Patents Examined by Aiqun Li
  • Patent number: 11795373
    Abstract: A liquid corrosion inhibitor composition for use with acid compositions for use in industrial activities, said corrosion inhibitor composition comprising: a thiourea derivative; a first type of amphoteric surfactant is selected from the group consisting of: a sultaine surfactant; a betaine surfactant; and combinations thereof; a second type of amphoteric surfactant; and a solvent.
    Type: Grant
    Filed: June 14, 2019
    Date of Patent: October 24, 2023
    Assignee: Dorf Ketal Chemicals FZE
    Inventors: Clay Purdy, Markus Weissenberger
  • Patent number: 11795367
    Abstract: This disclosure relates to compositions including a poly-alkene maleic anhydride copolymer, a PEG, and a crosslinker selected from an ethyleneamine, a benzenetricarboxylic acid, a benzimidazole, and combinations thereof. The poly-alkene maleic anhydride copolymer includes repeat units I and II: where R1, R1?, R2, and R2? are each independently selected from —H and —(C1-C5)alkyl. The disclosure also provides methods of treating a subterranean formation or cement construction using the compositions.
    Type: Grant
    Filed: July 15, 2020
    Date of Patent: October 24, 2023
    Assignee: Saudi Arabian Oil Company
    Inventor: Elizabeth Contreras
  • Patent number: 11795366
    Abstract: A coiled tubing wellbore fluid may include a base fluid; and a crosslinked and branched polymeric fluid loss control agent formed from at least an acrylamide monomer and a sulfonated anionic monomer; wherein the coiled tubing wellbore fluid has a low shear rate viscosity, measured at 120° F. at 3 rpm, of at least 20,000 centipoise.
    Type: Grant
    Filed: November 28, 2018
    Date of Patent: October 24, 2023
    Assignee: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventor: Balakrishnan Panamarathupalayam
  • Patent number: 11781055
    Abstract: Emulsions, treatment fluids and methods for treating subterranean formations are provided, wherein the emulsions comprise water, a water-immiscible liquid, one or more polymers, one or more ethoxylated amine compounds and optionally, one or more organic or inorganic salts. The emulsions are particularly suitable for use in harsh brine conditions.
    Type: Grant
    Filed: January 5, 2021
    Date of Patent: October 10, 2023
    Assignee: KEMIRA OYJ
    Inventors: Paul Waterman, Logan Jackson, Danny Nguyen, Ronald Robinson
  • Patent number: 11781060
    Abstract: An oil-based slurry that includes oil, a suspension package, a dispersion agent, a surfactant, and a dry water-soluble polymer.
    Type: Grant
    Filed: November 10, 2020
    Date of Patent: October 10, 2023
    Assignee: SELECT CHEMISTRY, LLC
    Inventors: Brian Price, Fatee Malekahmadi, Yifan Li
  • Patent number: 11773312
    Abstract: The present disclosure provides methods, compositions, and systems directed to filter cake removal embodying a delayed breaker fluid for oil-based drill-in fluids. A wellbore treatment method comprising: introducing a delayed breaker fluid into a wellbore, wherein the delayed breaker fluid comprises an aqueous base fluid, an acid precursor, and a carbodiimide; and contacting a filter cake in the wellbore with the delayed breaker fluid such that the filter cake is at least partially degraded by acid released from the acid precursor.
    Type: Grant
    Filed: March 31, 2022
    Date of Patent: October 3, 2023
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Catherine Martin Santos, William Walter Shumway, Jay Paul Deville
  • Patent number: 11773309
    Abstract: A method of improving rheological properties of a divalent brine based downhole treatment fluid at an elevated temperature comprises adding to the divalent brine based downhole treatment fluid a rheological modifier, which comprises a carboxylic acid ester, or a phosphate ester blended with an ethoxylated glycol, or a combination comprising at least one of the foregoing in an amount effective to improve the rheological properties of the divalent brine based downhole treatment fluid at a temperature of greater than about 200° F. The divalent brine based downhole treatment fluid comprises calcium bromide, calcium chloride, zinc bromide, zinc chloride, or a combination comprising at least one of the foregoing.
    Type: Grant
    Filed: August 3, 2022
    Date of Patent: October 3, 2023
    Assignee: BAKER HUGHES HOLDINGS LLC
    Inventors: Prahlad Yadav, Mohammed Al-Rabah, Gaurav Agrawal
  • Patent number: 11760922
    Abstract: Methods of preparing a crosslinked hydraulic fracturing fluid include combining a hydraulic fracturing fluid comprising a polyacrylamide polymer with a plurality of coated proppants. The plurality of coated proppants include a proppant particle and a resin proppant coating on the proppant particle. The resin proppant coating includes resin and a zirconium oxide crosslinker. The resin includes at least one of phenol, furan, epoxy, urethane, phenol-formaldehyde, polyester, vinyl ester, and urea aldehyde. Methods further include allowing the zirconium oxide crosslinker within the resin proppant coating to crosslink the polyacrylamide polymer within the hydraulic fracturing fluid at a pH of at least 10, thereby forming the crosslinked hydraulic fracturing fluid.
    Type: Grant
    Filed: September 13, 2021
    Date of Patent: September 19, 2023
    Assignees: Saudi Arabian Oil Company, Alfaisal University
    Inventors: Wengang Li, Edreese Alsharaeh, Mohammed Abdullah Bataweel
  • Patent number: 11746274
    Abstract: A composition includes an ionic liquid monomer having the following structure: where n is an integer from 1 to 5 and the ionic liquid monomer has a melting point less than 100° C. A method of making the ionic liquid includes providing a mixture comprising a sulfonic acid and a diamine in a solvent, and maintaining the mixture at a temperature ranging from 10 to 80° C. for a time ranging from 1 to 10 hours to form an ionic liquid monomer having a melting point less than 100° C. A method of making a polymer from the ionic liquid monomer is also provided.
    Type: Grant
    Filed: February 25, 2022
    Date of Patent: September 5, 2023
    Assignee: SAUDI ARABIAN OIL COMPANY
    Inventors: Xuan Zhang, Jose I. Rueda, Ming Han, Mohammed Bataweel, Ziyuan Qi
  • Patent number: 11746281
    Abstract: A method of making a proppant-gel matrix comprising: a) hydrating a gelling agent to form a hydrated gelling agent; b) adding a basic compound to the hydrated gelling agent to form a basic hydrated gelling agent having a pH in the range of 11.5 to 14.0; c) mixing the basic hydrated gelling agent and a proppant to form a basic hydrated gelling system; and d) adding a crosslinking agent to the basic hydrated gelling system to form the proppant-gel matrix, is disclosed. The proppant-gel matrix can then be used as a fracturing fluid in a hydraulic fracturing process.
    Type: Grant
    Filed: July 13, 2022
    Date of Patent: September 5, 2023
    Assignee: HEXION INC.
    Inventors: Charles Zha, Jan Beetge
  • Patent number: 11739253
    Abstract: Proteinaceous enhanced oil recovery operates on the principle that proteins can be denatured using chemicals to break them down into a viscous polymeric mixture that exhibits an EOR effect. In one or more embodiments, the proteins in question are sourced from an algae (spirulina) meal, which could be obtained as a waste product from wastewater treatment or bioprocessing operations, including biofuel production where the lipids are extracted for fuel but the large volumes of proteins are considered a waste material with little or negative value. In other embodiments, other biomasses are used, especially edible biomasses, thereby mitigating public resistance to drilling operations due to concerns of perceived toxicity of chemicals. This also mitigates legal liability from the use of chemicals that are known to be toxic. Additionally, the agents are denatured biomasses that have not undergone expensive purification or separation steps. This will make these agents highly cost competitive.
    Type: Grant
    Filed: September 4, 2020
    Date of Patent: August 29, 2023
    Assignee: University of Louisiana at Lafayette
    Inventors: William Chirdon, Peter Schexnayder, Garrett Thibodeaux, Nicholas Baudoin
  • Patent number: 11725132
    Abstract: Compositions may include those of the formula: (I) wherein R1 is an alkyl chain having a carbon number in the range of greater than 40 to 200, R2 is a multiester, R3 is hydrogen, an ion, or an alkyl chain having a carbon number in the range of 1 to 200, m is an integer selected from 0 to 4, and n is an integer selected from the range of 0 to 4, wherein the sum of m and n is 1 or greater. Compositions may include a reaction product of a polyisobutylene-substituted succinic anhydride and a hydroxy-functional dendrimer, wherein the molar ratio of polyisobutylene-substituted succinic anhydride to hydroxy-functional dendrimer is within the range of 10:1 to 30:1.
    Type: Grant
    Filed: October 14, 2021
    Date of Patent: August 15, 2023
    Assignee: STEPAN COMPANY
    Inventors: Rachael Anne Cole, Pradyumna Avinash Deshpande, Chandrashekhar Yeshwant Khandekar, Tore Nordvik, Loic Regnault De La Mothe, Elodie Shaw, Laure Canal, Marine Dugand, José Santiago
  • Patent number: 11718688
    Abstract: The hydroxyethyl cellulose derived from biomass is made by preparing a biomass by extracting resins and waxes, acid leaching, and alkali treatment to obtain a cellulose-rich residue, and then bleaching the cellulose-rich residue, followed by hydroxyethylation of the cellulose to obtain hydroxyethyl cellulose. The use of hydroxyethyl cellulose in brine treatment include reacting concentrated brine and hydroxyethyl cellulose with an effluent gas stream to capture CO2 and reduce salinity of the concentrated brine. The reduced salinity brine may then be useful for enhanced oil recovery methods.
    Type: Grant
    Filed: August 19, 2020
    Date of Patent: August 8, 2023
    Assignee: UNITED ARAB EMIRATES UNIVERSITY
    Inventors: Ameera Fares Mohammad, Ali H. Al-Marzouqi, Emmanuel Galiwango, Essa Georges Lwisa, Jawad Mustafa
  • Patent number: 11718782
    Abstract: A compound for use in oil recovery includes a quantum dot and a zwitterionic surfactant. The quantum dot has a diameter no greater than 25 nm and the quantum dot is bonded to the zwitterionic surfactant. A nanofluid for use in oil recovery includes the compound described above and a fluid carrier. A method for recovering oil from a formation includes flooding the formation with a nanofluid. The nanofluid has a quantum dot diameter no greater than 25 nm bonded to a zwitterionic surfactant and a fluid carrier.
    Type: Grant
    Filed: December 31, 2020
    Date of Patent: August 8, 2023
    Assignee: University of North Dakota
    Inventors: Yanxia Zhou, Xu Wu, Julia Xiaojun Zhao, Hui Pu
  • Patent number: 11713415
    Abstract: A self-suspending proppant that resists the adverse effects of calcium and other cations on swelling comprises a proppant substrate particle and a gelatinized non-extruder-derived neutral starch coating on the proppant substrate particle.
    Type: Grant
    Filed: November 19, 2019
    Date of Patent: August 1, 2023
    Assignee: Covia Solutions Inc.
    Inventors: Gedeng Ruan, Huaxiang Yang, Kanth Josyula, An Thien Nguyen
  • Patent number: 11708518
    Abstract: An additive composition includes a rheology modifier selected from alcohol ethoxylates, amine ethoxylates, or ethylene oxide/propylene oxide copolymers, wherein the rheology modifier has an HLB ranging from about 4 to 10; and a winterizing agent that is at least one aliphatic non-ionic surfactant that has a branched structure and/or includes at least one unsaturation, wherein the winterizing agent has an HLB value between about 8 and 10.5.
    Type: Grant
    Filed: February 26, 2018
    Date of Patent: July 25, 2023
    Assignee: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Dimitri M Khramov, Reda Karoum, Stephen Cliffe
  • Patent number: 11702495
    Abstract: A polymer composite of dissimilar polymers covalently bonded at the interface is disclosed.
    Type: Grant
    Filed: July 24, 2018
    Date of Patent: July 18, 2023
    Assignee: President and Fellows of Harvard College
    Inventors: Paul Le Floch, Xi Yao, Qihan Liu, Guodong Nian, Canhui Yang, Zhigang Suo
  • Patent number: 11702581
    Abstract: Reactivity mapping methods are provided. A method may include: analyzing each of a group of inorganic particles to generate data about physical and/or chemical properties of the inorganic particles; and generating correlations between the properties of inorganic particles based on the data.
    Type: Grant
    Filed: February 22, 2017
    Date of Patent: July 18, 2023
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Thomas Jason Pisklak, James Robert Benkley, Darrell Chad Brenneis, Ronnie Glen Morgan, Walmy Cuello Jimenez, John P. Singh
  • Patent number: 11692126
    Abstract: A method of pretreating a pipeline or apparatus is carried out by selecting a colloidal particle dispersion having inorganic nanoparticles with an average particle size of from 500 nm or less that exhibit properties of Brownian motion. Surfaces of a pipeline or apparatus are contacted with a treatment composition comprising the colloidal particle dispersion. The colloidal particles of the treatment composition are allowed to adhere the surfaces of the pipeline or apparatus to facilitate a reduction in friction of the surfaces of the pipeline or apparatus and/or lower the pressure drop of fluid flowing over the surfaces of the pipeline or apparatus and/or to reduce the formation of surface deposits on the surfaces of the pipeline or apparatus.
    Type: Grant
    Filed: March 21, 2022
    Date of Patent: July 4, 2023
    Assignee: Riddle's Dehi & Cbemical Services Co., Inc.
    Inventor: James A. Allred, Jr.
  • Patent number: 11685856
    Abstract: Relatively low molecular weight, branched polyethyleneimine (B-PE), a specific class of polyamine, has been shown to be effective at inhibiting the formation metal naphthenate precipitate (MNP) in systems and fluids that include an organic phase and an aqueous phase where the system or fluid further contains metal ions and tetra acid, and in particular the addition of low molecular weight, B-PE molecules prevents the formation of metal naphthenate precipitates/deposits in the fluids. Inhibition of alkali earth metal naphthenates (e.g. calcium naphthenate) and alkali metal naphthenates (e.g. sodium naphthenate) are particular non-limiting embodiments.
    Type: Grant
    Filed: May 21, 2021
    Date of Patent: June 27, 2023
    Assignee: Baker Hughes Oilfield Operations LLC
    Inventors: Jonathan Vargas, Joey Dacula Mangadlao