Abstract: Disclosed herein is a multilayer coating system present on a substrate and including at least two coating layers L1 and L2 different from one another, namely a first coating layer L1 applied over at least a portion of the substrate, and a second topcoat layer L2 applied over the first coating layer L1, where the topcoat layer L2 is formed from a coating composition including at least one block copolymer containing a backbone and at least two blocks B1 and B2 and side chains S1 and S2 including different polymeric moieties M1 and M2. Also disclosed herein are a method of preparing said multilayer coating system, a coated substrate obtainable therefrom, and a method of using a coating composition including the block copolymer for improving, in particular for increasing, the chromaticity of the multilayer coating system.

Abstract: Disclosed herein is a multilayer coating system present on a substrate and including at least three coating layers L1, L2 and L3 different from one another, namely a first pigmented coating layer L1 applied over at least a portion of the substrate, a second coating layer L2 applied over the first pigmented coating layer L1, and a third coating layer L3 applied over the second coating layer L2, where the second coating layer L2 is formed from a coating composition including at least one block copolymer containing a backbone and at least two blocks B1 and B2 and side chains S1 and S2 including different polymeric moieties M1 and M2. Also disclosed herein are a method of preparing said multilayer coating system, a coated substrate obtainable therefrom, and a method of using a coating composition including the block copolymer for improving the chromaticity of the multilayer coating system.

Abstract: Disclosed herein are a method for producing materials having at least one carbamate functionality, carbamate-functional materials obtained from the process, coating compositions including said carbamate-functional materials, and a process for at least partially coating a substrate with the coating compositions. The method disclosed herein reduces unwanted transesterification which can occur as a side reaction by using a tertiary alkyl carbamate in combination with a tin catalyst and thus results in increased yields and purity of the carbamate-functional materials.

Abstract: Disclosed herein are coating compositions including at least one carbamate-functional poly(ethylene-acrylate) copolymer as binder and at least one crosslinking agent, a method of coating substrates with such coating compositions and coated substrates obtained by the method. Further disclosed herein is a method of using such coating compositions for improving the scratch resistance of coating layers.

Abstract: Described herein is a 2K solvent borne coating system. The coating system includes an epoxy component (A), including: i) an epoxy resin; ii)—a solvent; iii)—at least one compound of formula (I): [(ER)x(R?O)y(HO)z(R?)t(SiO(4-x-y-z-t)]m??(I) and/or oligomer or polymer compounds of the compound of formula (I), and iv)—optionally, at least one non-catalytic additive; and an acid resin component (B), including: an carboxylic acid resin; a solvent; optionally, at least one catalyst; and optionally, at least one additive. Also described herein are a 2K coating composition, a method to coat an automotive substrate with the composition, and a scratch and mar resistant coated surface of the 2K coating composition.

Abstract: Disclosed herein are coating compositions, particularly UV-curable coating compositions, including at least one unsaturated ethylene copolymer as binder and optionally at least one photoinitiator, a method of coating substrates with such coating compositions, and coated substrates obtained by the method. Further disclosed herein is a method of using such coating compositions for improving the flexibility of coating layers, particularly primer layers.

Abstract: Disclosed herein is a method of preparing a multilayer coating system on a substrate including a step of applying at least one organic black pigment containing basecoat composition to a substrate and forming a first coating film thereon (1), optionally subsequently applying a second basecoat composition and forming a second coating film adjacent to the first coating film (2), and applying a pigmented topcoat composition to the first coating film in case optional step (2) is not performed (3a), or applying a clearcoat composition to the second coating film in case optional step (2) is performed, and where steps (1), (2) and (3b) are performed, or steps (1) and (3a) are performed, includes at least one non-black coloring pigment having a volume average particle size of <1000 nm in an amount in the range of from 0.01 to 7.50 wt.-%, based on its total solid content.

Abstract: Provided herein are composite materials comprising a layup consisting of one or more surfacing sheets comingled with a carbon fiber non-woven mat. The surfacing sheet may comprise polyamide-6 and the carbon fiber non-woven mat may comprise carbon fibers that have been recycled. The surfacing sheets comprise sub-micron scale particles for reducing the thermal expansion coefficient of the surfacing sheets. The resulting layup is suitable for use in the formation of articles, particularly articles requiring a smooth finish absent of defects caused by underlying surfaces having irregular compositions or textures.

Abstract: A storage stable one component aqueous basecoat composition containing a melamine formaldehyde crosslinker and a resin having groups reactive to the melamine formaldehyde crosslinker under acid catalysis is provided. The basecoat composition is curable at a temperature of 110° C. or less when cured wet on wet with a solvent borne clear coat composition containing a polyisocyanate crosslinker. Also provided is a wet on wet two layer coating containing the one component aqueous basecoat and the solvent borne clear coat, a wet on wet three layer coating containing an aqueous primer, the one component aqueous basecoat and the solvent borne clear coat and a cured topcoat coating obtained by curing the wet on wet two layer coating.

Abstract: A double coating, curing method, cured coating, and kit are provided. A first layer of the double coating can be a first cure coating composition, which has a first hydroxy-functional resin, a first crosslinking agent, and a non-polar catalyst. A second layer of a second cure coating composition can have a second hydroxy-functional resin, a second crosslinking agent, and a polar catalyst. The non-polar catalyst catalyzes crosslinking between the second hydroxy-functional resin and crosslinking agent, and not between the first hydroxy-functional resin and crosslinking agent. The polar catalyst catalyzes crosslinking between the first hydroxy-functional resin and crosslinking agent, and not between the second hydroxy-functional resin and crosslinking agent. The polarity of the catalysts can facilitate catalyst migration from one layer to the other. The separate compositions can be shelf-stable and/or the curing can occur at low temperature.

Abstract: Described herein is a process for producing a multilayer coating onto a fiber-reinforced composite material. Also described herein is a fiber-reinforced composite material coated with a multilayer coating obtainable by this process.

Abstract: Described herein is a 2K solvent borne coating system. The coating system includes an epoxy component (A), including: i) an epoxy resin; ii) a solvent; iii) at least one compound of formula (I): [(ER)x(R?O)y(HO)z(R?)t(SiO(4-x-y-z-t)]m??(I) and/or oligomer or polymer compounds of the compound of formula (I), and iv) optionally, at least one non-catalytic additive; and an acid resin component (B), including: an carboxylic acid resin; a solvent; optionally, at least one catalyst; and optionally, at least one additive. Also described herein are a 2K coating composition, a method to coat an automotive substrate with the composition, and a scratch and mar resistant coated surface of the 2K coating composition.

Abstract: A storage stable one component aqueous basecoat composition containing a melamine formaldehyde crosslinker and a resin having groups reactive to the melamine formaldehyde crosslinker under acid catalysis is provided. The basecoat composition is curable at a temperature of 110° C. or less when cured wet on wet with a solvent borne clear coat composition containing a polyisocyanate crosslinker. Also provided is a wet on wet two layer coating containing the one component aqueous basecoat and the solvent borne clear coat, a wet on wet three layer coating containing an aqueous primer, the one component aqueous basecoat and the solvent borne clear coat and a cured topcoat coating obtained by curing the wet on wet two layer coating.

Abstract: A double coating, curing method, cured coating, and kit are provided. A first layer of the double coating can be a first cure coating composition, which has a first hydroxy-functional resin, a first crosslinking agent, and a first catalyst. A second layer of a second cure coating composition can have a low hydrophilicity acrylic resin as a second hydroxy-functional resin, a second crosslinking agent, and a second catalyst. The first catalyst catalyzes crosslinking between the second hydroxy-functional resin and crosslinking agent, and not between the first hydroxy-functional resin and crosslinking agent. The second catalyst catalyzes crosslinking between the first hydroxy-functional resin and crosslinking agent, and not between the second hydroxy-functional resin and crosslinking agent. The first and/or second hydroxy functional resins can facilitate catalyst migration from one layer to the other. The separate compositions can be shelf-stable and/or the curing can occur at low temperature.

Abstract: Described herein is a process for producing a multilayer coating onto a fiber-reinforced composite material Also described herein is a fiber-reinforced composite material coated with a multilayer coating obtainable by this process.

Abstract: A double coating, curing method, cured coating, and kit are provided. A first layer of the double coating can be a first cure coating composition, which has a first hydroxy-functional resin, a first crosslinking agent, and a non-polar catalyst. A second layer of a second cure coating composition can have a second hydroxy-functional resin, a second crosslinking agent, and a polar catalyst. The non-polar catalyst catalyzes crosslinking between the second hydroxy-functional resin and crosslinking agent, and not between the first hydroxy-functional resin and crosslinking agent. The polar catalyst catalyzes crosslinking between the first hydroxy-functional resin and crosslinking agent, and not between the second hydroxy-functional resin and crosslinking agent. The polarity of the catalysts can facilitate catalyst migration from one layer to the other. The separate compositions can be shelf-stable and/or the curing can occur at low temperature.

Abstract: A double coating, curing method, cured coating, and kit are provided. A first layer of the double coating can be a first cure coating composition, which has a first hydroxy-functional resin, a first crosslinking agent, and a first catalyst. A second layer of a second cure coating composition can have a low hydrophilicity acrylic resin as a second hydroxy-functional resin, a second crosslinking agent, and a second catalyst. The first catalyst catalyzes crosslinking between the second hydroxy-functional resin and crosslinking agent, and not between the first hydroxy-functional resin and crosslinking agent. The second catalyst catalyzes crosslinking between the first hydroxy-functional resin and crosslinking agent, and not between the second hydroxy-functional resin and crosslinking agent. The first and/or second hydroxy functional resins can facilitate catalyst migration from one layer to the other. The separate compositions can be shelf-stable and/or the curing can occur at low temperature.

Abstract: A method of forming a passivated pigment slurry includes combining a resin and a pigment to form a pigment-resin slurry, wherein the pigment includes a plurality of flakes each having a surface. After combining, the method includes firstly reacting an orthosilicate and the pigment in the presence of the resin to form a coated pigment-resin slurry. The coated pigment-resin slurry includes the resin and a coated pigment including the plurality of flakes each encapsulated by a first layer formed from the orthosilicate on the surface. The method further includes, concurrent to or after firstly reacting, secondly reacting the coated pigment-resin slurry and an organosilane compound having a hydrolysable group and an organic group to coat the first layer and form the passivated pigment slurry. The passivated pigment slurry includes the resin and a passivated pigment including the plurality of flakes each coated with a second layer disposed on the first.

Abstract: A method of forming a passivated pigment slurry includes combining a resin and a pigment to form a pigment-resin slurry, wherein the pigment includes a plurality of flakes each having a surface. After combining, the method includes mixing the pigment-resin slurry and an orthosilicate to form a coated pigment-resin slurry. The coated pigment-resin slurry includes the resin and a coated pigment including the plurality of flakes each encapsulated by a first layer formed from silica and disposed on the surface. The method further includes reacting the coated pigment-resin slurry and an organosilane compound having a hydrolysable group and an organic functional group to coat the first layer and thereby form the passivated pigment slurry. The passivated pigment slurry includes the resin and a passivated pigment including the plurality of flakes each coated with a second layer disposed on the first layer.

Abstract: A method of forming a passivated pigment slurry includes combining a resin and a pigment to form a pigment-resin slurry, wherein the pigment includes a plurality of flakes each having a surface. After combining, the method includes mixing the pigment-resin slurry and an orthosilicate to form a coated pigment-resin slurry. The coated pigment-resin slurry includes the resin and a coated pigment including the plurality of flakes each encapsulated by a first layer formed from silica and disposed on the surface. The method further includes reacting the coated pigment-resin slurry and an organosilane compound having a hydrolysable group and an organic functional group to coat the first layer and thereby form the passivated pigment slurry. The passivated pigment slurry includes the resin and a passivated pigment including the plurality of flakes each coated with a second layer disposed on the first layer.