Abstract: A copolymer essentially consisting of: from 50 to 99 mole % of at least one recurring unit (R1), based on the total mole amount of the recurring units (R1) and (R2), wherein the recurring unit (R1) is derived from incorporation of 4,4?-terphenyl-p-diol and a dihaloaryl sulfone compound and from 1 to 50 mole % of at least one recurring unit (R2), based on the total mole amount of the recurring units (R1) and (R2), wherein the recurring unit (R2) is derived from incorporation of 4,4?-terphenyl-p-diol and a dihaloaryl ketone compound.

Abstract: A process for the preparation of dihalodiphenylsulfones such as 4,4?-dichlorodiphenyl sulfone or 4,4?-bis-(4-chlorophenylsulfonyl)biphenyl with high regioselectivity, at low temperature and in the absence of toxic reagents by reacting together at least one acid, at least one fluorinated anhydride and at least one halobenzene. The invented process is particularly suited for the manufacture of 4,4?-dichlorodiphenyl sulfone.

Abstract: A process for the preparation of dihalodiphenylsulfones_such as 4,4?-dichlorodiphenyl sulfone or 4,4?-bis-(4-chlorophenylsulfonyl)biphenyl with high regioselectivity, at low temperature and in the absence of toxic reagents by reacting together at least one acid, at least one fluorinated anhydride and at least one halobenzene. The invented process is particularly suited for the manufacture of 4,4?-dichlorodiphenyl sulfone.

Abstract: A process for the preparation of dihalodiphenylsulfones such as 4,4?-dichlorodiphenyl sulfone or 4,4?-bis-(4-chlorophenylsulfonyl)biphenyl with high regioselectivity, at low temperature and in the absence of toxic reagents by reacting together at least one acid, sulfur trioxide and at least one halobenzene. The invented process is particularly suited for the manufacture of 4,4?-dichlorodiphenyl sulfone.

Abstract: A chemical processing article comprising at least one part made of a poly(arylether sulfone) polymeric material comprising at least one poly(arylether sulfone) polymer, wherein said (t-PAES) polymer comprising more than 50% moles of recurring units (Rt) of formula (St): -E-Ar1—SO2—[Ar2-(T-Ar3)n-SO2]m—Ar4 wherein n and m, equal to or different from each other, are independently zero or an integer of 1 to 5, each of Ar1, Ar2, Ar3 and Ar4 equal to or different from each other and at each occurrence, is an aromatic moiety, T is a bond or a divalent group and E is of formula (Et) wherein each of R?, equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; j? is zero or is an integer from 1 to 4.

Abstract: An oil and gas recovery article comprising at least one part made of a poly(arylether sulfone) polymeric material comprising at least one poly(arylether sulfone) polymer, wherein said (t-PAES) polymer comprising more than 50% moles of recurring units (Rt) of formula (St): -E-Ar1—SO2—[Ar2-(T-Ar3)n—SO2]m—Ar4 wherein n and m, equal to or different from each other, are independently zero or an integer of 1 to 5, each of Ar1, Ar2, Ar3 and Ar4 equal to or different from each other and at each occurrence, is an aromatic moiety, T is a bond or a divalent group and E is of formula (Et), wherein each of R?, equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; j? is zero or is an integer from 1 to 4.

Abstract: A method for the preparation of a poly(ether ether ketone) (PEEK) includes: preparing the PEEK by aromatic nucleophilic substitution in the presence of: a) particulate sodium carbonate (Na2CO3), wherein said particulate sodium carbonate has a particle size distribution as follows: D90?45 ?m and D90?250 ?m and D99.5?710 ?m, wherein said particle size distribution is measured by mechanical sieving in accordance with ASTM E 359-00 (reapproved 2005), wherein said measurement is based on the mechanical separation of various fractions on a series of superimposed sieves which are superimposed by descending order of opening mesh of 1000 ?m, 500 ?m, 250 ?m, 180 ?m, 125 ?m, 90 ?m, 63 ?m, and 45 ?m; and b) potassium carbonate (K2CO3) in an amount ranging from 0.001 to about 0.05 mol K/mol Na.

Abstract: The present invention describes a process for preparing a poly(aryl ether ketone) by reacting a nucleophile with 4,4?-difluorobenzophenone (4,4?-DFBP) that is improved through the use of 4,4?-DFBP that meets one or more particular purity conditions. Also described are improved poly(aryl ether ketone) produced using the invention 4,4?-DFBP. Amounts of 2,4?-difluorobenzophenone (2,4?-DFBP), 4-monofluorobenzophenone (4-FBP), chlorine, and monochloromonofluorobenzophenone in 4,4?-DFBP are discussed.

Abstract: A poly(arylether sulfone) polymer [(t-PAES) polymer, herein after], wherein more than 70% moles of the recurring units are recurring units (Rt) of formula (St): -E-Ar1—S02-[Ar2-(T-Ar3)n—SO2]m-Ar4— (formula St) wherein: n and m, equal to or different from each other, are independently zero or an integer of 1 to 5, each of Ar1, Ar2, Ar3 and Ar4 equal to or different from each other and at each occurrence, is an aromatic moiety, T is a bond or a divalent group optionally comprising one or more than one heteroatom; —E is of formula (Et), wherein each of R?, equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; j? is zero or is an integer from 1 to 4, and said (t-PAES) polymer having a number average molecular weight (Mn) ranging from 41 000 to

Abstract: A poly(arylether sulfone) polymeric material comprising polymer molecules wherein more than 50% moles of the recurring units of said polymer molecules are recurring units (Rt), equal to or different from each other, complying with formula (St): -E-Ar1—S02-[Ar2-(T-Ar3)n-S02]m-Ar4— (formula St) wherein: n and m, equal to or different from each other, are independently zero or an integer of 1 to 5, each of Ar1, Ar2, Ar3 and Ar4 equal to or different from each other and at each occurrence, is an aromatic moiety, T is a bond or a divalent group optionally comprising one or more than one heteroatom—E is of formula (Et): wherein each of R?, equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; j? is zero or is an integer from 1 to 4; and wherein

Abstract: A composition [composition (C), herein after] comprising from 30 to 95% by weight of at least one poly(arylether sulfone) polymer, wherein said polymer comprising more than 50% moles of recurring units (Rt) of formula (St): -E-Ar1—SO2—[Ar2-(T-Ar3)n—SO2]m—Ar4-(formula S) wherein n and m, equal to or different from each other, are independently zero or an integer of 1 to 5, each of Ar1, Ar2, Ar3 and Ar4 equal to or different from each other and at each occurrence, is an aromatic moiety, T is a bond or a divalent group optionally comprising one or more than one heteroatom;and E is of formula (Et): herein each of R?, equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; j? is zero or is an integer from 1 to 4, from to 50% wt.

Abstract: A process for the manufacture of a haloaryl compound which comprises contacting a mixture of dihalodiarylsulfone isomers [mixture (M)] with sulfuric acid to provide a mixture of haloarylsulfonic acid isomers [mixture (M1)] and reacting mixture (M1) in the presence of water. The process is independent on the manufacturing process of mixture (M) and is advantageous in that the obtained haloaryl compound can be recycled to the first step of a dihalodiarylsulfone manufacturing process.

Abstract: The presence of certain impurities in diphenyl sulfone have a deleterious effect on the properties of the poly(aryletherketone)s produced therein, including one or more of color, melt stability, molecular weight, crystallinity, etc. and here identify those impurities and provide processes for the recovery of the diphenyl sulfone.

Abstract: Sodium carbonate (Na2CO3) having a certain particle size distribution and its use in preparing poly(aryl ether ketone)s, especially PEEK. Poly(aryl ether ketone)s made using the described sodium carbonate. A method for providing a sodium carbonate having a certain particle size distribution, which is especially well suited for the preparation of poly(aryl ether ketone)s.

Abstract: The presence of certain impurities in diphenyl sulfone have a deleterious effect on the properties of the poly(aryletherketone)s produced therein, including one or more of color, melt stability, molecular weight, crystallinity, etc. and here identify those impurities and provide processes for the recovery of the diphenyl sulfone.

Abstract: A poly(arylethersulfone) polymer comprising recurring units derived from at least one aromatic dihalocompound comprising at least one —S(?O)2— group and at least one diol (D) comprising at least one cycloaliphatic moiety (M).

Abstract: Poly(aryletherketone)s comprising fluoride end groups having improved melt stability, lower gel content and lower color are provided.

Abstract: A process for the manufacture of a haloaryl compound which comprises contacting a mixture of dihalodiarylsulfone isomers [mixture (M)] with sulfuric acid to provide a mixture of haloarylsulfonic acid isomers [mixture (M1)] and reacting mixture (M1) in the presence of water. The process is independent on the manufacturing process of mixture (M) and is advantageous in that the obtained haloaryl compound can be recycled to the first step of a dihalodiarylsulfone manufacturing process.

Abstract: A process for the preparation of dihalodiphenylsulfones_such as 4,4?-dichlorodiphenyl sulfone or 4,4?-bis-(4-chlorophenylsulfonyl)biphenyl with high regioselectivity, at low temperature and in the absence of toxic reagents by reacting together at least one acid, sulfur trioxide and at least one halobenzene. The invented process is particularly suited for the manufacture of 4,4?-dichlorodiphenyl sulfone.

Abstract: The presence of certain impurities in diphenyl sulfone have a deleterious effect on the properties of the poly(aryletherketone)s produced therein, including one or more of color, melt stability, molecular weight, crystallinity, etc. and here identify those impurities and provide processes for the recovery of the diphenyl sulfone.