Abstract: A catalyst for polymerization of olefins which comprises a vanadium compound of the formula: ##STR1## (where R.sup.1 is an alkyl group or aryl group having 1 to 8 carbon atoms; and R.sup.2 is an alkyl group or aryl group having from 1 to 8 carbon atoms, or hydrogen)and the organoaluminum compound of the formula R.sub.2 AlX (where R is a hydrocarbon group having 1 to 8 carbon atoms, and X is a halogen atom).
Abstract: A titamium containing catalyst component for olefin polymerizations which comprises contacting (a) a metal oxide, (b) a dihydrocarbyl magnesium, and (c) a hydrocarbyloxy group-containing compound with one another, contacting the thus obtained contact product with (d) a halogen-containing alcohol, and finally contacting the thus obtained contact product with (e) an electron donor compound and (f) a titanium compound.
Abstract: A catalyst for the hydrogenation of a diolefin, having palladium or a compound thereof and at least one co-catalyst component selected from the group consisting of ruthenium, rhodium, cobalt, and rhenium supported each in the form of an elemental metal or a metal compound on a support, its method of preparation and its use for said hydrogenation, particularly for the hydrogenation of cyclopentadiene to cyclopentene is described herein.
Abstract: A process for polymerizing one or more alpha-olefins in the presence of a catalyst system comprising (A) a solid titanium containing catalyst component said component prepared by contacting a magnesium alkoxide, a halogenated hydrocarbon, an electron donor and a titanium compound with one another, and (B) an organoaluminum cocatalyst. In preferred embodiments, the magnesium alkoxide is first contacted with a magnesium halide. The solid titanium containing compound can be treated with an organoaluminum compound.
Abstract: A process for producing a catalyst component for polymerization of olefins which comprises contacting (a) a metal oxide with (b) a magnesium alkoxide, contacting the resulting contact product with (c) a halogen-containing compound, and finally contacting the resulting contact product with (d) a titanium compound.
Abstract: Modified polymer compositions comprising elastomers blended with not more than 50 parts by weight of a crystalline polyolefin are prepared by reaction of the polymers with an unsaturated carboxylic acid or its acid anhydride. The modified composition optionally containing a filler, is particularly suitable for laminating to metals and other polymers; laminates show superior hot water resistance, salt water resistance and thermal shock resistance.
Abstract: A catalyst component for polymerization of olefins which is prepared by contacting a product obtained by contacting (A) a magnesium alkoxide, (B) a silicon compound having the hydrogen-silicon bond, and (C) a titanium compound with one another, with (D) (a) a hydrocarbon, (b) a halogenated hydrocarbon, and/or (c) a halide of an element selected from the elements of Groups IIIa, IVa, and Va of the Periodic Table.
Abstract: A process for producing a catalyst component for polymerization of olefins which comprises contacting (a) a metal oxide with (b) an organomagnesium compound represented by the formula RMgR' wherein R denotes a hydrocarbyl group and R' denotes a hydrocarbyl group or a halogen atom, contacting the resulting contacting product with (c) carbon dioxide, and further contacting the resulting contact product with (d) a titanium compound. Optionally, the carbon dioxide contacted product can be treated with the halogen-containing compound prior to contact with the titanium compound.
Abstract: In a melt spinning operation, a heated wash gas such as nitrogen or nitrogen and air is blown across the melt spinning nozzles to remove volatiles thereby preventing wetting of the nozzle discharge. The wash gas is maintained at a temperature substantially equal to the melt spinning temperature. The preferred melt spinning material is petroleum pitch.
Abstract: This invention relates to a method for catalytically manufacturing a low pour point petroleum product from distillates of crude oil, and more particularly to a method for economically manufacturing a low pour point petroleum product, such as the insulating oil, the lubricating oil used for various types of freezing devices, or the base oil for such lubricating oil, from a paraffin-based crude oil as the starting material without using any special rare crude oil such as naphthene-based crude oil. The catalyst comprises zeolite TSZ.
Abstract: The present invention provides a fibrous product of apatite comprising one or more apatites selected from a group of apatites represented by the general formula:M.sub.10 (ZO.sub.4).sub.6 X.sub.2wherein M represents Ca, Ba, Mg, Sr, Pb, Cd, Fe and the like, ZO.sub.4 represents PO.sub.4, AsO.sub.4, VO.sub.4, CO.sub.3 and the like, and X represents F, Cl, OH and the like. This fibrous product of apatite has many applications such as uses for medical treatment, large scale microorganism cultivating media and others, and particularly it is useful as apatite implant materials having a good compatibility with living organism and superior workability.A fibrous apatite product of this invention may be produced by a method comprising the steps of:(a) preparing a dispersion of apatite by dispersing fine apatite particles uniformly in a solution of binder in water, said apatite being one or more apatites selected from a group of apatites represented by the general formula:M.sub.10 (ZO.sub.4).sub.6 X.sub.
Abstract: A novel polyorgano(hydro)silazane having the compositional formula: (RSiHNH).sub.x [(RSiH).sub.1.5 N].sub.1-x, wherein R is an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, another group in which the atom directly bound to Si is carbon, an alkylsilyl group, an alkylamino group, or an alkoxy group, and 0.4<x<1. This polyorgano(hydro)silazane is produced by reacting a complex of organo(hydro)diholosilane and a base with dry ammonia. This novel silazane is useful as a ceramic starting material, a polymer hardening agent, a densifying agent, a surface coating material, etc., and can be produced safely and at a low cost.
Abstract: A thermoplastic resin composition which comprises 80 to 95 wt % of polycarbonate resin and 5 to 20 wt % of poly-p-methylstyrene. The thermoplastic resin composition is useful as a molding material for automotive parts, electric appliances, other industrial products and articles for daily use.
Abstract: In a process for producing an optically anisotropic carbonaceous pitch having a low softening point for the production of carbon material starting oil to be used is a tar-like substance which is a mixture of compounds not substantially containing chloroform insolubles but containing components having a boiling point of 540.degree. C. or more as principal components and consisting principally of carbon and hydrogen. The tar-like substance has a content of n-heptane insolubles of up to 1 wt % and contains an aromatic oil fraction and a resin fraction as the principal components of n-heptane soluble components. The aromatic carbon fraction, fa, is at least 0.7, the number-average molecular weight is up to 1,000 and the maximum molecular weight is up to 2,000 for each of the aromatic oil and resin fractions.
Abstract: A process for preparing a catalyst component for the polymerization of olefins which comprises the steps of contacting (a) a magnesium dialkoxide soluble in an inert solvent, (b) a silicon compound having the hydrogen-silicon bond, and (c) an electron donor compound with one another in the presence of an inert solvent, and contacting the resulting reaction product with (d) a titanium compound.
Abstract: A catalyst component for polymerization of olefins which is prepared by reacting a magnesium alkoxide with a silicon compound having at least one hydrogen-silicon bond, contacting the reaction product with a carboxylic acid halide and/or carboxylic acid anhydride, and contacting the resulting contact product with a titanium compound.
Abstract: A catalyst component for the polymerization of olefins which is prepared by contacting a contact reaction product of (a) a metal oxide, (b) an organic magnesium compound, and (c) an alkoxy group-containing compound held in contact with (d) a titanium compound.
Abstract: An oriented film is prepared by crosslinking a sheet of polyethylene (preferably HDPE) containing particulate inorganic slip and antiblock additions to provide maximum crosslinking at the surfaces of the sheet and minimum orientation at its middle layer portion, and thereafter heating and stretching the film to obtain an oriented HDPE of high clarity film of improved moisture proof.
Abstract: A polypropylene composition having superior clarity and good low-temperature impact resistance, said composition comprising 65 wt % to 95 wt % crystalline polypropylene and 5 wt % to 35 wt % of ethylene-propylene random copolymer containing higher than 70 wt % to 85 wt % of ethylene.