Abstract: Apparatuses and methods for producing covetic materials by exciting a hydrocarbon gas with pulse microwaves to form hydrocarbon radicals in a hot first region of a microwave reactor. Graphene nanoplatelets are formed by the nucleation, growth, and assembly of the hydrocarbon radicals, and contact a metal melt introduced downstream of the hot region to produce a mixture of molten metal and graphene nanoplatelets which assemble in-flight to form covetic materials.

Abstract: A dual-layer gradient electrode structure is provided for optimizing power and energy density in batteries. In use, for an electrode of a lithium-based battery, the electrode includes a first layer above an electrically conductive substrate, the first layer including a first plurality of carbon aggregates having a first porosity. Additionally, a second layer is above, at least in part, the first layer, the second layer having a second porosity, and including a second plurality of carbon aggregates. The second plurality of carbon aggregates includes a first group of aggregates and a second group of aggregates. The first group of aggregates is characterized by a first porous structure, and the second group of aggregates is characterized by a second porous structure. Further, the second porous structure is characterized by a density greater than the first porous structure, and the second porosity is greater than the first porosity.

Abstract: Resonant sensors for environmental health risk detection are disclosed. An adhesive may include at least one meso-scale or micro-scale resonator embedded within a material that comprises at least a portion of the adhesive. The at least one meso-scale or micro-scale resonator may be formed from a composite material. Additionally, the at least one meso-scale or micro-scale resonator may include a plurality of first carbon particles configured to uniquely resonate in response to an electromagnetic ping based at least in part on a concentration level of the first carbon particles within the at least one meso-scale or micro-scale resonator.

Abstract: Metal(s) (including various alloys, such as INCONEL(R) superalloys) are characterized by having carbon disposed within the metal lattice structure thereof. The carbon is primarily, or entirely, present at interstitial sites of the metal lattice, and may be present in amounts ranging from about 1.5 wt % to about 90 wt %. Carbon may be present in the form of graphene, which may be characterized as one or more coherent, planar layers of graphene. The carbon, moreover, forms non-polar covalent bonds with both metal atoms of the lattice and other carbon atoms present in the lattice. This facilitates substantially homogeneous dispersal of the carbon throughout the resultant material, conveying unique and advantageous properties such as strength-to-weight ratio, density, mechanical toughness, sheer strength, flex strength, hardness, anti-corrosiveness, electrical and/or thermal conductivity, etc. as described herein. In some approaches, the composition of matter may be powderized, or the powder may be pelletized.

Abstract: The presently disclosed concepts relate to ultra-efficient EV battery recycling systems. Alkali metal extraction (and in particular lithium extraction) is accomplished using a solid electrolyte membrane. By using a solid electrolyte embedded in a matrix, alkali metals, in particular lithium, can be (energy-wise) efficiently separated from feed solutions. The energy used to initially extract lithium from a feed solution is stored as electrochemical energy, which electrochemical energy is reclaimed in subsequent extraction processing steps. This energy storage and energy reclamation is performed in continuous ultra-efficient ongoing cycles. Since irrecoverable energy losses incurred in each cycle are limited to negligible amounts of joule heating of the system components and feed solution, the system can be sustainably powered using locally-generated renewable energy.

Abstract: A system and method are provided to create porous surface coatings. In use, a method is included for receiving, at a plasma spray torch, inputs comprising metallic particles and carbon particles, using the plasma spray torch to cause in-situ nucleation of the inputs to synthesize carbon-containing composite materials, and flowing the synthesized carbon-containing composite materials onto a substrate. Some or all of the synthesized carbon-containing composite materials may include a surface layer and/or a bonding layer. Additionally, the method may include tuning the inputs based on tuning characteristics, the tuning characteristics including one or more of: porosity, heat transfer, or resistance to corrosion. Further, the method may include tuning the inputs to optimize temperature redistribution across a surface layer of some or all of the synthesized carbon-containing composite materials.

Abstract: This disclosure provides a reactor system that includes a microwave source configured to generate a microwave energy, one or more energy sources configured to generate a thermal energy and a field-enhancing waveguide (FEWG) coupled to the microwave source. The FEWG includes a field-enhancing zone having a cross-sectional area that decreases along a length of the FEWG. The field-enhancing zone includes a supply gas inlet configured to receive a supply gas, a reaction zone configured to generate a plasma in response to excitation of the supply gas by the microwave energy, a process inlet configured to inject a raw material into the reaction zone, and an afterglow region configured to combine the plasma and the raw material in response to the thermal energy. An outlet outputs a plurality of carbon-inclusive particles resulting from the combination of the plasma and the raw material. Electrodes can be positioned proximate to the reaction zone.

Abstract: Sensors for detecting analytes are disclosed. In various implementations, the sensing device may include a substrate and a sensor array. The sensor array may be arranged on the substrate, and may include a plurality of sensors. In some implementations, at least two of the sensors may include a first carbon-based sensing material disposed between a first pair of electrodes, and a second carbon-based sensing material disposed between a second pair of electrodes. The first carbon-based sensing material may be configured to detect a presence of each analyte of a group of analytes, and the second carbon-based sensing material may be configured to confirm the presence of each analyte of a subset of the group of analytes. In some instances, the group of analytes includes at least twice as many different analytes as the subset of analytes.

Abstract: A container includes a surface defining a volume of the container, a first resonance portion disposed on a first portion of the surface of the container using one or more first carbon-based inks, and a second resonance portion disposed on a second portion of the surface of the container using one or more second carbon-based inks different than the one or more first carbon-based inks. The first resonance portion can resonate within a first range of frequencies in response to one or more electromagnetic pings received from a user device, and the second resonance portion can resonate within a second range of frequencies in response to the one or more electromagnetic pings, the second range of frequencies being different than the first range of frequencies. In some instances, the user device may be a smartphone, a radio frequency identification (RFID) reader, or a near-field communication (NFC) device.

Abstract: A lithium-sulfur cylindrical cell. The cell includes a cylindrical shell defining an inner volume, and a jelly roll disposed within the inner volume. The jelly roll includes an anode comprising lithium, where the anode is configured as a freestanding assembly. Additionally, the jelly roll comprises a cathode comprising sulfur. Further, the jelly roll comprises a first separator between a first side of the anode and a first side of the cathode. In cylindrical cell formats, the jelly roll comprises a windable second separator. As the jelly roll is wound, the second separator may come in direct contact with both a second side of the anode and with a second side of the cathode. Alternatively, as the jelly roll is wound, the second separator may come in direct contact with the second side of the anode and with a cathode current collector.

Abstract: A lithium-sulfur cylindrical cell. The cell includes a cylindrical shell defining an inner volume, and a jelly roll disposed within the inner volume. The jelly roll includes an anode comprising lithium, where the anode is configured as a freestanding assembly. Additionally, the jelly roll comprises a cathode comprising sulfur. Further, the jelly roll comprises a first separator between a first side of the anode and a first side of the cathode. In cylindrical cell formats, the jelly roll comprises a windable second separator. As the jelly roll is wound, the second separator may come in direct contact with both a second side of the anode and with a second side of the cathode. Alternatively, as the jelly roll is wound, the second separator may come in direct contact with the second side of the anode and with a cathode current collector.

Abstract: In some implementations, a metal air battery includes an anode and an cathode opposite to the anode. The cathode may be formed as a textured carbon-based scaffold and include an opening into the metal air battery. The metal air battery may include a nano-fibrous membrane (NFM) containing a liquid electrolyte and a functionalized carbon structure may be disposed between the cathode and the NFM. The functionalized carbon structure may allow moisture and oxygen from ambient air to permeate through the NFM and diffuse throughout the textured scaffold of the cathode. A moisture barrier layer may be laminated over the cathode and positioned, by a user, in one of two states. When in a first state, the moisture barrier layer may seal the opening. When in a second state, the moisture barrier layer may allow the moisture and the oxygen to enter the textured scaffold.

Abstract: A disclosed component may include at least one split-ring resonator, which may be embedded within a material. The split ring resonator may be formed from a three-dimensional (3D) monolithic carbonaceous growth and may detect an electromagnetic ping emitted from a user device. The split ring resonator may generate an electromagnetic return signal in response to the electromagnetic ping. The electromagnetic return signal may indicate a state of the material in a position proximate to a respective split ring resonator. In some aspects, the split-ring resonator may resonate at a first frequency in response to the electromagnetic ping when the material is in a first state, and may resonate at a second frequency in response to the electromagnetic ping when the material is in a second state. A resonant frequency of the 3D monolithic carbonaceous growth may be based on physical characteristics of the material.

Abstract: A material and method are provided for increasing catalytic activity of electrocatalysts. In use, a material comprises synthesized carbon-containing composite materials, synthesized metal-metal carbides, and a heterostructure material comprising the synthesized carbon-containing composite materials and the synthesized metal-metal carbides. The synthesized metal-metal carbides are atom-decorated, at least in part, on the synthesized carbon-containing composite material. Additionally, a method of increasing catalytic activity of an electrocatalyst includes dissolving a metal precursor into a first solution, where the metal precursor comprises a set of characteristics. A heterostructure material is created based on the first solution, wherein catalytic activity of the heterostructure material is a function of the set of characteristics, and wherein the heterostructure material includes a metal-metal carbide that is atom-decorated to synthesized carbon-containing composite materials.

Abstract: Inventive techniques for forming unique compositions of matter are disclosed, as well as various advantageous physical characteristics, and associated properties of the resultant materials. In particular, metal(s) (including various alloys, such as Inconel superalloys) are characterized by having carbon disposed within the metal lattice structure thereof. The carbon is primarily, or entirely, present at interstitial sites of the metal lattice, and may be present in amounts ranging from about 15 wt % to about 90 wt %. The carbon, moreover, forms non-polar covalent bonds with both metal atoms of the lattice and other carbon atoms present in the lattice. This facilitates substantially homogeneous dispersal of the carbon throughout the resultant material, conveying unique and advantageous properties such as strength-to-weight ratio, density, mechanical toughness, sheer strength, flex strength, hardness, anti-corrosiveness, electrical and/or thermal conductivity, etc. as described herein.

Abstract: Cement compositions including ordinary Portland cement, a secondary cementitious material (SCM) including one or more of pozzolan, metakaolin, limestone, or gypsum in an amount of up to approximately 70% of a replacement level of ordinary Portland cement, and between approximately 0.05% by weight of cement (bwoc) and 2% bwoc of aggregates of mesoporous carbon nanoparticles (3DG) carbons. The cement compositions regulate nucleation and time-lapsed growth of calcium silica hydrates during initial hydration. The 3DG carbons include aggregates of mesoporous carbon nanoparticles, which include one or more interconnected bundles of electrically conductive graphene layers. The 3DG carbons include oxygen containing functional groups disposed on one or more of the surfaces of the 3DG carbons or within the 3DG carbons.

Abstract: Methods include producing tunable carbon structures and combining carbon structures with a polymer to form a composite material. Carbon structures include crinkled graphene. Methods also include functionalizing the carbon structures, either in-situ, within the plasma reactor, or in a liquid collection facility. The plasma reactor has a first control for tuning the specific surface area (SSA) of the resulting tuned carbon structures as well as a second, independent control for tuning the SSA of the tuned carbon structures. The composite materials that result from mixing the tuned carbon structures with a polymer results in composite materials that exhibit exceptional favorable mechanical and/or other properties. Mechanisms that operate between the carbon structures and the polymer yield composite materials that exhibit these exceptional mechanical properties are also examined.

Abstract: A dual-layer gradient electrode structure is provided for reducing sulfide transfer. In use, an electrode of a lithium-based battery may comprise a first layer disposed above an electrically conductive substrate, the first layer including a first plurality of carbon aggregates having a first porosity. Additionally, the electrode may comprise a second layer disposed above the first layer, the second layer including a second plurality of carbon aggregates, the second layer including a second porosity which is greater than the first porosity, where a first group of particles of the second layer has a first concentration of interacting functional groups, and a second group of particles of the second layer has a second concentration of the interacting functional groups, the second concentration being greater than the first concentration.

Abstract: Resonant sensors for environmental health risk detection are disclosed. An adhesive may include at least one meso-scale or micro-scale resonator embedded within a material that comprises at least a portion of the adhesive. The at least one meso-scale or micro-scale resonator may be formed from a composite material. Additionally, the at least one meso-scale or micro-scale resonator may include a plurality of first carbon particles configured to uniquely resonate in response to an electromagnetic ping based at least in part on a concentration level of the first carbon particles within the at least one meso-scale or micro-scale resonator.

Abstract: Inventive techniques for forming unique compositions of matter are disclosed, as well as various advantageous physical characteristics, and associated properties of the resultant materials. In particular, particles comprising polymer matrices are characterized by having carbon disposed within the polymer matrix structure thereof. The carbon is primarily, or entirely, present at interstitial sites of the polymer matrix, and may be present in amounts ranging from about 15 wt % to about 90 wt %. The carbon, moreover, forms covalent bonds with both atoms of the polymer matrix and other carbon atoms present in, but not part of, the matrix. This facilitates substantially homogeneous dispersal of the carbon throughout the resultant material, conveying unique and advantageous properties such as strength-to-weight ratio, density, mechanical toughness, sheer strength, flex strength, hardness, anti-corrosiveness, electrical and/or thermal conductivity, etc. as described herein.