Patents Assigned to Toa Nenryo Kogyo Kabushiki Kaisha
  • Patent number: 4695557
    Abstract: A catalyst for polymerization of olefins which comprises a vanadium compound of the formula: ##STR1## (where R.sup.1 is an alkyl group or aryl group having 1 to 8 carbon atoms; and R.sup.2 is an alkyl group or aryl group having from 1 to 8 carbon atoms, or hydrogen)and the organoaluminum compound of the formula R.sub.2 AlX (where R is a hydrocarbon group having 1 to 8 carbon atoms, and X is a halogen atom).
    Type: Grant
    Filed: June 17, 1986
    Date of Patent: September 22, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Shigeo Suzuki, Yoshiharu Doi, Kazuo Soga
  • Patent number: 4693990
    Abstract: A titamium containing catalyst component for olefin polymerizations which comprises contacting (a) a metal oxide, (b) a dihydrocarbyl magnesium, and (c) a hydrocarbyloxy group-containing compound with one another, contacting the thus obtained contact product with (d) a halogen-containing alcohol, and finally contacting the thus obtained contact product with (e) an electron donor compound and (f) a titanium compound.
    Type: Grant
    Filed: July 3, 1986
    Date of Patent: September 15, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Furuhashi Hiroyuki, Tadashi Yamamoto, Masafumi Imai, Hiroshi Ueno
  • Patent number: 4691070
    Abstract: A catalyst for the hydrogenation of a diolefin, having palladium or a compound thereof and at least one co-catalyst component selected from the group consisting of ruthenium, rhodium, cobalt, and rhenium supported each in the form of an elemental metal or a metal compound on a support, its method of preparation and its use for said hydrogenation, particularly for the hydrogenation of cyclopentadiene to cyclopentene is described herein.
    Type: Grant
    Filed: November 20, 1986
    Date of Patent: September 1, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Teiji Nakamura, Eiichiro Nishikawa, Takeo Koyama
  • Patent number: 4686265
    Abstract: A process for polymerizing one or more alpha-olefins in the presence of a catalyst system comprising (A) a solid titanium containing catalyst component said component prepared by contacting a magnesium alkoxide, a halogenated hydrocarbon, an electron donor and a titanium compound with one another, and (B) an organoaluminum cocatalyst. In preferred embodiments, the magnesium alkoxide is first contacted with a magnesium halide. The solid titanium containing compound can be treated with an organoaluminum compound.
    Type: Grant
    Filed: May 29, 1986
    Date of Patent: August 11, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Kouji Maruyama, Takeshi Nomura, Hiroshi Ueno, Naomi Inaba
  • Patent number: 4686199
    Abstract: A process for producing a catalyst component for polymerization of olefins which comprises contacting (a) a metal oxide with (b) a magnesium alkoxide, contacting the resulting contact product with (c) a halogen-containing compound, and finally contacting the resulting contact product with (d) a titanium compound.
    Type: Grant
    Filed: November 27, 1985
    Date of Patent: August 11, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Mamoru Tachikawa, Masato Sakuma, Satoshi Ueki, Chihiro Imai, Tokuo Makishima
  • Patent number: 4684578
    Abstract: Modified polymer compositions comprising elastomers blended with not more than 50 parts by weight of a crystalline polyolefin are prepared by reaction of the polymers with an unsaturated carboxylic acid or its acid anhydride. The modified composition optionally containing a filler, is particularly suitable for laminating to metals and other polymers; laminates show superior hot water resistance, salt water resistance and thermal shock resistance.
    Type: Grant
    Filed: October 10, 1986
    Date of Patent: August 4, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Inoue, Makoto Miyazaki, Masaaki Isoi, Makoto Yoda
  • Patent number: 4683275
    Abstract: A copolymer of p-methylstyrene and N-substituted maleimide exhibits high temperature stability.
    Type: Grant
    Filed: September 20, 1985
    Date of Patent: July 28, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Masayuki Kato, Yoshio Taguchi, Chihiro Imai, Tokuo Makishima, deceased
  • Patent number: 4678768
    Abstract: A catalyst component for polymerization of olefins which is prepared by contacting a product obtained by contacting (A) a magnesium alkoxide, (B) a silicon compound having the hydrogen-silicon bond, and (C) a titanium compound with one another, with (D) (a) a hydrocarbon, (b) a halogenated hydrocarbon, and/or (c) a halide of an element selected from the elements of Groups IIIa, IVa, and Va of the Periodic Table.
    Type: Grant
    Filed: June 21, 1985
    Date of Patent: July 7, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Masahito Fujita, Makoto Miyazaki, Masami Kizaki, Yukio Nagashima, Yuichi Shimbori
  • Patent number: 4678767
    Abstract: A process for producing a catalyst component for polymerization of olefins which comprises contacting (a) a metal oxide with (b) an organomagnesium compound represented by the formula RMgR' wherein R denotes a hydrocarbyl group and R' denotes a hydrocarbyl group or a halogen atom, contacting the resulting contacting product with (c) carbon dioxide, and further contacting the resulting contact product with (d) a titanium compound. Optionally, the carbon dioxide contacted product can be treated with the halogen-containing compound prior to contact with the titanium compound.
    Type: Grant
    Filed: November 27, 1985
    Date of Patent: July 7, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Mamoru Tachikawa, Satoshi Ueki, Masato Sakuma, Chihiro Imai, Tokuo Makishima
  • Patent number: 4670202
    Abstract: In a melt spinning operation, a heated wash gas such as nitrogen or nitrogen and air is blown across the melt spinning nozzles to remove volatiles thereby preventing wetting of the nozzle discharge. The wash gas is maintained at a temperature substantially equal to the melt spinning temperature. The preferred melt spinning material is petroleum pitch.
    Type: Grant
    Filed: February 21, 1984
    Date of Patent: June 2, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Yoshio Uenoyama, Kiyoshi Takazawa, Takayuki Izumi
  • Patent number: 4664775
    Abstract: This invention relates to a method for catalytically manufacturing a low pour point petroleum product from distillates of crude oil, and more particularly to a method for economically manufacturing a low pour point petroleum product, such as the insulating oil, the lubricating oil used for various types of freezing devices, or the base oil for such lubricating oil, from a paraffin-based crude oil as the starting material without using any special rare crude oil such as naphthene-based crude oil. The catalyst comprises zeolite TSZ.
    Type: Grant
    Filed: July 26, 1983
    Date of Patent: May 12, 1987
    Assignee: TOA Nenryo Kogyo Kabushiki Kaisha
    Inventors: Tsugio Maejima, Wataru Kobayashi, Kenji Ashibe, Nobuaki Tagaya, Satoshi Sakurada
  • Patent number: 4659617
    Abstract: The present invention provides a fibrous product of apatite comprising one or more apatites selected from a group of apatites represented by the general formula:M.sub.10 (ZO.sub.4).sub.6 X.sub.2wherein M represents Ca, Ba, Mg, Sr, Pb, Cd, Fe and the like, ZO.sub.4 represents PO.sub.4, AsO.sub.4, VO.sub.4, CO.sub.3 and the like, and X represents F, Cl, OH and the like. This fibrous product of apatite has many applications such as uses for medical treatment, large scale microorganism cultivating media and others, and particularly it is useful as apatite implant materials having a good compatibility with living organism and superior workability.A fibrous apatite product of this invention may be produced by a method comprising the steps of:(a) preparing a dispersion of apatite by dispersing fine apatite particles uniformly in a solution of binder in water, said apatite being one or more apatites selected from a group of apatites represented by the general formula:M.sub.10 (ZO.sub.4).sub.6 X.sub.
    Type: Grant
    Filed: September 6, 1985
    Date of Patent: April 21, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Shigeo Fujii, Shoichi Mori, Jyoichi Tabuchi
  • Patent number: 4659850
    Abstract: A novel polyorgano(hydro)silazane having the compositional formula: (RSiHNH).sub.x [(RSiH).sub.1.5 N].sub.1-x, wherein R is an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, another group in which the atom directly bound to Si is carbon, an alkylsilyl group, an alkylamino group, or an alkoxy group, and 0.4<x<1. This polyorgano(hydro)silazane is produced by reacting a complex of organo(hydro)diholosilane and a base with dry ammonia. This novel silazane is useful as a ceramic starting material, a polymer hardening agent, a densifying agent, a surface coating material, etc., and can be produced safely and at a low cost.
    Type: Grant
    Filed: April 9, 1986
    Date of Patent: April 21, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Mikiro Arai, Takeshi Isoda, Osamu Funayama
  • Patent number: 4657980
    Abstract: A thermoplastic resin composition which comprises 80 to 95 wt % of polycarbonate resin and 5 to 20 wt % of poly-p-methylstyrene. The thermoplastic resin composition is useful as a molding material for automotive parts, electric appliances, other industrial products and articles for daily use.
    Type: Grant
    Filed: October 18, 1985
    Date of Patent: April 14, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Yuji Fujita, Noboru Yamamoto
  • Patent number: 4655902
    Abstract: In a process for producing an optically anisotropic carbonaceous pitch having a low softening point for the production of carbon material starting oil to be used is a tar-like substance which is a mixture of compounds not substantially containing chloroform insolubles but containing components having a boiling point of 540.degree. C. or more as principal components and consisting principally of carbon and hydrogen. The tar-like substance has a content of n-heptane insolubles of up to 1 wt % and contains an aromatic oil fraction and a resin fraction as the principal components of n-heptane soluble components. The aromatic carbon fraction, fa, is at least 0.7, the number-average molecular weight is up to 1,000 and the maximum molecular weight is up to 2,000 for each of the aromatic oil and resin fractions.
    Type: Grant
    Filed: September 3, 1985
    Date of Patent: April 7, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Takayuki Izumi, Tsutomu Naito, Masuo Shinya, Tomio Nomura
  • Patent number: 4654318
    Abstract: A process for preparing a catalyst component for the polymerization of olefins which comprises the steps of contacting (a) a magnesium dialkoxide soluble in an inert solvent, (b) a silicon compound having the hydrogen-silicon bond, and (c) an electron donor compound with one another in the presence of an inert solvent, and contacting the resulting reaction product with (d) a titanium compound.
    Type: Grant
    Filed: February 26, 1985
    Date of Patent: March 31, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Tadashi Yamamoto, Masafumi Imai, Hiroyuki Furuhashi, Hiroshi Ueno, Naomi Inaba
  • Patent number: 4652541
    Abstract: A catalyst component for polymerization of olefins which is prepared by reacting a magnesium alkoxide with a silicon compound having at least one hydrogen-silicon bond, contacting the reaction product with a carboxylic acid halide and/or carboxylic acid anhydride, and contacting the resulting contact product with a titanium compound.
    Type: Grant
    Filed: August 20, 1984
    Date of Patent: March 24, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Masafumi Imai, Tadashi Yamamoto, Hiroyuki Furuhashi, Hiroshi Ueno, Naomi Inaba
  • Patent number: 4647550
    Abstract: A catalyst component for the polymerization of olefins which is prepared by contacting a contact reaction product of (a) a metal oxide, (b) an organic magnesium compound, and (c) an alkoxy group-containing compound held in contact with (d) a titanium compound.
    Type: Grant
    Filed: July 31, 1985
    Date of Patent: March 3, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Tadanao Kohora, Satoshi Ueki, Mamoru Tachikawa, Chihiro Imai, Tokuo Makishima, deceased
  • Patent number: 4636340
    Abstract: An oriented film is prepared by crosslinking a sheet of polyethylene (preferably HDPE) containing particulate inorganic slip and antiblock additions to provide maximum crosslinking at the surfaces of the sheet and minimum orientation at its middle layer portion, and thereafter heating and stretching the film to obtain an oriented HDPE of high clarity film of improved moisture proof.
    Type: Grant
    Filed: December 18, 1984
    Date of Patent: January 13, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Yasushi Itaba, Tadao Yoshino, Yutaka Yoshifuji, Keichiro Saito, Jyoichi Tabuchi
  • Patent number: 4634740
    Abstract: A polypropylene composition having superior clarity and good low-temperature impact resistance, said composition comprising 65 wt % to 95 wt % crystalline polypropylene and 5 wt % to 35 wt % of ethylene-propylene random copolymer containing higher than 70 wt % to 85 wt % of ethylene.
    Type: Grant
    Filed: April 8, 1985
    Date of Patent: January 6, 1987
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Yuji Fujita, Tadao Ikeda, Tokuo Makishima, deceased