Patents Assigned to Mitsubishi Rayon Company, Ltd.
  • Patent number: 4977241
    Abstract: Disclosed herein is a particulate polymer prepared by the agglomeration of polymer particles contained in a polymer latex. The particulate polymer is composed of primary particles having particle sizes of at least 20 .mu.m and/or secondary particles formed by the agglomeration of at least some of the primary particles and is in the form of a compact mass substantially free of voids. The particulate polymer is prepared by coagulating the polymer latex in the presence of a coagulant and an organic liquid having low solubility in water. The particulate polymer has a high bulk specific gravity and contains few fine particles. It is thus easy to handle and allows the consumption of energy to be reduced in the drying step.
    Type: Grant
    Filed: December 24, 1987
    Date of Patent: December 11, 1990
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Teruhiko Sugimori, Fumio Suzuki, Hideaki Habara, Hiromasa Inada
  • Patent number: 4974924
    Abstract: A plug for an optical fiber cable comprises a plug proper having a line-inserting portion for insertion of an optical fiber and a primary covering layer in a state communicating with the interior, an optical fiber-inserting portion for inserting only the optical fiber, a cylindrical portion formed on the outer wall of the line-inserting portion to caulk and fix the line, and a pressing portion having a concave-convex part formed to anchor the filamentary reinforcing fiber exposed from the end of the optical fiber cable onto the periphery of the pressing portion, and at least one ferrule for caulking the filamentary reinforcing fiber exposed from the end of the optical fiber cable to the concave-convex part of the pressing portion of the plug proper, and further, caulking the secondary covering layer.
    Type: Grant
    Filed: May 4, 1989
    Date of Patent: December 4, 1990
    Assignee: Mitsubishi Rayon Company Ltd.
    Inventors: Hiroshi Okada, Masatoshi Toda, Shingo Suzuki
  • Patent number: 4971879
    Abstract: A polymer binder, in which the content of a residual monomer is not more than 200 ppm, generates a smell only to a very slight extent and provides a toner having an improved blocking resistance and resistance against a plasticizer for polyvinyl chloride. The polymer binder is prepared by maintaining a polymer suspension obtained by suspension polymerization at a temperature of not lower than the glass transition temperature of the polymer and distilling water in an amount of 5 to 60% by weight based on the amount of water present at the time of termination of the polymerization.
    Type: Grant
    Filed: May 8, 1989
    Date of Patent: November 20, 1990
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Sadao Kimura, Ryo Funato, Keiji Yoshida
  • Patent number: 4966435
    Abstract: A plastic core-plastic cladding optical fiber is described wherein the core is composed of a copolymer of a perfluorodioxole represented by the following formula: ##STR1## wherein R and R' independently represent F or CF.sub.3, with at least one other ethylenically unsaturated monomer substantially free of CH bonds and the copolymer has no first order transition temperature as determined by the differential scanning colorimetry (DSC) and has a second order transition temperature not lower than 100.degree. C. as determined by DSC.
    Type: Grant
    Filed: November 29, 1989
    Date of Patent: October 30, 1990
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Tsuruyoshi Matsumoto, Takashi Yamamoto, Teruhiko Sugimori, Katsuhiko Shimada
  • Patent number: 4966432
    Abstract: An optical coupler comprising N number (where N stands for an integer of not less than 2) of optical fibers having one ends integrated and the other ends branched and N number of optical coupler parts, wherein the top end of each light branching-coupling optical fiber has a plane of 360.degree./N including an inclined branching fiber-abutting plane inclined at an angle .theta. to the optical fiber axis and a light-coupling plane vertical to the abutting plane, each of the optical coupler parts is constructed by inserting the light branching-coupling optical fiber in an optical fiber-retaining hole of a block having the same plane as the branching fiber-abutting plane of the optical fiber and a light-coupling plane vertical to the abutting plane, and the branching fiber-abutting planes of the optical coupler parts are engaged with each other to construct a optical coupler.
    Type: Grant
    Filed: October 24, 1989
    Date of Patent: October 30, 1990
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Hiroshi Okada, Masatoshi Toda, Shingo Suzuki, Manabu Kagami, Masayoshi Komiya
  • Patent number: 4963639
    Abstract: Disclosed is a radiation curable resin composition permitting good dispersion of magnetic powders and forming a highly durable cured film, and hence suitable for use in the formation of magnetic recording media. This resin composition consists essentially of a urethane (meth)acrylate obtained by the reaction of(A) a hydroxyl-containing compound (I) composed of an amido hydroxy compound (a.sub.1) having at least one amido group and at least one isocyanate-reactive hydroxyl group in the molecule, and at least one polyol compound (a.sub.2) selected from polyester polyols, polyether polyols and alkyl polyols, the number of moles (x.sub.1) of the hydroxyl groups present in the amido hydroxy compound (a.sub.1) being from 5 to 80% of the total number of moles of the hydroxyl groups contained in component (A) and the number of moles (x.sub.2) of the hydroxyl groups present in the polyol compound (a.sub.
    Type: Grant
    Filed: December 22, 1987
    Date of Patent: October 16, 1990
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Mitsuo Sato, Toshikazu Aoki, Yukishige Takamatsu, Hideyasu Ryoke
  • Patent number: 4959438
    Abstract: An epoxy resin composition is disclosed, which comprises the following elements:(A) a bifunctional epoxy resin;(B) a trifunctional epoxy resin;(C) a phenolic compound represented by the following general formula: ##STR1## wherein X.sub.1, X.sub.2, X.sub.3, X.sub.4, X.sub.5, X.sub.6, X.sub.7, X.sub.8, X.sub.9, X.sub.10, X.sub.11, X.sub.12, R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom or a methyl group; and(D) 4,4'-diaminodiphenyl sulfone or 3,3'-diaminodiphenyl sulfone, wherein the molar ratio of epoxy groups in element (A) to those in element (B) is in the range of from 1/4.0 to 1/0.1, element (C) is used in an amount that satisfies the condition:1/0.9.ltoreq.(A+B)/C.ltoreq.1/0.1and element (D) is used in an amount that satisfies the condition:1/1.3.ltoreq.(A+B-C)/D.ltoreq.1/0.
    Type: Grant
    Filed: January 27, 1989
    Date of Patent: September 25, 1990
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Hisashi Tada, Akira Agata, Masahiro Saruta, Takashi Murata
  • Patent number: 4956411
    Abstract: An epoxy resin composition is disclosed that can be cured at a temperature of 150.degree. C. or below, and can be used to provide a high performance carbon fiber composite material having a 0.degree. direction bending strength of 220 kg/mm.sup.2 or over, and an interlayer shear strength of 10 kg/mm.sup.2 or over.The composition is made up of:(A) an epoxy compound containing 10 to 100% by weight of m- or o-methyl-p-N,N-diglycidyl-aminophenyl-ester or its oligomer,(B) diaminodiphenylsulfone and/or diaminodiphenylmethane,(C) dicyandiamide, 2,6-xylenylbiguanide, o-tolylbiguanide, diphenylguanidine, adipil dihydrazide, azelayl dihydrazide, or isophthalic acid dihydrazide, and(D) a urea compound.
    Type: Grant
    Filed: January 30, 1989
    Date of Patent: September 11, 1990
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Hisashi Tada, Yoshinobu Shiraishi, Shigetsugu Hayashi
  • Patent number: 4940778
    Abstract: A methacrylimide group-containing polymer having improved moldability as well as good heat resistance and transparency is prepared by heat treating a methacrylimide group-containing polymer having imide ring structural units of the formula: ##STR1## wherein R represents a hydrogen, an alkyl, cycloalkyl, aryl, alkaryl, aralkyl or allyl group 1 to 20 carbon atoms, at a temperature of 190 to 350 C. in the presence of a tertiary amine of the formula: ##STR2## wherein R.sub.1, R.sub.2 and R.sub.3 independently represent an alkyl, aryl, aralkyl or alkaryl group having 1 to 20 carbon atoms, and two of R.sub.1, R.sub.2 and R.sub.3 may be linked to form a ring together with the nitrogen atom.
    Type: Grant
    Filed: July 18, 1988
    Date of Patent: July 10, 1990
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Hisao Anzai, Kozi Nishida, Isao Sasaki, Hideaki Makino, Masami Ohtani
  • Patent number: 4932107
    Abstract: Disclosed is a method wherein open spaces in woven fabrics useful as industrial materials, such as coated cloth and cloth for fiber-reinforced plastics, are reduced by allowing the woven fabrics to pass under pressure between a pair of rolls at least one of which vibrates in the axial direction thereof.
    Type: Grant
    Filed: July 17, 1989
    Date of Patent: June 12, 1990
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Hazime Gotoh, Tadasi Yokoti
  • Patent number: 4927915
    Abstract: An antistatic polymeric material having surface electrical resistivity of smaller than 10.sup.10 .OMEGA./.quadrature. order and/or half life time of shorter than 40 seconds can be obtained by heat-treating at 60-140.degree. C. for 2-60 minutes a polymeric material in a state moistened with an aqueous solution containing 0.5-5% by weight of stannic chloride.
    Type: Grant
    Filed: October 6, 1988
    Date of Patent: May 22, 1990
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Saburo Hiraoka, Shinji Hama, Mitsuo Senga
  • Patent number: 4925514
    Abstract: Disclosed is a light attenuator comprising a stick or rod composed of a light-transmitting material, and a light-attenuating layer composed of a thermoplastic resin and formed on at least one end face of the stick or rod, wherein finely divided particles having a light-absorbing or light-scattering property are uniformly incorporated in the thermoplastic resin. This light attenuator is made by forming a light-attenuating thermoplastic resin layer having incorporated therein the light-absorbing or light-scattering finely divided particles on a release film or paper; placing the light-attenuating layer formed on the release film or paper on a heating plate; press-bonding the end face of a rod or stick composed of a light-transmitting material inserted and set in a ferrule to the surface of the release film or paper; cooling the bonded assembly; and then peeling the release film or paper to transfer the light-attenuating layer to the end face of the light-transmitting rod or stick.
    Type: Grant
    Filed: May 4, 1989
    Date of Patent: May 15, 1990
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Hiroshi Okada, Shingo Suzuki, Manabu Kagami, Chiaki Suematsu
  • Patent number: 4921909
    Abstract: Emulsion polymerization type thermoplastic resin of high performance can be produced by the following methods: namely, a method which comprises removing an aqueous phase from a two-phase mixture comprising a latex of polymer (1) produced by emulsion polymerization, a water soluble agent (2) in an amount of 10% by weight or less of said polymer (1) which is capable of coagulating the latex of polymer (1) and an organic agent (3) in an amount of 0.1 to 6 times the weight of said polymer (1) which is capable of dissolving both an uncrosslinked polymer contained in said polymer (1) and thermoplastic polymer (4) mentioned hereinbelow and has a solubility in water of 5% by weight or less at 25.degree. C.
    Type: Grant
    Filed: December 24, 1986
    Date of Patent: May 1, 1990
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Teruhiko Sugimori, Noriyuki Tajiri, Yutaro Fukuda
  • Patent number: 4911514
    Abstract: An optical coupler comprising N number (where N stands for an integer of not less than 2) of optical fibers having one ends integrated and the other ends branched and N number of optical coupler parts, wherein the top end of each light branching-coupling optical fiber has a plane of 360.degree./N including an inclined branching fiber-abutting plane inclined at an angle .theta. to the optical fiber axis and a light-coupling plane vertical to the abutting plane, each of the optical coupler parts is constructed by inserting the light branching-coupling optical fiber in an optical fiber-retaining hole of a block having the same plane as the branching fiber-abutting plane of the optical fiber and a light-coupling plane vertical to the abutting plane, and the branching fiber-abutting planes of the optical coupler parts are engaged with each other to construct a optical coupler.
    Type: Grant
    Filed: April 14, 1988
    Date of Patent: March 27, 1990
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Hiroshi Okada, Masatoshi Toda, Shingo Suzuki, Manabu Kagami, Masayoshi Komiya
  • Patent number: 4910850
    Abstract: A method for coagulation of a polymer latex by feeding the polymer latex to an extruder having a base plate and a plurality of fine tubes fixed to said base plate and extending therefrom, said fine tubes being mutually spaced by at least 1 mm and protruding from said base plate by at least 3 mm, and discharging said polymer latex through said fine tubes into a coagulation solution to coagulate the latex.
    Type: Grant
    Filed: August 1, 1988
    Date of Patent: March 27, 1990
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Teruhiko Sugimori, Noriyuki Tajiri, Akio Hironaka, Hideaki Habara
  • Patent number: 4910291
    Abstract: An optical article such as optical disk and optical lens, made of an amorphous thermoplastic polyester resin comprised of recurring units, each recurring unit having an aromatic ring in the main chain thereof and an aromatic ring in the side chain thereof. The optical article have a good heat resistance, resistance to absorption of moisture and optical characteristics.
    Type: Grant
    Filed: August 5, 1988
    Date of Patent: March 20, 1990
    Assignee: Mitsubishi Rayon Company Ltd.
    Inventors: Naoki Yamamoto, Hiroshi Mori, Akira Nakata
  • Patent number: 4879329
    Abstract: An impact resistant flame-retardand resin composition comprising:100 parts by weight of a polymer mixture comprising a polycarbonate resin (A), a rubber-reinforced vinyl copolymer (B) and, optionally, a vinyl polymer (C);from 3 to 50 parts by weight of a high molecular weight halogenated compound of the following formula I having a halogen content of at least 10% by weight: ##STR1## wherein n is an average polymerization degree of from 35 to 100, each X independently represents hydrogen, chlorine or bromine, each of i, j, k and l is an integer of from 1 to 4, and each of R and R' independently is hydrogen, a methyl group, an epoxypropyl group, a phenyl group or ##STR2## wherein m is 0, 1, 2 or 3; and from 2 to 30 parts by weight of an antimony compound.
    Type: Grant
    Filed: October 18, 1988
    Date of Patent: November 7, 1989
    Assignee: Mitsubishi Rayon Company Ltd.
    Inventors: Masafumi Hongo, Mitsuaki Noda
  • Patent number: 4877922
    Abstract: Disclosed is an easily-dyeable resin composition used in a sublimation type heat-sensitive transfer process. The composition comprises 100 parts by weight of a mixture composed of 40 to 95% by weight of a polyester resin and 5 to 60% of a crosslinking agent curable with active energy rays, and 0.01 to 12 parts by weight of a surface active agent selected from silicon-containing surface active agents and fluorine-containing surface active agents.
    Type: Grant
    Filed: March 27, 1989
    Date of Patent: October 31, 1989
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Isao Sasaki, Kenji Kushi, Nobuyoshi Taguchi
  • Patent number: 4877687
    Abstract: A synthetic resin molded article having good antistatic properties is disclosed, which is composed of a body of a synthetic resin (B) having a surface layer which is predominantly comprised of an antistatic polymer (A) and is integral with the body (B). The antistatic polymer (A) mainly composed of units of a quaternary ammonium base monomer of the formula: ##STR1##wherein R.sub.1 is H or methyl, R.sub.2 through R.sub.4 are H, unsubstituted or substituted (C.sub.1-9) alkyl, m is 1-10 and X.sup.- is an anion of a quaternizing agent. The molded article is made by forming a film of the antistatic polymer (A) on the molding surface of a casting mold, casting a polymerizable material to be formed into the synthetic resin (B) as the base material in the casting mold, and polymerizing the polymerizable material to form a body of the synthetic resin (B), simultaneously rendering the film of the polymer (A) integral with the body of the base material.
    Type: Grant
    Filed: September 14, 1987
    Date of Patent: October 31, 1989
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Kiyotaka Azegami, Suehiro Tayama, Naoki Yamamoto, Akira Yanagase, Hiroki Hatakeyama
  • Patent number: 4876306
    Abstract: A process for preparing a thermoplastic resin, which comprises polymerizing a monomer mixture containing at least 80% by weight of at least one member selected from the group consisting of an alkyl methacrylate, an alkyl acrylate, an aromatic vinyl compound, acrylonitrile, methacrylonitrile and butadiene by using as an emulsifier a compound having a group of the formula --PO.sub.3 M.sub.2 or --PO.sub.2 M wherein M is an alkali metal or an alkaline earth metal, to form a latex, and contacting the latex with an aqueous magnesium sulfate solution having a concentration of from 0.1 to 30% by weight.
    Type: Grant
    Filed: March 14, 1988
    Date of Patent: October 24, 1989
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Satoshi Kurokawa, Suehiro Tayama, Fumio Sato