Patents by Inventor Antonios K. Doufas
Antonios K. Doufas has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9322114Abstract: This invention relates to polypropylene fibers and fabrics containing polypropylene fibers, the fibers comprising propylene polymers comprising at least 50 mol % propylene, said polymers having: a) a melt flow rate (MFR, ASTM 1238, 230° C., 2.16 kg) of about 10 dg/min to about 25 dg/min; b) a dimensionless Stress Ratio/Loss Tangent Index R2 [defined by Eq. (8)] at 190° C. from about 1.5 to about 30; c) an onset temperature of crystallization under flow, Tc,rheol, (as determined by SAOS rheology, 190° C., 1° C./min, where said polymer has 0 wt % nucleating agent present), of at least about 123° C.; d) an average meso run length determined by 13C NMR of at least about 55 or higher; and e) optionally, a loss tangent, tan ?, [defined by Eq. (2)] at an angular frequency of 0.1 rad/s at 190° C. from about 14 to about 70.Type: GrantFiled: December 3, 2012Date of Patent: April 26, 2016Assignees: EXXONMOBIL CHEMICAL PATENTS INC., REIFENHAUSER GMBH & CO. KG MASCHINENFABRIKInventors: Jeanne Marie MacDonald, Antonios K. Doufas, Jerome Sarrazin, William Michael Ferry, Rahul Ravindra Kulkarni, Derek Wade Thurman, Cynthia Ann Mitchell, Detlef Frey, Peter Schlag, Hans-Georg Geus, Claudio Cinquemani
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Publication number: 20160053419Abstract: This invention relates to polypropylene fibers and fabrics containing polypropylene fibers, the fibers comprising propylene polymers comprising at least 50 mol % propylene, said polymers having: a) a melt flow rate (MFR, ASTM 1238, 230° C., 2.16 kg) of about 10 dg/min to about 25 dg/min; b) a dimensionless Stress Ratio/Loss Tangent Index R2 [defined by Eq. (8)] at 190° C. from about 1.5 to about 30; c) an onset temperature of crystallization under flow, Tc,rheol, (as determined by SAOS rheology, 190° C., 1° C./min, where said polymer has 0 wt % nucleating agent present), of at least about 123° C.; d) an average meso run length determined by 13C NMR of at least about 55 or higher; and e) optionally, a loss tangent, tan?, [defined by Eq. (2)] at an angular frequency of 0.1 rad/s at 190° C. from about 14 to about 70.Type: ApplicationFiled: September 2, 2015Publication date: February 25, 2016Inventors: Jeanne Marie MacDonald, Antonios K. DOUFAS, Jerome SARRAZIN, William Michael FERRY, Rahul Ravindra KULKARNI, Derek Wade THURMAN, Cynthia Ann MITCHELL, Detlef FREY, Peter SCHLAG, Hans-Georg GEUS, Claudio CINQUEMANI
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Publication number: 20150307699Abstract: This invention relates to propylene polymers comprising at least 50 mol % propylene, said polymers having: a) a melt flow rate (MFR, ASTM 1238, 230° C., 2.16 kg) of 10 dg/min to 25 dg/min; b) a Dimensionless Stress Ratio/Loss Tangent Index R2 at 190° C. from 1.5 to 28; c) an onset temperature of crystallization under flow, Tc,rheol (as determined by SAOS rheology, 190° C., 1° C./min, where said polymer has 0 wt % nucleating agent present), of at least 131° C.; d) an average meso run length determined by 13C NMR of at least 90 or higher; and e) optionally, a loss tangent, tan ?, (defined by Eq. (2)) at an angular frequency of 0.1 rad/s at 190° C. from 14 to 70.Type: ApplicationFiled: November 25, 2013Publication date: October 29, 2015Inventors: Jeanne Marie MACDONALD, Antonios K. DOUFAS, Jerome SARRAZIN, William Michael FERRY, Charles J. RUFF, Rahul Ravindra KULKARNI, Derek Wade THURMAN, Cynthia A. MITCHELL
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Publication number: 20140155854Abstract: This invention relates to polypropylene fibers and fabrics containing polypropylene fibers, the fibers comprising propylene polymers comprising at least 50 mol % propylene, said polymers having: a) a melt flow rate (MFR, ASTM 1238, 230° C., 2.16 kg) of about 10 dg/min to about 25 dg/min; b) a dimensionless Stress Ratio/Loss Tangent Index R2 [defined by Eq. (8)] at 190° C. from about 1.5 to about 30; c) an onset temperature of crystallization under flow, Tc,rheol, (as determined by SAOS rheology, 190° C., 1° C./min, where said polymer has 0 wt % nucleating agent present), of at least about 123° C.; d) an average meso run length determined by 13C NMR of at least about 55 or higher; and e) optionally, a loss tangent, tan ?, [defined by Eq. (2)] at an angular frequency of 0.1 rad/s at 190° C. from about 14 to about 70.Type: ApplicationFiled: December 3, 2012Publication date: June 5, 2014Applicants: ExxonMobil Chemical Patents Inc.Inventors: Jeanne Marie MacDonald, Antonios K. Doufas, Jerome Sarrazin, William Michael Ferry, Rahul Ravindra Kulkarni, Derek Wade Thurman, Cynthia Ann Mitchell, Detlef Frey, Peter Schlag, Hans-Georg Geus, Claudio Cinquemani
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Publication number: 20120157599Abstract: The present invention relates to a class of impact copolymer polypropylene (ICP) compositions exhibiting the advantageous combination of excellent tiger (flow) marking performance in large/long molded parts, very low gels count and exceptional mold flowability (high MFR) despite the high viscosity ratio (e.g., >4) between rubber and propylene based matrix phases. The inventive compositions exhibit significantly reduced the levels of volatiles, and excellent stiffness-impact balance used as standalone materials or in filled compounds. The significantly reduced number of large gels leads to excellent surface appearance and paintability of the molded parts. The composition of the present invention is made with a bulk/gas reactor process (i.e., non-slurry/non-solvent process) that has the advantage of process simplicity, process efficiency and simplicity of compositional structure relative to the complexity in structure and process of making of compositions in the prior art.Type: ApplicationFiled: December 16, 2011Publication date: June 21, 2012Inventors: Antonios K. Doufas, Edward Catalina, William C. Thurston, Rita Majewski
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Patent number: 8067319Abstract: A fiber is obtainable from or comprises an ethylene/?-olefin interpolymer characterized by an elastic recovery, Re, in percent at 300 percent strain and 1 cycle and a density, d, in grams/cubic centimeter, wherein the elastic recovery and the density satisfy the following relationship: Re>1481?1629(d). Such interpolymer can also be characterized by other properties. The fibers made therefrom have a relatively high elastic recovery and a relatively low coefficient of friction. The fibers can be cross-linked, if desired. Woven or non-woven fabrics can be made from such fibers.Type: GrantFiled: July 19, 2010Date of Patent: November 29, 2011Assignee: Dow Global Technologies LLCInventors: Benjamin C. Poon, Yunwa W. Cheung, Shih-Yaw Lai, Ashish Sen, Hongyu Chen, Yuen-Yuen D. Chiu, Rajen M. Patel, Andy C. Chang, Antonios K. Doufas, Hong Peng
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Patent number: 8044135Abstract: The present invention relates to an impact-resistant olefin polymer composition including a polypropylene matrix having a weight average molecular weight and an ethylene-containing polymer including an ethylene-propylene copolymer having a molecular weight higher than the weight average molecular weight of the polypropylene matrix, the composition containing about 20 to 35 percent xylene solubles, and the xylene solubles fraction of the composition containing less than about 39 weight percent ethylene units, based on the combined weight of olefin monomers in the copolymer. The present invention further relates to impact copolymer compositions with a melt flow rate greater than about 8 that meet or exceed all pallet testing requirements.Type: GrantFiled: February 24, 2010Date of Patent: October 25, 2011Assignee: Braskem America, Inc.Inventors: Antonios K. Doufas, Carol R. Barvinchak, Edward Catalina
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Publication number: 20110207883Abstract: The present invention relates to an impact-resistant olefin polymer composition including a polypropylene matrix having a weight average molecular weight and an ethylene-containing polymer including an ethylene-propylene copolymer having a molecular weight higher than the weight average molecular weight of the polypropylene matrix, the composition containing about 20 to 35 percent xylene solubles, and the xylene solubles fraction of the composition containing less than about 39 weight percent ethylene units, based on the combined weight of olefin monomers in the copolymer. The present invention further relates to impact copolymer compositions with a melt flow rate greater than about 8 that meet or exceed all pallet testing requirements.Type: ApplicationFiled: February 24, 2010Publication date: August 25, 2011Inventors: Antonios K. Doufas, Carol R. Barvinchak, Edward Catalina
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Patent number: 7947367Abstract: A fiber is obtainable from or comprises an ethylene/?-olefin interpolymer characterized by an elastic recovery, Re, in percent at 300 percent strain and (1) cycle and a density, d, in grams/cubic centimeter, wherein the elastic recovery and the density satisfy the following relationship: Re>1481?1629(d). Such interpolymer can also be characterized by other properties. The fibers made therefrom have a relatively high elastic recovery and a relatively low coefficient of friction. The fibers can be cross-linked, if desired. Woven or non-woven fabrics can be made from such fibers.Type: GrantFiled: March 15, 2006Date of Patent: May 24, 2011Assignee: Dow Global Technologies LLCInventors: Benjamin C. Poon, Yunwa W. Cheung, Shih-Yaw Lai, Ashish Sen, Hongyu Chen, Yuen-Yuen D. Chiu, Rajen M. Patel, Andy C. Chang, Antonios K. Doufas, Hong Peng
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Publication number: 20100279571Abstract: A fiber is obtainable from or comprises an ethylene/?-olefin interpolymer characterized by an elastic recovery, Re, in percent at 300 percent strain and 1 cycle and a density, d, in grams/cubic centimeter, wherein the elastic recovery and the density satisfy the following relationship: Re>1481?1629(d). Such interpolymer can also be characterized by other properties. The fibers made therefrom have a relatively high elastic recovery and a relatively low coefficient of friction. The fibers can be cross-linked, if desired. Woven or non-woven fabrics can be made from such fibers.Type: ApplicationFiled: July 19, 2010Publication date: November 4, 2010Inventors: Benjamin C. Poon, Yunwa W. Cheung, Shih-Yaw Lai, Ashish Sen, Hongyu Chen, Yuen-Yuen D. Chiu, Rajen M. Patel, Andy C. Chang, Antonios K. Doufas, Hong Peng
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Patent number: 7803728Abstract: A fiber is obtainable from or comprises an ethylene/?-olefin interpolymer characterized by an elastic recovery, Re, in percent at 300 percent strain and 1 cycle and a density, d, in grams/cubic centimeter, wherein the elastic recovery and the density satisfy the following relationship: Re>1481?1629(d). Such interpolymer can also be characterized by other properties. The fibers made therefrom have a relatively high elastic recovery and a relatively low coefficient of friction. The fibers can be cross-linked, if desired. Woven or non-woven fabrics can be made from such fibers.Type: GrantFiled: March 15, 2006Date of Patent: September 28, 2010Assignee: Dow Global Technologies Inc.Inventors: Benjamin C. Poon, Yunwa W. Cheung, Shih-Yaw Lai, Ashish Sen, Hongyu Chen, Yuen-Yuen D. Chiu, Rajen M. Patel, Andy C. Chang, Antonios K. Doufas, Hong Peng
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Patent number: 7737061Abstract: This invention relates to polyolefin compositions. In particular, the invention pertains to elastic polymer compositions that can be more easily processed on cast film lines, extrusion lamination or coating lines due to improved resistance to draw resonance. The compositions of the present invention preferably comprise an elastomeric polyolefin resin and a high pressure low density type resin.Type: GrantFiled: March 15, 2006Date of Patent: June 15, 2010Assignee: Dow Global Technologies Inc.Inventors: Andy C. Chang, Ronald J. Weeks, Hong Peng, Antonios K. Doufas, Yunwa W. Cheung
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Patent number: 7732052Abstract: This invention relates to polyolefin compositions. In particular, the invention pertains to elastic polymer compositions that can be more easily processed on cast film lines, extrusion lamination or coating lines due to improved resistance to draw resonance. The compositions of the present invention preferably comprise an elastomeric polyolefin resin and a high pressure low density type resin.Type: GrantFiled: February 15, 2008Date of Patent: June 8, 2010Assignee: Dow Global Technologies Inc.Inventors: Andy C. Chang, Ronald J. Weeks, Hong Peng, Antonios K. Doufas, Yunwa Wilson Cheung
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Patent number: 7504347Abstract: A fiber is obtainable from or comprises a propylene/?-olefin interpolymer characterized by an elastic recovery, Re, in percent at 300 percent strain and 1 cycle and a density, d, in grams/cubic centimeter, wherein the elastic recovery and the density satisfy the following relationship: Re>1481-1629 (d). Such interpolymer can also be characterized by other properties. The fibers made therefrom have a relatively high elastic recovery and a relatively low coefficient of friction. The fibers can be cross-linked, if desired. Woven or non-woven fabrics can be made from such fibers.Type: GrantFiled: March 15, 2006Date of Patent: March 17, 2009Assignee: Dow Global Technologies Inc.Inventors: Benjamin C. Poon, Yunwa W. Cheung, Shih-Yaw Lai, Ashish Sen, Hongyu Chen, Yuen-Yuen D. Chiu, Rajen M. Patel, Andy C. Chang, Antonios K. Doufas, Hong Peng
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Publication number: 20090042472Abstract: A fiber is obtainable from or comprises an ethylene/?-olefin interpolymer characterized by an elastic recovery, Re, in percent at 300 percent strain and (1) cycle and a density, d, in grams/cubic centimeter, wherein the elastic recovery and the density satisfy the following relationship: Re>1481?1629(d). Such interpolymer can also be characterized by other properties. The fibers made therefrom have a relatively high elastic recovery and a relatively low coefficient of friction. The fibers can be cross-linked, if desired. Woven or non-woven fabrics can be made from such fibers.Type: ApplicationFiled: March 15, 2006Publication date: February 12, 2009Inventors: Benjamin C. Poon, Yunwa W. Cheung, Shih-Yaw Lai, Ashish Sen, Hongyu Chen, Yuen-Yuen D. Chiu, Rajen M. Patel, Andy C. Chang, Antonios K. Doufas, Hong Peng
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Publication number: 20080280517Abstract: This invention relates to polyolefin compositions. In particular, the invention pertains to elastic polymer compositions that can be more easily processed on cast film lines, extrusion lamination or coating lines due to improved resistance to draw resonance. The compositions of the present invention preferably comprise an elastomeric polyolefin resin and a high pressure low density type resin.Type: ApplicationFiled: March 15, 2006Publication date: November 13, 2008Inventors: Andy C. Chang, Ronald J. Weeks, Hong Peng, Antonio K. Doufas, Yunwa W. Cheung
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Publication number: 20080268244Abstract: Improvements in the aesthetic appearance and performance properties of heterophasic polymers is obtained through the breaking up and dispersion of large gels. According to the current invention, a novel process is provided for filtration of heterophasic polymers using a fiber metal felt (FMF) media. Molded articles made from impact copolymers prepared according to the present invention have improved appearance and fracture mechanics relative to impact copolymers produced according to prior art methods.Type: ApplicationFiled: April 30, 2007Publication date: October 30, 2008Inventors: Antonios K. Doufas, Jeffrey S. Salek, Ronald A. Andrekanic, William C. Thurston, Leon M. Rice
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Publication number: 20080234435Abstract: This invention relates to polyolefin compositions. In particular, the invention pertains to elastic polymer compositions that can be more easily processed on cast film lines, extrusion lamination or coating lines due to improved resistance to draw resonance. The compositions of the present invention preferably comprise an elastomeric polyolefin resin and a high pressure low density type resin.Type: ApplicationFiled: February 15, 2008Publication date: September 25, 2008Applicant: Dow Global Technologies IncInventors: Andy C. Chang, Ronald J. Weeks, Hong Peng, Antonios K. Doufas, Yunwa W. Cheung
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Publication number: 20080199673Abstract: The present invention relates to propylene-based nonwoven layers made by the meltblown process, and laminates incorporating such layers. The meltblown layers of the present invention comprise propylene copolymers characterized by having less than 50 percent crystallinity. The meltblown layers of the present invention show an improved combination of extensibility and tensile strength. The laminate structures of the present invention are characterized by a combination of low bending modulus with high peel strength.Type: ApplicationFiled: August 3, 2006Publication date: August 21, 2008Inventors: Thomas T. Allgeuer, Andy C. Chang, Gert J. Claasen, Antonios K. Doufas, Edward N. Knickerbocker, Hong Peng, Randy E. Pepper, Jozef J. Van Dun
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Patent number: 7413803Abstract: Extensible bicomponent fibers and webs particularly adapted for disposable personal care product component applications. Sheath/core configurations providing desirable feel properties for elastic embodiments when compared with conventional elastic fibers and webs are obtained with specific olefin polymer combinations and sheath configurations.Type: GrantFiled: August 3, 2006Date of Patent: August 19, 2008Assignee: Dow Global Technologies Inc.Inventors: Joy F. Jordan, Renette E. Richard, Christian L. Sanders, Varunesh Sharma, Stephen M. Englebert, Bryon P. Day, Andy C. Chang, Hong Peng, Jozef J. I. Van Dun, Randy E. Pepper, Edward N. Knickerbocker, Antonios K. Doufas, Rajen M. Patel