Patents Assigned to U.S. Department of Energy
  • Publication number: 20180141859
    Abstract: An optical sensor device includes an optical waveguide portion having a core, the core having a first refractive index, and a functional material layer coupled to the optical fiber portion, the functional material layer being made of a metal oxide material, the functional material layer being structured to have a second refractive index, the second refractive index being less than the first refractive index. The functional material layer may be a nanostructure material comprising the metal oxide material with a plurality of holes or voids formed therein such that the functional material layer is caused to have the second refractive index.
    Type: Application
    Filed: January 17, 2018
    Publication date: May 24, 2018
    Applicants: UNIVERSITY OF PITTSBURGH-OF THE COMMONWEALTH SYSTEM OF HIGHER EDUCATION, U.S. DEPARTMENT OF ENERGY
    Inventors: Peng Chen, Jacob Lorenzi Poole, Paul R. Ohodnicki, Michael Paul Buric
  • Patent number: 9975080
    Abstract: Exemplary embodiments relate to methods for removal of CO2 and other acid gases from gaseous fuels prior to combustion. Exemplary methods may be used for CO2 capture, H2 purification and natural gas sweetening. Exemplary methods use at least one ionic liquid that has excellent CO2 solubility, selectivity over hydrogen, low viscosity, and resistance to H2S.
    Type: Grant
    Filed: February 16, 2016
    Date of Patent: May 22, 2018
    Assignee: U.S. Department of Energy
    Inventors: David Luebke, Hunaid Nulwala, Brian Kail, Fan Shi, Robert L Thompson, Nicholas Siefert
  • Patent number: 9964494
    Abstract: A sensor using thermally emissive materials for chemical spectroscopy analysis includes an emissive material, wherein the emissive material includes the thermally emissive materials which emit electromagnetic radiation, wherein the electromagnetic radiation is modified due to chemical composition in an environment; and a detector adapted to detect the electromagnetic radiation, wherein the electromagnetic radiation is indicative of the chemical interaction changes and hence chemical composition and/or chemical composition changes of the environment. The emissive material can be utilized with an optical fiber sensor, with the optical fiber sensor operating without the emissive material probed with a light source external to the material.
    Type: Grant
    Filed: May 20, 2016
    Date of Patent: May 8, 2018
    Assignee: U.S. Department of Energy
    Inventors: Zsolt Poole, Paul R. Ohodnicki
  • Patent number: 9960341
    Abstract: A high frequency magnetostrictive transducer includes a magnetostrictive rod or wire inserted co-axially into a driving coil, wherein the driving coil includes a coil arrangement with a plurality of small coil segments along the magnetostrictive rod or wire; wherein frequency operation of the high frequency magnetostrictive transducer is controlled by a length of the small coil segments and a material type of the magnetostrictive rod or wire. This design of the high frequency magnetostrictive transducer retains the beneficial aspects of the magnetostrictive design, while reducing its primary drawback, lower frequency operation.
    Type: Grant
    Filed: November 26, 2014
    Date of Patent: May 1, 2018
    Assignee: U.S. Department of Energy
    Inventors: Joshua Earl Daw, Steven Cheney Taylor, Joy Lynn Rempe
  • Patent number: 9956532
    Abstract: An apparatus and method for generating a swirl is disclosed that is used to induce an axi-symmetric swirling flow to an incoming flow. The disclosed subject matter induces a uniform and axi-symmetric swirl, circumferentially around a discharge location, thus imparting a more accurate, repeatable, continuous, and controllable swirl and mixing condition of interest. Moreover, the disclosed subject matter performs the swirl injection at a lower pressure drop in comparison to a more traditional methods and devices.
    Type: Grant
    Filed: November 6, 2014
    Date of Patent: May 1, 2018
    Assignee: U.S. Department of Energy
    Inventors: Robert E. Haden, Donald G. Lorentz
  • Patent number: 9960428
    Abstract: Provided herein is a method for electrocatalyst infiltration of a porous substrate, of particular use for preparation of a cathode for a solid oxide fuel cell. The method generally comprises preparing an electrocatalyst infiltrate solution comprising an electrocatalyst, surfactant, chelating agent, and a solvent; pretreating a porous mixed ionic-electric conductive substrate; and applying the electrocatalyst infiltration solution to the porous mixed ionic-electric conductive substrate.
    Type: Grant
    Filed: July 13, 2016
    Date of Patent: May 1, 2018
    Assignee: U.S. Department of Energy
    Inventors: Kirk Gerdes, Shiwoo Lee, Regis Dowd
  • Patent number: 9957911
    Abstract: An engine control system of a vehicle includes a fuel control module that controls fuel injection of a first cylinder of an engine based on a first target air/fuel ratio that is fuel lean relative to a stoichiometric air/fuel ratio and that controls fuel injection of a second cylinder of the engine based on a second target air/fuel ratio that is fuel rich relative to stoichiometry. The first cylinder outputs exhaust to a first three way catalyst (TWC), and the second cylinder outputs exhaust to an exhaust gas recirculation (EGR) valve. An EGR control module controls opening of the EGR valve to: (i) a second TWC that reacts with nitrogen oxides (NOx) in the exhaust and outputs ammonia to a selective catalytic reduction (SCR) catalyst; and (ii) a conduit that recirculates exhaust back to an intake system of the engine.
    Type: Grant
    Filed: February 18, 2016
    Date of Patent: May 1, 2018
    Assignees: GM GLOBAL TECHNOLOGY OPERATIONS LLC, U.S. Department of Energy
    Inventors: David P. Sczomak, Kushal Narayanaswamy, Edward J. Keating
  • Patent number: 9957593
    Abstract: A ductile alloy is provided comprising molybdenum, chromium and aluminum, wherein the alloy has a ductile to brittle transition temperature of about 300 C after radiation exposure. The invention also provides a method for producing a ductile alloy, the method comprising purifying a base metal defining a lattice; and combining the base metal with chromium and aluminum, whereas the weight percent of chromium is sufficient to provide solute sites within the lattice for point defect annihilation.
    Type: Grant
    Filed: February 27, 2014
    Date of Patent: May 1, 2018
    Assignee: U.S. Department of Energy
    Inventor: Brian V. Cockeram
  • Patent number: 9880041
    Abstract: Disclosed is a volume sensor having a first axis, a second axis, and a third axis, each axis including a laser source configured to emit a beam; a parallel beam generating assembly configured to receive the beam and split the beam into a first parallel beam and a second parallel beam, a beam-collimating assembly configured to receive the first parallel beam and the second parallel beam and output a first beam sheet and a second beam sheet, the first beam sheet and the second beam sheet being configured to traverse the object aperture; a first collecting lens and a second collecting lens; and a first photodetector and a second photodetector, the first photodetector and the second photodetector configured to output an electrical signal proportional to the object; wherein the first axis, the second axis, and the third axis are arranged at an angular offset with respect to each other.
    Type: Grant
    Filed: August 8, 2017
    Date of Patent: January 30, 2018
    Assignee: U.S. Department of Energy
    Inventors: Michael H. Lane, James L. Doyle, Jr., Michael J. Brinkman
  • Patent number: 9878280
    Abstract: The present disclosure is directed to a method for enriching an inlet air stream utilizing a number of enrichment sub-units connected in series, where each enrichment sub-unit conducts both a dissolution and degasification cycle. Each enrichment sub-unit comprises a compressor, an aeration unit, a deaeration unit, and a pump for the recirculation of water between the aeration and deaeration units. The methodology provides a manner in which the relationship between the respective Henry's coefficients of the oxygen and nitrogen in water may be exploited to enrich the O2 volume percent and diminish the N2 volume percent over repeated dissolution and degasification cycles. By utilizing a number of enrichment sub-units connected in series, the water contained in each enrichment sub-unit acts to progressively increase the O2 volume percent. Additional enrichment sub-units may be added and utilized until the O2 volume percent equals or exceeds a target O2 volume percent.
    Type: Grant
    Filed: January 6, 2015
    Date of Patent: January 30, 2018
    Assignee: U.S. Department of Energy
    Inventors: Anna Nakano, Jinichiro Nakano, James P. Bennett
  • Patent number: 9840756
    Abstract: Embodiments relate to systems and methods for regenerating and recirculating a CO, H2 or combinations thereof utilized for metal oxide reduction in a reduction furnace. The reduction furnace receives the reducing agent, reduces the metal oxide, and generates an exhaust of the oxidized product. The oxidized product is transferred to a mixing vessel, where the oxidized product, a calcium oxide, and a vanadium oxide interact to regenerate the reducing agent from the oxidized product. The regenerated reducing agent is transferred back to the reduction furnace for continued metal oxide reductions.
    Type: Grant
    Filed: July 2, 2015
    Date of Patent: December 12, 2017
    Assignee: U.S. Department of Energy
    Inventors: Jinichiro Nakano, James P. Bennett, Anna Nakano
  • Patent number: 9843400
    Abstract: A passive, linear arrangement of a sonic crystal-based apparatus and method including a 1D sonic crystal, a nonlinear medium, and an acoustic low-pass filter, for permitting unidirectional broadband ultrasound propagation as a collimated beam for underwater, air or other fluid communication, are described. The signal to be transmitted is first used to modulate a high-frequency ultrasonic carrier wave which is directed into the sonic crystal side of the apparatus. The apparatus processes the modulated signal, whereby the original low-frequency signal exits the apparatus as a collimated beam on the side of the apparatus opposite the sonic crystal. The sonic crystal provides a bandpass acoustic filter through which the modulated high-frequency ultrasonic signal passes, and the nonlinear medium demodulates the modulated signal and recovers the low-frequency sound beam. The low-pass filter removes remaining high-frequency components, and contributes to the unidirectional property of the apparatus.
    Type: Grant
    Filed: April 6, 2015
    Date of Patent: December 12, 2017
    Assignee: U.S. Department of Energy
    Inventors: Dipen N. Sinha, Cristian Pantea
  • Patent number: 9841306
    Abstract: Disclosed is a volume sensor having first, second, and third laser sources emitting first, second, and third laser beams; first, second, and third beam splitters splitting the first, second, and third laser beams into first, second, and third beam pairs; first, second, and third optical assemblies expanding the first, second, and third beam pairs into first, second, and third pairs of parallel beam sheets; fourth, fifth, and sixth optical assemblies focusing the first, second, and third beam sheet pairs into fourth, fifth, and sixth beam pairs; and first, second, and third detector pairs receiving the fourth, fifth, and sixth beam pairs and converting a change in intensity of at least one of the beam pairs resulting from an object passing through at least one of the first, second, and third parallel beam sheets into at least one electrical signal proportional to a three-dimensional representation of the object.
    Type: Grant
    Filed: November 3, 2015
    Date of Patent: December 12, 2017
    Assignee: U.S. Department of Energy
    Inventors: Michael H. Lane, James L. Doyle, Jr., Michael J. Brinkman
  • Patent number: 9797594
    Abstract: The disclosure provides a tri-metallic ferrite oxygen carrier for the chemical looping combustion of carbonaceous fuels. The tri-metallic ferrite oxygen carrier comprises CuxFeyMnzO4-?, where CuxFeyMnzO4-? is a chemical composition. Generally, 0.5?x?2.0, 0.2?y?2.5, and 0.2?z?2.5, and in some embodiments, 0.8?x?1.2, y?1.2, and z?0.8. The tri-metallic ferrite oxygen carrier may be used in various applications for the combustion of carbonaceous fuels, including as an oxygen carrier for chemical looping combustion.
    Type: Grant
    Filed: February 27, 2015
    Date of Patent: October 24, 2017
    Assignee: U.S. Department of Energy
    Inventors: Ranjani V. Siriwardane, Yueying Fan
  • Patent number: 9759493
    Abstract: The disclosure provides a fluid-cooled heat sink having a heat transfer base, a shroud, and a plurality of heat transfer fins in thermal communication with the heat transfer base and the shroud, where the heat transfer base, heat transfer fins, and the shroud form a central fluid channel through which a forced or free cooling fluid may flow. The heat transfer pins are arranged around the central fluid channel with a flow space provided between adjacent pins, allowing for some portion of the central fluid channel flow to divert through the flow space. The arrangement reduces the pressure drop of the flow through the fins, optimizes average heat transfer coefficients, reduces contact and fin-pin resistances, and reduces the physical footprint of the heat sink in an operating environment.
    Type: Grant
    Filed: February 20, 2015
    Date of Patent: September 12, 2017
    Assignee: U.S. Department of Energy
    Inventors: Desikan Bharathan, Kevin Bennion, Kenneth Kelly, Sreekant Narumanchi
  • Patent number: 9696256
    Abstract: The disclosure relates to a plasmon resonance-based method for H2 sensing in a gas stream utilizing a hydrogen sensing material. The hydrogen sensing material is comprises Pd-based or Pt-based nanoparticles having an average nanoparticle diameter of less than about 100 nanometers dispersed in an inert matrix having a bandgap greater than or equal to 5 eV, and an oxygen ion conductivity less than approximately 10?7 S/cm at a temperature of 700° C. Exemplary inert matrix materials include SiO2, Al2O3, and Si3N4 as well as modifications to modify the effective refractive indices through combinations and/or doping of such materials. The hydrogen sensing material utilized in the method of this disclosure may be prepared using means known in the art for the production of nanoparticles dispersed within a supporting matrix including sol-gel based wet chemistry techniques, impregnation techniques, implantation techniques, sputtering techniques, and others.
    Type: Grant
    Filed: October 20, 2015
    Date of Patent: July 4, 2017
    Assignee: U.S. Department of Energy
    Inventors: Paul R. Ohodnicki, Jr., John P. Baltrus, Thomas D. Brown
  • Patent number: 9666310
    Abstract: Systems and methods for accident tolerant oxide fuel. One or more disks can be placed between fuel pellets comprising UO2, wherein such disks possess a higher thermal conductivity material than that of the UO2 to provide enhanced heat rejection thereof. Additionally, a cladding coating comprising zircaloy coated with a material that provides stability and high melting capability can be provided. The pellets can be configured as annular pellets having an annulus filled with the higher thermal conductivity material. The material coating the zircaloy can be, for example, Zr5Si4 or another silicide such as, for example, a Zr-Silicide that limits corrosion. The aforementioned higher thermal conductivity material can be, for example, Si, ZrxSiy, Zr, or Al2O3.
    Type: Grant
    Filed: March 19, 2013
    Date of Patent: May 30, 2017
    Assignee: U.S. Department of Energy
    Inventor: Robert D. Mariani
  • Patent number: 9643123
    Abstract: Methods and compositions useful, for example, for physical solvent carbon capture. A method comprising: contacting at least one first composition comprising carbon dioxide with at least one second composition to at least partially dissolve the carbon dioxide of the first composition in the second composition, wherein the second composition comprises at least one siloxane compound which is covalently modified with at least one non-siloxane group comprising at least one heteroatom. Polydimethylsiloxane (PDMS) materials and ethylene-glycol based materials have high carbon dioxide solubility but suffer from various problems. PDMS is hydrophobic but suffers from low selectivity. Ethylene-glycol based systems have good solubility and selectivity, but suffer from high affinity to water. Solvents were developed which keep the desired combinations of properties, and result in a simplified, overall process for carbon dioxide removal from a mixed gas stream.
    Type: Grant
    Filed: October 27, 2014
    Date of Patent: May 9, 2017
    Assignees: CARNEGIE MELLON UNIVERSITY, U.S. DEPARTMENT OF ENERGY
    Inventors: Hunaid Nulwala, David Luebke
  • Patent number: 9636631
    Abstract: The disclosure provides an apparatus and method for the separation of a paramagnetic component from a mixture using a mechanical membrane apparatus. The mechanical membrane comprises a supporting material having a plurality of pores where each pore is surrounded by a plurality of magnetic regions. The magnetic regions augment a magnetic field on one side of the supporting material while mitigating the field to near zero on the opposite side. In operation, a flow of fluid such as air comprising a paramagnetic component such as O2 is directed toward the mechanical membrane, and the paramagnetic component is typically attracted toward a magnetic field surrounding a pore while dimagnetic components such as N2 are generally repelled. As some portion of the fluid passes through the plurality of magnetic apertures to the opposite side of the mechanical membrane, the mechanical membrane generates a fluid enriched in the paramagnetic component.
    Type: Grant
    Filed: April 13, 2015
    Date of Patent: May 2, 2017
    Assignee: U.S. Department of Energy
    Inventor: David Maurice
  • Patent number: 9625421
    Abstract: A scanner system and method for acquisition of position-based ultrasonic inspection data are described. The scanner system includes an inspection probe and a first non-contact linear encoder having a first sensor and a first scale to track inspection probe position. The first sensor is positioned to maintain a continuous non-contact interface between the first sensor and the first scale and to maintain a continuous alignment of the first sensor with the inspection probe. The scanner system may be used to acquire two-dimensional inspection probe position data by including a second non-contact linear encoder having a second sensor and a second scale, the second sensor positioned to maintain a continuous non-contact interface between the second sensor and the second scale and to maintain a continuous alignment of the second sensor with the first sensor.
    Type: Grant
    Filed: April 16, 2014
    Date of Patent: April 18, 2017
    Assignee: U.S. Department of Energy
    Inventor: Charles Keith Sword