Abstract: A liquid filter article, including: a housing having an inlet, an outlet, and an adsorbent bed there between, the bed comprising: a first stage having a first adsorbent, the first adsorbent including an activated carbon honeycomb infused with a plurality of zero valent iron nanoparticles (“Fe-AC”); and a second stage having a second adsorbent, the second adsorbent being selected from iron oxide particles supported on activated carbon honeycomb (“FEOX-AC”), iron oxide particles supported on activated alumina honeycomb (“FeOX-AA”), or a combination thereof, wherein the first stage is in fluid communication with the second stage. Also disclosed is a method of using the liquid filter article to remediate heavy metals in water.

Abstract: A method etching a glass material comprises providing an etchant comprising 10-30% HF, 5-15% HNO3,and at least 10% H3PO4 by volume constituted such that the ratio HF:HNO3 by volume is in the range of 1.7:1 to 2.3:1, providing a glass material to be etched, and contacting the glass material with the etchant. The etchant desirably has no other acid components. The method may be performed with the etchant temperature within the range of 20-30° C. The glass material may be an aluminosilicate glass. Ultrasound energy may be applied to the etchant, to the glass material, or both.

Abstract: Described herein are methods of making metallic or elemental silver. These methods generally include a step of forming a reaction dispersion that includes a silver-containing compound, an organic acid, and a solvent that includes an alcohol, followed by mixing the reaction dispersion for a time and at a temperature effective to form a reaction product that includes metallic silver from a cationic silver species of the silver-containing compound. Also described herein are metallic or elemental silver produced by these methods.

Abstract: Described herein are methods of recovering silver from solution to produce metallic (i.e., elemental) silver. These methods generally include a step of providing a silver-containing aqueous solution that includes cationic silver species, followed by a step of forming a reaction solution that includes an organic acid, a buffering agent, and the cationic silver species, and a step of generating a reaction product that includes metallic silver by reducing the concentration of the cationic silver species in the reaction solution. Also described herein are metallic or elemental silver produced by these methods.

Abstract: A method of making a filter article having a honeycomb substrate having adsorbent filled channels, including: sealing the first end of a porous, cellular honeycomb substrate; filling the channels of the cellular honeycomb substrate with a dry adsorbent source material; sealing the second end of the filled honeycomb to form a sealed honeycomb; contacting the sealed honeycomb and water for a time sufficient to convert the dry precursor material in-situ to a paste; removing the seals from the first and second ends; and heating the contacted honeycomb to convert the paste to an adsorbent. Also disclosed is a filter article having a honeycomb substrate having adsorbent filled channels and methods of using the article.

Abstract: Described herein are methods for improved transfer of graphene from formation substrates to target substrates. In particular, the methods described herein are useful in the transfer of high-quality chemical vapor deposition-grown monolayers of graphene from metal, e.g., copper, formation substrates to ultrathin, flexible glass targets. The improved processes provide graphene materials with less defects in the structure.

Abstract: Described herein are methods for improved transfer of graphene from formation substrates to target substrates. In particular, the methods described herein are useful in the transfer of high-quality chemical vapor deposition-grown monolayers of graphene from metal, e.g., copper, formation substrates via non-polymeric methods. The improved processes provide graphene materials with less defects in the structure.

Abstract: A method etching a glass material comprises providing an etchant comprising 10-30% HF, 5-15% HNO3, and at least 10% H3PO4 by volume constituted such that the ratio HF:HNO3 by volume is in the range of 1.7:1 to 2.3:1, providing a glass material to be etched, and contacting the glass material with the etchant. The etchant desirably has no other acid components. The method may be performed with the etchant temperature within the range of 20-30° C. The glass material may be an aluminosilicate glass. Ultrasound energy may be applied to the etchant, to the glass material, or both.

Abstract: A non-extruded filter article, including: an activated carbon honeycomb substrate having a plurality of flow-through channels and porous walls, and the activated carbon substrate comprises a carbon in from 90 to 99.9 wt. % of the article, and the porous walls have a percentage porosity of from 40% to 65%. Also disclosed is a non-extrusion method of making the article and a method of using the article.

Abstract: A method of making a filter article having a honeycomb substrate having adsorbent filled channels, including: sealing the first end of a porous, cellular honeycomb substrate; filling the channels of the cellular honeycomb substrate with a dry adsorbent source material; sealing the second end of the filled honeycomb to form a sealed honeycomb; contacting the sealed honeycomb and water for a time sufficient to convert the dry precursor material in-situ to a paste; removing the seals from the first and second ends; and heating the contacted honeycomb to convert the paste to an adsorbent. Also disclosed is a filter article having a honeycomb substrate having adsorbent filled channels and methods of using the article.

Abstract: A liquid filter article, including: a housing having an inlet, an outlet, and an adsorbent bed there between, the bed comprising: a first stage having a first adsorbent, the first adsorbent including an activated carbon honeycomb infused with a plurality of zero valent iron nanoparticles (“Fe-AC”); and a second stage having a second adsorbent, the second adsorbent being selected from iron oxide particles supported on activated carbon honeycomb (“FEOX-AC”), iron oxide particles supported on activated alumina honeycomb (“FeOX-AA”), or a combination thereof, wherein the first stage is in fluid communication with the second stage. Also disclosed is a method of using the liquid filter article to remediate heavy metals in water.

Abstract: Methods for making activated carbon-supported transition metal-based nanoparticles include (a) impregnated activated carbon with at least one transition metal-containing compound, and (b) heating the impregnated activated carbon at a temperature and for a time sufficient to carbothermally reduce the transition metal-containing compound. Also disclosed are activated carbon-supported transition metal-based nanoparticles produced by such methods. Further disclosed are methods for treating water and waste streams that include contacting the water or waste streams with the activated carbon-supported transition metal-based nanoparticles.

Abstract: A method of making an activated carbon honeycomb filter article, as defined herein, including: extruding a batch mixture to form an extruded honeycomb body, the batch including: an activated carbon powder; a first organic binder powder; a rheological plasticizing liquid; a porous inorganic binder powder; an extrusion aid; and water by superaddition, drying the extruded honeycomb body; and heat treating the dried honeycomb body. Also disclosed is an honeycomb filter article, having: an activated carbon; a porous inorganic binder powder; a BET surface area of from 950 m2/g to 1600 m2/g; a cell density of from 50 to 2000 cpsi; and a density of from 0.5 to 0.8 g/cm3.

Abstract: Embodiments of a method of making a sorbent comprise providing a monolith having a plurality of internal channels, providing at least one silica coating onto walls of the plurality of internal channels by applying a silica coating solution, and providing at least one chitosan coating on the silica coating by applying a chitosan coating solution.

Abstract: Described herein are methods of making metallic or elemental silver in the solid state. These methods generally include a step of forming an at least substantially solvent-free solid state reaction mixture that includes a silver-containing compound and an organic acid, followed by heating the reaction mixture at a temperature and for a time effective to form metallic silver from a cationic silver species of the silver-containing compound. Also described herein are metallic or elemental silver produced by these methods.

Abstract: The disclosure relates to methods for making carbon-supported transition metal-based nanoparticles, comprising (a) mixing at least one carbon feedstock, at least one transition metal-containing feedstock, at least one organic binder, and at least one resin binder to form a feedstock mixture, (b) extruding the feedstock mixture, and (c) heating the extruded feedstock mixture at a temperature and for a time sufficient to carbothermally reduce the transition metal-containing feedstock. Also disclosed herein are carbon-supported transition metal-based nanoparticles produced by such methods. Further disclosed herein are methods for treating water and waste streams comprising contacting the water or waste streams with the carbon-supported transition metal-based nanoparticles.

Abstract: Described herein are methods of recovering silver from solution to produce metallic (i.e., elemental) silver. These methods generally include a step of providing a silver-containing aqueous solution that includes cationic silver species, followed by a step of forming a reaction solution that includes an organic acid, a buffering agent, and the cationic silver species, and a step of generating a reaction product that includes metallic silver by reducing the concentration of the cationic silver species in the reaction solution. Also described herein are metallic or elemental silver produced by these methods.

Abstract: Described herein are methods of making metallic or elemental silver. These methods generally include a step of forming a reaction dispersion that includes a silver-containing compound, an organic acid, and a solvent that includes an alcohol, followed by mixing the reaction dispersion for a time and at a temperature effective to form a reaction product that includes metallic silver from a cationic silver species of the silver-containing compound. Also described herein are metallic or elemental silver produced by these methods.

Abstract: Methods and apparatus provide for zero valent nanoparticles coated with a stabilizer to inhibit oxidation, where the coating includes at least one of activated carbon, graphene, an inorganic oxide, and an organic material.

Abstract: Methods and apparatus provide for subjecting water contaminated with one or more heavy metals to an ion exchange process such that a total quantity of anions within the water are reduced; and subsequent to the anion exchange process, bringing the contaminated water into contact with zero valent nanoparticles to remove at least some of the heavy metal from the water.