Abstract: Described is an edible, water insoluble film which is a blend of polysaccharide and protein and, in particular, a ternary blend of konjac flour as a major constituent, agar and gelatin. Also, described is a method of forming the film including a deacetylating step to insolubilize the konjac flour.

Abstract: Bixin containing coloring compositions and self-coloring casings, particularly tubular cellulosic food casings, coated therewith, which compositions contain bixin, a water-soluble film forming agent, preferably hydroxypropylcellulose, a polyphosphate and optionally an antioxidant.

Abstract: Disclosed is a method of extruding a solution of cellulose and an amine oxide cellulose solvent as a tube about a sizing mandrel which diametrically stretches the extruded tube. An aqueous poly(ethylene oxide) solution is introduced into the interior of the extruded tube to facilitate passage of the tube over the sizing mandrel and to extract the amine oxide cellulose solvent from the tube. After such extraction, the aqueous poly(ethylene oxide) solution containing the extracted amine oxide cellulose solvent is contacted with an anion exchanger to remove the poly(ethylene oxide) so the amine oxide cellulose solvent can be recovered.

Abstract: A curl resistant battery separator of a noncellulosic nonwoven substrate extrusion coated on at least one surface with a cellulose film and process for making such separator by contacting a nonwoven noncellulosic textile substrate with a cellulose or cellulose derivative solution on at least one side of said substrate; converting the solution to a solid cellulose or cellulose derivative, preferably having a degree of polymerization of at least 350, more preferably at least 600, to form a coated substrate; washing said substrate in an aqueous solution; drying the coated substrate under biaxial tension to provide a battery separator having a moisture content of from about 4 to 25 wt. % based on the bone dry gauge of the separator(BDG); and then holding the separator for at least 8 hours at elevated temperatures of at least 40.degree. C. in the presence of a controlled amount of moisture to produce a separator which is stabilized against curling and has a moisture content between about 4 to 25 wt.

Abstract: A polymer blend and mono-and multilayer films made therefrom having improved properties such as heat sealing or puncture resistance wherein the blend has a first polymer of ethylene and at least one .alpha.-olefin having a polymer melting point between 55 to 75.degree. C.; a second polymer of ethylene and at least one .alpha.-olefin having a polymer melting point between 85 to 110.degree. C. and a third thermoplastic polymer having a melting point between 115 to 130.degree. C.; and optionally a fourth polymer e.g. EVA, having a melting point between 90 to 100.degree. C.

Abstract: A vented food casing having a plurality of die cut vent openings which are uniform and free-draining so as to provide the casing with a vent rate for air and liquids such as meat juices which is substantially constant around the periphery of the casing. The vent opening being formed by a die cutting operation by drawing flattened casing between rollers, one of which has made punches that mate with female die openings on another roller.

Abstract: The tubular extrusion of a thermoplastic nonderivatized cellulose solution about a mandrel and through a long air gap in excess of 304 mm is facilitated by use of a mandrel which is extensible from the extrusion die. On extrusion start-up, the mandrel extends a short length from the die. For steady-state operation, the mandrel is extended its full length from the die. Also disclosed is a mandrel structure to facilitate the introduction of a nonsolvent liquid into the interior of the extruded tube at a high location on start-up of extrusion and at a lower location during steady-state operation.

Abstract: A multilayer, preferably biaxially oriented, film suitable for processing and/or packaging cook-in foods such as ham, roast beef and poultry having an excellent combination of oxygen barrier, heat seal and optical properties comprising at least five essential sequential layers with a first layer of a copolymer of propene and at least one C.sub.2 -C.sub.8 .alpha.-olefin having a propene content of at least 60 wt. % and preferably having a melting point <140 .degree. C.; a second layer of (1) a first copolymer of ethylene and at least one C.sub.4 -C.sub.8 .alpha.-olefin having a density of from 0.900 to 0.915 g/cm.sup.3 and a melt index of less than 1.0 dg/min., (2) a second copolymer of ethylene with from 4 to 18%, preferably 4 to 12%, of a vinyl ester or alkyl acrylate, (3) an anhydride-modified third copolymer of ethylene with at least one .alpha.-olefin, a vinyl ester or an alkyl acrylate, and (4) optionally a fourth copolymer of ethylene and at least one C.sub.3 -C.sub.8 .alpha.

Abstract: The tubular extrusion of a thermoplastic nonderivatized cellulose solution about a mandrel and through a long air gap in excess of 304 mm is facilitated by use of a mandrel which is extensible from the extrusion die. On extrusion start-up, the mandrel extends a short length from the die. For steady-state operation, the mandrel is extended its full length from the die. Also disclosed is a mandrel structure to facilitate the introduction of a nonsolvent liquid into the interior of the extruded tube at a high location on start-up of extrusion and at a lower location during steady-state operation. The mandrel also includes a sizing portion having circumferential grooves which gather gas bubbles that may evolve at the interface between the extruded tube and the sizing portion. Vertical channels in the sizing portion connect these grooves and provide the passage of gas bubbles into a volume below the mandrel.

Abstract: A crosslinked cellulose composite film including a regenerated cellulose matrix containing a uniform dispersion of hemp fibers and a poly(ethylene oxide) plasticizer. A method for forming the film includes mixing a slurry of the hemp, poly(ethylene oxide) and a cellulose solvent with a cellulose solution, extruding the mixture, regenerating the cellulose from the solution to form the matrix containing hemp fibers, contacting with a crosslinking agent and then drying.

Abstract: The present invention relates to compounded fibrous dope compositions of amine oxide cellulose solutions having a uniformly dispersed second fibrous material, methods of producing the compositions, and shaped articles such as fibers, paper, films, and food casings produced from the compositions.

Abstract: A cellulose food casing comprising a nonderivatized cellulose film precipitated in tubular form from an extruded thermoplastic solution of cellulose, an amine oxide cellulose solvent and water.

Abstract: Tubular, biaxially stretched, heat shrinkable multilayer film food casings comprising inner and outer polyamide layers on either side of a core layer predominantly of one or more ethylenic polymers having a functional moiety selected from the group of esters, anhydrides, and carboxylic acids, and a coextrusion process for making the film.

Abstract: Disclosed is a food product encased in a water insoluble film of glucomannan and a method for its manufacture. In the process an aqueous solution of glucomannan is cast onto the food product surface and then is deacetylated and coagulated in sire by contact with a saturated salt solution having either an acidic or basic pH. The coagulated solution is cured and dried in the presence of salt and subsequently washed and further dried to provide the water insoluble film.

Abstract: In a method for forming a cellulose tube suitable for use as a food casing or as cellophane film, in which a solution of nonderivatized cellulose, tertiary amine N-oxide and water is extruded through an air gap of at least five inches, and into a water bath, such that a wet cellulose tube is formed. The wet tube is inflated from about 55% to 140% or more and dried thereby substantially retaining its work-to-rupture characteristics, especially when compared to viscose-derived tubes.

Abstract: In a method for forming a cellulose tube suitable for use as a food casing, in which a solution of nonderivatized cellulose, tertiary amine N-oxide and water is extruded through a die gap and the extruded tube is downwardly drawn through an air gap while being internally cooled and then is passed into a water bath, the tube transverse direction tensile strength being increased by drawing the extruded tube through an air length of at least about five inches and exposing the exterior surface of the extruded tube to cooling air in the air gap.

Abstract: A biaxially stretched, heat sealable, thermoplastic, flexible, food packaging film, preferably multilayer, having an outer heat sealable layer comprising an ethylene vinyl ester copolymer, preferably a blend of two different EVA copolymers wherein said heat sealing layer (which is preferably crosslinked by irradiation) has an M.sub.w of 50,000 or more, and an M.sub.n between 1000 and 18,000.

Abstract: A heat-shrinkable, multilayer film suitable for use in fabricating bags for packaging primal and sub-primal meat cuts and processed meats. The multilayer film has a first outer layer of a first ethylene-vinyl acetate copolymer, a core layer of a barrier film comprising a polyvinylidene chloride copolymer, and a second outer layer of a second ethylene-vinyl acetate copolymer. The multilayer film is preferably made by co-extrusion of the layers, and then it is biaxially stretched. After biaxial stretching, the multilayer film is irradiated to a dosage level of between 1 megarad and 5 megarads and heat-sealed in the form of a bag. The bag has improved toughness properties and heat-sealing characteristics.

Abstract: A polyolefin blown or slot cast monolayer or multilayer stretch film useful as a trayed overwrap e.g. for fresh red meat includes at least three layers in the multilayer embodiment each of which contains an ethylene alpha-olefin copolymer having a density below 0.915 g/cm.sup.3 and having a melting point of at least 90.degree. C. with at least one outer layer and preferably also the first outer layer or the core layer having a second ethylene alpha olefin copolymer having a melting point less than 80.degree. C. blended therein.

Abstract: Disclosed is a method of preparing an extruded cellulosic film which contains a uniform dispersion of hemp fibers by first adding the fibers to an amine oxide cellulose solvent to form a slurry, mixing the slurry with a molten aqueous solution of cellulose and amine oxide cellulose solvent extruding the mixture end then regenerating the dissolved cellulose.