Abstract: A method of treating a kaolin particulate material to improve one or more of its properties by removal of impurity particles therein which includes: producing a dispersed aqueous suspension of a kaolin particulate material containing at least 0.1% by weight, based on the dry weight of the kaolin particulate material of separable particulate impurity; diluting said dispersed aqueous suspension by adding a diluent thereto; adding a selective flocculation polymer to the diluted suspension; allowing the suspension containing the polymer to separate in a selective flocculation separator into layers comprising a flocculated product layer and a deflocculated impurity layer containing the separable impurity; and extracting the separated layers from the separator, wherein at least a portion of said deflocculated impurity layer is recirculated for use as at least a portion of the aforementioned diluent.
Type:
Grant
Filed:
February 7, 2007
Date of Patent:
October 1, 2013
Assignee:
Imerys Pigments, Inc.
Inventors:
Robert J. Pruett, Jim Richardson, William Limousin, Ismail Yildirim, Jun Yuan
Abstract: Disclosed are a gas-liquid separator, a hydrogen generating apparatus, and a fuel cell generation system, having the same. The gas-liquid separator can include an inflow path, into which a fluid material having a liquid and a gas flows; a centrifugal path, connected to the inflow path to receive the fluid material and formed spirally such that the fluid material is separated into the liquid and the gas by difference in centrifugal forces, an outer side of the centrifugal path having stronger affinity for the liquid than an inner side of the centrifugal path; and an outflow path, connected to the centrifugal path and discharging the liquid and the gas, which have been separated in the centrifugal path. With the present invention, it is possible to efficiently separate gas such as hydrogen and liquid such as a electrolyte solution without complex devices.
Type:
Grant
Filed:
June 5, 2009
Date of Patent:
October 1, 2013
Assignee:
Samsung Electro-Mechanics Co., Ltd.
Inventors:
Eon-Soo Lee, Jae-Hyuk Jang, Hye-Yeon Cha
Abstract: The invention relates to a process carried out continuously in one or more reactors connected in series for the preparation of sodium titanate nanotubes and their derivatives obtained by ion exchange and/or thermal treatment, by reacting titanium oxides with sodium hydroxide under suitable hydrothermal conditions to obtain or control the morphology of nanostructural titanates. The reaction mixture is introduced continuously into the reactor at a feed rate that is the same as the rate of discharge of the product. When more than one reactor is used, the material leaving the first reactor is used to feed the next reactor, and a differential of temperature is applied between the reactors in such a way as to obtain in the average, a temperature of between 60° C. and 180° C.
Type:
Grant
Filed:
January 17, 2008
Date of Patent:
October 1, 2013
Assignee:
Petroleo Brasileiro S.A., Petrobras
Inventors:
Edisson Morgado Junior, Marco Antonio Santos De Abreu, Gustavo Torres Moure
Abstract: A thermal energy transfer element includes a thermally conductive core and, in some embodiments, a sleeve. The core has first and second portions. The first portion is for placement in direct contact with and to be surrounded by an electrolyte. The sleeve surrounds at least the first portion of the transfer element. The first portion conducts thermal energy between the electrolyte and the second portion.
Abstract: This disclosure is directed to a method for preparing a new crystalline molecular sieve designated SSZ-87, which is synthesized using an N,N?-diisopropyl-N,N?-diethylbicyclo[2.2.2]oct-7-ene-2,3:5,6-dipyrrolidinium dication as a structure directing agent.
Abstract: This disclosure is directed to a new crystalline molecular sieve designated SSZ-87, which is synthesized using an N,N?-diisopropyl-N,N?-diethylbicyclo[2.2.2]oct-7-ene-2,3:5,6-dipyrrolidinium dication as a structure directing agent.
Abstract: The present invention is directed to a hydroisomerization process using a new crystalline molecular sieve designated SSZ-81, which is synthesized using a structure directing agent selected from 1,5-bis(1-azonia-bicyclo[2.2.2]octane)pentane dications, 1,5-bis(1,4-diazabicyclo[2.2.2]octane)pentane dications, and mixtures thereof.
Abstract: The present invention concerns a nitrogen-free and sulfur-free odorant for hydrogen gas containing at least one acrylic acid C1-C6-alkyl ester and acetophenone, its use for the odorization of hydrogen gas, a process for the odorization of hydrogen gas and hydrogen gas containing an odorant according to the invention.
Abstract: EMM-11 is a novel synthetic crystalline microporous material having a single crystalline phase with a unique 3-dimensional channel system comprising three sets of channels, namely a first set comprising 10-ring channels, and a second set and third set comprising 8-ring channels, having a unique T-atom connectivity and X-ray diffraction pattern which identify it as a novel material, and may be prepared with an organic structure directing agent, preferably, 3-isopropyl-1-methyl-1H-imidazol-3-ium. EMM-11 may be used in organic compounds conversion and absorptive processes.
Type:
Grant
Filed:
March 12, 2012
Date of Patent:
October 1, 2013
Assignee:
ExxonMobil Chemical Patents Inc.
Inventors:
Karl G. Strohmaier, Douglas L. Dorset, Gordon J. Kennedy
Abstract: There is provided a process for producing a DDR-type zeolite having: a raw material solution preparation step of preparing a raw material solution containing 1-adamantaneamine hydrochloride, silica (SiO2), and water at a 1-adamantaneamine hydrochloride/SiO2 molar ratio of 0.002 to 0.5 and a water/SiO2 molar ratio of 10 to 500, and a crystal growth step of subjecting the raw material solution and a DDR-type zeolite powder to a heat treatment in a state that both the raw material solution and the DDR-type zeolite powder are brought into contact with each other to grow crystals of the DDR-type zeolite by the use of the DDR-type zeolite powder as seed crystals.
Abstract: Modified molecular sieve characterized by improved sodium-resisting contamination activity and preparation method thereof are provided. The method comprises: adding molecular sieve in phosphorus-containing organic solution, and reacting for 10-200 minutes at temperature of 70-200° C. and pressure of 0.2-1.2 MPa, and then filtering, drying and calcining. The said modified molecular sieve contains 90-99 wt. % molecular sieve as dry basis and 1-10 wt. % phosphorus as oxide. The said method can improve the capability of sodium-resisting contamination effectively, and its technology is simple and fits the existing catalyst production apparatus and process. The said modified molecular sieve has high sodium-resisting contamination activity, and the model catalyst by sodium contamination has high activity retention.
Type:
Grant
Filed:
December 1, 2009
Date of Patent:
October 1, 2013
Assignee:
PetroChina Company Limited
Inventors:
Xionghou Gao, Dong Ji, Haitao Zhang, Hongchang Duan, Di Li, ZhengGuo Tan, Yi Su, Chenxi Zhang, Yi Wang, Yanqing Ma, Yanbo Sun
Abstract: The present invention is directed to a new crystalline molecular sieve designated SSZ-81, which is synthesized using a structure directing agent selected from 1,5-bis(1-azonia-bicyclo[2.2.2]octane)pentane dications, 1,5-bis(1,4-diazabicyclo[2.2.2]octane)pentane dications, and mixtures thereof.
Abstract: Disclosed is a method for preparing molecular sieve SSZ-23 using a mixture of an N,N,N-trialkyl adamantammonium cation structure directing agent and an N,N?-dialkyl-1,4-diazabicyclo[2.2.2]octane dication.
Abstract: The subject invention pertains to metal organic frameworks (MOF) having zeolite-net-like topology, their methods of use, and their modes of synthesis. The ZMOFs are produced by combining predesigned tetrahedral building, generated in situ using heterochelation, with polyfunctional ligands that have the commensurate angle and the required donor groups for the chelation. Each molecular building block is contrasted of a single metal ion and ligands with both heterochelation functionality and bridging functionality. Advantageously, zeolite-net-like MOFs of the subject invention are porous and contain large functional cavities, which is useful for encapsulating large molecules.
Abstract: Iron-comprising heterogeneous catalyst and a process for producing it, which comprises the steps of thermal decomposition of gaseous iron pentacarbonyl to give carbonyl iron powder having spherical primary particles, treatment of carbonyl iron powder with hydrogen, resulting in the metallic spherical primary particles at least partially forming agglomerates, contacting the agglomerates with iron pentacarbonyl, and thermal decomposition of the iron pentacarbonyl to give at least predominantly pore-free and void-free secondary particles.
Type:
Grant
Filed:
November 4, 2010
Date of Patent:
April 2, 2013
Assignee:
BASF SE
Inventors:
Jochen Steiner, Kerem Bay, Ralf Böhling, Ekkehard Schwab
Abstract: The present invention relates to a process for the preparation of zeolites having B-CHA framework structure and a composition comprising the molar ratio (n SiO2):B2O3, wherein n is at least 10, the process comprising (i) preparation of an aqueous solution containing at least one source for B2O3, at least one source for SiO2, at least one source of seeding crystals of chabazite structure, at least one organic structure directing agent (SDA) other than Tetramethylammonium hydroxide (TMAOH), acting as a template for the B-CHA structure, and Tetramethylammonium hydroxide (TMAOH), wherein the SDA or mixtures thereof are employed in such amounts that the aqueous solution in (i) exhibits a molar ratio of SDA:TMAOH of 0.
Abstract: A material or compound is provided having a spinel structure and corresponding to the formula LiyNi0.5Mn1.5?xIVMnxIIIAzO4?d, where: 0.02?x?0.35; d>0; A is selected from the group comprising Na, K, Mg, Nb, Al, Ni, Co, Zr, Cr, Fe, Cu, Ti, Zn, Si and Mo; 0.8?y?1.2; 0?z?0.1; and has a mesh parameter of between 8.174 and 8.179 ?.
Type:
Grant
Filed:
November 30, 2011
Date of Patent:
March 26, 2013
Assignee:
Commissariat a l'Energie Atomique
Inventors:
Severine Jouanneau, Frederic Le Cras, Carole Bourbon, Helene Lignier
Abstract: A negative electrode material for a nonaqueous secondary battery capable of realizing a nonaqueous secondary battery having a small charging/discharging irreversible capacity at an initial cycle and exhibiting an excellent high-rate charging/discharging characteristics and an excellent cycle performances is provided. The main component of the material is graphite particles. The median diameter is 5 ?m or more, and 40 ?m or less in the volume-basis particle size distribution based on the laser diffraction/scattering particle size distribution measurement. The tapping density is 0.7 g/cm3 or more. The specific surface area measured by a BET method is 0.2 m2/g or more, and 8 m2/g or less. The average circularity is 0.83 or more, and 1.00 or less. When an electrode is produced by a predetermined method for manufacturing an electrode and, the resulting electrode is subjected to X-ray diffraction, the graphite crystal orientation ratio I110/I004 on the electrode is 0.
Type:
Grant
Filed:
August 30, 2005
Date of Patent:
March 26, 2013
Assignees:
Mitsubishi Chemical Corporation, Tokai Carbon Co., Ltd.
Abstract: High-surface-area carbon nanostructures coated with a smooth and conformal submonolayer-to-multilayer thin metal films and their method of manufacture are described. The preferred manufacturing process involves the initial oxidation of the carbon nanostructures followed by immersion in a solution with the desired pH to create negative surface dipoles. The nanostructures are subsequently immersed in an alkaline solution containing non-noble metal ions which adsorb at surface reaction sites. The metal ions are then reduced via chemical or electrical means and the nanostructures are exposed to a solution containing a salt of one or more noble metals which replace adsorbed non-noble surface metal atoms by galvanic displacement. Subsequent film growth may be performed via the initial quasi-underpotential deposition of a non-noble metal followed by immersion in a solution comprising a more noble metal.