC.
    Inventors: Emil Delgado, Bradley Keown
  • Patent number: 8377854
    Abstract: Liquid hydrocarbons are gelled by the introduction of a phosphate ester and a crosslinking agent for use in oil recovery. Generally a proppant, delayed gel breaker and other modifiers are added to the gelled hydrocarbon to improve the oil recovery process. The phosphate ester used in this method and composition for oil recovery has low volatility and good stability during hydrocarbon distillation resulting in improved distillation efficiency in a refinery.
    Type: Grant
    Filed: November 23, 2009
    Date of Patent: February 19, 2013
    Assignee: Ethox Chemicals LLC
    Inventors: Emil Delgado, Bradley Keown
  • Publication number: 20120318158
    Abstract: Embodiments of the present invention provide a composition useful as an additive to a printing ink. In one embodiment a composition is used that includes a biologically derived base material formed from one or more saturated or unsaturated straight or branched chain triglycerides or combinations thereof, wherein the triglycerides are partially to fully hydrogenated and have a viscosity between about 50 and about 200,000 centipoise at temperatures about 72 degrees Fahrenheit. In another embodiment, the composition further includes a finely divided additive selected from the group consisting of polytetrafluoroethylene or hydrogenated triglycerides in an intimate admixture with the base material. Other aspects relate to a method of making an ink additive and method for printing paper stock by letter press or lithography.
    Type: Application
    Filed: August 26, 2012
    Publication date: December 20, 2012
    Applicant: Ethox Chemicals, LLC
    Inventors: Calvin M. Wicker, JR., Bharat Desai, Paul Sullivan
  • Publication number: 20120238483
    Abstract: This invention relates to novel compounds derived from the reaction of diamines or polyamines with alkylene oxides. The invention also relates to novel compounds derived from the reaction of amine terminated polyethers with epoxide functional compounds. The novel compounds of the invention are particularly useful as wetting and foam control agents. The disclosed compounds exhibit exceptional antifoaming and defoaming activity while simultaneously reducing the dynamic surface tension when incorporated at low levels in water-based systems.
    Type: Application
    Filed: June 4, 2012
    Publication date: September 20, 2012
    Applicant: Ethox Chemicals, LLC.
    Inventors: James T Tanner, Charles F. Palmer, JR., Calvin M. Wicker, JR.
  • Patent number: 8252105
    Abstract: Embodiments of the present invention provide a composition useful as an additive to a printing ink. In one embodiment a composition is used that includes a biologically derived base material formed from one or more saturated or unsaturated straight or branched chain triglycerides or combinations thereof, wherein the triglycerides are partially to fully hydrogenated and have a viscosity between about 50 and about 200,000 centipoise at temperatures about 72 degrees Fahrenheit. In another embodiment, the composition further includes a finely divided additive selected from the group consisting of polytetrafluoroethylene or hydrogenated triglycerides in an intimate admixture with the base material. Other aspects relate to a method of making an ink additive and method for printing paper stock by letter press or lithography.
    Type: Grant
    Filed: February 15, 2008
    Date of Patent: August 28, 2012
    Assignee: Ethox Chemicals LLC
    Inventors: Calvin M. Wicker, Jr., Bharat Desai, Paul Sullivan
  • Patent number: 8193144
    Abstract: This invention relates to novel compounds derived from the reaction of diamines or polyamines with alkylene oxides. The invention also relates to novel compounds derived from the reaction of amine terminated polyethers with epoxide functional compounds. The novel compounds of the invention are particularly useful as wetting and foam control agents. The disclosed compounds exhibit exceptional antifoaming and defoaming activity while simultaneously reducing the dynamic surface tension when incorporated at low levels in water-based systems.
    Type: Grant
    Filed: October 1, 2008
    Date of Patent: June 5, 2012
    Assignee: Ethox Chemicals LLC
    Inventors: James T. Tanner, Charles F. Palmer, Jr., Calvin M. Wicker, Jr.
  • Publication number: 20120136119
    Abstract: The present invention relates to the use of Styrenated Phenol Ethoxylates as surfactants in emulsion polymerization. The present invention further relates to the use of both anionic and nonionic Styrenated Phenol Ethoxylates in emulsion polymerization. Latexes with small average particle and narrow particle size distributions are obtained. Prepared latexes also have low coagulum levels and exhibit excellent mechanical and chemical stability.
    Type: Application
    Filed: November 28, 2011
    Publication date: May 31, 2012
    Applicant: Ethox Chemicals, LLC
    Inventors: Lawrence C. Davis, Edward R. Godwin, Charles V. Hinton, James T. Tanner
  • Publication number: 20120136118
    Abstract: The present invention relates to the use of Styrenated Phenol Ethoxylates as surfactants in emulsion polymerization. The present invention further relates to the use of both anionic and nonionic Styrenated Phenol Ethoxylates in emulsion polymerization. Latexes with small average particle and narrow particle size distributions are obtained. Prepared latexes also have low coagulum levels and exhibit excellent mechanical and chemical stability.
    Type: Application
    Filed: November 28, 2011
    Publication date: May 31, 2012
    Applicant: Ethox Chemicals, LLC
    Inventors: Lawrence C. Davis, Edward R. Godwin, Charles V. Hinton, James T. Tanner