Patents Assigned to Rhodia Inc.
  • Publication number: 20070244027
    Abstract: The present invention relates to methods for using polymeric suds enhancers (stabilizers) to increase the suds and/or foam volume and suds and/or foam retention in suds-forming and/or foam-forming compositions comprising such polymeric suds stabilizers. Suitable suds-forming and/or foam-forming compositions comprise one or more polymeric suds stabilizers. The polymeric suds stabilizers suitable for use in the methods and/or compositions of the present invention comprise cationic, anionic, and noncharged monomer units, or units having mixtures thereof, wherein said polymers have an average cationic charge density from about 0.05 to about 5 units per 100 daltons molecular weight at a pH of from about 4 to about 12.
    Type: Application
    Filed: June 18, 2007
    Publication date: October 18, 2007
    Applicants: THE PROCTER & GAMBLE COMPANY, RHODIA INC.
    Inventors: Mark SIVIK, Jean-Francois Bodet, Bernard William, William Scheper, Dominic Yeung, Vance Bergeron
  • Patent number: 7279446
    Abstract: A method of treating a subterranean formation by injecting down a well an aqueous fluid containing a viscoelastic surfactant fluid comprising an enhanced shear recovery agent wherein shear recovery time of the viscoelastic surfactant fluid is reduced by the addition of the enhanced shear recovery agent, and a viscoelastic surfactant fluid composition thereof.
    Type: Grant
    Filed: November 14, 2005
    Date of Patent: October 9, 2007
    Assignees: Rhodia Inc., Schlumberger Technology Corporation
    Inventors: Allwyn Colaco, Jean-Pierre Marchand, Fang Li, Manilal S. Dahanayake
  • Patent number: 7259192
    Abstract: A method of depolymerizing galactomannan-type polysaccharide polymers and xanthan, preferably galactomannans, to a pre-selected lower molecular weight by irradiation with high energy electron beams. The preferred galactomannans for treatment according to this method are guar gum, guar splits and hydroxypropyl guar. In a preferred embodiment the guar gum is depolymerized preferably to a molecular weight of about 150,000 Daltons to about 200,000 Daltons. The depolymerized guar has a polydispersity of less than about 3.0 and is useful in oil well fracturing to enhance oil production.
    Type: Grant
    Filed: June 24, 2003
    Date of Patent: August 21, 2007
    Assignee: Rhodia, Inc.
    Inventors: Leo Zhaoqing Liu, Christian Priou
  • Patent number: 7247693
    Abstract: A polymer includes repetitive units derived from a monomer compound according to formula (I): wherein R1 is a hydrogen atom, a methyl group or an ethyl group, A, which is identical or different, is a group comprising an ester group of formula -A1-C(O)—O-A2-, or an amide group of formula -A1-C(O)—NR10-A2-, wherein: R10, which is identical or different, is hydrogen or an alkyl, hydroxyalkyl, or aminoalkyl C1-C6 linear or branched group, A1, which is identical or different is a covalent bond or a group of formula —(CH2)p1— wherein p1 is an integer of from 1 to 6, A2, which is identical or different, is a linear or branched hydrocarbon group comprising optionally N, O, or S heteroatoms or heterogroups, optionally substituted, optionally forming or comprising a cycle, R1, R2, R3, R5 and R6, which are identical or different, are hydrogen, alkyl, hydroxyalkyl, or aminoalkyl C1-C6 linear or branched groups, or, if inside the brackets, form a heterocycle with group A2, m is an integer of from 1 to 10, n is an inte
    Type: Grant
    Filed: January 6, 2006
    Date of Patent: July 24, 2007
    Assignee: Rhodia Inc.
    Inventors: Leo Zhaoqing Liu, Dominic Wai-Kwing Yeung
  • Patent number: 7241729
    Abstract: The present invention relates to methods for using polymeric suds enhancers (stabilizers) to increase the suds and/or foam volume and suds and/or foam retention in suds-forming and/or foam-forming compositions comprising such polymeric suds stabilizers. Suitable suds-forming and/or foam-forming compositions comprise one or more polymeric suds stabilizers. The polymeric suds stabilizers suitable for use in the methods and/or compositions of the present invention comprise cationic, anionic, and noncharged monomer units, or units having mixtures thereof, wherein said polymers have an average cationic charge density from about 0.05 to about 5 units per 100 daltons molecular weight at a pH of from about 4 to about 12.
    Type: Grant
    Filed: August 19, 2004
    Date of Patent: July 10, 2007
    Assignees: Rhodia Inc., The Procter & Gamble Company
    Inventors: Mark Robert Sivik, Jean-Francois Bodet, Bernard William Kluesener, William Michael Scheper, Dominic Wai-Kwing Yeung, Vance Bergeron
  • Patent number: 7226620
    Abstract: A compressible tricalcium phosphate agglomerate comprises tricalcium phosphate particles, each having an outer surface, and a binder comprising a polyvinylpyrollidone, carrageenan, or a guar gum, supported on at least a portion of the outer surface of at least a portion of the tricalcium phosphate particles.
    Type: Grant
    Filed: May 4, 2005
    Date of Patent: June 5, 2007
    Assignee: Rhodia Inc.
    Inventors: Lewis Roe Hendricks, Jill Marie Jobbins, Wayne Camarco
  • Patent number: 7208554
    Abstract: A process for preparing polyoxyalkylene phosphonates in high yield and purity without extensive isolation procedures. The process also enables hydroxy terminated polyoxyalkylene phosphonates to be produced with their attendant high aqueous solubility and the availability of the reactive group to have the end functionality easily molecularly modified. Products produced by these processes have enhanced dispersion, coating, adhesion, and plasticizing characteristics as a result of the lack of any steric hinderance on these polyoxyalkylene phosphonates.
    Type: Grant
    Filed: April 5, 2005
    Date of Patent: April 24, 2007
    Assignee: Rhodia Inc.
    Inventors: Shiming Wo, John Marshall Baker
  • Patent number: 7067076
    Abstract: The invention is directed to a phosphonate composition having flame retardant properties. The phosphonate composition of the invention has the general formula: wherein R1 and R2 are independently C1–C4 alkyl, R3 is H or C1–C4 alkyl, and R4 is linear or branched C9–C22 alkyl, C9–C22 cycloalkyl, C9–C22 aryl or C9–C22 aralkyl and n=0 or 1. The invention is also directed to a method of producing the phosphonate composition having flame retardant properties.
    Type: Grant
    Filed: July 29, 2004
    Date of Patent: June 27, 2006
    Assignee: Rhodia Inc.
    Inventors: Shiming Wo, Dwight Shamblee
  • Patent number: 7064232
    Abstract: The invention relates to the preparation of hydrophobic modified diquaternary cationic monomers and their copolymer as well as the use such monomers and copolymers as thickening agents/rheology modifiers for acidic compositions. The hydrophobic modified diquaternary cationic monomer having the general formula: wherein X is selected from O, NH, or NR; Y is any alkyl, alkylene with or without heteroatoms, and R0, R1, R2 R3, R4, which are identical or different, are selected from C1–C4 alkyl groups, R is selected from any alkyl group with or without heteroatoms, and R5 is a hydrphobe having an alkyl chain of more than 4 atoms.
    Type: Grant
    Filed: December 7, 2004
    Date of Patent: June 20, 2006
    Assignee: Rhodia Inc.
    Inventors: Leo Z. Liu, Jeanne Chang
  • Patent number: 7057065
    Abstract: A process for preparing vinylphosphonic acid compounds and silyl esters thereof in which a bis(haloalkyl)vinylphosphonate is reacted with an organosilyl halide to produce a silyl ester which can then be converted to the acid by reaction with a proton donor.
    Type: Grant
    Filed: March 19, 2003
    Date of Patent: June 6, 2006
    Assignee: Rhodia Inc.
    Inventor: Johnson D. Koola
  • Patent number: 7049463
    Abstract: In a process for the production of dialkylphosphinic acids, especially branched, dialkylphosphinic acids in high purity via the reaction of an alpha olefin with a hypophosphorous acid or a salt thereof, the improvement comprising conducting the reaction in the presence of a stoichiometric excess of the olefin and isolating and purifying the desired dialkylphosphinic acid product by neutralizing the monoalkylphosphinic acid by-product with an aqueous base; removing the aqueous phase in which the neutralized monoalkylphosphinic acid is preferentially solubilized; acidifying the dialkyl product in the organic phase; and isolating the purified product.
    Type: Grant
    Filed: October 24, 2005
    Date of Patent: May 23, 2006
    Assignee: Rhodia Inc.
    Inventors: Shiming Wo, Floryan De Campo
  • Patent number: 7049385
    Abstract: The present invention relates to the use of C2–C24 aliphatic diols, preferably 1,2 propane diol as a thixotropic enhancing diluent in moisture curable organosiloxane compositions, especially in the presence of silicone-polyether block copolymer thixotropes and to the application of these compositions on vertical substrates.
    Type: Grant
    Filed: February 11, 2003
    Date of Patent: May 23, 2006
    Assignee: Rhodia Inc.
    Inventors: Steven Eric Heilman, Brian Patrick Bayly
  • Patent number: 7034177
    Abstract: A process of producing cyanoalkyl tetraalkylphosphordiamidites at least substantially free of amine hydrohalide with improved storage stability.
    Type: Grant
    Filed: June 9, 2003
    Date of Patent: April 25, 2006
    Assignee: Rhodia Inc
    Inventors: Dwight Shamblee, Shiming Wo, Bing Wang
  • Patent number: 7034193
    Abstract: A method for purifying a spent acid catalyst from an acid catalyzed chemical reaction that generates a mixture of a product, spent add and tar, includes the steps of separating the mixture of product, spent acid, and tar into a product fraction and a spent acid fraction, said spent acid fraction comprising a mixture of spent acid and tar, and separating the spent acid fraction, by flotation separation, centrifugation, or liquid-liquid coalescence, into a tar fraction and a de-tarred spent acid fraction. The fluidized tar and the de-tarred spent acid can each be further processed to produce concentrated acid.
    Type: Grant
    Filed: April 15, 2004
    Date of Patent: April 25, 2006
    Assignee: Rhodia Inc.
    Inventors: Richard Wai-Chun Liu, Philip Dean Hill, Thomas Edwin Pruitt, Forrest Lee Sanders, Albert Yi Yang
  • Patent number: 7030275
    Abstract: Monomer compounds comprising several cationic groups, a process for making such compounds and polymers derived from such compounds are provided.
    Type: Grant
    Filed: June 3, 2003
    Date of Patent: April 18, 2006
    Assignee: Rhodia Inc.
    Inventor: Leo Zhaoqing Liu
  • Patent number: 6939976
    Abstract: A process for the production of allyl succinic anhydride comprising reacting a mixture of propene with maleic anhydride in the presence of a catalyst comprised of an alkyl tin chloride as provided. The process can be run efficiently at temperatures below about 200° C. without and the formation of polymer or decomposition by-products.
    Type: Grant
    Filed: April 9, 2004
    Date of Patent: September 6, 2005
    Assignee: Rhodia Inc.
    Inventors: Euen Gunn, Jean-Christophe Galland, Blaise Didillon, Thomas Delacroix
  • Publication number: 20050124738
    Abstract: The present invention relates to methods for using zwitterionic polymeric suds enhancers (stabilizers) to increase the suds and/or foam volume and suds and/or foam retention in suds-forming and/or foam-forming compositions comprising such zwitterionic polymeric suds stabilizers. Suitable suds-forming and/or foam-forming compositions comprise one or more zwitterionic polymeric suds stabilizers.
    Type: Application
    Filed: November 24, 2004
    Publication date: June 9, 2005
    Applicants: The Procter & Gamble Company, Rhodia Inc.
    Inventors: Mark Sivik, Jean-Francois Bodet, Bernard Kluesener, William Scheper, Dominic Yeung, Vance Bergeron
  • Publication number: 20050113272
    Abstract: The present invention relates to a block polymeric material. Typically the block polymer comprises units capable of having an average cationic charge density of about 15 or less, preferably 5 or less, more preferably from about 0.05 to about 5, even more preferably from about 0.05 to about 2.77, even more preferably from about 0.1 to about 2.75, most preferably from about 0.75 to about 2.25 units per 100 daltons molecular weight at a pH of from about 4 to about 12. The polymeric material is a suds enhancer and a suds volume extender for personal care products such as soaps and shampoos. The compositions have increased effectiveness for preventing re-deposition of grease during hand and body washing. The polymers are also effective as a soil release agent in fabric cleaning compositions.
    Type: Application
    Filed: January 3, 2005
    Publication date: May 26, 2005
    Applicant: RHODIA, INC.
    Inventors: Dominic Yeung, Vance Bergeron, Jean-Francois Bodet, Mark Sivik, Bernard Kluesener, William Scheper
  • Patent number: 6884884
    Abstract: The present invention relates to a method for depolymerizing galactomannan and derivatives thereof. The present invention relates to compositions comprising galactomannan and derivatives thereof prepared according to the methods of this invention and uses for the compositions. The present invention also relates to compositions comprising hydroxypropylgalactomannan having a specific polydispersity index, weight average molecular weight and viscosity in solution.
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: April 26, 2005
    Assignee: Rhodia, Inc.
    Inventors: Jesse Magallanes, Sylvain Diguet, William Stivers
  • Patent number: 6838514
    Abstract: A polymer produced by polymerizing via water-in-oil emulsion polymerization one or more water soluble monomers with one or more polyalkoxylated monomers wherein said one or more polyalkoxylated monomers contains at least 25 alkylene oxide units and wherein said product demonstrates thermothickening properties, its method of manufacture and use thereof is disclosed.
    Type: Grant
    Filed: April 9, 2003
    Date of Patent: January 4, 2005
    Assignee: Rhodia Inc.
    Inventors: Dominic Wai Kwing Yeung, Leo Zhaoqing Liu, Bruno RC Langlois, Dominique Charmot, Pascale Corpart