Abstract: A composite cement material is prepared from cement material and carbon nanotubes, wherein the carbon nanotubes are present from about 0.02 wt % to about 0.10 wt % based on weight of cement material. The process for preparing such cement compositions includes sonicating a mixture of a surfactant, water, and carbon nanotubes; and blending the dispersion and the cement material to form a cementitious paste. The process may also include curing the cementitious paste. The composite cement materials are useful in a variety of cement applications where a reduction in nanoscale flaws and fractures is desired.
Type:
Grant
Filed:
February 6, 2009
Date of Patent:
June 14, 2016
Assignee:
Northwestern University
Inventors:
Surendra P. Shah, Maria S. Konsta-Gdoutos, Zoi S. Metaxa
Abstract: A dry, free-flowing cement composition that comprises dry cement particles and flow inducing particulates that comprise solid adsorbent particulates having adsorbed thereon a flow inducing chemical, ethylene glycol, and water. The water is present in an amount from 5% to 30.3% by weight of the solid adsorbent particulates, the ethylene glycol is present in an amount from 3.25 to 20% by weight of the solid adsorbent particulates, and the flow inducing particulate is present in an amount from 0.005% to 5% by weight of the cement. The dry, free-flowing cement composition is free-flowing at temperatures at least as low as 10° F.
Type:
Grant
Filed:
June 24, 2015
Date of Patent:
June 7, 2016
Assignee:
Halliburton Energy Services, Inc.
Inventors:
Sam Lewis, Rita McKinley, Russell Fitzgerald
Abstract: A wellbore cement composition includes substantially unhydrated cement powder and additive powder for cement. The additive powder is formulated from ingredients including a liquid additive for cement and solid carrier particles. The liquid additive is absorbed by the solid carrier particles. A wellbore cementing method includes using a dry cement composition, adding water to the dry cement composition, forming a cement slurry, placing the slurry in a wellbore, and setting the placed slurry. The dry cement composition contains substantially unhydrated cement powder and retarder powder for cement. The retarder powder contains a retarder absorbed by solid carrier particles.
Type:
Grant
Filed:
November 12, 2013
Date of Patent:
June 7, 2016
Assignee:
BAKER HUGHES INCORPORATED
Inventors:
Mark A. Vorderbruggen, Guido G. Narvaez, Diana Cardona, Dong Shen
Abstract: A shrinkage compensating concrete does not require restraint. The expansive forces developed during hydration compensate for concrete shrinkage, obviating the need for any added internal or external restraint element. Using this new shrinkage compensating concrete, substantially crack-free slabs may be built without using restraining steel bars, fibers, or other separate restraining element. The shrinkage compensating concrete includes a cement that develops internal expansive forces that never exceed the tensile strength of the concrete, such that the internal expansion compensates for the concrete shrinkage. The expansive cement may be an ASTMS, M or S cement, or other expansive cements may also be used.
Abstract: A dry mortar mixture based on at least one hydraulic and/or latently hydraulic binder which in the made-up and not yet cured state has firm properties is claimed. The novel dry mortar mixture is characterized in that it contains at least one representative of a dispersant and at least one compound having superabsorbent properties. This mixture makes it possible to carry over the advantages of known tile adhesives for horizontal application to vertical application possibilities.
Type:
Grant
Filed:
October 28, 2010
Date of Patent:
May 31, 2016
Assignee:
BASF CONSTRUCTION POLYMERS GmbH
Inventors:
Michael Eberwein, Christian Trieflinger, Michael Schinabeck, Jutta Karin Langlotz, Stefan Friedrich, Gregor Herth
Abstract: Light to ultra-light cement compositions with modified rheological properties. The cement composition includes cement, hydrophobic nano-silica, at least one additive and a sufficient amount of water to make a cement slurry with high compressive strength, low porosity, low free water, and low fluid loss with a quick thickening time.
Type:
Grant
Filed:
August 6, 2014
Date of Patent:
May 31, 2016
Assignee:
RESEARCH INSTITUTE OF PETROLEUM INDUSTRY
Inventors:
Hamid Soltanian, Ali Reza Mortazavi, Mohammad Javad Modjtahedi, Mahmoud Reza Badamaki, Ali Mesbah, Ali Reza Khoshniyat, Mohammad Reza Kamali
Abstract: The presently disclosed and claimed inventive concept(s) relates generally to a hydraulic composition with a prolonged open time. More particularly, the composition comprises at least one cement retarder and at least one accelerator. The presently disclosed and claimed inventive concept(s) further relates to a dry mortar composition comprising the hydraulic composition having prolonged open time without deterioration of the other cement tile adhesive properties such as workability, setting time, strength development and sag resistance.
Type:
Grant
Filed:
March 13, 2014
Date of Patent:
May 31, 2016
Assignee:
Hercules Incorporated
Inventors:
Wilfried Adolf Hohn, Stefan Hucko, Alexander Adolphe Kindler, Vera Louise Nilles, Martin Wunderlich
Abstract: An oil well cementing product comprising DTPA-coated synthetic calcined gypsum, at least one accelerator, at least one retarder, at least one plasticizer and limestone is provided. Also provided are methods for cementing oil wells with mixtures comprising DTPA-coated synthetic calcined gypsum, at least one accelerator, at least one retarder, at least one plasticizer and limestone.
Type:
Grant
Filed:
February 17, 2015
Date of Patent:
May 24, 2016
Assignee:
UNITED STATES GYPSUM COMPANY
Inventors:
Dennis Mark Lettkeman, John Wesley Wilson, Doug Blackburn, Brian K. Ball, Raymond A. Kaligian, Mike L. Cloud
Abstract: The process using multiple waste streams to manufacture synthetic lightweight aggregate includes providing a mixture of aggregate wash and at least one of another waste stream, such as waste lube oil or sewage sludge. The mixture is formed into pellets and subjected to various firing stages and temperatures in which the calcination and subsequent bloating occurs. The mixture can also be added to natural clays to form corresponding pellets. The bloating promotes formation of porous cavities, and once cooled, the pellets form lightweight, low density synthetic aggregates suitable for use as building materials, thermal insulators, and the like.
Type:
Grant
Filed:
August 20, 2014
Date of Patent:
May 17, 2016
Assignee:
KUWAIT INSTITUTE FOR SCIENTIFIC RESEARCH
Inventors:
Suad Al-Bahar, Saud Al-Otaibi, Sharifa Al-Fadala, Ali Abduljaleel, Mahmoud Fawzy Taha, Fatma Al-Fahad, Amer Al-Arbeid, Tarun K. Mukherjee
Abstract: Compositions and methods for increasing grinding efficiency of cement, cement clinker, raw materials for cement, and other inorganic particles. Use of biomass-derived polyols such as diols, triols, or mixtures thereof, optionally with a conventional grinding aid, cement quality improver, and/or hexavalent chromium reducer, are believed to provide less risk of sludging when compared to glycerides obtained from fossil fuel sources.
Type:
Grant
Filed:
March 16, 2015
Date of Patent:
May 3, 2016
Assignee:
GCP Applied Technologies Inc.
Inventors:
Leslie A. Jardine, Charlotte Porteneuve, Gerard Blond
Abstract: A method for making a low-alkali fly ash cement includes forming a mixture of class C fly ash and an aqueous solution and forming low-alkali fly ash cement from the mixture. The aqueous solution has an alkali at a molar concentration between about 0.002 M and about 2 M. A low-alkali fly ash cement includes class C fly ash and an alkali activating agent. The low-alkali fly ash cement contains between about 3×10?4 wt % alkali activating agent and about 2 wt % alkali activating agent. A method for making fly ash cement includes forming a mixture of class C fly ash and water, wet pressing the mixture and forming fly ash cement from the mixture by curing the mixture at a temperature between about 60° C. and about 90° C.
Abstract: This invention relates to using a unique blend of components of a composite cement and subjecting them to a rotary mill process using variably sized and shaped media to reduce the blends' particle size. The invention is novel in that it mills the blended materials together to achieve reduced particle size, increased particle surface area, higher compressive strength and lower permeability. In one embodiment, the invention combines fly ash or other pozzolan material with a cement of any type at varying rations between 1% and 99%.
Abstract: A method for making geopolymer cementitious binder compositions for cementitious products such as concrete, precast construction elements and panels, mortar and repair materials, and the like is disclosed. The geopolymer cementitious compositions of some embodiments are made by mixing a synergistic mixture of thermally activated aluminosilicate mineral, calcium aluminate cement, a calcium sulfate and a chemical activator with water.
Abstract: Compositions are disclosed that comprise at least one compound of formula IV: wherein the variable are as defined in the specification. The compositions are antimicrobial and optionally curable, and useful, inter alia, in dental, medical, and industrial applications for reinforcement and/or adhering two surfaces together.
Type:
Grant
Filed:
August 24, 2012
Date of Patent:
April 19, 2016
Assignee:
KIMMERLING HOLDINGS GROUP, LLC
Inventors:
John D. Blizzard, Kirk Kimmerling, Joseph P. Rapp
Abstract: Perfumed stones adapted to store perfume so as to release the smell over an extended period, and a method of manufacture of perfumed stones, is disclosed. The stones find particular suitability in perfumed jewelry.
Type:
Grant
Filed:
April 7, 2014
Date of Patent:
April 19, 2016
Inventors:
Renee Susan Van Veen, Jean Pierre Goedermans
Abstract: A method for forming a composite structure, using a mandrel that is later removed from the composite structure, involves production of a mandrel by depositing a particulate mixture, including an aggregate and a binder, into a mold and removing the mandrel from the mold. The mandrel may be treated while still in the mold by heating, curing with an agent, microwave energy, or by some combination thereof. Once finished, the mandrel can be used in manufacturing polymer and/or composite components. The mandrel can also include materials that can be easily removed from the finished composite structure by water, shakeout, chemically dissolving, or by some combination thereof. The mandrel can be a self-expanding mandrel, and can be used in a process or system for the manufacture of composite structures.
Abstract: In one aspect, methods of storing one or more combustion waste products are described herein. Combustion waste products stored by a method described herein can include solid combustion waste products such as coal ash and/or gaseous combustion products such as carbon dioxide. In some embodiments, a method of storing carbon dioxide comprises providing a carbon dioxide storage medium comprising porous concrete having a macroporous and microporous pore structure and flowing carbon dioxide captured from a combustion flue gas source into the pore structure of the porous concrete.
Type:
Grant
Filed:
August 30, 2013
Date of Patent:
April 12, 2016
Assignees:
China University of Mining & Technology, University of North Carolina at Charlotte
Abstract: A particulate material for the production of a cement foam which material includes particles including, attached to the particle surface, a surfactant which renders the particles hydrophilic, the surfactant including a moiety which is hydrolysable under alkaline conditions, which surfactant, after loss of the moiety by alkaline hydrolysis, renders the particles partially hydrophobic.
Abstract: A thickened composition comprising a polymer, a divalent ions source, water and cement is disclosed. Such composition enables fluid loss reduction and higher gel strength. This may be useful for treating a well for example as a fluid spacer or a scavenger; this may also be used a hydraulic fracturing fluid.
Abstract: A construction material mixture used as a concrete additive contains a puzzolanic substrate and a photocatalyst. The puzzolanic substrate and the photocatalyst are available in the form of a dry mixture. The construction material mixture is a cement free dry mixture, wherein the photocatalyst has a primary particle size of between 2 nm and 100 nm. The puzzolanic substrate consists of at least 90 weight % of fly ash with a grain size of between 0.1 ?m and 1 mm. The substrate and the photocatalyst are available completely mixed so that the photocatalyst is at least partially distributed on the surface of the substrate.
Type:
Grant
Filed:
November 15, 2012
Date of Patent:
March 29, 2016
Assignees:
Steag Power Minerals GmbH, Kronos International, Inc.
Inventors:
Werner Krohm, Jürgen Bender, Christian Scheidt