Abstract: The invention provides for compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein the composition comprises a post-contacted organometal compound, a post-contacted organoaluminum compound, and a post-contacted solid oxide compound treated with boron and fluoride.

Abstract: This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition comprises contacting a organometal compound/organoaluminum mixture, a treated solid oxide compound, and, optionally, a second organoaluminum compound.

Abstract: Novel catalyst systems which comprise diimine nickel complexes comprising additional ligands selected from the group consisting of acetylacetonate, hexaflourylacetylacetonate, halogens and mixtures thereof can be used with methylaluminoxane in slurry polymerization processes to polymerize mono-1-olefins and, optionally one or more higher mono-1-olefin comonomer(s), to produce high molecular weight polymers.

Abstract: This invention provides a process for producing a catalyst composition comprising contacting at least one group 4 metallocene, at least one organoaluminum compound, and at least one solid. The solid is selected from the group consisting of titanium tetrafluoride, zirconium tetrafluoride, and a treated solid oxide compound. The treated solid oxide compound comprises a solid oxide compound having titanium tetrafluoride or zirconium tetrafluoride deposited on the surface of the solid oxide compound. The solid oxide compound comprises oxygen and at least one element selected from the group consisting of groups 2-9 and 11-17 of the Periodic Table of Elements, including lanthanides and actinides. This invention also provides the catalyst composition produced by this process.

Abstract: A process to produce a propylene polymer is provided. The process comprising contacting at least one organometal compound, at least one organoaluminum compound, at least one treated solid oxide compound, propylene, and ethylene in a polymerization zone under polymerization conditions to produce the propylene polymer.

Abstract: This invention is directed to an organometal compound catalyst that is useful for polymerizing at least one monomer to produce a polymer. The catalyst is produced by combining a titanium, zirconium or hafnium organometal compound, preferably a metallocene, at least one organoaluminum compound, and a treated solid oxide. The treated solid oxide compound contains at least one halogen, zirconium and a solid oxide compound.

Abstract: This invention provides a catalyst composition for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition comprises an organometal compound, an organoaluminum compound, and a treated solid oxide compound comprising nickel, a halogen, and a solid oxide compound.

Abstract: A process to produce a first catalyst composition is provided. The process comprises contacting at least one first organometal compound, oxygen bridged mono-cyclopentadienyl transition metal dimer, and at least one activator to produce the first catalyst composition. The activator is selected from the group consisting of aluminoxanes, fluoro-organo borates, and treated solid oxide components in combination with at least one organoaluminum compound. In another embodiment of this invention, a process to produce a second catalyst composition for producing bimodal polymers is provided. The process comprises contacting at least one first organometal compound, at least one activator, and at least one second organometal compound to produce the second catalyst composition. The first and second catalyst compositions are also provided as well as polymerization processes using these compositions to produce polymers.

Abstract: This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition comprises contacting a organometal compound/organoaluminum mixture, a treated solid oxide compound, and, optionally, a second organoaluminum compound. The solid oxide has been treated with an electron-withdrawing compound, in particular a chlorine, preferably zinc chloride and carbon tetrachloride.

Abstract: Novel catalyst systems which comprise diimine nickel complexes comprising additional ligands selected from the group consisting of acetylacetonate, hexaflourylacetylacetonate, halogens and mixtures thereof can be used with methylaluminoxane in slurry polymerization processes to polymerize mono-1-olefins and, optionally one or more higher mono-1-olefin comonomer(s), to produce high molecular weight polymers.

Abstract: This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition comprises a post-contacted organometal compound, a post-contacted organoaluminum compound, and a post-contacted fluorided solid oxide compound.

Abstract: Bridged and unbridged fluorenyl-containing metallocenes of the formula R″x(FlRn)(CpRm)MQk wherein Fl is a fluorenyl radical, Cp is a cyclopentadienyl, indenyl, tetrahydroindenyl, or fluorenyl radical, each R is an organo radical, R″ is a structural bridge linking (FlRn) and (CpRm), M is a metal selected from the group consisting of IVB, VB, and VIB metals, each Q is selected from the group consisting of hydrocarbyl or hydrocarbyloxy radicals and halogen, x is 1 or 0, k is an integer sufficient to fill out the remaining valences of M, n is in the range of 0 to 7, and m is 0 to 7, further characterized by the fact that if (CpRm) is unsubstituted fluorenyl and metallocene is an unbridged metallocene, then n is 1 to 7 and if R″ is 1,1-dimethylmethylene and (CpRm) is unsubstituted cyclopentadienyl or 3-methylcyclopentadienyl, then n is 1 to 7.

Abstract: This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition comprises a post-contacted organometal compound, a post-contacted organoaluminum compound, and a post-contacted fluorided silica-alumina.

Abstract: Bridged fluorenyl-containing metallocenes of metals of Groups 4-6 and their use in forming homopolymers of alpha olefins or polymers of ethylene and optionally minor amounts of alpha olefins, wherein in each case at least one of the cyclic groups of the bridged ligand is a fluorenyl and the other is selected from indenyl, tetrahydroindenyl, fluorenyl, and in the case of the polymerization of ethylene optionally cyclopentadienyl.

Abstract: This invention provides catalyst composition for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition comprises as organometal compound, as organoaluminum compound, and a fluorided solid oxide compound.

Abstract: This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition comprises a post-contacted organometal compound, a post-contacted organoaluminum compound, and a post-contacted treated solid oxide compound. The post-contacted treated solid oxide compound has been treated with a vanadium compound, calcied, then treated with a halogen-containing compound.

Abstract: This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce said polymer, wherein said catalyst composition comprises a post-contacted organometal compound, a post-contacted organoaluminum compound, and a post-contacted treated solid oxide compound.

Abstract: This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition comprises a post-contacted organometal compound, a post-contacted organoaluminum compound, and a post-contacted fluorided silica-alumina.

Abstract: Novel catalyst systems which comprise diimine nickel complexes comprising additional ligands selected from the group consisting of acetylacetonate, hexaflourylacetylacetonate, halogens and mixtures thereof can be used with methylaluminoxane in slurry polymerization processes to polymerize mono-1-olefins and, optionally one or more higher mono-1-olefin comonomer(s), to produce high molecular weight polymers.

Abstract: This invention provides a compositions that are useful for polymerizing at least one monomer into at least one polymer.