Patents Assigned to Toa Nenryo Kogyo Kabushiki Kaisha
  • Patent number: 4737481
    Abstract: A process for producing catalyst ingredient for use in olefin polymerization which comprises contacting (A) a magnesium hydrocarbyloxide and (B) a silicon compound having hydrogen-silicon bonds in the presence of a hydrocarbon medium, contacting the thus obtained solid product (C) a halogenated titanium compound in the presence or absence of a hydrocarbon medium and then adding to contact (D) an electron donating compound.
    Type: Grant
    Filed: December 17, 1986
    Date of Patent: April 12, 1988
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Masahide Murata, Hiroyuki Furuhashi, Masafumi Imai, Hiroshi Ueno
  • Patent number: 4737555
    Abstract: A process for producing a catalyst component for polymerization of olefins which comprises contacting (a) a metal oxide with (b) an organomagnesium compound represented by the formula RMgR' wherein R denotes a hydrocarbyl group and R' denotes a hydrocarbyl group or a halogen atom, contacting the resulting contacting product with (c) carbon dioxide, and further contacting the resulting contact product with (d) a titanium compound. Optionally, the carbon dioxide contacted contact product can be treated with the halogen-containing compound prior to contact with the titanium compound.
    Type: Grant
    Filed: April 22, 1987
    Date of Patent: April 12, 1988
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Mamoru Tachikawa, Satoshi Ueki, Masato Sakuma, Chihiro Imai, Tokuo Makishima
  • Patent number: 4734196
    Abstract: A micro-porous membrane of ultra-high-molecular-weight alpha-olefin polymer having a weight-average molecular weight greater than 5.times.10.sup.5, the micro-porous membrane having through holes 0.01 to 1 micrometer in average pore size, with a void ratio from 30 to 90% and being oriented such that the linear draw ratio in one axis is greater than two and the areal draw ratio is greater than ten. The micro-porous membrane is obtained by forming a gel-like object from a solution of an alpha-olefin polymer having a weight-average molecular weight greater than 5.times.10.sup.5, removing at least 10 wt % of the solvent contained in the gel-like object so that the gel-like object contains 10 to 90 wt % of alpa-olefin polymer, orientating the gel-like object at a temperature lower than that which is 10.degree. C. above the melting point of the alpa-olefin polymer, and removing the residual solvent from the orientated product.
    Type: Grant
    Filed: February 24, 1986
    Date of Patent: March 29, 1988
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Koichi Kono, Shoichi Mori, Kenji Miyasaka, Jyoichi Tabuchi
  • Patent number: 4733820
    Abstract: This invention consists of a vibration element for use on an ultrasonic injection nozzle, the vibrating element being formed around its outer periphery with a multi-stepped edged portion having one or more projecting steps each defining an edge, the edges having the same diameter and the edged portion being adapted to be supplied with liquid.
    Type: Grant
    Filed: December 6, 1985
    Date of Patent: March 29, 1988
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Masami Endo, Kakuro Kokubo, Hideo Hirabayashi, Yoshinobu Nakamura, Daijiro Hosogai
  • Patent number: 4726523
    Abstract: An ultrasonic injection nozzle includes an ultrasonic generator, an elongated vibrating element, a liquid feeder and a solenoid valve. The vibrating element has a first and second end. The generator is connected to the first end. A multi-stepped edge portion is connected to the second end. Each step of the edged portion defines an edge. The liquid feeder is located adjacent the second end. The solenoid valve is in communication with the liquid feeder.
    Type: Grant
    Filed: December 6, 1985
    Date of Patent: February 23, 1988
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Kakuro Kokubo, Masami Endo, Hideo Hirabayashi, Yoshinobu Nakamura, Daijiro Hosogai
  • Patent number: 4726524
    Abstract: The present invention consists of an ultrasonic atomizing vibratory element having a multi-stepped edged portion formed around the outer periphery thereof. The edged portion has at least two steps each defining an edge and being adapted to be supplied with liquid to be atomized. The vibratory element is provided with a liquid supply groove extending generally longitudinally to supply the liquid to the edge portion in a consistent and stable manner.
    Type: Grant
    Filed: May 9, 1986
    Date of Patent: February 23, 1988
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Kiyoe Ishikawa, Hiromi Nakamura
  • Patent number: 4726522
    Abstract: The present invention consists of a vibrating element for ultrasonic atomization formed around its inner or outer periphery with a multi-stepped edged portion having at least two steps, each edged portion defining an edge, the edged portions being supplied with liquid for atomization, wherein the multi-stepped edged portion includes successively connected continuous curved surfaces where the steps are partially formed with a curved surface.
    Type: Grant
    Filed: May 9, 1986
    Date of Patent: February 23, 1988
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Kakuro Kokubo, Masami Endo, Daijiro Hosogai
  • Patent number: 4726525
    Abstract: The present invention consists of a vibrating element for ultrasonic injection in which the edged portion for atomizing liquid includes helical screw threads having either a uniformed diameter or varying diameters.
    Type: Grant
    Filed: May 9, 1986
    Date of Patent: February 23, 1988
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Yoshiaki Yonekawa, Yoshinobu Nakamura, Yoshiyasu Oba
  • Patent number: 4727049
    Abstract: A catalyst component for the polymerization of olefins which is prepared by contacting (1) a contact reaction product of (a) a metal oxide, (b) a dihydrocarbyl magnesium, and (c) a halogen-containing alcohol held with (d) an electron-donating compound, and (e) a titanium compound.
    Type: Grant
    Filed: July 5, 1985
    Date of Patent: February 23, 1988
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Hiroyuki Furuhashi, Tadashi Yamamoto, Masafumi Imai, Hiroshi Ueno
  • Patent number: 4725420
    Abstract: Silanes are produced by the disproportionation and/or redistribution reaction of chlorosilanes using a novel catalyst having a longer life and consisting of a quaternary phosphonium salt bonded to an organic macromolecule or polymer, represented by the following general formula: ##STR1## wherein .circle.P is an organic macromolecule or polymer, A is a bridging group between phosphorus and the organic macromolecule or polymer, R.sup.1, R.sup.2 and R.sup.3 are selected from the group consisting of hydrogen, C.sub.1 -C.sub.20 alkyl groups and aralkyl groups such as benzyl and phenethyl groups, which can contain oxygen or halogen atoms, and X is a halogen atom.
    Type: Grant
    Filed: September 19, 1986
    Date of Patent: February 16, 1988
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Mamoru Tachikawa, Kazutoshi Takatsuna, Kouji Shiozawa, Yoshiharu Okumura, Takeo Koyama
  • Patent number: 4719025
    Abstract: A wear-resistant, synthetic lubricating oil composition comprises as a base oil a synthetic oil mixture consisting of (A) a diester of an aliphatic dibasic acid having 4-14 carbon atoms and an alcohol having so many carbon atoms or a mixture of several such diesters and having a viscosity at 100.degree. C. of 2.0-7.0 mm.sup.2 /s, and (B) a polyoxyalkylene glycol whose alkylene group contains 2-5 carbon atoms or a mixture of several such glycols and having a viscosity at 100.degree. C. of at least 20 mm.sup.2 /s. The base oil exhibits viscosity values of 9 mm.sup.2 /s or above at 100.degree. C. and 6.times.10.sup.4 mPa.s or below at -40.degree. C.
    Type: Grant
    Filed: August 5, 1985
    Date of Patent: January 12, 1988
    Assignees: Toyota Jidosha Kabushiki Kaisha, Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Kenyu Akiyama, Sadao Wada, Michihide Tokashiki
  • Patent number: 4717755
    Abstract: A process for producing a propylene polymer having a carbonyl group at the terminal, said process comprising polymerizing propylene to give a living propylene polymer in the presence of a catalyst composed of beta-diketone vanadium chelate and an aluminum compound represented by the formula R.sub.2 AlX (wherein R is a hydrocarbon group having 1 to 8 carbon atoms and X is a halogen atom), and reacting the living propylene polymer with a carbonylating agent.
    Type: Grant
    Filed: December 19, 1985
    Date of Patent: January 5, 1988
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Yoshiharu Doi, Kazuo Soga, Satoshi Ueki, Makoto Miyazaki
  • Patent number: 4716206
    Abstract: A process for homopolymerizing an olefin or copolymerizing an olefin with another olefin in the presence of a catalyst composed of(a) a solid catalyst component containing magnesium atoms, titanium atoms, halogen atoms, and an electron donor compound,(b) an organoaluminum compound represented by the formula R.sup.1 R.sup.2 R.sup.3 Al (wherein R.sup.1, R.sup.2, and R.sup.3, which may be the same or different, each denote a C.sub.1-20 alkyl, alkenyl, cycloalkyl, aryl, aralkyl, or alkoxy group, or a hydrogen atom;(c) an organoaluminum compound represented by the formula R.sup.4.sub.3-n AlX.sub.n (wherein R.sup.4 denotes a C.sub.1-20 alkyl, alkenyl, cycloalkyl, aryl, aralkyl, or alkoxy group; X denotes a halogen atom; and n.gtoreq.1),(d) an electron donor compound containing a nitrogen atom, sulfur atom, oxygen atom, or phosphorus atom, and(e) an aromatic ester compound.
    Type: Grant
    Filed: November 5, 1986
    Date of Patent: December 29, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Masahito Fujita, Masami Kizaki, Makoto Miyazaki, Naomi Inaba
  • Patent number: 4711940
    Abstract: A process for preparing a catalyst component for the polymerization of olefins which comprises the steps of contacting (a) a magnesium dialkoxide soluble in an inert solvent, (b) a silicon compound having the hydrogen-silicon bond, and (c) an electron donor compound with one another in the presence of an inert solvent, and contacting the resulting reaction product with (d) a titanium compound.
    Type: Grant
    Filed: October 29, 1986
    Date of Patent: December 8, 1987
    Assignee: TOA Nenryo Kogyo Kabushiki Kaisha
    Inventors: Tadashi Yamamoto, Masafumi Imai, Hiroyuki Furuhashi, Hiroshi Ueno, Naomi Inaba
  • Patent number: 4711939
    Abstract: A catalyst component for polymerization of olefins which is prepared by reacting a magnesium alkoxide with a silicon compound having at least one hydrogen-silicon bond, contacting the reaction product with a carboxylic acid halide and/or carboxylic acid anhydride, and contacting the resulting contact product with a titanium compound.
    Type: Grant
    Filed: October 30, 1986
    Date of Patent: December 8, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Masafumi Imai, Tadashi Yamamoto, Hiroyuki Furuhashi, Hiroshi Ueno, Naomi Inaba
  • Patent number: 4705830
    Abstract: A block copolymer is disclosed which includes an ethylene-propylene copolymer segment (A) and a tetrahydrofuran segment (B). The weight ratio of (A) to (B) is 5/95 to 95/5, and the block copolymer has a number-average molecular weight of about 1,000 to about 1,000,000.
    Type: Grant
    Filed: May 24, 1985
    Date of Patent: November 10, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Tokuo Makishima, deceased, by Nobuko Makishima, legal representative, by Satoshi Ueki, legal representative, by Chichiro Imai, legal representative
  • Patent number: 4704196
    Abstract: A process for the surface treatment of carbon fiber tows each consisting of a multiplicity of filaments, comprises treating the tows by electrolytic oxidation, using each tow as a positive electrode and applying an electric current in the form of pulses. The pulse spacing is such that the electric supply and non-supply durations are 0.02-20 sec. each, preferably 0.1-5 seconds each. The pulse shape is rectangular, triangular, or sine waves. The applied voltage is 3-15 V and the current density 0.2-1000 A/m.sup.2, preferably 1-100 A/m.sup.2, more preferably 5-20 A/m.sup.2. The electrolyte is an aqueous solution of an oxidizing agent, strong acid or base, neutral salt, or weak acid or base.
    Type: Grant
    Filed: November 17, 1986
    Date of Patent: November 3, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Makoto Saito, Hiroshi Inoue, Noboru Yamamoto
  • Patent number: 4704438
    Abstract: A novel styrene copolymer having a functional group, i.e. silyl group on the para-position of the aromatic ring, useful as a functional polymer, is provided. An effective process for the production thereof comprises contacting a random or block copolymer of p-methylstyrene and .alpha.-methylstyrene with an organolithium compound to lithiate partly the p-methyl group in the copolymer and then reacting the lithiated copolymer with a silicon compound represented by the general formula (R.sup.1)(R.sup.2)(R.sup.3)SiX wherein R.sup.1, R.sup.2 and R.sup.3 are, same or different, alkyl groups with 1 to 6 carbon atoms or alkenyl groups with 2 to 6 carbon atoms, at least one of R.sup.1, R.sup.2 and R.sup.3 being an alkenyl group, and X is a halogen atom.
    Type: Grant
    Filed: April 6, 1987
    Date of Patent: November 3, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Tadashi Niwa, Masayuki Kato, Yoshio Taguchi, Chihiro Imai
  • Patent number: 4704433
    Abstract: A novel block copolymer is disclosed which includes a random ethylene-propylene copolymer segment (A) and a methacrylate segment (B). The block copolymer has a number-average molecular weight of about 1,000 to about 600,000 and a ratio of (A) to (B) of 15/85 to 97/3 by weight.
    Type: Grant
    Filed: May 24, 1985
    Date of Patent: November 3, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Satoshi Ueki, Chihiro Imai, Tokuo Makishima, deceased
  • Patent number: 4702414
    Abstract: An ultrasonic injection nozzle includes an ultrasonic vibration generating device and a vibrating element. The vibrating element is connected to the vibration generating device so as to be vibrated thereby. The vibrating element has formed at its forward end an edged portion to and along which a liquid material is delivered to be atomized.
    Type: Grant
    Filed: April 15, 1985
    Date of Patent: October 27, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Hideo Hirabayashi, Masami Endo, Kakuro Kokubo