Abstract: The present invention provides a superhard film-coated member having a diamond or diamond-like carbon film strongly bonded to a cemented carbide substrate and a method of manufacturing such a member. The cemented carbide substrate is subjected to heat treatment to cause the bonding metal in a region of the substrate near to its surface to migrate to the surface so as to form hemispherical deposits thereon. The deposits are left undisturbed or a part or all thereof are removed, and subsequently diamond and/or diamond-like carbon is grown on the substrate surface by a chemical vapor deposition process. The deposits formed on the substrate surface have the effect of significantly improving the bonding strength between the superhard films and the cemented carbide substrate to allow formation of thicker film coatings.

Abstract: A methacrylic resin composition with improved tacky adhesion comprising 100 parts by weight of a partially cross-linked polymer gel obtained by partially polymerizing a mixture comprising (A) 40 to 99% by weight of unsaturated monomer mixtures with or without containing the polymers thereof dissolved and (B) 60 to 1% by weight of a cross-linking agent, thereby allowing the total polymer content to be kept not exceeding 80% by weight, and increased by 4 to 62% by weight over the polymer content of said mixture, and 1 to 100 parts by weight of a syrup mainly composed of alkyl methacrylates containing the polymers thereof dissolved.

Abstract: A sintered diamond compact or high pressure form boron nitride compact with an improved brazability, suitable for use for wear resisting tools, cutting tools, drill bits, dressers and wire-drawing dies is provided. This compact comprises a compact part containing at least 20% by volume of diamond and/or high pressure form boron nitride and a cemented carbide substrate bonded directly or through an interlayer to the compact part, characterized in that the surface of the compact is coated, at least partly, with a thin film consisting essentially of at least one member selected from the group consisting of carbides, carbonitrides and nitrides and mixtures or solid solutions thereof of at least one element selected from the group consisting of silicon and Group IVa, Va and VIa of Periodic Table, and having a thickness of 1 to 20 .mu.m.

Abstract: A composite tool with a higher bonding strength and higher heat resistance is provided comprising an insert of a hard material such as composite diamond or BN compacts and a support of a hard metal or alloy such as steel and cemented carbides, having a larger volume than the insert, the insert and support being bonded by friction welding through an interlayer of a high strength metal or alloy such as Co and Ni with a thickness of at most 1 mm.

Abstract: A composite tool with a higher bonding strength and higher heat resistance is provided comprising an insert of a hard material such as composite diamond or BN compacts and a support of a hard metal or alloy such as steel and cemented carbides, having a larger volume than the insert, the insert and support being bonded by friction welding through an interlayer of a high strength metal or alloy such as Co and Ni with a thickness of at most 1 mm.

Abstract: A stick of composite materials comprises a hot-pressed super-hard head member containing higher than 50 vol % of a diamond powder and/or a high pressure boron nitride powder, and a supporting member which is bonded at one of its ends with the hot-pressed super-hard head member. The stick of composite materials is characterized in that:the bonding between the head member and the supporting member is formed during the hot press process of the head member;the stick is of an elongated form, preferably of a cylindrical form of which the sectional diameter or equivalent sectional diameter is not larger than 3 mm;the length of the head member is 0.3 to 2.0 mm in the axial direction of the stick; and thatthe supporting member is more than five times longer in its axial direction than the head member.The stick of composite materials is usable as a blank for the microdrill, micropunch and the head of the dot character printer.

Abstract: A composite sintered material suitably used as a material for a drill has a sandwich structure comprising a hard layer of a sintered diamond compact including an iron group metal sandwiched between a pair of substrates and intermediate layers. The pair of intermediate layers each has a thickness of 10 to 500 microns. The intermediate layers are bonded respectively to one of the opposite surfaces of the hard layer, with each of the intermediate layers comprising a material which has a thermal expansion coefficient of 3.0.times.10.sup.-6 to 6.0.times.10.sup.-6 /.degree.C. and which prevent the transfer of the iron group metal therethrough in the course of sintering of the hard material. The pair of substrates are bonded respectively to one of the surfaces of the intermediate layers to form a sandwich construction with the hard layer. The substrates comprise a metal or alloy having a thermal expansion coefficient lower than 6.0.times.10.sup.-6 /.degree.C.

Abstract: A process for producing a cutting tool having a rake face and flank face which intersect to form a cutting edge, which cutting tool comprises a substrate consisting of a sintered hard metal and a coating film provided thereon consisting of a material with a higher hardness than the substrate, which method involves subjecting the substrate to a coating treatment and honing treatment in such a manner that the coating film near the cutting edge has such a thickness that the thickness continuously increases in directions away from the cutting edge along both the rake face and the flank face from a minimum value, including zero, at the cutting edge, such that the thickness of the coating at the rake face reaches a maximum thickness at a first distance from the cutting edge and the thickness at the flank face reaches a maximum thickness at a second distance from the cutting edge, wherein the first distance is greater than the second distance.

Abstract: A cutting insert having excellent toughness as well as wear resistance is provided comprising a substrate consisting of a sintered hard metal or alloy such as cemented carbides and a coating film provided thereon consisting of a material having a higher hardness than the substrate, characterized in that the coating film near the cutting edge is continuously made thinner or removed toward both the rake face and flank face.

Abstract: This invention relates to a hard alloy comprising two phases: a hard phase consisting of at least one compound having a crystal structure of simple hexagonal MC type (M: metal; C: carbon) selected from the group consisting of mixed carbides, carbonitrides and carboxynitrides of molybdenum and tungsten, and a binder phase consisting of at least one element selected from the group consisting of iron, cobalt and nickel. The hard phase is prepared by carburizing an (Mo, W) alloy obtained by reducing oxides of molybdenum and tungsten with a particle size of at most 1 micron, is composed of coarse particles with a mean particle size of at least 3 microns, and has a uniform molybdenum to tungsten ratio in the particles. The hard alloy has a gross composition within the range of the shaded portion ABCDEA in FIG. 1.

Abstract: A method for producing a sintered ferrous alloy containing at least one alloying element whose standard free energy for oxide formation at 1,000.degree. C. is 11,000 cal/g mol O.sub.2 or less is described. The method comprises a sintering procedure comprising steps of elevating the temperature of a green compact comprising said at least one alloying element, sintering it in a sintering furnace and cooling it, wherein the pressure in the sintering furnace is maintained at between about 0.2 and 500 Torr by supplying a reducing gas during at least a part of the sintering procedure under reduced pressure.

Abstract: A method for detecting defective press punching, comprising steps of causing an electromagnetic sensor to approach a punched hole of a blank after products are punched by a press, and discriminating the quality of the punched products from the output level of the electromagnetic sensor that changes according to whether or not the circumference of the punched hole constitutes a closed loop electrically, and a device for performing the method.

Abstract: Process for the production of bonded hard alloys, which comprises inserting a thin sheet of a Fe group metal or its alloy as a filler in between the surfaces of at least one kind of hard alloy, and applying a high energy beam to a part or all of the thin sheet to melt and solidify the thin sheet in a slit form, thereby bonding the hard alloys together.

Abstract: The invention relates to a sintered body for use in a cutting tool comprising a cutting edge forming part having particularly high hardness and wear resistance bonded to a supporting member having high plastic deformability, stiffness, transverse rupture strength, thermal conductivity, thermal expansion coefficient, resistance to corrosion, oxidization and the like, and to a method for producing the same. A diamond powder or high pressure form boron nitride powder is placed in contact with preliminarily sintered cermet constituted by carbide crystals chiefly comprising molibdenum in the form of (Mo, W)C bonded by iron group metals, the combined body being sintered at a temperature and pressure under which the diamond powder or high pressure form boron nitride powder is thermodynamically stable so that the sintered body of the diamond or high pressure form boron nitride is bonded to the cermet thereby enabling to obtain a sintered body having the said high properties for use in a cutting tool.

Abstract: The invention relates to a diamond sintered compact wherein diamond crystal particles are uniformly orientated in a particular direction and the method for producing the same, and has for an object to provide a diamond sintered compact having a high thermal conductivity particularly suitable for heat sink for use in the field of electronics.According to the invention, graphite is used as carbonaceous raw material, diamond crystal particles having such elongated shape that the ratio of the length of the long axis to that of the short axis is more than 2 being synthesized in such state that the greater part of the crystal particles have their long axes uniformly oriented in a particular direction, the crystal particles being sintered in the direction of the long axes thereof so that transformation of the graphite into diamond and sintering thereof may be accomplished synchronously.

Abstract: The invention relates to a diamond sintered compact wherein diamond crystal particles are uniformly oriented in a particular direction and the method for producing the same, and has for an object to provide a diamond sintered compact having a high thermal conductivity particularly suitable for heat sink for use in the field of electronics.According to the invention, graphite is used as carbonaceous raw material, diamond crystal particles having such elongated shape that the ratio of the length of the long axis to that of the short axis is more than 2 being synthesized in such state that the greater part of the crystal particles have their long axes uniformly oriented in a particular direction, the crystal particles being sintered in the direction of the long axes thereof so that transformation of the graphite into diamond and sintering thereof may be accomplished synchronously.

Abstract: The invention enables to obtain a compound sintered compact for use in a cutting tool having particularly high properties in respect of bonded strength, hardness, wear resistance, plastic deformability and rigidity by bonding a diamond or cubic boron nitride containing hard layer to a cemented carbide substrate with interposition of an intermediate bonding layer.

Abstract: The invention relates to a sintered compact for use in an ultrahard tool having high resistance to heat and wear, outstanding thermal conductivity and thermal shock resistance property at elevated temperature, and suitable for high-speed cutting, and to a method for producing the same. A powder mixture comprising 20-80 volume % high pressure form boron nitride powder, the residual part consisting of Al.sub.2 O.sub.3 powder or a compound ceramic powder principally comprising Al.sub.2 O.sub.3 powder and also containing carbides, nitrides of IVb, Vb, VIb metals of the periodic table, mutual solid solution thereof or admixture thereof, is sintered as it stands or after pressing under a high pressure and a high temperature so that Al.sub.2 O.sub.3 of the compound ceramic constitutes a continuous phase in the structure of the sintered compact, and the half width of (116) in the X-ray diffraction of CuK.alpha. ray of Al.sub.2 O.sub.

Abstract: The present invention relates to a process for the production of a solid solution constructed of at least one hard phase having a crystal structure of simple hexagonal type and selected from mixed carbides or carbonitrides of molybdenum and tungsten, which process comprises preparing an alloy powder consisting of a solid solution of molybdenum and tungsten, adding to the alloy powder carbon in an amount necessary for forming (Mo, W).sub.2 C and/or (Mo, W).sub.2 (CN), heating the mixture at a temperature at which (Mo, W).sub.2 C and/or (Mo, W).sub.2 (CN) is stable, adding to the (Mo, W).sub.2 C and/or (Mo, W).sub.2 (CN) carbon in an amount necessary for forming (Mo, W)C and/or (Mo, W)(CN) optionally with an iron group metal and then heating the mixture at a temperature at which (Mo, W)C and/or (Mo, W)(CN) is stable.

Abstract: The present invention relates to a composite diamond compact for a wire drawing die, in which a part or all of the circumference of a diamond sintered body is surrounded by a cermet consisting of a hard compound of (Mo, W)C type carbide crystals containing molybdenum as a predominant component, bonded by an iron group metal, and the binder phase of the diamond sintered body contains an iron group metal and fine carbide crystals containing molybdenum as a predominant component.