Abstract: A compound comprising a blend of polypropylene with the reaction of a functionalized polypropylene and polyether amine in which the polyetheramine is grafted into the functionalized polypropylene in a customary mixing apparatus is disclosed. The blend may include an elastomer such as EP rubber and/or a filler such as glass. A process for producing the reaction product of the functionalized polypropylene and the polyether amine by melting with polypropylene in a customary mixing apparatus is also disclosed. Blends of the present invention are advantageously useful to prepare paintable automotive body parts.

Abstract: Improved methods and apparatus for the preparation of maleic anhydride by reacting a hydrocarbon having at least four carbon atoms in a straight chain with molecular oxygen in a catalytic reactor, the reactor comprising a fixed catalyst bed having active sites comprising a vanadium-phosphorus-oxygen catalyst for the catalytic oxidation of the hydrocarbon to maleic anhydride, said process further comprising the continuous or intermittent introduction of a phosphorus-containing agent to the reactor. The introduction of the phosphorus-containing agent into the maleic anhydride production system is controlled so to provide for a more uniform distribution of the phosphorus-containing agent throughout the reactor. The methods of the invention are effective to reduce deposits of the phosphorus-containing agent or decomposition products of the phosphorus-containing agent on reactor surfaces other than the catalytic bed thereby decreasing reactor maintenance and increasing reactor lifetime.

Abstract: Methods of dissolving copper into electrolytic solutions, such as solutions comprising nitrogen compounds, by supplying an anodic current to a copper or copper-containing metal that is in contact with an electrolytic solution comprising a nitrogen compound (such as 2-hydroxyethylamine) and carbon dioxide. Anodic current may be provided by, for example, galvanic coupling with a material having a more positive reduction potential in the electrolytic solution (or given the system of electrolytic solutions) than copper, and/or by applying an impressed anodic current to the copper or copper-containing metal. Separate reaction vessels may be employed to house a first copper metal and a second cathode metal, as well as the electrolytic solutions associated with each.

Abstract: A method of preparing hydroxyalkylcarbamates from six-membered cyclic carbonates. The method involves reacting a six-membered cyclic carbonate with anhydrous ammonia or aqueous ammonium hydroxide. The present invention also provides for hydroxyalkylcarbamates prepared from six-membered cyclic carbonates, and for coating compositions comprising hydroxyalkylcarbamates prepared according to the present invention.

Abstract: Provided herein are subcombinations from which polyurethane foams and polyurethane foams containing polyisocyanurates may be prepared. The subcombinations are unique in that they contain components which synergistically act towards promoting compatibility between a blowing agent and the remaining components of the formulation. Through the use of the teachings herein, blowing agent concentrations in excess of 25% by weight of the total subcombination may be incorporated.

Abstract: A thickened composition and process useful for removing paint, comprising: a carbonate such as propylene carbonate or ethylene carbonate, a thickener such as polyvinyl pyrrolidone (PVP), hydrogen peroxide and water. The composition may include additional cosolvents such as glycol ethers and alcohols such as benzyl alcohol, and/or dibasic ester (DBE).

Abstract: A compound comprising a blend of polypropylene with the reaction of a functionalized polypropylene and polyether amine in which the polyether amine is grafted into the functionalized polypropylene in a customary mixing apparatus is disclosed. The blend may include an elastomer such as EP rubber and/or a filler such as glass. A process for producing the reaction product of the functonalized polypropylene and the polyether amine by melting with polypropylene in a customary mixing apparatus is also disclosed. Blends of the present invention are advantageously useful to prepare paintable automotive body parts. A polyether monoamine that contains from about 36 to about 44 ethylene units and from about 1 to about 6 propylene units, and processes and blends using same.

Abstract: Polyalkyl hydroxyaromatics may be prepared from polyalkylenes and hydroxyaromatics in the presence of an acid catalyst and an organic solvent having a boiling point range with an initial boiling point value of below or about the boiling point of the selected hydroxyaromatic reactants and final boiling point of above or equal to about the boiling point of alkylhydroxyaromatic by-product of the reaction. Using this method, accumulation of undesirable alkylhydroxyaromatic by-product/s in a reaction vessel may be minimized, and/or viscosity of polyalkyl hydroxyaromatic product reduced, allowing for increased ease of transfer and transportation.

Abstract: Process useful to clean and remove uncured resins. The resins to be treaded include epoxy, polyester (fiberglass) and polyurethane foam. The compositions include alkylene carbonate, including propylene and ethylene carbonate.

Abstract: This invention concerns a composition useful as a paint remover, comprising: alkylene carbonate such as propylene carbonate or ethylene carbonate, hydrogen peroxide, and water, and optionally an alcohol such as benzyl alcohol. In another broad respect, his invention concerns a process for removing paint, comprising: applying a composition containing alkylene carbonate, hydrogen peroxide, and water to a painted surface for a time and under conditions effective to cause blistering or bubbling of the paint. In another broad respect, this invention is a composition useful as a paint remover, comprising: dialkyl carbonate, hydrogen peroxide, and water, optionally containing an alcohol, optionally containing a glycol ether. In another broad respect, this invention is a process for removing paint, comprising: applying a composition containing dialkyl carbonate, hydrogen peroxide, and water to a painted surface for a time and under conditions effective to cause blistering or bubbling of the paint.

Abstract: This invention is directed to a fluorine-containing mordenite catalyst and use thereof in the manufacture of linear alkylbenzene (LAB) by alkylation of benzene with an olefin. The paraffin may have from about 10 to 14 carbons. The fluorine-containing mordenite is prepared typically by treatment with an aqueous hydrogen fluoride solution. The benzene alkylation may be conducted using reactive distillation. This invention is also directed to a process for production of LAB having a high 2-phenyl isomer content by combining LAB product from the fluorine-containing mordenite product from a conventional LAB alkylation catalyst such as hydrogen fluoride.

Abstract: This invention concerns a composition useful as a paint remover, comprising: alkylene carbonate such as propylene carbonate or ethylene carbonate, hydrogen peroxide, and water, and optionally an alcohol such as benzyl alcohol. In another broad respect, this invention concerns a process for removing paint, comprising: applying a composition containing alkylene carbonate, hydrogen peroxide, and water to a painted surface for a time and under conditions effective to cause blistering or bubbling of the paint. In another broad respect, this invention is a composition useful as a paint remover, comprising: dialkyl carbonate, hydrogen peroxide, and water, optionally containing an alcohol, optionally containing a glycol ether. In another broad respect, this invention is a process for removing paint, comprising: applying a composition containing dialkyl carbonate, hydrogen peroxide, and water to a painted surface for a time and under conditions effective to cause blistering or bubbling of the paint.

Abstract: A composition useful as a paint remover. The composition may include a carbonate, a dibasic ester and a mono-ester. The composition may also contain an organic sulfur-containing compound such as dimethyl sulfoxide (DMSO), a glycol ether, a ketone, or combination thereof. The composition may be used in a process for removing paint by applying it to a painted surface. The compositions have several important attributes, including low toxicity and high efficacy in removing paint and coatings.

Abstract: This invention concerns a process to provide high purity alkylene carbonate though use of multiple distillations wherein the unused fractions are recycled to the reactor.

Abstract: This invention concerns a composition comprising a blend of polyolefin with the reaction of a functionalized polyolefin and polyetheramine in which the polyetheramine is grafted into the functionalized polyolefin in a customary mixing apparatus. A process for producing the reaction product of functionalized polypropylene and polyetheramine by melting with polypropylene in a customary mixing apparatus is also disclosed. Blends of the present invention are advantageously useful to prepare paintable automotive body parts. This invention further includes dyeable polyolefin compositions containing the reaction product of functionalized polyolefin and polyetheramine. Dyeable polyolefin fibers, including polypropylene fibers, are disclosed, which may be made by melt spinning, and which may be employed to make woven and non-woven fabric.

Abstract: A compound comprising a blend of polypropylene with the reaction of a functionalized polypropylene and polyether amine in which the polyetheramine is grafted into the functionalized polypropylene in a customary mixing apparatus is disclosed. The blend may include an elastomer such as EP rubber and/or a filler such as glass. A process for producing the reaction product of the functionalized polypropylene and the polyether amine by melting with polypropylene in a customary mixing apparatus is also disclosed. Blends of the present invention are advantageously useful to prepare paintable automotive body parts.

Abstract: This invention is directed to a fluorine-containing mordenite catalyst and use thereof in the manufacture of linear alkylbenzene (LAB) by alkylation of benzene with an olefin. The olefin may have from about 10 to 14 carbons. The fluorine-containing mordenite is prepared typically by treatment with an aqueous hydrogen fluoride solution. The benzene alkylation may be conducted using reactive distillation. This invention is also directed to a process for production of LAB having a high 2-phenyl isomer content by use of the fluorine-containing mordenite in conjunction with a conventional solid LAB alkylation catalyst. The two catalysts may be used in a mixed catalyst bed or may be packed in series, with the relative proportions being adjusted to provide a desired 2-phenyl isomer content of in the final product.

Abstract: Methods and compositions relating to solubilization of alkylbenzene sulfonate surfactants in detergent formulations. Addition of one or more ethylene oxide/propylene oxide block copolymers to detergents including alkylbenzene sulfonate surfactants may be used to increase solubility of the alkylbenzene sulfonate surfactants. Increased solubility of the alkyl benzene sulfonate surfactants serves to lower the cloud point of the detergents permitting, for example, the formulation of liquid detergent compositions containing greater concentrations of low 2-phenyl linear alkylbenzene sulfonate surfactants.

Abstract: This invention concerns a composition comprising a blend of polyolefin with the reaction of a functionalized polyolefin and polyetheramine in which the polyetheramine is grafted into the functionalized polyolefin in a customary mixing apparatus. A process for producing the reaction product of functionalized polypropylene and polyetheramine by melting with polypropylene in a customary mixing apparatus is also disclosed. Blends of the present invention are advantageously useful to prepare paintable automotive body parts. This invention further includes dyeable polyolefin compositions containing the reaction product of functionalized polyolefin and polyetheramine. Dyeable polyolefin fibers, including polypropylene fibers, are disclosed, which may be made by melt spinning, and which may be employed to make woven and non-woven fabric.

Abstract: Processes for the purification and color stabilization of crude maleic anhydride by distillation in a batch or continuous distillation column.