Abstract: Nitration of aromatics wherein gasified aromatic compounds and nitric acid are contacted with a silicon-aluminum catalyst.

Abstract: A method for producing fluoronitrobenzene compounds by reacting chloronitrobenzene compounds with a fluoride salt in the presence of a quaternary ammonium salt phase-transfer catalyst, wherein the catalyst is added to the reaction mixture incrementally during the course of the reaction. The incremental addition of catalyst allows the use of elevated reaction temperatures which, although sometimes causing catalyst inactivation, result in yields and reaction rates which are improved over those of methods involving a single catalyst addition.

Abstract: Aromatic hydrocarbons are nitrated by reacting the aromatic hydrocarbon in a nitrogen tetroxide-containing liquid reaction medium, in the presence of a beta-dicarbonyl compound having a "W" configuration with a carbonyl group at each apex of the "W", such as a metal acetylacetonate, preferably at a pressure and temperature sufficient to maintain the nitrogen tetroxide in the liquid state. Addition of an inert organic co-solvent to the liquid nitrogen tetroxide for the metal acetylacetonate promoted nitration of benzene essentially eliminates the production of dinitrobenzenes.

Abstract: Process for producing a joint between two metal wires for use in the construction of thermocouples or neutron flux probes or sensors having a small external diameter is disclosed.A stack is formed from two wires placed end to end and having an interface. This stack is placed in a tube which is sealed at both ends. The tube is made from a material, whose thermal expansion coefficient is well below that of the two wires. Spacers or shims are placed between the free ends of both wires. The assembly is exposed to a temperature such that the two contacting ends of the wires are welded under the action of the difference in the elongations of the tube and the wires.

Abstract: Aromatic compounds are nitrated in the vapor phase via a process comprising contacting the aromatic compound with a nitrating agent in the presence of a nitration promotion catalyst which comprises the adduct of:(a) an alumina-silica-metal oxide combination represented by the formula:(Al.sub.2 O.sub.3).sub.a (SiO.sub.2).sub.b (M.sub.2/n O).sub.cwherein M is a metal cation selected from the group consisting of the lanthanides or rare earths, Groups 1b, 2b, 5b, 6b, 7b, and 8 of the Periodic Table of the Elements, and mixtures thereof, and a, b, and c represent weight percent of the Al.sub.2 O.sub.3, SiO.sub.2, and M.sub.2/n O components, respectively, in the alumina-silica-metal oxide combination, with a being 0 to 100, b being 0 to 100, and c being 0 to 50, and n represents an integer from 1 to 7 of the valence of the metal cation, with the proviso that the sum of (a+b) must be greater than 0, and(b) a catalytically effective amount of sulfur trioxide.

Abstract: This invention relates to a new manner of carrying out chemical reactions by injection of selected forms of energy into the reaction zone by novel means. By applying this principal, many new processes result with application in a large number of different industries. The new process is generally capable of operation at room temperatures, which has advantages in the creation of certain sensitive products including uniformly doped semi-conductors, new catalysts, pure gases, high purity materials of any kind, controlled coatings, new polymers, combustion enhancement, difficult separation, petroleum refinery operations, and carrying out any reaction in which the injection of specific energy types is helpful.

Abstract: A thermal sensor for detecting temperature distribution in a deposit layer on the refractory walls of a blast furnace or the like, including a temperature probe assembly having temperature sensing areas at different points along the length thereof, an outer protective casing for accommodating the probe assembly, a number of annular fin members fitted on the temperature sensing areas of the probe assembly and secured to the outer protective casing, and an insulating material filled between the outer protective casing and the probe assembly for thermally insulating the fine members from each other.

Abstract: The present invention relates to a cartridge primer seating tool which combines a seating tool with a primer feed system and includes a housing provided with a shell holder, in combination with primer stem for loading a primer into a shell and a primer dispenser for placing a primer in the primer stem communicating with a cam drive mounted in the housing.

Abstract: A process for the preparation of nitro-olefins comprising reacting a compound of the formula ##STR1## where R and R.sup.1 can be hydrogen, alkyl of 1-20 carbon atoms or phenyl, with an aldehyde acceptor selected from the group consisting of alkylene polyols or aromatic polyols, in the presence of an alkaline catalyst or a Lewis acid catalyst.

Abstract: An ozonizer formed of an interior electrode in the form of an electrically conducting tube arranged concentrically in an electrically insulating tube and spaced at a distance radially therefrom to form a discharge channel. The electrically insulating tube has an exterior surface on which are provided at least two parallel electrically conducting sleeves, which are separated axially relative to one another and surrounding the insulating tube to form the exterior electrode of the ozonizer. Each sleeve is connected respectively by way of a switching element to an energy supply device. The electrically conducting tube is also connected to the energy supply device.

Abstract: Disclosed is a method for increasing the burning rate of solid propellants hich contain metal staples and/or metal flakes, etc., through the use of an electrical field effect created by the application of direct-current to a propellant grain placed between direct-current electrodes. This method also provides a means of correcting for anisotropy of burning rate in propellants which contain metal staples, metal flakes, etc., where non-random orientation may occur at the motor wall and mandrel surface.

Abstract: A multipoint thermocouple assembly for monitoring temperatures at various locations in a utilization environment includes an elongate thermocouple support strap insertable lengthwise into a protective hollow well or the like. Mounted on the support strap are a plurality of thermocouples which are generally held against longitudinal movement relative to the support strap but the respective measuring junctions thereof are supported by respective camming members connected to a common cable for simultaneous longitudinal movement of the camming members relative to the support strap for urging the measuring junctions outwardly into thermally conductive engagement with respective wall portions of the well. The support strap and actuation cable are laterally flexible so that the assembly may be coiled for ease in fabrication, installation and shipping.

Abstract: A process and apparatus for solidifying radioactive waste liquid containing dissolved and/or suspended solids is disclosed. The process includes chemically treating for pH adjustement and precipitation of solids, concentrating solids with a thin-film evaporator to provide liquid concentrate containing about 50% solids, and drying the concentrate with heated mixing apparatus. The heated mixing apparatus includes a heated wall and working means for shearing dried concentrate from internal surfaces and subdividing dry concentrate into dry, powdery particles. The working means includes a rotor and helical means for positively advancing the concentrate and resulting dry particles from inlet to outlet of the mixing apparatus. The dry particles may also be encapsulated in a matrix material. Entrained particles in the vapor stream from the evaporator and mixer are removed in an integral particle separator and the vapor is subsequently condensed and may be recycled upstream of the thin-film evaporator.

Abstract: A method for co-conversion of aqueous solutions of one or more heavy metal nitrates wherein thermal decomposition within a temperature range of about 300.degree. to 800.degree. C. is carried out in the presence of about 50 to 500% molar concentration of ammonium nitrate to total metal.

Abstract: A gas generating propellant charge which is made by piling explosive powder sheets having a plurality of projections on at least one surface thereof so as to make contact them with each other is excellent in firing characteristics, and the explosive powders in the gas generating propellant charge can be burnt in a short time, thereby generating a large amount of gas.

Abstract: In a light valve, comprising a cell containing a suspension of particles in a liquid suspending medium, the improvement wherein said light valve suspension comprises particles of a perhalide of an alkaloid acid salt or a light-polarizing metal halide or perhalide suspended in said liquid suspending medium and a protective polymer effective to inhibit agglomeration of said particles dissolved in said liquid suspending medium, said liquid suspending medium comprising an electrically resistive, inert, low molecular weight, liquid fluorocarbon polymer having a specific gravity at room temperature of at least about 1.5 and having at least about 50% of its atoms constituted by halogen atoms, at least 60% of said halogen atoms being fluorine and the balance chlorine and/or bromine, and an electrically resistive organic liquid miscible with the fluorocarbon liquid, said fluid suspending medium being operable to suspend said particles in substantial gravitational equilibrium.

Abstract: A thermocouple cable reinforced with high strength, low creep fatigue resistant aramid fibers. The aramid fibers are pultruded over a central core of thermocouple wires. A water impervious, abrasion resistant, strippable cover is extruded over the fibers and wires to hold them firmly in place.

Abstract: Fire extinguishant composition comprising a mixture of a finely divided aluminum compound and alkali metal, stannous or plumbous halide. Aluminum compound may be aluminum hydroxide, alumina or boehmite but preferably it is an alkali metal dawsonite. The metal halide may be an alkali metal, e.g. potassium iodide, bromide or chloride or stannous or plumbous iodide, bromide or chloride. Potassium iodide is preferred.

Abstract: Novel tetraazido polyesters comprising compounds of the following generic formula ##STR1## and methods of preparation of these polyesters.

Abstract: A radioactive .sup.57 Co source consists of the intermetallic composition CoSb.sub.3 which emits an energetically non-disintegrated 14.4 KeV line. This composition is strictly stoichiometrical and may be dissolved in excess Sb. The atom percent proportion of .sup.57 Co may be up to 25%.