Abstract: Methods are provided for forming a coating system on a gas turbine component. In one embodiment, and by way of example only, the method includes cold spraying a material onto the component surface to form an overlay coating, the material comprising MCrAlY, wherein M comprises a constituent selected from the group consisting of Ni, Co, or Fe, or combinations of Ni, Co, and Fe. Then, the overlay coating is heat treated. The overlay coating is then shot peened and vibro polished. A thermal barrier coating is then applied onto the overlay coating to form the coating system via air plasma spaying or electron beam physical vapor deposition technique.

Abstract: There is provided a method for depositing a modified MCrAlY coating on a surface of a gas turbine engine component. The method includes cold gas dynamic spraying techniques to provide a metallurgical bond between a substrate, such as a superalloy substrate, and the modified MCrAlY composition. The method further includes post deposition heat treatments including hot isostatic pressing. The modified MCrAlY composition includes one or more elements of Pt, Hf, Si, Zr, Ta, Re, Ru, Nb, B, and C, which improves the corrosion and environmental resistance of the coated component.

Abstract: There is provided a method for depositing a modified MCrAlY coating on a surface of a gas turbine engine component. The method includes cold gas dynamic spraying techniques to provide a metallurgical bond between a substrate, such as a superalloy substrate, and the modified MCrAlY composition. The method further includes post deposition heat treatments including hot isostatic pressing.

Abstract: A protective barrier coating system including a diffusion barrier coating and an oxidation barrier coating and method for use in protecting silicon-based ceramic turbine engine components. A complete barrier coating system includes a thermal barrier coating of stabilized zirconia and an environmental barrier coating of an alloyed tantalum oxide. The oxidation barrier coating includes a layer of metallic silicates formed on a substrate of silicon nitride or silicon carbide to be protected. The oxidation barrier coating can include silicates of scandium, ytterbia or yttrium. The oxidation barrier coating may also include an inner layer of Si2ON2 between the diffusion barrier and the metallic silicate layer. The oxidation barrier coating can be applied to the substrate by spraying, slurry dipping and sintering, by a sol-gel process followed by sintering, by plasma spray, or by electron beam-physical vapor deposition.

Abstract: A component comprising a silicon-based substrate and a diffusion barrier coating disposed on the silicon-based substrate. The diffusion barrier coating comprises an isolation layer disposed directly on the silicon-based substrate and at least one oxygen barrier layer disposed on the isolation layer. The oxygen barrier layer prevents the diffusion of oxygen therethrough, and prevents excessive oxidation of the silicon-based substrate. The isolation layer(s) prevent contaminants and impurities from reacting with the oxygen barrier layer. An environmental barrier coating may be disposed on the diffusion barrier coating, and a thermal barrier coating may be disposed on the environmental barrier coating. Methods for making a component having a diffusion barrier coating are also disclosed.

Abstract: A durable protective coating may be formed by applying a thin layer of metastable alumina to a bond coating on a substrate. A thermal barrier coating may then be applied to the metastable alumina and the resulting part may be heat treated to transform the metastable alumina to a mixed alpha alumina having particles of the thermal barrier coating, such as zirconia in the case of an yttria stabilized zirconia thermal barrier coating, dispersed therein. The resulting thermal barrier coating may inhibit microbuckling of the thermally grown oxide scale that grows over time at the thermal barrier coating-bond coating interface.

Abstract: A method for joining a first component surface to a ceramic component surface includes cold gas-dynamic spraying a first metal powder onto the ceramic component surface to form a first metal coating. The first component surface is then bonded to the metal coating on the ceramic component surface. The bonding step may be a thermal process such as a brazing process. A mechanical bond may also be formed by an interference fitting such as press or shrink fitting.

Abstract: A plurality of powders is admixed to form a substantially homogenous powder mixture comprising each of the alloy elements. At least one of the powders consists essentially of a substantially pure elemental metal. The substantially homogenous powder mixture is cold gas-dynamic sprayed on the substrate to form a coating of the alloy elements. The coating is then heated until the alloy elements inter-diffuse and form the alloy. In an exemplary embodiment, the substantially homogenous powder mixture includes stoichiometric amounts of each of the alloy elements, and each of the powders consists essentially of a substantially pure form of one of the alloy elements.

Abstract: A method is provided for forming a graded coating on a surface of a substrate. The method comprises the step of cold gas-dynamic spraying powder mixtures on the substrate surface to form the graded coating thereon. The method does not distort the substrate and does not require the use of an apparatus that needs to be stopped and re-started each time the composition of the graded coating changes. Moreover, the method is generally inexpensive, efficient, and yields high quality graded coatings.

Abstract: A turbine engine component includes an electron beam-physical vapor deposition thermal barrier coating covering at least a portion of a substrate. The thermal barrier coating includes an inner layer having a columnar-grained microstructure with inter-columnar gap porosity. The inner layer includes a stabilized ceramic material. The thermal barrier coating also includes a substantially non-porous outer layer, covering the inner layer and including the stabilized ceramic material. The outer layer is deposited with continuous line-of-sight exposure to the vapor source under oxygen deficient conditions. The outer layer may further comprise a dopant oxide that is more readily reducible than the stabilized ceramic material. During deposition, the outer layer may also have an oxygen deficient stoichiometry with respect to the inner layer. Oxygen stoichiometry in the outer layer may be restored by exposure of the coated component to an oxidizing environment.

Abstract: A method for coating a surface of a metal component comprises the steps of cold gas-dynamic spraying a powder material on the metal component surface to form a coating, the powder material being sufficiently heated to impact the metal component surface at between about 30% and about 70% of the powder material's melting temperature in kelvins. Another method for coating a surface of a metal component using a powder material comprises the steps of heating the metal component surface to between about 30% and about 70% of the substrate's melting temperature, and then of the powder material's melting temperature in kelvins, and cold gas-dynamic spraying the powder material on the metal component surface to form a coating.

Abstract: Oxidation protection of a titanium-based alloy is provided with improved fatigue properties by a titanium aluminide coating of between 2 to 12 microns by diffusing the Al into the Ti at a temperature below the melting point of the Al. The coating is gas deposited and protects the titanium-based alloys from oxidation at high temperature utilization.

Abstract: A component for a turbine engine component includes a ceramic substrate having a surface, an environmental barrier layer bonded to the substrate surface, and an impact-resistance layer bonded to the environmental barrier layer, the impact-resistance layer having a melting point higher than about 2700° F., and further having a between about 10 and about 30% porosity. The impact-resistance layer, environmental barrier layer, and interfaces at which the environmental layer is bound to the substrate surface and the impact-resistance layer are more readily shearable than the substrate. A method for protecting a turbine engine component from environmental and particle impact-related damage includes the steps of coating a substrate surface with the environmental barrier layer, and coating the environmental barrier layer with the impact-resistance layer.

Abstract: The present invention provides methods and materials for use in applying a coating on a surface of a magnesium component. The method includes the steps of: accelerating a coating powder to a velocity of between about 500 to about 1200 meters/second, wherein the coating powder comprises a material selected from the group consisting of aluminum, aluminum alloys, titanium, titanium alloys, and composites; directing the coating powder through a convergent-divergent nozzle onto the surface of the magnesium component; and forming a coating on the surface of the magnesium component so as to substantially cover the surface of the magnesium component. The coating thickness may be between approximately 0.1 to approximately 1.0 mm.

Abstract: In a method for coating a surface of a turbine component with an environment-resistant aluminide, a coating is formed by cold gas-dynamic spraying a powder material on the turbine component surface, the powder material comprising aluminum, platinum, and at least one additional metal selected from the group consisting of nickel, chromium, hafnium, silicon, yttrium, rhenium, zirconium, cobalt, and tantalum. After forming the coating, at least one thermal diffusion treatment is performed on the turbine component to metallurgically homogenize the coating and thereby form an aluminide coating that includes by weight about 12 to about 30% aluminum, up to about 50% platinum, about 2 to about 25% chromium, about 1 to about 5% hafnium, about 1 to about 5% silicon, about 0.1 to about 1% yttrium, and about 1 to about 3% Zr, and nickel.

Abstract: A component comprising a silicon-based substrate and a braze-based protective coating disposed on the silicon-based substrate. The braze-based coating comprises a brazed layer, wherein the brazed layer comprises at least one intermetallic compound. A scale layer may be formed on the brazed layer. An environmental barrier coating may be disposed directly on the brazed layer or directly on the scale layer. A thermal barrier coating may be disposed on the environmental barrier coating. Methods for making a Si-based component having a braze-based protective coating are also disclosed.

Abstract: A catalyst system for removing one or more components from a fluid stream includes a binder layer and a plurality of catalyst structures affixed to, and protruding from, the binder layer such that the catalyst structure surface is directly exposed to the fluid stream. Methods for preparing a catalyst system, and for selectively removing components from a fluid stream via a catalyst system are also disclosed.

Abstract: A turbine blade tip and shroud clearance control coating system comprising a dense abrasive blade tip layer and an abradable shroud layer are provided. The dense abrasive coating may comprise cubic zirconia, hafnia or mixtures thereof and the abradable layer may be a nanolaminate thermal barrier coating that is softer than the dense abrasive layer.

Abstract: The present invention thus provides an improved method for coating turbine engine components. The method utilizes a cold high velocity gas spray technique to coat turbine blades, compressor blades, impellers, blisks, and other turbine engine components. These methods can be used to coat a variety of surfaces thereon, thus improving the overall durability, reliability and performance of the turbine engine itself. The method includes the deposition of powders of alloys of nickel and aluminum wherein the powders are formed so as to have an amorphous microstructure. Layers of the alloys may be deposited and built up by cold high velocity gas spraying. The coated items displayed improved characteristics such as hardness, strength, and corrosion resistance.

Abstract: A catalyst system for removing one or more components from a fluid stream includes a binder layer and a plurality of catalyst structures affixed to, and protruding from, the binder layer such that the catalyst structure surface is directly exposed to the fluid stream. Methods for preparing a catalyst system, and for selectively removing components from a fluid stream via a catalyst system are also disclosed.