Abstract: A composition is disclosed which comprises:(A) a compound represented by the formula ##STR1## wherein: R.sup.1 and R.sup.2 are independently hydrocarbyl groups of from about 2 to about 24 carbon atoms; R.sup.3 is a trivalent hydrocarbyl group of from 1 to about 16 carbon atoms; R.sup.4 is CH.sub.2 CH.sub.2 O, CH.sub.2 CH.sub.2 CH.sub.2 O or a mixture thereof; X is SO.sub.3.sup.-, SO.sub.4.sup.- or COO.sup.- ; and Y is an alkali metal or ##STR2## wherein R.sup.5, R.sup.6, R.sup.7 and R.sup.8 are independently hydrogen or methyl; and n is a number ranging from zero to about 15; and(B) a compound represented by the formula R.sup.9 -(R.sup.10).sub.m A.sup.-D.sup.+wherein: R.sup.9 is a hydrocarbyl group of from about 8 to about 24 carbon atoms; R.sup.10 is CH.sub.2 CH.sub.2 O, CH.sub.2 CH.sub.2 CH.sub.2 O or a mixture thereof; A is SO.sub.3.sup.-, SO.sub.4.sup.- or COO.sup.- ; D is an alkali metal or ##STR3## wherein R.sup.11, R.sup.12, R.sup.13 and R.sup.
Abstract: A composition of matter wherein amino resins such as melamine formaldehyde ("MF") resins modify polysaccharide polymers thereby forming gels with transitional metal ions useful for profile control where said polymers have amine, amide, hydroxyl and thiol funmctionalities. Said gels are thermally stable, brine tolerant and rehealable. Said resin modified polysaccharide polymers can be used in their liquid or ungelled state as a mobility control agent in a reservoir during the removal of hydrocarbonaceous fluids therefrom.
Abstract: A corrosion inhibitor for ferrous and non-ferrous aqueous systems comprising (a) a water soluble phosphonic acid or salt thereof, preferably an amino methylene phosphonic acid; (b) a phosphonocarboxylic acid, preferably a phosphonoalkane carboxylic acid; (c) an azole, preferably benzotriazole or tolyltriazole; and (d) a water soluble molybdate salt, preferably sodium molybdate.
Abstract: A process is disclosed for producing a powdered antimony pentoxide composition that rapidly disperses on contact with water. The process comprises spray drying the antimony sol at a temperature of from 180.degree. to 210.degree. F.
Type:
Grant
Filed:
March 16, 1987
Date of Patent:
February 14, 1989
Assignee:
Phillips Petroleum Company
Inventors:
Richard E. Lowery, Denton C. Fentress, Don W. Godbehere
Abstract: A composition, useful for dissolving sulfur, which comprises a major amount of a disulfide or polysulfide and a catalyst comprising one or more polyalkyleneoxyamines or polyamines, and methods for using the composition in a system to prevent sulfur-plugging, are disclosed.
Type:
Grant
Filed:
May 8, 1987
Date of Patent:
February 14, 1989
Assignee:
Pennwalt Corporation
Inventors:
Glenn T. Carroll, Michael J. Lindstrom, William J. Tuszynski
Abstract: Solid sodium bromide and aqueous sodium bromide solutions incorporate sodium tartrate and one or more amides of nitrolotriacetic acid in order to inhibit floc formation in aqueous sodium bromide solutions in the pH range 6-12 and in order to insure that the solid sodium bromide is free flowing.
Abstract: Powder-form lubricant additives for water-based drilling fluids which contain from 95 to 30% by weight, based on the total weight of the powder, of highly disperse silicas, from 5 to 70% by weight, based on the total weight of the powder, of one or more fatty acid alkyl esters corresponding to the following general formula.R.sup.1 COOR.sup.2 (I)in which R.sup.1 is a straight-chain or branched, saturated or mono- or polyunsaturated C.sub.9 -C.sub.21 alkyl or alkenyl radical and R.sup.2 is a straight-chain or branched C.sub.1 -C.sub.12 alkyl radical, and/or polyesters obtainable by reaction of di-, oligo- or poly-hydroxy compounds with carboxylic acids and/or distillation residues from the transesterification of native fatty acid esters and, optionally, other additives known for lubricating purposes in quantities of from 0 to 20% by weight, based on the total weight of the powder, and to the use of these powder-form additives in drilling fluids for oil well and mine drilling in quantities of from 0.
Abstract: A fracturing fluid based on quar gum exhibiting good viscosity and stability at temperatures from about 80.degree. C. to at least about 120.degree. C. The fracturing fluid includes a guar gum, a zirconium or hafnium cross-linking agent, and a bicarbonate salt in an aqueous solution at a pH from about 8 to about 10.
Type:
Grant
Filed:
August 3, 1987
Date of Patent:
January 31, 1989
Assignee:
Dowell Schlumberger Incorporated
Inventors:
Harold D. Brannon, Richard M. Hodge, Kevin W. England
Abstract: A crosslinker composition that can produce delayed crosslinking of an aqueous solution of a crosslinkable organic polymer. The composition comprises a metal compound, preferably an organic metal complex, and most preferably an organic zirconium complex. The composition further contains an organic hydroxycarboxylic acid, preferably hydroxyacetic acid. The pH of the composition is preferably no more than 4.8. The pH of the composition is further preferably such that when sufficient amount of composition is added to an aqueous polymer solution to result in delayed crosslinking of the polymer, the composition produces a pH in the resulting gel solution, preferably of between about 3 and about 4.5. Gel solutions produced using the composition are particularly useful in fracturing subterranean formations, and in particular in fracturing subterranean formations penetrated by an oil well in which fracturing process carbon dioxide and a proppant are added to the fracturing fluid.
Abstract: A composition for use in agglomerating and removing solid contaminants in well fluids is disclosed. The composition comprises a carrier and the amide/glyceride reaction product obtained by heating a secondary amine in the presence of a fat or oil. The composition is used in processes to agglomerate the solids in contaminated well fluid and in which the agent is diluted and used as a preflush prior to replacing drilling mud with fresh well fluid.
Abstract: A method of breaking gelled viscosities of oil-based gelled fracturing fluids used in low temperature formations having operating temperatures ranging between about 60.degree.-120.degree. F. which comprises treating said oil-based gelled fracturing fluids with an effective amount of a chemical breaker consisting essentially of an effective admixture of hydrated lime and sodium bicarbonate.
Abstract: An oil recovery process in which oil is displaced by a viscous alkaline aqueous solution is improved by using such an aqueous alkaline solution containing a water-thickening polymer partially hydrolyzed polyacrylamide polymer and a stabilizer consisting essentially of a 2-mercaptobenzothiazole in the presence of a sulfur-containing oxygen scavenger. A readily oxidizable alcohol or glycol may also be included.
Type:
Grant
Filed:
July 20, 1987
Date of Patent:
January 3, 1989
Assignee:
Shell Oil Company
Inventors:
Jeffrey G. Southwick, Richard C. Nelson
Abstract: There is provided an aqueous brine fluid containing a high salt concentration and a polyvinylpyrrolidone polymer or copolymer which serves to increase the viscosity thereof, particularly at elevated temperatures of above about 300.degree. F. These fluids are particularly useful as drilling fluids for the drilling of oil and gas wells.
Abstract: Onium species of nitrogen, phosphorus or sulfur are useful to precipitate ferric ion, existing as tetrahaloferrate anion, from strong haloacid solutions. The precipitants are useful in the field of well acidizing, because tetrahaloferrate anion attacks polymeric and viscoelastic surfactant thickeners used to thicken haloacid solutions.
Abstract: A new and improved composition and method for profile modification of subterranean formations characterized by high reservoir temperatures and/or harsh brine conditions are disclosed. The new and improved profile modification agents comprise a gelable composition comprising:(a) water;(b) a water-thickening and crosslinkable amount of a water-dispersible copolymer comprising from about 1 to about 99 mol % of units derived from an N,N.sup.1 -dialkylacrylamide monomer copolymerized with from about 1 to about 99 mol % of units derived from acrylic acid or a salt thereof; and(c) an amount of a polyvalent metal sufficient to crosslink the copolymer to form a stable gel. The profile modification agents are effective to alter the permeability of preselected portions of an underground formation by forming strong gels which are stable in harsh brine at temperatures of up to about 120.degree. C. The composition and method are particularly adapted for use in enhanced oil recovery operations.
Abstract: The present invention relates to corrosion inhibitors which can be used with calcium-free drilling, completion and workover fluids in carbonate or sulfate containing wells. More particularly, the invention relates to the use of sodium, ammonium and/or calcium thiocyanate alone, or in combination with specific aldose group antioxidants, as corrosion inhibitors. Aldose group antioxidants include arabinose, ascorbic acid, isoascorbic acid, gluconic acid, alkali metal, and alkaline earth or other metal ascorbates, isoascorbates and gluconates and mixtures thereof. Additionally, ammonium thioglycolate may be incorporated as a further corrosion inhibitor.
Abstract: A composition of matter where a polymer is partially hydrolyzed to form a polymer intermediate which can be gelled. Said polymer intermediate consists of 2-acrylamido-2-methylpropane-3 sulfonate, N-vinyl-N-methyl acetamide, acrylamide, and an alkali metal hydroxide. When cross-linked with a transitional metal ion said polymer intermediate forms a gel suitable for profile control use under harsh conditions. Said gel is exceptionally stable under the hot temperature and saline conditions encountered in profile control usage during a water flood or carbon dioxide oil recovery operation.
Type:
Grant
Filed:
December 22, 1986
Date of Patent:
November 15, 1988
Assignee:
Mobil Oil Corporation
Inventors:
Dennis H. Hoskin, Thomas O. Mitchell, Paul Shu
Abstract: Thio group corrosion inhibitors and aldose group antioxidants when combined provide a synergistic corrosion inhibition system for clear, high density oil and gas completion and workover fluids.
Abstract: Impressed current cathodic protection systems employing an anode having a cobalt spinel type surface, said surface having the formula: M.sub.x Z.sub.y Co.sub.(3-(x+y)) O.sub.4, where M is a metal or a mixture of two or more metals selected from the group of metals contained in Groups IB, IIA, and IIB of the periodic table of the elements, where Z is a metal or a mixture of two or more metals selected from the group of metals contained in Group IA of the periodic table of the elements, where 0.ltoreq.x.ltoreq.1, where 0.ltoreq.y.ltoreq.0.5, and where 0.ltoreq.(x+2y).ltoreq.1.
Type:
Grant
Filed:
April 13, 1987
Date of Patent:
November 1, 1988
Assignee:
The Dow Chemical Company
Inventors:
Raul A. Castillo, Donald L. Caldwell, Ralph W. Parham, Jr.
Abstract: An epitaxial layer is used to place the surface of a crystal in compression o as to greatly increase the durability of the crystal such as a laser medium crystal.
Type:
Grant
Filed:
November 7, 1986
Date of Patent:
December 6, 1988
Assignee:
The United States of America as represented by the Department of Energy
Inventors:
Robert C. Morris, John E. Marion, II, Devlin M. Gaultieri