Patents Examined by J. Ziegler
  • Patent number: 4451611
    Abstract: An improved process for producing a polymer blend which exhibits an anisotropic melt phase and is capable of forming shaped articles having satisfactory mechanical properties (e.g. tensile strength, flexural strength, and Izod impact strength) is provided. The process comprises the steps of (a) post-polymerizing a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase apart from the blend and (b) subsequently intimately mixing together approximately 85 to 95 percent by weight of the wholly aromatic polyester and approximately 5 to 15 percent by weight of a polyalkylene terephthalate. Accordingly, the wholly aromatic polyester which is capable of forming an anisotropic melt phase serves as the continuous phase in the resulting blend.
    Type: Grant
    Filed: December 15, 1981
    Date of Patent: May 29, 1984
    Assignee: Celanese Corporation
    Inventors: David E. Cincotta, Frank M. Berardinelli
  • Patent number: 4451617
    Abstract: A miscible polyblend comprising an .alpha., .beta.-ethylencially unsaturated dicarboxylic acid or its anhydride copolymerized with at least one monovinyl-substituted aryl hydrocarbon monomer and an imide derivative of maleic anhydride copolymerized with at least one monovinyl-substituted-aryl hydrocarbon monomer is disclosed.
    Type: Grant
    Filed: August 16, 1982
    Date of Patent: May 29, 1984
    Assignee: Atlantic Richfield Company
    Inventor: Bi L. Khac
  • Patent number: 4450256
    Abstract: A thermoplastic resin which is outstanding in impact resistance and heat distortion resistance and is discolored only little by heat is produced by polymerizing, in the presence of diene type synthetic rubber, a monomer mixture of acrylonitrile and styrene, adding thereto a monomer mixture containing more than 80 wt % of .alpha.-methylstyrene, and then adding thereto little by little a monomer mixture containing more than 70 wt % of acrylonitrile, whereby 95-70 parts by weight of monomer is polymerized in the presence of 5-30 parts by weight of the diene type synthetic rubber.
    Type: Grant
    Filed: January 12, 1983
    Date of Patent: May 22, 1984
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Sigemi Matsumoto, Fumiya Nagoshi
  • Patent number: 4448929
    Abstract: A protective colloid for use in an interfacial polymerization process comprising a graft copolymer of polyvinyl alcohol and methyl vinyl ether/maleic acid.
    Type: Grant
    Filed: June 1, 1982
    Date of Patent: May 15, 1984
    Assignee: Stauffer Chemical Company
    Inventors: Marius Rodson, Herbert B. Scher
  • Patent number: 4448932
    Abstract: This invention relates to a polyvinyl chloride resin composition containing said resin and a significant amount of a polymer of butadiene in the form of a shell-core polymer wherein a polymer of methylmethacrylate forms said shell and completely encapsulates the core containing the butadiene polymer.
    Type: Grant
    Filed: September 2, 1982
    Date of Patent: May 15, 1984
    Assignee: GAF Corporation
    Inventors: Yehuda Ozari, Suzanne B. Nelsen, Andrew Klein
  • Patent number: 4448931
    Abstract: A resin composition comprising a polyphenylene ether resin and a rubber-modified polystyrene resin, wherein at least 80% of the rubber particles based on the total number of rubber particles in the elastomeric phase of the rubber-modified polystyrene resin have a particle diameter in the range of 0.5 to 4 microns, and the elastomeric phase has a particle size distribution index, SDI, defined by the equation ##EQU1## wherein x is the diameter in microns of the particles, and n is the number of particles having a particle diameter of x microns, of not more than 1.9.
    Type: Grant
    Filed: April 16, 1982
    Date of Patent: May 15, 1984
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Akikazu Amagai
  • Patent number: 4447578
    Abstract: A thermoplastic resin composition having high heat resistance coupled with high impact resistance is obtained by combining a predominant amount of (A) a copolymer of methyl methacrylate, acrylonitrile, 2-isopropenylnaphthalene and .alpha.-methylstyrene, and (B) a graft copolymer of methyl methacrylate, optionally with styrene and acrylonitrile, on a butadiene rubber.
    Type: Grant
    Filed: December 20, 1982
    Date of Patent: May 8, 1984
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Takayuki Katto, Yasumasa Komatsu, Zenya Shiiki
  • Patent number: 4447571
    Abstract: A process for providing water based anionic polyurethanes having improved thermal oxidation color stability. Water dispersed amine salts of anionic prepolymers prepared from the reaction of polyhydroxy compounds and dihydroxy carboxylic acids with diisocyanates are chain-extended with hydrazine or hydrazide and thereafter optionally with a diamine, when cured at temperatures in excess of 150.degree. C., form polyurethane products having substantially no discoloration and good mechanical properties. Alternately, the hydrazide may be employed as an additive rather than as a chain-extender. The process is particularly useful when employing cross-linking agents which react only at high temperatures.
    Type: Grant
    Filed: October 15, 1981
    Date of Patent: May 8, 1984
    Assignee: Witco Chemical Corporation
    Inventors: Shmuel Dabi, Peter Loewrigkeit
  • Patent number: 4446278
    Abstract: A new class of polymer blends comprising (I) block copolymers of polyphenylene oxides and sterically-hindered aromatic polycarbonates and (II) vinyl aromatic resins.
    Type: Grant
    Filed: May 12, 1983
    Date of Patent: May 1, 1984
    Assignee: General Electric Company
    Inventor: George R. Loucks
  • Patent number: 4446277
    Abstract: A thermoplastic molding material based on a styrene polymer which has been made impact-resistant, and on a polyphenylene ether, wherein the impact-resistant styrene polymer comprises a soft component which has a mean particle diameter of greater than 0.3 .mu.m and contains an acrylic ester polymer as the elastomeric component. The novel molding materials possess improved flow and give moldings having improved aging resistance.
    Type: Grant
    Filed: May 23, 1983
    Date of Patent: May 1, 1984
    Assignee: BASF Aktiengesellschaft
    Inventors: Franz Brandstetter, Adolf Echte, Franz Haaf, Juergen Hambrecht, Herbert Naarmann
  • Patent number: 4444950
    Abstract: A thermoplastic resin composition improved in weld strength which comprises (A) a polycarbonate resin and (B) a rubber modified copolymer with (C) an epoxy group-containing olefin copolymer.
    Type: Grant
    Filed: March 1, 1983
    Date of Patent: April 24, 1984
    Assignee: Sumitomo Naugatuck Co., Ltd.
    Inventors: Hajime Sakano, Akitoshi Ito, Motoichi Yano, Yasuhiro Honda
  • Patent number: 4444951
    Abstract: Molding compositions are prepared from blends of (A) thermoplastic polynorbornene nitrile polymers; (B) styrene/maleic anhydride polymers; (C) at least one of the polymers selected from the group consisting of ABS polymers, MBS polymers, and styrene/acrylonitrile polymers. Component B, the styrene/maleic anhydride polymer may optionally contain a termonomer such as methylmethacrylate or acrylonitrile and a rubber component.
    Type: Grant
    Filed: April 11, 1983
    Date of Patent: April 24, 1984
    Assignee: Monsanto Company
    Inventor: Robert A. Mendelson
  • Patent number: 4443503
    Abstract: Disclosed is an anti-corrosive coating composition comprising (a) 100 parts by weight of an unsaturated polyester resin, (b) 10 to 100 parts by weight of a glass flake having an average thickness of 0.5 to 5 microns and an average particle size of 100 to 400 microns, or 10 to 70 parts by weight of said glass flake and 10 to 150 parts of scaly metal pigment, (c) 0.1 to 1.0 part by weight of a ketone peroxide and (d) 0.5 to 2.0 parts by weight of a hydroperoxide and/or a peroxy ester. Also disclosed is a process for forming anti-corrosive coatings, which comprises spray-coating the above anti-corrosive coating composition to a thickness of 300 to 1500 microns by using a spray gun having a spray tip diameter of 0.5 to 3 mm.
    Type: Grant
    Filed: September 2, 1982
    Date of Patent: April 17, 1984
    Assignee: Dai Nippon Toryo Co., Ltd.
    Inventors: Minoru Hoshino, Tosio Shinohara, Hiroyuki Tanabe, Tooru Taki, Shunsuke Nakayama
  • Patent number: 4443583
    Abstract: A process for the production of polychloroprene mixtures of sol and gel polymers in a ratio, by weight, of rom 1:4 to 9:1, the gel polymer being produced by radical emulsion polymerization from chloroprene in the presence of 4 to 10% by weight of water soluble disproportionated abietic acid, and the sol polymer being produced by radical emulsion polymerization of chloroprene in the presence of not more than 3.5% by weight of a water soluble disproportionated abietic acid with the polychloroprene mixture containing at most 3.8% of said acid.
    Type: Grant
    Filed: June 10, 1982
    Date of Patent: April 17, 1984
    Assignee: Bayer Aktiengesellschaft
    Inventors: Rudiger Musch, Gottfried Pampus, Rudolf Casper, Peter Muller, Wilhelm Gobel
  • Patent number: 4443582
    Abstract: This invention relates to a polychloroprene elastomer distinguished by good processing properties and high tensile strength in the form of a polychloroprene mixture containing a sol polymer and a gel polymer in a ratio, by weight, of from 1:4 to 9:1, characterized in that both polymers have been produced in the presence of from 2.5 to 4.0 parts, by weight, of the potassium salt of disproportionated abietic acid (expressed as acid), from 0.3 to 1.0 part, by weight, of a condensation product of naphthalene sulphonic acid and formaldehyde and from 0.1 to 1.5 parts, by weight, of potassium hydroxide, based in each case on 100 parts, by weight, of monomer, and in that the gel polymer is a copolymer of chloroprene and from 1.5 to 2.5 mole percent, based on total monomer, of a diester corresponding to the following general formula: ##STR1## wherein R.sub.1 and R.sub.2 represent hydrogen, chlorine or C.sub.1 -C.sub.4 alkyl; andX represents C.sub.2 -C.sub.10 alkylene.
    Type: Grant
    Filed: May 19, 1982
    Date of Patent: April 17, 1984
    Assignee: Bayer Aktiengesellschaft
    Inventors: Rudiger Musch, Gottfried Pampus, Peter Muller, Ulrich Eisele, Wolfgang Konter, Wilhelm Gobel
  • Patent number: 4442262
    Abstract: Disclosed herein is a composition of a polyester-block copolymer, comprising 5 to 80% by weight of at least one kind of graft-copolymer obtained by graft-copolymerizing 50 to 25 parts by weight of a monomeric mixture predominantly consisting essentially of styrene and methyl methacrylate and containing 0.01 to 3.0% by weight of a cross-linking agent with 50 to 75 parts by weight of a cross-linked elastomeric trunk polymer containing not less than 50% by weight of rubber like segment selected from the group consisting of butadiene unit and C.sub.4 to C.sub.10 -alkyl acrylate units, and 0.01 to 3.0% by weight of a cross-linking agent, and 95 to 20% by weight of a polyester-block copolymer, the composition giving shaped articles of favorable superficial appearance even when processed by shape-forming under conditions of mixing and kneading of a relatively low degree.
    Type: Grant
    Filed: November 17, 1981
    Date of Patent: April 10, 1984
    Assignees: Kureha Kagaku Kogyo Kabushiki Kaisha, Toyo Boseki Kabushiki Kaisha
    Inventors: Haruhiko Yusa, Mitsuru Hoshino, Akira Kurosaki, Hironobu Furusawa, Chikara Sugitawa
  • Patent number: 4442265
    Abstract: A polymeric blend containing (1) copolymer of lactone with conjugated diene or monovinylarene or both conjugated diene and monovinylarene, (2) acrylic ester polymer and (3) coumarone-indene resin.
    Type: Grant
    Filed: September 29, 1982
    Date of Patent: April 10, 1984
    Assignee: Phillips Petroleum Company
    Inventor: John R. Haws
  • Patent number: 4440912
    Abstract: Novel copolymers are prepared by the interaction of low or high molecular weight polyarylates, such as bisphenol A-isophthalate-terephthalate polyarylates, or bisphenol A-isophthalate-terephthalate-carbonate polyarylates and a high molecular weight diprimary dialcohol polyester polymer, such as polyethylene terephthalate polymer. The resulting copolymers are transparent and tough. They maintain their dimensional stability over a wide range of temperature from 75.degree.-175.degree. C., are soluble in chlorinated solvents, and have one glass transition point.
    Type: Grant
    Filed: April 23, 1982
    Date of Patent: April 3, 1984
    Assignee: General Electric Company
    Inventors: Daniel W. Fox, Bruce A. Kaduk, John B. Starr, Jr.
  • Patent number: 4440906
    Abstract: The use of tricyclodecenyl alcohol in place of other crosslinking agents for crosslinking the soft component of impact-resistant polystyrene based on a polystyrene-grafted poly(alkyl acrylate) improves the flow of mixtures of the said polystyrene with polyphenylene ethers.
    Type: Grant
    Filed: January 6, 1982
    Date of Patent: April 3, 1984
    Assignee: BASF Aktiengesellschaft
    Inventors: Franz Brandstetter, Juergen Hambrecht, Adolf Echte
  • Patent number: 4440905
    Abstract: Improved impact modifier composition comprising elastomeric impact modifier polymer and dunkelsperser in a weight ratio of about 99.5/0.5 to 96/4 which is subject to substantially reduced gel formation in rigid thermoplastic matrix polymer formulations. Also disclosed are such formulations, as well as processes for preparing the improved impact modifier compositions.
    Type: Grant
    Filed: August 13, 1981
    Date of Patent: April 3, 1984
    Assignee: Rohm and Haas Company
    Inventor: David L. Dunkelberger