Abstract: A thermosettable coating composition comprises a reaction product of a polyurethane polymer having at least one pendant carbamate functional group and a crosslinker reactive with the at least one pendant carbamate functional group. The polyurethane polymer is a polymerization reaction product of at least one diol having a primary carbamate functional group and at least one polyisocyanate. A method of forming a thermosettable coating composition includes polymerizing a mixture to form the polyurethane polymer, and combining the polyurethane polymer and a crosslinker reactive with the at least one pendant carbamate functional group to form the thermosettable coating composition. A coated article formed from the thermosettable coating composition is also disclosed.

Abstract: A method of forming a passivated pigment slurry includes combining a resin and a pigment to form a pigment-resin slurry, wherein the pigment includes a plurality of flakes each having a surface. After combining, the method includes mixing the pigment-resin slurry and an orthosilicate to form a coated pigment-resin slurry. The coated pigment-resin slurry includes the resin and a coated pigment including the plurality of flakes each encapsulated by a first layer formed from silica and disposed on the surface. The method further includes reacting the coated pigment-resin slurry and an organosilane compound having a hydrolysable group and an organic functional group to coat the first layer and thereby form the passivated pigment slurry. The passivated pigment slurry includes the resin and a passivated pigment including the plurality of flakes each coated with a second layer disposed on the first layer.

Abstract: Described is a high solids coating composition having exceptional rheological properties and appearances comprising (a) a thermosetting binder, (b) from about 0.1 to about 10 wt. % based on binder solids of solid polyurea particles prepared by the reaction of a mixture of a polyisocyanate and an amino reactant comprising a primary or secondary monoamine that optionally has a hydroxyl or ether group or both, and (c) from about 2 to about 25 wt. % on resin solids of an acrylic polymer having a number average molecular weight of from about 2000 to about 8000 and a glass transition temperature of from about 50 to about 120° C.

Abstract: A coating system includes a clear coat layer and a sealant. The clear coat layer is formed from a clear coat composition that comprises a crosslinkable carbamate-functional resin and an aminoplast. Optionally, the coating system further includes a sub-clear coat layer. The sealant is bonded to the clear coat layer opposite the sub-clear coat layer. Optionally, the coating system further includes a tie coat layer and that is disposed between the sealant and the clear coat layer. An adhesion promoter is present in the clear coat composition in an amount of less than or equal to about 3% by weight based on the total weight of resin solids of the clear coat composition. Further, the adhesion promoter is present in at least one of the sub-clear coat composition and the tie coat composition in an amount sufficient to increase adhesion between the clear coat layer and the sealant.

Abstract: Described is a high solids coating composition having exceptional rheological properties and appearances comprising (a) a thermosetting binder, (b) from about 0.1 to about 10 wt. % based on binder solids of solid polyurea particles prepared by the reaction of a mixture of a polyisocyanate and an amino reactant comprising a primary or secondary monoamine that optionally has a hydroxyl or ether group or both, and (c) from about 2 to about 25 wt. % on resin solids of an acrylic polymer having a number average molecular weight of from about 2000 to about 8000 and a glass transition temperature of from about 50 to about 120° C.

Abstract: A method of curing a coating composition and a method of forming a cured coating on an automobile component are provided. The coating composition comprises a radical polymerizable compound and an organoborane-amine complex having an organoborane initiator, an amine blocking agent, and water. The method of curing the coating composition comprises the steps of combining the organoborane-amine complex, the radical polymerizable compound, and water to form the coating composition. Carbon dioxide is introduced into the coating composition or into a composition including at least one of the organoborane-amine complex, the radical polymerizable compound, and water prior to forming the coating composition. Carbonic acid is formed in situ within the coating composition through reaction of the water and carbon dioxide. The organoborane-amine complex is decomplexed with the carbonic acid thereby separating the organoborane initiator and the amine blocking agent.

Abstract: A high solids, non-aqueous dispersion, clearcoat composition is disclosed, comprising a functional polymer selected from the group consisting of a) carbamate-functional polymers and b) hydroxyl-functional polymers; c) a curing agent selected from the group consisting of aminoplast resins and blocked polyisocyanates; and d) a weak non-polar solvent, wherein the coating is high solids, substantially clear and transparent, and further comprises a dispersed phase and a continuous phase.

Abstract: A method of curing a coating composition and a method of forming a cured coating on an automobile component are provided. The coating composition comprises a radical polymerizable compound and an organoborane-amine complex having an organoborane initiator, an amine blocking agent, and water. The method of curing the coating composition comprises the steps of combining the organoborane-amine complex, the radical polymerizable compound, and water to form the coating composition. Carbon dioxide is introduced into the coating composition or into a composition including at least one of the organoborane-amine complex, the radical polymerizable compound, and water prior to forming the coating composition. Carbonic acid is formed in situ within the coating composition through reaction of the water and carbon dioxide. The organoborane-amine complex is de-complexed with the carbonic acid thereby separating the organoborane initiator and the amine blocking agent.

Abstract: A paint coating system comprises a substrate and a first paint layer disposed on the substrate. The first paint layer is formed from a first composition comprising either a first decomplexing agent or a first organoborane complex. The paint coating system further comprises a second paint layer disposed on the first paint layer. The second paint layer is formed from a second composition comprising the other of the first decomplexing agent and the first organoborane complex. At least one of the first and second compositions further comprises a radical polymerizable compound. A method of producing a multilayered paint coating includes the steps of providing the substrate, applying a first paint layer on the substrate, applying a second paint layer on the first paint layer, and curing the at least one of the first and second paint layers.

Abstract: A coating composition comprises a crosslinkable carbamate-functional resin and an aminoplast. The aminoplast comprises the reaction product of an aldehyde and a melamine. The aminoplast has a content of imino groups of less than or equal to about 10%, a content of alkylol groups of at least about 7%, and a remainder of groups being alkoxyalkyl groups, all based on a total number of reactive sites present in the melamine prior to reaction. A coating system includes a clear coat layer that comprises the reaction product of the crosslinkable carbamate-functional resin and the aminoplast. Threshold adhesion strength, in accordance with MVSS standards, can be achieved between glass and the coating system when the crosslinkable carbamate-functional resin and the specific aminoplast set forth above are reacted to form the clear coat layer, while minimizing problems associated with high viscosity of aminoplasts having a high content of imino groups of greater than 10%.

Abstract: A coating composition is used to form a clearcoat layer of a film system including a basecoat layer and the clearcoat layer. The coating composition includes a carbamate functional polymer, a cross-linking agent reactive with the carbamate functional polymer, and an acid functional polymer substantially non-reactive with the carbamate functional polymer and the cross-linking agent. The acid functional polymer has an acid value of at least 50 mg KOH/g and contributes to an increased resistance to acid etch of the clearcoat layer. The acid functional polymer also contributes to an increased intercoat adhesion of the basecoat layer and the clearcoat layer thereby decreasing a possibility of separation/delamination of the basecoat layer and the clearcoat layer.

Abstract: A coating system includes a clear coat layer and a sealant. The clear coat layer is formed from a clear coat composition that comprises a crosslinkable carbamate-functional resin and an aminoplast. Optionally, the coating system further includes a sub-clear coat layer that is formed from a sub-clear coat composition. The sealant is bonded to the clear coat layer opposite the sub-clear coat layer. Optionally, the coating system further includes a tie coat layer that is formed from a tie coat composition and that is disposed between the sealant and the clear coat layer. An adhesion promoter is present in the clear coat composition in an amount of less than or equal to about 3% by weight based on the total weight of resin solids of the clear coat composition. Further, the adhesion promoter is present in at least one of the sub-clear coat composition and the tie coat composition in an amount sufficient to increase adhesion between the clear coat layer and the sealant.

Abstract: A technique of treating an automotive coating to modify surface-specific physical properties thereof while retaining bulk physical properties of the automotive coating includes the step of generating a plasma discharge in a plasma generating assembly. The automotive coating is treated with the plasma discharge. The automotive coating is completely cured prior to treatment with the plasma discharge. To treat the automotive coating, either 1) a precursor material is introduced into the plasma discharge to form a thin film on the automotive coating, or 2) the plasma discharge is free of a precursor material and weak bonds are destroyed on or near the surface of the automotive coating.

Abstract: The present invention provides a method of preparing an organosol of inorganic particles, comprising mixing an aqueous dispersion or sol of inorganic particles with an organic liquid and a polymer or oligomer having functionality that adsorbs onto the inorganic particles; and allowing the mixture to separate into an aqueous layer and an organic layer, the organic layer comprising the inorganic particles. The invention also provides a polymer composition or coating composition made by this method. A coating composition is applied to a substrate and cured to provide a coating layer on the substrate. A polymer composition containing the inorganic particles is molded into an article.

Abstract: A coating composition, particularly a clearcoat composition, which may be a two-component clearcoat composition, comprises a film-forming material, a crosslinking agent, and a nonlinear polysiloxane polymer having a functional group reactive with the crosslinking agent. The coating composition exhibits excellent scratch resistance and adhesion of repair coating layers and sealants, such as windshield sealants.

Abstract: A coating composition comprises a crosslinkable carbamate-functional resin and an aminoplast. The aminoplast comprises the reaction product of an aldehyde and a melamine. The aminoplast has a content of imino groups of less than or equal to about 10%, a content of alkylol groups of at least about 7%, and a remainder of groups being alkoxyalkyl groups, all based on a total number of reactive sites present in the melamine prior to reaction. A coating system includes a clear coat layer that comprises the reaction product of the crosslinkable carbamate-functional resin and the aminoplast. Threshold adhesion strength, in accordance with MVSS standards, can be achieved between glass and the coating system when the crosslinkable carbamate-functional resin and the specific aminoplast set forth above are reacted to form the clear coat layer, while minimizing problems associated with high viscosity of aminoplasts having a high content of imino groups of greater than 10%.

Abstract: A compound in which n is 0, 1, 2, or 3; R1, R2, R7, and R8 are each independently alkyl group, including cycloalkyl, an alkylaryl group, or an aryl group, optionally with one or more heteroatoms, with the proviso that R1 and R2 can together form a cycloalkylene group and, independently, R7 and R8 can together form a cycloalkylene group; Y is an oxygen free radical, a sulfur free radical, OR9 or SR9; R3, R4, R5, R6, and R9 are each independently H or an alkyl group, a cycloalkyl group, an aryl group, or an alkylaryl group, optionally with one or more heteroatoms; and compositions, such as basecoat and clearcoat coating compositions, containing such compounds.

Abstract: The present invention provides a test method for simulating outdoor exposure conditions for testing a coated substrate to evaluate environmental etching of paint caused by acid rain. The test method requires that the test substrate have an acid solution having a pH of less than 6.0 applied thereto by spray or in atomized droplets. The substrate is held in a substantially horizontal position of less than 15° to the horizontal and exposed to heat of above a black panel temperature of 30° C. and light during testing. The light source must emit light in the spectral distribution of at least visible and ultraviolet light, including the spectral distribution of sunlight. Following exposure to testing the substrate is evaluated for environmental etch.

Abstract: A two-component solvent-borne clearcoat composition comprising an unblocked acid catalyst, a film-forming binder, and an aminoplast crosslinking agent (e.g., a melamine formaldehyde crosslinking agent) surprisingly provides enhanced appearance when compared to a one-component clearcoating composition containing blocked acid catalyst cured at temperatures above 121° C. (250° F.).

Abstract: A coating composition comprises a thermosetting binder, comprising a crosslinker, a first, hard material having functionality reactive with the crosslinker, and a second, soft material having functionality reactive with the crosslinker. The first, hard material is a polymer, oligomer or compound, the first material having a glass transition temperature of at least 40° C., a number average molecular weight of 2000 or less, and an equivalent weight of 150 to 600 grams per equivalent of functionality reactive with the crosslinker. The second, soft material is a compound that is an amorphous mixture of four or more isomers, near isomers, and/or homologous structures and has from two to four functional groups that form thermally irreversible linkages with the crosslinker under cure conditions, wherein each functional group is separated from each other functional group by at least four atoms.