Patents Examined by John Boyd
  • Patent number: 5206215
    Abstract: A process for obtaining precursors for high critical temperature superconductor ceramics by precipitating salts which are insoluble in water comprises the following stages: A starting solution of soluble salts is prepared in which the cations are in the stoichiometric proportions of the required superconductor phase. A first full precipitation is carried out of a first series of cations at a first value of pH. The first precipitates obtained is filtered out and washed and the filtrate is retained. The pH of the filtrate is changed to a second value and the residual cations are precipitated. The second precipitate is filtered. The first and second precipitates are homogenized. The product obtained is dried, calcined, and ground.
    Type: Grant
    Filed: March 13, 1992
    Date of Patent: April 27, 1993
    Assignee: Alcatel Alsthom Compagnie Generale d'Electricite
    Inventors: Gerard Duperray, Francoise Ducatel
  • Patent number: 5204317
    Abstract: A method for making a high critical current density Bi.sub.2 CaSr.sub.2 Cu.sub.2 O.sub.8 superconductor includes mixing suitable solid state reactants in amounts sufficient to create a reactant mixture having a ratio of approximately 4 Bi atoms:3 Ca atoms:3 Sr atoms:4 Cu atoms and oxygen. The reactant mixture is heated to a sufficient temperature for a sufficient time to sinter the reactant mixture and form a Bi.sub.2 CaSr.sub.2 Cu.sub.2 O.sub.8 superconductor.
    Type: Grant
    Filed: July 29, 1991
    Date of Patent: April 20, 1993
    Assignee: United Technologies Corporation
    Inventors: Francis S. Galasso, David A. Condit
  • Patent number: 5194421
    Abstract: The present invention provides an oxide superconductor which is mainly composed of bismuth, lead, strontium, calcium, magnesium, and copper and has the composition represented by the formula:Bi.sub.1-A Pb.sub.A Sr.sub.1-B Mg.sub.B Ca.sub.1 Cu.sub.1.7.+-.0.3 Oxwherein A=0.15-0.35 and B=0.05-0.3 in which numerals represent atomic ratio and an oxide superconductor which is mainly composed of bismuth, lead, strontium, calcium, magnesium, barium and copper and has the composition represented by the formula:Bi.sub.1-A Pb.sub.A Sr.sub.1-(B+C) (Mg.sub.B Ba.sub.C)Ca.sub.1 Cu.sub.1.7.+-.0.3 Oxwherein A=0.15-0.35, B=0.05-0.3 and C=0.02-0.2 in which numerals represent atomic ratio. Methods for producing these superconductors are also provided.
    Type: Grant
    Filed: November 20, 1991
    Date of Patent: March 16, 1993
    Assignee: Hitachi Chemical Company
    Inventors: Shuichiro Shimoda, Toranosuke Ashizawa, Keiji Sumiya, Hideji Kuwajima, Minoru Ishihara, Shozo Yamana
  • Patent number: 5189009
    Abstract: A method of preparing a superconducting oxide by combining the metallic elements of the oxide to form an alloy, followed by oxidation of the alloy to form the oxide. Superconducting oxide-metal composites are prepared in which a noble metal phase intimately mixed with the oxide phase results in improved mechanical properties. The superconducting oxides and oxide-metal composites are provided in a variety of useful forms.
    Type: Grant
    Filed: April 30, 1992
    Date of Patent: February 23, 1993
    Assignee: Massachusetts Institute of Technology
    Inventors: Gregory J. Yurek, John B. VanderSande
  • Patent number: 5189011
    Abstract: A now superconducting material comprising a compound oxide represented by the general formula:(Sr,.gamma.).sub.x (La,.delta.).sub.1-x .epsilon..sub.y Cu.sub.1-y O.sub.3-zin which".gamma." represents an element of IIa group of the periodic table except Sr, an atomic ratio of .gamma. to Sr being selected in a range between 1% and 90%,".delta." represents an element of IIIa group of the periodic except La, an atomic ratio of .delta. to La is selected in a range between 1% and 90%,".epsilon." represents a metal element of Vb group of the periodic table, x, y and z are numbers each satisfies ranges of 0.ltoreq.x.ltoreq.1,0.ltoreq.y.ltoreq.1, and 0.ltoreq.z.ltoreq.1 respectively, and the expression of (Sr,.gamma.) and (La,.delta.) mean that the respective elements position predetermined sites in a crystal in a predetermined proportion.
    Type: Grant
    Filed: December 27, 1991
    Date of Patent: February 23, 1993
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Hideo Itozaki, Saburo Tanaka, Nobuhiko Fujita, Shuji Yazu, Tetsuji Jodai
  • Patent number: 5183799
    Abstract: Oxide materials of (L.sub.x A.sub.1-x).sub.i MO.sub.y, (L.sub.x A.sub.1-x).sub.i M.sub.1-z Cu.sub.z O.sub.y and (L.sub.x A.sub.1-x).sub.i MO.sub.j-.delta. G.sub.k, wherein L is Sc, Y, lanthanides, etc.; A is Ba, Sr. Ca, etc.; M is V, Nb, Ta, T, Zr or Hf; 0<x<1; 0<z<1; i=1, 3/2 or 2; 0<y.ltoreq.4; Gis F, Cl or N; .delta. is oxygen defect, and having a perovskite-like crystal structure, show superconductivity at a temperature higher than the liquid nitrogen temperature.
    Type: Grant
    Filed: July 10, 1991
    Date of Patent: February 2, 1993
    Assignee: Hitachi, Ltd.
    Inventors: Tetsuya Ogushi, Yoshinori Hakuraku, Hisanao Ogata
  • Patent number: 5174926
    Abstract: A piezoresistive pressure transducer employing a sapphire force collector diaphragm having piezoresistive films of silicon epitaxially formed on a major surface thereof, preferably in a Wheatstone bridge pattern. The silicon piezoresistive film is preferably of a thickness of from 1,000 to 60,000 angstroms and is doped with boron in the range of from 5.times.10.sup.17 to 9.times.10.sup.20 atoms/cc. Electrical lead traces and electrical contact pads are also formed on the major surface of the force collector diaphragm. The diaphragm is mounted on a pressure cell base having a cavity in the upper surface thereof, the diaphragm enclosing the cavity so as to form a chamber with the piezoresistive silicon films within said chamber. The diaphragm is hermetically bonded by a ceramic glass to the base in a vacuum such that the chamber provides a vacuum pressure reference.
    Type: Grant
    Filed: August 8, 1990
    Date of Patent: December 29, 1992
    Inventor: Armen N. Sahagen
  • Patent number: 5173476
    Abstract: A superconductor consisting of a sufficiently pure phase of the oxides of Bi, Sr, Ca, and Cu to exhibit a resistive zero near 110K resulting from the process of forming a mixture of Bi.sub.2 O.sub.3, SrCO.sub.3, CaCO.sub.3 and CuO into aparticulate compact wherein the atom ratios are Bi.sub.2, Sr.sub.1.2-2.2, Ca.sub.1.8-2.4, Cu.sub.3. Thereafter, heating the particulate compact rapidly in the presence of oxygen to an elevated temperature near the melting point of the oxides to form a sintered compact, and then maintaining the sintered compact at the elevated temperature for a prolonged period of time. The sintered compact is cooled and reground. Thereafter, the reground particulate material is compacted and heated in the presence of oxygen to an elevated temperature near the melting point of the oxide and maintained at the elevated temperature for a time sufficient to provide a sufficiently pure phase to exhibit a resistive zero near 110K.
    Type: Grant
    Filed: October 3, 1988
    Date of Patent: December 22, 1992
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Boyd W. Veal, John W. Downey, Daniel J. Lam, Arvydas P. Paulikas
  • Patent number: 5173475
    Abstract: A Bi-Pb-Sr-Ba-Ca-Cu-O system superconductor having a composition of:Bi.sub.l Pb.sub.m Sr.sub.p Ba.sub.q Ca.sub.y Cu.sub.z O.sub.xwherein l, m, p, q, y and z satisfy the following inequalities:0.50<l<1.500.01.ltoreq.m.ltoreq.0.600.70.ltoreq.p.ltoreq.1.600.005.ltoreq.q.ltoreq.0.800.70.ltoreq.y.ltoreq.1.601.40.ltoreq.z.ltoreq.3.00which has the critical temperature of at least 77 K, and contains the high T.sub.c phase in a high fraction.
    Type: Grant
    Filed: June 29, 1989
    Date of Patent: December 22, 1992
    Assignees: Kabushiki Kaisha Kobe Seiko Sho, NEC Corporation, Osaka Cement Co., Ltd., Seisan Kaihatsu Kagaku Kenkyusho, Toda Kogyo Corp., Tosoh Corporation
    Inventors: Toshio Takada, Mikio Takano, Yoshinari Miura, Jun Takada, Kiichi Oda, Naoichi Yamamoto
  • Patent number: 5164362
    Abstract: A high temperature superconductor having the formula Tl-Sr-Ca-Cu-O and a transition temperature about 70 K (with some evidence of a 100 K phase) is provided. Processes for making high temperature superconductors are also provided.
    Type: Grant
    Filed: September 29, 1988
    Date of Patent: November 17, 1992
    Assignee: University of Arkansas
    Inventors: Allen M. Hermann, Zhengzhi Sheng
  • Patent number: 5151407
    Abstract: Bulk form of superconducting materials are produced by pouring a melt a O.sub.2 -containing superconducting material into a heated mold, cooling the mold until solidification begins, removing the cast object from the mold, gradually cooling the cast object to prevent the development of thermal stresses, and then annealing the cast, cooled object to restore O.sub.2 to near equilibrium levels. The bulk form produced according to the present invention may be used as a sputtering target in the production of wires, or as a bulk form semiconductor.
    Type: Grant
    Filed: February 28, 1990
    Date of Patent: September 29, 1992
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Virgil Provenzano, Anand K. Singh, M. A. Imam, Kuntimadi Sadananda, William F. Henshaw
  • Patent number: 5151409
    Abstract: A superconducting oxide composition comprising Ln-Th-Cu-O wherein Ln indicates at least one element selected from a group consisting of Pr, Nd, Pm, Sm, Eu, Gd and Er. A superconducting structure is formed in such a manner that at least an insulating layer is sandwiched between two superconductor layers but the superconductor layers are electrically coupled with each other, and a superconducting device including the superconducting structure is constructed so as to perform a switching operation for an electric signal, to detect a light signal, and to detect the intensity of a magnetic field. Another superconducting device is formed so that two superconductor layers are put in direct contact with each other, and a tunnel current between the superconductor layers can be controlled.
    Type: Grant
    Filed: January 24, 1990
    Date of Patent: September 29, 1992
    Assignee: Hitachi, Ltd.
    Inventors: Masahiko Hiratani, Shin'ichiro Saitoh, Katsuki Miyauchi, Tsuyoshi Seko
  • Patent number: 5149684
    Abstract: A process for preparing a superconductor-coated substrate including calcining a mixture of powdered yttrium or rare earth oxide (R), barium carbonate and copper oxide in a controlled atmosphere and in accordance with a predetermined temperature profile to form a superconductor powder having a stoichiometric ratio of R-Ba-Cu of approximately 1-2-3. The melting transition width of the resulting powder is relatively narrow, such that the melting onset temperature is above the high temperatures advantageously used to sinter the powder on the substrate.
    Type: Grant
    Filed: April 9, 1991
    Date of Patent: September 22, 1992
    Assignee: General Atomics
    Inventors: Lawrence D. Woolf, Frederick H. Elsner, Clyde H. Shearer
  • Patent number: 5149687
    Abstract: An oriented superconducting material may be made by cold pressing a nonoriented superconducting material selected from the group consisting of Bi.sub.1, Bi.sub.2, Tl.sub.1, Tl.sub.2, Pb substituted Bi.sub.1, Pb substituted Bi.sub.2, Pb substituted Tl.sub.1, and Pb substituted Tl.sub.2 superconductor materials at a pressure sufficient to form an oriented superconducting material.
    Type: Grant
    Filed: April 1, 1991
    Date of Patent: September 22, 1992
    Assignee: United Technologies Corporation
    Inventor: Francis S. Galasso
  • Patent number: 5145834
    Abstract: A new high temperature superconducting system with transition temperature above 120 K is disclosed. One superconductor in that system in a preferred embodiment comprises TlRBaCuO wherein R is chosen from Group 2A elements excluding Ba. In a preferred embodiment, the superconductor is TlCaBaCuO. In another preferred embodiment, the superconductor comprises TlSrCuO. Processes for making high temperature superconducting system are also disclosed.
    Type: Grant
    Filed: August 26, 1991
    Date of Patent: September 8, 1992
    Assignee: University of Arkansas
    Inventors: Allen M. Hermann, Zhengzhi Sheng
  • Patent number: 5143895
    Abstract: The disclosed superconducting oxide material has a crystal structure of either Nd.sub.2 CuO.sub.4 type or oxygen-deficient perovskite type and mainly consists of a composition having a general chemical formula of (R.sub.1-x A.sub.x).sub.m+1 Cu.sub.m O.sub.3m+1-y, R being at least one rare earth element selected from the group consisting of Pr, Nd, Sm, Eu, Gd, Dy, Tb, Ho, Er, Tm, Yb, and Lu, A being Ce or Th, m being an integer of 1, 2, 3, . . . .infin. (m=.infin. standing for (R.sub.1-x A.sub.x)CuO.sub.3-y), 0.ltoreq.x.ltoreq.1, 0.ltoreq.y.ltoreq.m, Cu in the material having an average valence of not larger than +2 for all R, A, m, x, and y.The disclosed superconducting oxide material may have a general chemical formula of Nd.sub.2-x-z Ce.sub.x Sr.sub.z CuO.sub.4-y, 0.ltoreq.x.ltoreq.1, 0.ltoreq.y.ltoreq.1, and 0.ltoreq.z.ltoreq.1.The above superconducting oxide material can be made by mixing powdery starting materials for the composition, sintering the mixture at 1,000.degree. to 1,100.degree. C.
    Type: Grant
    Filed: January 25, 1990
    Date of Patent: September 1, 1992
    Assignee: The University of Tokyo
    Inventors: Shinichi Uchida, Yoshinori Tokura, Hidenori Takagi
  • Patent number: 5140002
    Abstract: The disclosed substance has a general chemical formula of Y.sub.3-x --Ba.sub.x Cu.sub.y --O.sub.z, x being 0 to 1, y being 3 to 6, and z being 6 to 12. At a temperature below 90.degree.-95.degree. K., the disclosed substance shows superconductive photoconductivity or even both superconductivity, either real or potential, and photoconductivity in response to incident exciting light in a wavelength range of 420 to 640 nm. The substance is produced by heating a mixture of starting material therefor at 750.degree.-1,050.degree. C. for 1-10 hours so as to cause solid phase reaction, cooling gradually, shaping under pressure, sintering at 670.degree.-1,050.degree. C., and cooling either quickly at a rate of 2,000.degree.-900.degree. C./sec or slowly at a rate of 150.degree.-200.degree. C./hour.
    Type: Grant
    Filed: May 3, 1991
    Date of Patent: August 18, 1992
    Assignee: The University of Tokyo
    Inventor: Taizo Masumi
  • Patent number: 5126316
    Abstract: Compositions having the nominal formula Bi.sub.2 Sr.sub.3-x Y.sub.x Cu.sub.2 O.sub.8+y wherein x is from about 0.05 to about 0.45 and y is from about 0 to about 1 are superconducting.
    Type: Grant
    Filed: August 24, 1988
    Date of Patent: June 30, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Arthur W. Sleight, Munirpallam A. Subramanian
  • Patent number: 5122503
    Abstract: The present invention relates to a superconducting material that is, substances having compositions expressed by empirical formulae Y.sub.1-x Ba.sub.x CuO.sub.3, YBa.sub.2 Cu.sub.3 O.sub.7 and LnBa.sub.2 Cu.sub.3 O.sub.7 and critical temperatures of 90 K. or more, and to a method of producing the same in which for example Y.sub.2 O.sub.3, BaCO.sub.3 and CuO are blended at a mixture molar ratio of 1:2:6 and the resulting mixture is molded under pressure followed by slowly cooling in an oxidizing atmosphere.
    Type: Grant
    Filed: April 9, 1991
    Date of Patent: June 16, 1992
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Masaru Yamano, Atsuo Mizukami, Masao Nakao, Shingo Terakado, Ryohkan Yuasa, Masaaki Nemoto, Hiromi Mukaida, Kazuaki Shikiti
  • Patent number: 5120365
    Abstract: A new pigment mixture consisting of 40-80% by weight calcium carbonate and/or dolomite and 20-60% by weight talc or 20-60% of a talc-kaolin mixture or 20-60% by weight of a talc-mica mixture gives substantial improvements in the use in the paper industry, in particular in the production of lightweight coated rotogravure papers.
    Type: Grant
    Filed: October 25, 1990
    Date of Patent: June 9, 1992
    Assignee: Pluss-Staufer AG
    Inventor: Werner Kogler