Patents Examined by Geraldine Letscher
  • Patent number: 6828089
    Abstract: This invention relates to a silver halide photographic emulsion in which a silver emulsion high in silver iodide content of 80% by mol to 100% by mol based on the silver iodide content is chemically sensitized by at least one of methods of chalcogen sensitization and gold sensitization under the conditions that pAg is from 1.5 to 7.0, as well as a thermally developable photosensitive material having at least one image forming layer containing at least a non-photosensitive organic silver salt, a photosensitive silver halide, a reducing agent and a binder on a support, and having at least one non-image recording protection layer to the image forming layer on the side remote from the support, and exposed by a laser beam in which the material contains the silver emulsion high in silver iodide content.
    Type: Grant
    Filed: March 28, 2003
    Date of Patent: December 7, 2004
    Assignee: Fuji Photo Film Co., LTD
    Inventor: Hiroyuki Mifune
  • Patent number: 6824967
    Abstract: A method of preparing a dye solution having a high concentration and high stability, wherein a counter ion-free dye and a base having a pKa value of from 6.6 to 9.0 are dissolved in a solvent having a relative dielectric constant of at least 10 at 20° C., and a silver halide emulsion and a silver halide photographic material which are reduced in fogging by the use of the dye solution prepared in accordance with the aforesaid method.
    Type: Grant
    Filed: August 18, 2003
    Date of Patent: November 30, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuo Nakamura, Katsuyuki Takada
  • Patent number: 6824968
    Abstract: A silver halide color reversal photographic light-sensitive material comprising at least one interimage effect imparting layer (a) defined below and at least one interimage effect imparting layer (b) defined below, wherein, when the photographic light-sensitive material is exposed to light of a “skin color” having the spectral distribution of Table 1 described in the specification and is then subjected to development, a ratio of the chroma C*70 at a brightness L*=70 represented by CIE Lab color system to the chroma C*50 at a brightness L*=50, C*70/C*50, is 0.7 or more. (a) an interimage effect imparting layer containing a short-wavelength green-sensitive silver halide emulsion having a weight-averaged wavelength of a spectral sensitivity distribution of 500 to 560 nm; (b) an interimage effect imparting layer containing a red-sensitive silver halide emulsion having a weight-averaged wavelength of a spectral sensitivity distribution of 580 to 700 nm.
    Type: Grant
    Filed: October 10, 2003
    Date of Patent: November 30, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yutaka Maeno, Sadanobu Shuto, Akihiro Kakinuma
  • Patent number: 6821719
    Abstract: A process for producing a deformed image comprising the steps of: digitally exposing a color photographic silver halide material, said color photographic silver halide material comprising on a deformable plastic support at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler; conventionally processing said exposed color photographic material to produce an image; and deforming said color photographic material.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: November 23, 2004
    Assignee: AGFA-Gevaert
    Inventors: Ly Cuong, Markus Geiger, Leon Vermeulen, Arno Schmuck
  • Patent number: 6821687
    Abstract: A photo mask for fabricating a semiconductor device having a dual damascene structure which has a via coupled with a lower wiring layer and has an upper wiring layer coupled with the via. The via and the upper wiring layer are fabricated by filling a via hole and a wiring groove formed in an interlayer insulating film that is formed on the lower wiring layer with a wiring material. The photo mask has a via alignment mark which is used for aligning the via hole with respect to the lower wiring layer and/or a via alignment mark which is used for aligning the wiring groove with respect to the via hole. The width of the via alignment mark is equal to or larger than the width which is optically detectable and an aspect ratio of the via alignment mark is equal to or larger than one fourth of the aspect ratio of the via hole. Preferably, the width of the via alignment mark is equal to or larger than the width of the via hole.
    Type: Grant
    Filed: April 2, 2002
    Date of Patent: November 23, 2004
    Assignee: NEC Electronics Corporation
    Inventors: Nobuaki Hamanaka, Takashi Yokoyama, Kazutoshi Shiba, Noriaki Oda
  • Patent number: 6818390
    Abstract: A deformable color photographic silver halide material, said color photographic silver halide material comprising on a deformable plastic support at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler can be deformed without loss in image quality and is suitable for large formats and automatic processing.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: November 16, 2004
    Assignee: AGFA-Gevaert
    Inventors: Ly Cuong, Markus Geiger, Leon Vermeulen, Arno Schmuck
  • Patent number: 6815153
    Abstract: This invention relates to a silver halide photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein said photographic element has an ISO speed rating of 800 or greater and has an integrated RMS green granularity equal to or less than 11.2.
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: November 9, 2004
    Assignee: Eastman Kodak Company
    Inventors: James A. Friday, Roger A. Weiss, Anabisdally I. Bodden
  • Patent number: 6815152
    Abstract: A silver halide color photographic photosensitive material comprising: a transmitting support; at least three types of photosensitive hydrophilic colloid layers disposed on the support, each type including at least one of a yellow, a magenta and a cyan color forming coupler; silver halide emulsion particles, which have a color sensitivity different from the other types, wherein at least one of the color sensitivities comprises green-sensitivity; and an Fe content of no more than 2×10−5 moles/m2; each silver halide emulsion particle including a halogen composition, which comprises at least one of silver chlorobromide, silver chloroiodide, silver chloroiodide bromide and silver chloride having a silver chloride content ratio of 95% by mole or more, an average sphere-equivalent particle diameter of the green-sensitive silver halogen emulsion particles comprising no more than 0.25 &mgr;m and at least one type of the green-sensitive silver halogen emulsion particles being doped with Ir.
    Type: Grant
    Filed: September 26, 2002
    Date of Patent: November 9, 2004
    Assignee: Fuji Photo Film. Co., Ltd.
    Inventors: Kiyohito Takada, Hidekazu Sakai, Terukazu Yanagi
  • Patent number: 6811963
    Abstract: This invention relates to a silver halide photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of the dye image forming units contains layers of differing sensitivities, and the layer of highest sensitivity contains a development promoting agent or a specific coupler as described herein, or a combination thereof, and a silver halide emulsion comprising tabular silver halide grains having associated therewith at least two dye layers comprising (a) an inner dye layer adjacent to the silver ha
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: November 2, 2004
    Assignee: Eastman Kodak Company
    Inventors: Sharon G. Johnston, Stephen P. Singer, Drake M. Michno, James A. Friday, David R. Foster
  • Patent number: 6808871
    Abstract: A silver halide emulsion is disclosed, comprising silver halide grains, wherein at least 50% of total grain projected area is accounted for by tabular grains having an aspect ratio of 10 to 100 and at least 50% by number of total grains is accounted for by tabular grains having at least 30 dislocation lines per grain in the fringe portion of the grain, and the emulsion contains a compound having a function of permitting injection of at least two electrons into silver halide via photoexcitation by a single photon.
    Type: Grant
    Filed: October 8, 2002
    Date of Patent: October 26, 2004
    Assignee: Konica Corporation
    Inventors: Katsuhiko Suzuki, Yoshiko Iwai
  • Patent number: 6808870
    Abstract: A light-sensitive silver halide grain containing at least one metal complex, wherein when an a-axis, a b-axis and a c-axis of a silver halide crystal lattice are each established taking as an origin a central metal of the metal complex incorporated into the silver halide grain, the metal complex has in a ligand thereof a site which can form any bond of a covalent bond, a dative bond and an ionic bond, or a bond in a mixed form of these bonds with a silver ion on a lattice point which does not exist on any of the a-axis, the b-axis and the c-axis. The silver halide photographic material has no reciprocity failure over a wide range of exposure illuminations without desensitization and decrease of contrast on the low intensity side.
    Type: Grant
    Filed: September 23, 2002
    Date of Patent: October 26, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadanobu Sato, Takahiro Matsuno, Masaru Takasaki, Tadashi Inaba
  • Patent number: 6806042
    Abstract: A print material having a support, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, characterised in that the red-sensitive layer contains at least one oil former, the cyan coupler is of the formula in which R1 means a hydrogen atom or an alkyl group, R2 means an alkyl, aryl or hetaryl group, R3 means an alkyl or aryl group, R4 means an alkyl, alkenyl, alkoxy, aryloxy, acyloxy, acylamino, sulfonyloxy, sulfamoylamino, sulfonamido, ureido, hydroxycarbonyl, hydroxycarbonylamino, carbamoyl, alkylthio, arylthio, alkylamino or arylamino group or a hydrogen atom and Z means a hydrogen atom or a group eliminable under the conditions of chromogenic development, and the ratio by weight of oil former to cyan coupler is less than 1:1, is distinguished by exc
    Type: Grant
    Filed: July 2, 2003
    Date of Patent: October 19, 2004
    Assignee: Agfa-Gevaert
    Inventors: Ralf Weimann, Markus Geiger, Cuong Ly, Klaus Sinzger, Beate Weber, Heinz Wiesen
  • Patent number: 6806043
    Abstract: A silver halide photographic light-sensitive material is disclosed, comprising a support having thereon at least one light-sensitive silver halide emulsion layer, wherein said emulsion layer contains a compound represented by the following formula (1): Dye1&Parenopenst;L1&Parenopenst;Dye2)m1)m2  (1) wherein Dye1 represents a cyanine chromophore, Dye2 represents a merocyanine dye having in the acid nucleus thereof at least one dissociative group having a pKa of 5 or less, and L1 represents a linking group represented by -G1-(A1-G2)t1-(wherein G1 and G2 each independently represents an alkylene, alkenylene or arylene group which may be substituted, A1 represents, irrespective of the direction, —O—, —S—, —SO2—, —NR3—, —COO—, —CONR4— or —SO2NR5— (wherein R3 to R5 each independently represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group or a heterocyclic group) and t1 represents an integer of 1 to 1
    Type: Grant
    Filed: March 22, 2002
    Date of Patent: October 19, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroo Takizawa
  • Patent number: 6803181
    Abstract: A dye-forming coupler of the formula (I). A silver halide photographic light-sensitive material that contains at least one dye-forming coupler of the formula (I). A method for producing an azomethine dye, which method comprises using a compound of the formula (I): wherein E is an aryl, heterocyclic, or —C(═O)W group, in which W is a nitrogen-containing heterocyclic group, Z is an aryl or heterocyclic group, and X and Y each independently are ═O, ═S or ═N—R, in which R is a substituent, with the proviso that when E is an aryl or heterocyclic group, X and Y each are ═O, and that when E is a —C(═O)W group, Z is a substituted aryl group.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: October 12, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeki Uehira, Jun Ogasawara, Kiyoshi Takeuchi, Yasuhiro Shimada, Yasuaki Deguchi
  • Patent number: 6794122
    Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide photographic emulsion layer, wherein the emulsion layer contains at least one compound of formulae (Ia), (Ib) and (Ic) and at least one compound of formula (II): wherein Z1 represents S, O, Se, Te, N or C; R, R31 and R32 each are an alkyl, aryl or heterocyclic group; D is a group necessary for forming a methine dye; V1 to V4 represent H or a monovalent substituent; M and M3 each are a charge-balancing counter ion; m and m3 each are a number or 0 or more necessary for neutralizing the charge of the molecule; Z31 and Z32 each are an atomic group necessary for forming the nitrogen-containing hetero-ring; L31 to L37 each represent a methine group; p31 and p32 each are 0 or 1; n3 is 0, 1, 2, 3 or 4, but the compound of formula (II) does not include the compounds of formulae (Ia), (Ib) and (Ic).
    Type: Grant
    Filed: December 4, 2002
    Date of Patent: September 21, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takanori Hioki, Tetsuo Nakamura
  • Patent number: 6794121
    Abstract: This invention relates to a method of spectrally sensitizing a silver halide emulsion comprising the following steps in the following order a) providing a silver halide emulsion comprising tabular silver halide grains having an inner dye layer adjacent to the silver halide grain, said dye layer comprising at least one dye (Dye 1) that is capable of spectrally sensitizing silver halide, b) adding to the emulsion at least one dye (Dye 2) capable of providing a second dye layer adjacent to the inner dye layer, and c) adding to the emulsion a non-cationic surfactant or a scavenger for oxidized developer, or a combination of the two, to form a silver halide emulsion comprising silver halide grains having associated therewith two dye layers, wherein the dye layers are held together by non-covalent forces or by in situ bond formation; the outer dye layer adsorbs light at equal or higher energy than the inner dye layer; and the energy emission wavelength of the outer dye layer overlaps with the energy absorption
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: September 21, 2004
    Assignee: Eastman Kodak Company
    Inventors: David R. Foster, Stephen P. Singer, William J. Harrison, Alan R. Pitt
  • Patent number: 6790602
    Abstract: This invention relates to a method of spectrally sensitizing a silver halide emulsion comprising the following steps in the following order a) providing a silver halide emulsion comprising tabular silver halide grains having an inner dye layer adjacent to the silver halide grain, said dye layer comprising at least one dye (Dye 1) that is capable of spectrally sensitizing silver halide, b) adding to the emulsion at least one dye (Dye 2) capable of providing a second dye layer adjacent to the inner dye layer, and c) adding to the emulsion a non-cationic surfactant or a scavenger for oxidized developer, or a combination of the two, to form a silver halide emulsion comprising silver halide grains having associated therewith two dye layers, wherein the dye layers are held together by non-covalent forces or by in situ bond formation; the outer dye layer adsorbs light at equal or higher energy than the inner dye layer; and the energy emission wavelength of the outer dye layer overlaps with the energy absorption
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: September 14, 2004
    Assignee: Eastman Kodak Company
    Inventors: David R. Foster, Stephen P. Singer, William J. Harrison, Alan R. Pitt
  • Patent number: 6787297
    Abstract: This invention provides a silver halide photographic element comprising at least one silver halide emulsion comprising silver halide grains which have associated therewith at least an inner dye layer and an outer dye layer wherein the outer dye layer comprises a dye having at least one substituent that has a positive charge, said photographic element further comprising a cyanine dye of formula (I) or (II) (as described in the specification) that is capable of spectrally sensitizing a silver halide emulsion.
    Type: Grant
    Filed: May 12, 2003
    Date of Patent: September 7, 2004
    Assignee: Eastman Kodak Company
    Inventors: Steven G. Link, Richard L. Parton, Robert D. Wilson, Roger A. Bryant, William J. Harrison
  • Patent number: 6787296
    Abstract: Silver halide emulsions are disclosed comprising tabular silver halide grains containing dislocation lines in the peripheral region of the major faces; the tabular grains comprising a high iodide phase which is internal to and along the dislocation lines and an internal region which is surrounded by the high iodide phase and comprised of substantially homogeneous silver halide phase and having an average iodide content of not more than 1 mol %. Silver halide photographic materials by the use of the emulsion are also disclosed.
    Type: Grant
    Filed: May 20, 2002
    Date of Patent: September 7, 2004
    Assignee: Konica Corporation
    Inventors: Rieko Ren, Tomoyuki Nakayama
  • Patent number: 6783923
    Abstract: A silver halide color photosensitive material comprising at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one blue-sensitive silver halide emulsion layer, on a support. The photosensitive material has an indicated speed of 800 or higher, and an ISO speed of 1.25 times the indicated speed or higher.
    Type: Grant
    Filed: July 16, 2003
    Date of Patent: August 31, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takeichi Tatsuta, Yoichi Suga, Kohzaburoh Yamada