Patents Assigned to Senju Metal Industry Co., Ltd.
  • Patent number: 11590614
    Abstract: A flux comprising an organic acid; a solvent; and polyoxyethylene behenyl alcohol having an average number of moles of ethylene oxide added of 7 to 40 mol.
    Type: Grant
    Filed: October 21, 2019
    Date of Patent: February 28, 2023
    Assignee: SENJU METAL INDUSTRY CO., LTD.
    Inventors: Ayaka Shirakawa, Hiroshi Sugii, Atsumi Takahashi, Daisuke Maruko, Hiroyoshi Kawasaki, Masato Shiratori
  • Patent number: 11583959
    Abstract: A solder alloy is provided which suppresses the change in a solder paste over time, decreases the temperature difference between the liquidus-line temperature and the solidus temperature, and exhibits a high reliability. The solder alloy has an alloy constitution composed of: 10 ppm by mass or more and less than 25 ppm by mass of As; at least one selected from the group consisting of 0 ppm by mass to 10000 ppm by mass of Bi and 0 ppm by mass to 5100 ppm by mass of Pb; more than 0 ppm by mass and no more than 3000 ppm by mass of Sb; and a remaining amount of Sn; and satisfies both the formula (1) and the formula (2). 300?3As+Sb+Bi+Pb??(1) 0.1?{(3As+Sb)/(Bi+Pb)}×100?200??(2) In the formula (1) and the formula (2), As, Sb, Bi, and Pb each represents an amount thereof (ppm by mass) in the alloy constitution.
    Type: Grant
    Filed: January 31, 2020
    Date of Patent: February 21, 2023
    Assignee: SENJU METAL INDUSTRY CO., LTD.
    Inventors: Hiroyoshi Kawasaki, Osamu Munekata, Masato Shiratori
  • Patent number: 11577344
    Abstract: A solder alloy has an alloy composition consisting of, in mass %, Ag: 0 to 4%, Cu: 0.1 to 1.0%, Ni: 0.01 to 0.3%, Sb: 5.1 to 7.5%, Bi: 0.1 to 4.5%, Co: 0.001 to 0.3%, P: 0.001 to 0.2%, and the balance being Sn.
    Type: Grant
    Filed: July 28, 2021
    Date of Patent: February 14, 2023
    Assignee: SENJU METAL INDUSTRY CO., LTD.
    Inventors: Yuuki Iijima, Shunsaku Yoshikawa, Takashi Saito
  • Publication number: 20230039027
    Abstract: In a layered bonding material 10, a coefficient of linear expansion of a base material 11 is 5.5 to 15.5 ppm/K and a first surface and a second surface of the base material 11 are coated with pieces of lead-free solder 12a and 12b.
    Type: Application
    Filed: March 19, 2021
    Publication date: February 9, 2023
    Applicant: SENJU METAL INDUSTRY CO., LTD.
    Inventors: Naoto KAMEDA, Masato TSUCHIYA, Katsuji NAKAMURA, Osamu MUNEKATA, Kaichi TSURUTA
  • Patent number: 11571772
    Abstract: Provided is a flux that allows soldering to be performed without requiring a step of removing a Cu-OSP film even with a Cu-OSP processed substrate. This flux containing rosin, an organic acid, a benzimidazole-based compound, and a solvent is characterized in that 30% by mass or more and 70% by mass or less of the rosin, 1% by mass or more and 10% by mass or less of the organic acid, 0.2% by mass or more and 10% by mass or less of the benzimidazole-based compound, and 20% by mass or more and 60% by mass or less of the solvent, wherein the benzimidazole-based compound is composed of at least one of 2-alkylbenzimidazole and a salt of 2-alkylbenzimidazole hydrohalide.
    Type: Grant
    Filed: January 24, 2020
    Date of Patent: February 7, 2023
    Assignee: Senju Metal Industry Co., Ltd.
    Inventors: Takahiro Nishizaki, Takashi Hagiwara, Hiroyoshi Kawasaki
  • Patent number: 11571770
    Abstract: Provided are a solder alloy which has excellent temperature cycle characteristics and in which yellowish discoloration is suppressed, excellent wettability is maintained, and an increase in viscosity of a solder paste over time can be suppressed, and a solder paste, a solder ball, and a solder joint in which the solder alloy is used. The solder alloy consists of, by mass %, 1.0% to 5.0% of Ag, 0.5% to 3.0% of Cu, 0.5% to 7.0% of Sb, 0.0040% to 0.025% of As, and a balance of Sn.
    Type: Grant
    Filed: May 15, 2020
    Date of Patent: February 7, 2023
    Assignee: SENJU METAL INDUSTRY CO., LTD.
    Inventors: Hiroyoshi Kawasaki, Masato Shiratori, Yuji Kawamata
  • Patent number: 11571771
    Abstract: If a flux contains an amount of thixotropic agent necessary for obtaining the effect of suppressing a heating sagging, the amount of flux residue increases, and, if applied for uses that do not involve washing, a large amount of flux residue derived from the thixotropic agent remains around the soldered portions, thereby affecting chemical and electrical reliability; and that washing performance is poor in uses involving washing of the flux residue. Accordingly, this soldering flux contains nanofibers of one or more kinds from among polysaccharides, modified polysaccharides, and incompletely modified polysaccharides being modified from polysaccharides into modified polysaccharides, by an amount of 50 wt ppm or more and 3000 wt ppm or less with respect to a total amount of flux.
    Type: Grant
    Filed: July 9, 2018
    Date of Patent: February 7, 2023
    Assignee: Senju Metal Industry Co., Ltd.
    Inventors: Kazuya Kitazawa, Takayuki Kobayashi, Yusuke Kawano
  • Publication number: 20220402057
    Abstract: A magnetic-field melting solder that melts by the action of an AC magnetic field is provided. The magnetic-field melting solder includes solder material; and magnetic material composing of ferrite or Ni, a proportion of the magnetic material to the entire magnetic-field melting solder being 0.005% to 5% by weight. A joining method using the magnetic-field melting solder includes providing the magnetic-field melting solder between an electrode on a substrate and an electrode of an electronic component, and joining together the electrode on the substrate and the electrode of the electronic component by generating an AC magnetic field around the substrate and thereby melting the magnetic-field melting solder.
    Type: Application
    Filed: November 18, 2020
    Publication date: December 22, 2022
    Applicants: SENJU METAL INDUSTRY CO., LTD., National Institute of Advanced Industrial Science and Technology
    Inventors: Haruya SAKUMA, Kenichi TOMITSUKA, Hisahiko YOSHIDA, Kenji KANAZAWA, Sei UEMURA, Takashi NAKAMURA, Masateru NISHIOKA
  • Publication number: 20220355420
    Abstract: A solder alloy comprises Ag: 3.1 to 4.0% by mass, Cu: 0.6 to 0.8% by mass, Bi: 1.5 to 5.5% by mass, Sb: 1.0 to 6.0% by mass, Co: 0.001 to 0.030% by mass, Fe: 0.02 to 0.05% by mass, and a balance Sn.
    Type: Application
    Filed: June 22, 2021
    Publication date: November 10, 2022
    Applicant: SENJU METAL INDUSTRY CO., LTD.
    Inventors: Shunsaku YOSHIKAWA, Takashi SAITO, Yuuki IIJIMA, Kanta DEI, Takahiro MATSUFUJI
  • Patent number: 11495566
    Abstract: A core material has a core; a solder layer provided outside the core and being a solder alloy containing Sn and at least any one element of Ag, Cu, Sb, Ni, Co, Ge, Ga, Fe, Al, In, Cd, Zn, Pb, Au, P, S, Si, Ti, Mg, Pd, and Pt; and a Sn layer provided outside the solder layer. The solder layer has a thickness of 1 ?m or more on one side. The Sn layer has a thickness of 0.1 ?m or more on one side. A thickness of the Sn layer is 0.215% or more and 36% or less of the thickness of the solder layer.
    Type: Grant
    Filed: September 10, 2021
    Date of Patent: November 8, 2022
    Assignee: SENJU METAL INDUSTRY CO., LTD.
    Inventors: Shigeki Kondoh, Masato Tsuchiya, Hiroyuki Iwamoto, Hiroshi Okada, Daisuke Souma
  • Patent number: 11478869
    Abstract: A method includes applying a first flux onto an electrode provided on a substrate and placing a solder material on the electrode, heating the substrate to form a solder bump on the electrode, deforming the solder bump to provide a flat surface or a depressed portion on the solder bump, applying a second flux to the solder bump; placing a core material on the solder bump, the core material including a core portion and a solder layer that covers a surface of the core portion, and heating the substrate to join the core material to the electrode by the solder bump and the solder layer.
    Type: Grant
    Filed: June 3, 2021
    Date of Patent: October 25, 2022
    Assignee: SENJU METAL INDUSTRY CO., LTD.
    Inventors: Takahiro Hattori, Hiroki Sudo, Hiroshi Okada, Daisuke Souma
  • Publication number: 20220331916
    Abstract: A solder paste includes a solder powder and a flux. The flux includes a rosin, an activator, a solvent, and a thixotropic agent containing a polyethylene glycol. A content of the polyethylene glycol is 10 mass % to 20 mass % with respect to a total mass of the flux, a content of the thixotropic agent excluding the polyethylene glycol is 5 mass % or less with respect to the total mass of the flux, and a content of the rosin is more than 15 mass % and 50 mass % or less with respect to the total mass of the flux.
    Type: Application
    Filed: August 28, 2020
    Publication date: October 20, 2022
    Applicant: SENJU METAL INDUSTRY CO., LTD.
    Inventors: Ryuji UKAI, Kengo OHTA, Sakie OKADA, Kazuya KITAZAWA
  • Patent number: 11465244
    Abstract: A solder alloy that contains 0.005 mass % or more and 0.1 mass % or less of Mn, 0.001 mass % or more and 0.1 mass % or less of Ge, and a balance of Sn. A plurality of Ge oxides is distributed on an outermost surface side of an oxide film including Sn oxide, Mn oxide and Ge oxide by adding 0.005 mass % or more and 0.1 mass % or less of Mn, 0.001 mass % or more and 0.1 mass % or less of Ge to the solder alloy having a principal ingredient of Sn, so that it is possible to obtain the discolor-inhibiting effect even under the high-temperature and high-humidity environment.
    Type: Grant
    Filed: February 15, 2016
    Date of Patent: October 11, 2022
    Assignee: Senju Metal Industry Co., Ltd.
    Inventors: Ken Tachibana, Takahiro Hattori
  • Patent number: 11413711
    Abstract: Provided are a flux, resin flux cored solder and a flux coated pellet which are washable with water. Resin flux cored solder is composed of solder having a linear shape and a flux filled in a substantially central part (core) of the cross section of the solder. The flux contains an amine for salt formation and an organic acid for salt formation, in which the amount of the organic acid is within a range between 10 parts by mass or more and 645 parts by mass or less based on 100 parts by mass of the amine. The organic acid for salt formation is composed of at least one organic acid selected from the group consisting of malonic acid, succinic acid, glutaric acid, tartaric acid, malic acid, diglycolic acid, and citric acid.
    Type: Grant
    Filed: November 13, 2018
    Date of Patent: August 16, 2022
    Assignee: Senju Metal Industry Co., Ltd.
    Inventors: Motohiro Onitsuka, Yoko Kurasawa, Hiroyuki Yamasaki, Atsumi Takahashi, Toshihisa Kugi, Hiroyoshi Kawasaki
  • Patent number: 11407068
    Abstract: Provided are a flux composition that is applicable without any film formation step, and solder paste, a solder joint and a solder joining method using the flux composition. The flux composition contains 20 wt % or more and 50 wt % or less of an epoxy resin, 15 wt % or more and 45 wt % or less of diallyl bisphenol A, and 1 wt % or more and 30 wt % or less of organic acid.
    Type: Grant
    Filed: August 1, 2019
    Date of Patent: August 9, 2022
    Assignee: Senju Metal Industry Co., Ltd.
    Inventors: Yasuhiro Kajikawa, Hiroyoshi Kawasaki, Hiroshi Sugii, Yoshinori Hiraoka
  • Publication number: 20220212294
    Abstract: A core material has a core 12; a solder layer 16 made of a (Sn—Bi)-based solder alloy provided on an outer side of the core 12; and a Sn layer 20 provided on an outer side of the solder layer 16. The core contains metal or a resin. When a concentration ratio of Bi contained in the solder layer 16 is a concentration ratio (%)=a measured value of Bi (% by mass)/a target Bi content (% by mass), or a concentration ratio (%)=an average value of measured values of Bi (% by mass)/a target Bi content (% by mass), the concentration ratio is 91.4% to 106.7%. The thickness of the Sn layer 20 is 0.215% or more and 36% or less of the thickness of the solder layer 16.
    Type: Application
    Filed: September 30, 2020
    Publication date: July 7, 2022
    Applicant: SENJU METAL INDUSTRY CO., LTD.
    Inventors: Shigeki KONDOH, Masato TSUCHIYA, Hiroki SUDO, Hiroshi OKADA, Daisuke SOUMA
  • Patent number: 11376694
    Abstract: Provided is flux that can achieve a low residue so as to make it possible to ensure solder wettability, ensure holding properties of a solder ball, and suppress the amount of residue after soldering and enable application for use without washing. The flux includes 1-15% by weight of an organic acid mixture comprising an organic acid with 10 or more carbon atoms, 50-90% by weight of isobornyl cyclohexanol, and 5-45% by weight of a different solvent. The proportion of the isobornyl cyclohexanol is 50-95% by weight, where 100% by weight is the total of the isobornyl cyclohexanol and the different solvent. The organic acid mixture comprising the organic acid with 10 or more carbon atoms comprises 2-methylnonanedioic acid, 4-(methoxycarbonyl)-2,4-dimethylundecanedioic acid, 4,6-bis(methoxycarbonyl)-2,4,6-trimethyldecanedioic acid, and 8,9-bis(methoxycarbonyl)-8,9-dimethylhexadecanedioic acid.
    Type: Grant
    Filed: January 15, 2019
    Date of Patent: July 5, 2022
    Assignee: Senju Metal Industry Co., Ltd.
    Inventors: Tomohisa Kawanago, Miyuki Hiraoka, Takahiro Nishizaki, Hiroyoshi Kawasaki, Masato Shiratori
  • Patent number: 11377715
    Abstract: Provided are a solder alloy, which has excellent heat cycle characteristics and in which Cu erosion and yellowish discoloration are suppressed, and an increase in viscosity of a solder paste over time is suppressed, a solder paste, a solder ball, a solder preform, a solder joint, and a circuit. The solder alloy has an alloy composition consisting of, by mass %, 2.8% to 4% of Ag, 1.5% to 6% of Bi, 0.8% to 1.2% of Cu, 0.0040% to 0.025% of As, and a balance of Sn.
    Type: Grant
    Filed: May 15, 2020
    Date of Patent: July 5, 2022
    Assignee: SENJU METAL INDUSTRY CO., LTD.
    Inventors: Hiroyoshi Kawasaki, Masato Shiratori, Yuji Kawamata
  • Publication number: 20220203483
    Abstract: A flux according to the present invention contains a rosin methyl ester in which the flux is a solid or solid-like flux at 25° C., and is used for an inside of a flux-cored solder or an exterior of a flux-coated solder.
    Type: Application
    Filed: February 1, 2021
    Publication date: June 30, 2022
    Applicant: SENJU METAL INDUSTRY CO., LTD.
    Inventors: Yoko Kurasawa, Hiroaki Iseki, Kenta Nakajima
  • Patent number: 11370069
    Abstract: The object of the present invention is to provide a flux composition and a solder paste composition in which scattering of flux is suppressed. A flux composition comprising an anti-scattering agent represented by formula (1) below, wherein Z is optionally substituted alkylene, R1 and R2 are each independently optionally substituted alkyl, optionally substituted aralkyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted cycloalkyl, or optionally substituted heterocycloalkyl, R3 and R4 are each independently optionally substituted alkyl.
    Type: Grant
    Filed: April 12, 2018
    Date of Patent: June 28, 2022
    Assignee: SENJU METAL INDUSTRY CO., LTD.
    Inventors: Tomoko Nonaka, Tomoko Nagai