Abstract: Described herein are methods for treating a subterranean formation penetrated by a wellbore with a retarded acidizing fluid containing an acid and an acid retarding agent, the concentrations of which are adjusted based on measured parameter values of the formation. Also described is a method for treating a subterranean formation by introducing an acid to the formation following the introduction of an acid retarding agent to the formation. Also described is a method for acid fracturing a subterranean formation including reducing the concentration of an acid retarding agent contained in a retarded acidizing fluid over the course of the acid fracturing operation.
Type:
Grant
Filed:
May 26, 2021
Date of Patent:
June 27, 2023
Assignee:
Schlumberger Technology Corporation
Inventors:
Xiangdong Qiu, Dominic Joseph Brady, Ziad Al-Jalal, Mohan Kanaka Raju Panga, Christopher Daeffler
Abstract: A continuous process for forming a coated proppant, said process comprising the steps of: (a) washing particles, (b) drying the particles at a first predetermined temperature, (c) cooling the particles, (d) feeding the cooled particles with a second predetermined temperature lower than the first predetermined temperature to an inlet of a combined continuous mixer and conveyor unit, (e) feeding a coating composition into the combined continuous mixer and conveyor unit, (f) mixing and simultaneously conveying the particles and the coating composition for a predetermined time, (g) curing the coating composition by transfer of heat from the particles, (h) discharging the coated particles from an outlet of the combined continuous mixer and conveyor unit, wherein said process does not comprise a step of heating the particles after the drying.
Type:
Grant
Filed:
December 6, 2019
Date of Patent:
June 6, 2023
Assignee:
Dow Global Technologies LLC
Inventors:
Praveen Agarwal, Arjun Raghuraman, Juan Carlos Medina
Abstract: Cured cements, cement slurries, and methods of making cured cement and methods of using cement slurries are provided. The method of making a modified cement slurry includes adding particles comprising carbon nanotube sponges disposed on sacrificial templates to a cement slurry to form the modified cement slurry and allowing the sacrificial templates to disintegrate, thereby leaving the carbon nanotube sponges dispersed throughout the modified cement slurry.
Abstract: The present invention discloses a preparation method for the plant-based nano corrosion inhibition bactericide for oilfield, comprising the following steps: Step 1. Prepare the aloin liquid; Step 2. Stir the carbon nanotube, hydroxyethyl methacrylate and acrylic acid to react for 4 h at a constant temperature of 80° C. to get the carbon nanotube after fiber treatment, namely the modified carbon nanotube; Step 3. Mix the aloin liquid with imidazoline-ammonium-salt, add acetonitrile, and then add modified carbon nanotube, increase the temperature to 95° C. stir and react for 12 hours, and filter after naturally cooling down to room temperature and get the carbon nanotube loaded with bactericide; Step 4. Stir the carbon nanotube loaded with bactericide, diphenylmethane diisocyanate and polycaprolactone to react for 6 hours at a constant temperature of 95° C. and in the reaction process, continuously inject helium to get the target bactericide.
Type:
Grant
Filed:
July 13, 2022
Date of Patent:
April 11, 2023
Assignee:
Southwest Petroleum University
Inventors:
Xiankang Zhong, Haonan Li, Zhi Zhang, Junying Hu, Li Zhou, Xi Yuan, Lingjie Li
Abstract: Embodiments relate to use of graphite nanoplatelets (GnP) to enhance the mechanical and durability characteristics of cement that may be used as cement sheaths in wellbores of oil and gas wells. Generally, undesired permeability of cement is caused by diffusion of trapped oil and/or natural gas through the cementitious matrix of the cement, leading to material degradation of the cement. Methods disclosed involve using modified GnPs (having physically modified surfaces or chemically modified surfaces energies) to generate a cementitious nanocomposite with uniformly dispersed GnPs, which can effectively arrest the undesired diffusion mechanism. Modified GnPs can also increase the strength of interfacial adhesion (e.g., interfacial bonds and interfacial energies) between the GnP and the cement matrix (e.g., hydrations of the cement). Physical modification of GnP can involve non-covalent treatment techniques. Chemical modification of GnP can involve covalent treatment techniques.
Type:
Grant
Filed:
March 31, 2020
Date of Patent:
April 4, 2023
Assignee:
THE PENN STATE RESEARCH FOUNDATION
Inventors:
Arash Dahi Taleghani, Seyedeh Maryam Tabatabaei
Abstract: Polymer matrix particles useful for inhibiting scale formation in oil and gas wells are described. The insoluble, porous, crosslinked polymer matrix includes a polymer backbone and ionic functional groups covalently bonded to the backbone, the ionic functional groups being capable of selectively attracting and binding salt scale-forming ions when in contact with a liquid containing such ions.
Type:
Grant
Filed:
August 2, 2021
Date of Patent:
April 4, 2023
Assignee:
Battelle Memorial Institute
Inventors:
Anthony D. Duong, Ramanathan S. Lalgudi, Phillip N. Denen
Abstract: A method of using a suppression factor fluid during a well activity is provided. The method comprising the steps of introducing a suppression factor fluid into a wellbore, the suppression factor fluid comprising an untreated divalent brine, and a suppression sugar alcohol, the suppression sugar alcohol in an amount operable to achieve a suppression factor of at least 0.1, wherein a density upper limitation of the suppression factor fluid is greater than the density upper limitation of the divalent brine; wherein the suppression factor fluid is in the absence of zinc; and completing the well activity in the wellbore, such that the suppression sugar alcohol inhibits crystallization during the well activity.
Abstract: The invention provides a wellbore fluid which comprises an aqueous continuous phase and, dissolved in said aqueous continuous phase, at least one salt containing an imidazolium cation having at least 6 carbon atoms, and a method of carrying out a wellbore operation, which comprises introducing into a wellbore in a clay-containing formation, a wellbore fluid according to the invention. The described salts are effective shale inhibitors.
Type:
Grant
Filed:
November 27, 2008
Date of Patent:
March 14, 2023
Assignee:
The Queen's University Belfast
Inventors:
Mark Aston, Kenneth Richard Seddon, David Francis Wassell
Abstract: A composition for inhibiting corrosion and/or removing hydrocarbonaceous deposits in oil and gas applications is provided. The composition comprises an iron sulfide dissolver, an organic solvent, and a corrosion inhibitor.
Type:
Grant
Filed:
November 30, 2017
Date of Patent:
March 7, 2023
Assignee:
ChampionX USA Inc.
Inventors:
Brian Michael Bennett, Kim R. Solomon, Carter Silvernail, Ana Ferrer Carrera
Abstract: Emulsifier particles and methods for making and using same. The emulsifier particles can include an alkali metal salt or an alkaline earth metal salt of a carboxylic acid terminated fatty amine condensate, an alkali metal salt or an alkaline earth metal salt of a modified tall oil, or a blend of an alkali metal salt or an alkaline earth metal salt of a carboxylic acid terminated fatty amine condensate and an alkali metal salt or an alkaline earth metal salt of a modified tall oil. The emulsifier particles can have a BET specific surface area of about 0.3 m2/g to about 1 m2/g. The method for making the emulsifier particles can include reducing a size of an emulsifier solid via a mechanical attrition process to produce the emulsifier particles.
Abstract: An additive composition includes a rheology modifier selected from alcohol ethoxylates, amine ethoxylates, or ethylene oxide/propylene oxide copolymers, wherein the rheology modifier has an HLB ranging from about 4 to 10; and a winterizing agent that is at least one aliphatic non-ionic surfactant that has a branched structure and/or includes at least one unsaturation, wherein the winterizing agent has an HLB value between about 8 and 10.5.
Type:
Grant
Filed:
February 26, 2018
Date of Patent:
February 21, 2023
Assignee:
SCHLUMBERGER TECHNOLOGY CORPORATION
Inventors:
Dimitri M. Khramov, Reda Karoum, Stephen Cliffe
Abstract: This invention relates to a surfactant composition, production and use thereof in tertiary oil recovery. The present surfactant composition comprises a cationic surfactant and an anionic-nonionic surfactant, and exhibits significantly improved interfacial activity and stability as compared with the prior art. With the present surfactant composition, a flooding fluid composition for tertiary oil recovery with improved oil displacement efficiency and oil washing capability as compared with the prior art could be produced.
Type:
Grant
Filed:
June 11, 2020
Date of Patent:
February 14, 2023
Assignees:
CHINA PETROLEUM & CHEMICAL CORPORATION, SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC
Abstract: A method of reducing the viscosity of a crude oil, the method comprising adding to the crude oil (i) a surfactant compound including at least two hydrophobic groups wherein the resultant mixture has a water content of less than 10 vol %.
Type:
Grant
Filed:
June 29, 2018
Date of Patent:
January 31, 2023
Assignee:
INNOSPEC OIL FIELD CHEMICALS LLC
Inventors:
Ian Malcolm McRobbie, Joseph Sustayta, Luis Angel Ziga, Jr.
Abstract: A reversible gel composition including nanosilica and polyethylene oxide, the nanosilica and polyethylene oxide present at concentrations operable to allow for the reversible gel composition to be a flowable liquid at pH greater than about 8 and operable to allow for the reversible gel composition to be a substantially solid gel at pH less than about 8.
Type:
Grant
Filed:
November 18, 2020
Date of Patent:
January 24, 2023
Assignee:
Saudi Arabian Oil Company
Inventors:
Peter Boul, Abeer Mohammad Al-Olayan, Diana Rasner
Abstract: The present invention concerns the use of at least one compound A comprising at least one —SH or —S—, M+group, at least one —C-G-C— chain, in which G represents an atom from column 16 of the periodic table, not comprising a carboxy group —C(?O)—OH or —C(?O)—O—, and of a molar mass of between 90 g·mol-1 and 1000 g·mol-1, as an additive in a formulation inhibiting corrosion in metals used in the oil industry, and more generally in any kind of industry involving the drilling of ores or fossil compounds, such as gas or oil, in order to improve both the anti-corrosion performance and the storage stability of same. The invention also concerns said corrosion-inhibiting formulations comprising at least one compound A.
Type:
Grant
Filed:
January 28, 2021
Date of Patent:
January 17, 2023
Assignee:
ARKEMA FRANCE
Inventors:
Tong Eak Pou, Denis Alonzo, Gilles Barreto, Kevin Hisler
Abstract: A method for consolidating sand in a subsurface formation includes introducing a consolidation composition into the subsurface formation. The consolidation composition includes asphaltene and maltene dissolved in a solvent. After introducing the consolidation composition, the method further includes introducing an aqueous composition to the subsurface formation in order to precipitate the asphaltene in the subsurface formation. The precipitated asphaltene consolidates sand within the subsurface formation and the maltene forms channels throughout the subsurface formation, thereby increasing the permeability of the subsurface formation.
Abstract: In accordance with one or more embodiments of the present disclosure, a drilling fluid may include a base fluid and one or more formaldehyde-based resins. The drilling fluid may further comprise one or more water-soluble acid catalyst precursors or the reaction products of such water-soluble acid catalyst precursors. The base fluid may include an aqueous or non-aqueous solution. The present disclosure also describes sealed subterranean petroleum formations that include such drilling fluids and methods for sealing subterranean wellbores by utilizing such drilling fluids.
Type:
Grant
Filed:
June 24, 2019
Date of Patent:
December 27, 2022
Assignee:
Saudi Arabian Oil Company
Inventors:
Vikrant Wagle, Abdullah Al-Yami, Nasser Alalhareth
Abstract: Various embodiments disclosed relate to cement activator compositions for treatment of subterranean formations. In various embodiments, the present invention provides a method of treating a subterranean formation including placing in the subterranean formation a liquid cement activator composition including water, an alkali sulfate salt, a polyphosphate salt, and a stabilizer polymer.
Type:
Grant
Filed:
January 21, 2021
Date of Patent:
December 27, 2022
Assignee:
Halliburton Energy Services, Inc.
Inventors:
Janelle Haydon, Sean William Riggio, Kyriacos Agapiou, Thomas Jason Pisklak, Samuel Lewis
Abstract: The present invention relates to a hydrated crystalline form of 2-acrylamido-2-methylpropane sulfonic acid having a 2-theta powder X-ray diffraction diagram comprising peaks at 10.58°, 11.2°, 12.65°, 13.66°, 16.28°, 18.45°, 20°, 20.4°, 22.5°, 25.5°, 25.88°, 26.47°, 28.52°, 30.28°, 30.8°, 34.09°, 38.19°, 40.69°, 41.82°, 43.74°, 46.04° degrees (+/?0.1°). The present invention also relates to a production method for this form of 2-acrylamido-2-methylpropane sulfonic acid and a preparation method for an aqueous solution A of a salt of this form of 2-acrylamido-2-methylpropane sulfonic acid, and the (co)polymer of this form of -acrylamido-2-methylpropane sulfonic acid.