Abstract: Viscoelastic surfactant based aqueous fluid systems useful as thickening agents in various applications, e.g. to suspend particles produced during the excavation of geologic formations. The surfactants are zwitterionic/amphoteric surfactants such as dihydroxyl alkyl glycinate, alkyl ampho acetate or propionate, alkyl betaine, alkyl amidopropyl betaine and alkylimino mono- or di-propionates derived from certain waxes, fats and oils. The thickening agent is used in conjunction with an inorganic water-soluble salt or organic additive such as phthalic acid, salicylic acid or their salts.
Type:
Grant
Filed:
July 6, 2001
Date of Patent:
December 14, 2004
Assignee:
Rhodia, Inc.
Inventors:
Manilal S. Dahanayake, Jiang Yang, Joseph H. Y. Niu, Paul Joel Derian, Ruoxin Li, David Dino
Abstract: A subject-matter of the present invention is a process for the preparation of a latex by radical aqueous emulsion polymerization in the presence of at least one ethylenically unsaturated monomer, of at least one radical polymerization initiator and of at least one surface-active block copolymer comprising at least one hydrophilic block and at least one hydrophobic block which is prepared by a “living” or “controlled” preparation process, the said copolymer exhibiting a number-average molecular mass of between 2 000 and 20 000, preferably between 4 000 and 16 000, a glass transition temperature of the hydrophobic block of less than 30° C., preferably of less than 25° C., and greater than −100° C., and a surface tension of less than 60 millinewtons per metre (mN/m), preferably of less than 50 mN/m, measured at a concentration in demineralized water of less than or equal to 10−4 mol/l at 20° C.
Abstract: Disclosed are pumpable surfactant compositions of alkanolamine salts of alkyl phosphate esters. The compositions have a solids content of about 60% by weight or more. Alkanolamines useful in preparation of the alkyl phosphate ester salts of the compositions of the present invention have the following formula III:
wherein R4 to R6 are, individually, hydrogen or C1-8, linear or branched alkyl, alkenyl, alkaryl or aralkyl hydrocarbon moieties, which optionally may contain carbocyclic rings. At least one of the amine substituents is different from the other two. For at least one of the three substituents on the amine nitrogen, the sum of s and t (s+t) or v and w (v+w) or x and y (x+y) is equal to or greater than 1 and the corresponding R (R4, R5 or R6) is hydrogen. The subscripts p and q, individually, may be the same or different and are integers from 2 to 4.
Type:
Grant
Filed:
June 3, 2002
Date of Patent:
November 23, 2004
Assignee:
Rhodia, Inc.
Inventors:
Robert Lee Reierson, Pascal Jean-Claude Herve, Subhash Soman, Ronny Jon Eng
Abstract: There is a process for removing by-product tar during the manufacture of isopropyl alcohol. The process comprises the following: a) reacting propylene with concentrated sulfuric acid and water to form isopropyl alcohol and a spent acid having a by-product tar; b) capturing at least a portion of the isopropyl alcohol; c) contacting the spent acid with a gas in bubble form; d) allowing a least a portion of the tar to separate from the remainder of the spent acid to form a layer of tar and a layer of cleaned acid solution; e) capturing the tar; and h) recycling the cleaned acid solution to step a) as a source of sulfuric acid. There is also a process for removing by-product tar during the manufacture of methyl ethyl ketone. The process is substantially the same except that 1-butene is substituted for propylene. There is also a process for removing tar from a spent acid.
Type:
Grant
Filed:
April 17, 2003
Date of Patent:
November 16, 2004
Assignee:
Rhodia, Inc.
Inventors:
Richard Wai-Chun Liu, Philip Dean Hill, Thomas Edwin Pruitt, Forrest Lee Sanders, Albert Yi Yang
Abstract: There is a process for removing by-product tar during the manufacture of isopropyl alcohol. The process comprises the following: a) reacting propylene with concentrated sulfuric acid and water to form isopropyl alcohol and a spent acid having a by-product tar; b) capturing at leas a portion of the isopropyl alcohol; c) contacting the spent acid with a gas in bubble form; d) allowing a least a portion of the tar to separate from the remainder of the spent acid to form a layer of tar and a layer of cleaned acid solution; e) capturing the tar; and h) recycling the cleaned acid solution to step a) as a source of sulfuric acid. There is also a process for removing by-product tar during the manufacture of methyl ethyl ketone. The process is substantially the same except that 1-butene is substituted for propylene. There is also a process for removing tar from a spent acid.
Type:
Application
Filed:
April 17, 2003
Publication date:
October 21, 2004
Applicant:
Rhodia Inc.
Inventors:
Richard Wai-Chun Liu, Philip Dean Hill, Thomas Edwin Pruitt, Forrest Lee Sanders, Albert Yi Yang
Abstract: A dietary supplement composition contains phosphorus and from greater than 1.3 to less than 2.2 parts by weight calcium per part by weight phosphorus, and may, optionally, further contain Vitamin D, Vitamin B12, folate and Vitamin B6, provides components that have been linked to bone health.
Abstract: The invention relates to a block copolymer and more especially to a thermoplastic elastomer block copolymer. The block copolymer is a diblock (block A)-(bloc B) copolymer, a triblock (block A)-(block B)-(block A), or a triblock (block A)-(block B)-(block C) copolymer, wherein block A is a stiff block, block B is a soft block, and block C is a stiff block. Block A or Block B comprises repetitive units deriving from segregation monomers.
Abstract: Viscoelastic surfactant based aqueous fluid systems useful as thickening agents in various applications, e.g. to suspend particles produced during the excavation of geologic formations. The surfactants are zwitterionic/amphoteric surfactants such as dihydroxyl alkyl glycinate, alkyl ampho acetate or propionate, alkyl betaine, alkyl amidopropyl betaine and alkylimino mono- or di-propionates derived from certain waxes, fats and oils. The thickening agent is used in conjunction with an inorganic water-soluble salt or organic additive such as phthalic acid, salicylic acid or their salts.
Type:
Application
Filed:
March 15, 2004
Publication date:
September 9, 2004
Applicant:
RHODIA, INC.
Inventors:
Manilal S. Dahayanake, Jiang Yang, Joseph H. Y. Niu, Paul-Joel Derian, Ruoxin Li, David Dino
Abstract: A process and apparatus for removing or reducing the levels of pathogenic bacteria present on an eviscerated carcass. The process includes introducing the eviscerated carcass to a cleaning apparatus. The cleaning apparatus generally includes a housing structure having an entrance and an exit. Disposed within the housing structure is a rotating brush assembly and a spray assembly. The brushing assembly provides brushing and massaging actions to the surfaces of the carcass whereas the spraying assembly simultaneously directs a cleaning solution onto the surfaces of the carcass.
Abstract: A composition and processes for treating meat to reduce and or prevent the occurrence of pale, soft, and exudative characteristics in the meat. The composition generally comprises a phosphate compound, a protein, carrageenan, and a hydrocolloid other carrageenan. The composition can be further formulated into a brine solution.
Abstract: A process and apparatus for removing or reducing the levels of pathogenic bacteria present on an eviscerated carcass. The process includes introducing the eviscerated carcass to a cleaning apparatus. The cleaning apparatus generally includes a housing structure having an entrance and an exit. Disposed within the housing structure is a rotating brush assembly and a spray assembly. The brushing assembly provides brushing and massaging actions to the surfaces of the carcass whereas the spraying assembly simultaneously directs a cleaning solution onto the surfaces of the carcass.
Abstract: A sulfonated polyester compound useful as a soil release agent having isophthalate and terephthalate groups wherein the molar ratio of isophthalate groups to terephthalate groups is at least 0.15.
Type:
Grant
Filed:
July 23, 2002
Date of Patent:
December 2, 2003
Assignee:
Rhodia Inc
Inventors:
Shiming Wo, Jeanne Chang, Stephen Kauder
Abstract: There is a method of coating a carbonyl-containing plastic substrate. The method has the step of applying to the substrate a paint having a latex polymer having imidazolidone monomeric content up to about 50 wt % based upon the weight of the latex polymer.
Abstract: An antibacterial composition comprising: (a) a first component including at least one gram positive bacteristatic or bactericidal compound selected from the group consisting of: antibiotics, pediocin, and lacticin class bacteriocins, and lytic enzymes; and (b) a second component including at least one compound selected from the group consisting of hops acids, or hops acid derivatives, hops resin; and hops resin derivatives; and the method of applying said composition to the surfaces of solid food.
Abstract: An improved method for making polyphosphoric acid from phosphoric acid includes the steps of introducing a first phosphoric acid feed stream into the top end of a packed column, introducing a second phosphoric acid feed stream into a stream of hot air to form a stream of hot air and acid, introducing the stream of hot air and acid into the bottom end of the column, and polymerizing phosphoric acid of the first and second phosphoric acid feed streams to make polyphosphoric acid. By-product phosphoric acids containing organic contaminants may be substituted for all or part of the phosphoric acid stream being introduced into the bottom end of the column to allow recovery of the phosphorus values of the by-product phosphoric acids.
Type:
Grant
Filed:
March 25, 2002
Date of Patent:
September 9, 2003
Assignee:
Rhodia Inc.
Inventors:
Dennis L. Myers, Robert W. Hudson, Nathan P. Mills, David Michael Razmus, Vincent Payen
Abstract: Acetaminophen compositions are disclosed which are capable of being directly compressed, without addition of other components, into an tablet dosage form, and which include, based on the total weight of the dry components of the composition, from about 80 percent by weight to about 98 percent by weight acetaminophen, a fluidizing agent, a binder compound, a starch, a disintegrant and a lubricant.
Type:
Grant
Filed:
March 14, 2001
Date of Patent:
August 19, 2003
Assignee:
Rhodia Inc.
Inventors:
Ajay Hasmukhlal Upadhyay, Wayne Camarco
Abstract: Disclosed is a process for making alkoxylates of organic compounds. The process requires a) providing an active hydrogen organic compound having 1 to 22 carbon atoms, and b) alkoxylating the organic compound with an alkylene oxide in the presence of a catalytically effective amount of a catalyst compound corresponding to either formula (I) or formula (II):
B(&phgr;)3 (I)
H+B(&phgr;)4− (II)
wherein B is a boron atom and H is a hydrogen atom; &phgr; is a phenyl moiety having substituents selected from the group consisting of 1 to 5 fluorine atoms, 1 to 5 CF3 moieties, 1 to 5 OCF3 or SCF3 moieties or OR; wherein C is a carbon atom, O is an oxygen atom, S is a sulfur atom and F is a fluorine atom; wherein R is a hydrogen atom or an alkyl or aryl group having from 1 to 22 carbon atoms. The process affords a product of very narrow molecular weight distribution with a low degree of both residual active hydrogen organic starting material and undesirable by-products.
Abstract: Phosphinato-substituted propane- and butanepolycarboxylic acids and derivatives thereof are useful as crosslinking agents for cellulosic materials to render them wrinkle resistant and/or iron free in a durable press process.
Abstract: There is provided a process for treating industrial wastewater that substantially eliminates the generation of excess solids in the system requiring mechanical removal. The wastewater undergoes an equalization step wherein hydraulic flow is smoothed and the pH of the wastewater is adjusted to near neutral pH conditions. The equalized wastewater is then transferred to aeration tanks where the organic process wastes are absorbed, metabolized, or otherwise biodegraded by the microorganisms in the mixed liquor in the aeration tanks. After the aeration step, the wastewater is separated by gravity in a clarifying step to separate the wastewater into a liquid phase and a semi-solid phase. The clarified liquid phase is withdrawn from the clarifier and discharged, while the semi-solid phase is transferred either directly back to the aeration/biological treatment step, as recycle-activated sludge, or into a bioreactor as waste-activated sludge. In the bioreactor the semi-solid phase is subjected to active aeration.
Abstract: A method of producing sulfonated polyester compounds suitable for use as a soil releasing agent and/or textile sizing agent in which a sulfonated acid or ester is reacted with a hydroxy-containing compound to form a sulfonated hydroxy terminated ester which then undergoes a transesterification reaction with a poly(ethylene) terephthalate based polyester followed by polycondensation to form the desired sulfonated polyester compound.