Abstract: A method of manufacturing a gate electrode of a MOS transistor including a tungsten carbon nitride layer is disclosed. After a high dielectric layer is formed on a substrate, a source gas including tungsten amine derivative flows onto the high dielectric layer. A tungsten carbon nitride layer is formed on the high dielectric layer by decomposing the source gas. Thereafter, a gate electrode is formed by patterning the tungsten carbon nitride layer. According to the present invention, a gate electrode having a work function of over 4.9 eV is formed.

Abstract: In a semiconductor device with dual gates and a method of manufacturing the same, a dielectric layer and first and second metallic conductive layers are successively formed on the semiconductor substrate having first and second regions. The second metallic conductive layer which is formed on the first metallic conductive layer of the second region is etched to form a metal pattern. The first metallic conductive layer is etched using the metal pattern as an etching mask. A polysilicon layer is formed on the dielectric layer and the metal pattern. The first gate electrode is formed by etching portions of the polysilicon layer, the metal pattern, and the first metallic conductive layer of the first region. The second gate electrode is formed by etching a portion of the polysilicon layer formed directly on the dielectric layer of the second region.

Abstract: A semiconductor device having a dual gate is formed on a substrate having a dielectric layer. A first metallic conductive layer is formed on the dielectric layer to a first thickness, and annealed to have a reduced etching rate. A second metallic conductive layer is formed on the first metallic conductive layer to a second thickness that is greater than the first thickness. A portion of the second metallic conductive layer formed in a second area of the substrate is removed using an etching selectivity. A first gate structure having a first metallic gate including the first and the second metallic conductive layers is formed in a first area of the substrate. A second gate structure having a second metallic gate is formed in the second area. A gate dielectric layer is not exposed to an etching chemical due to the first metallic conductive layer, so its dielectric characteristics are not degraded.

Abstract: In some embodiments of the present invention, methods of forming a tantalum carbon nitride layer include introducing a source gas including a tantalum metal complex onto a substrate, wherein one or more of the ligands of the tantalum metal complex include nitrogen and one or more of the ligands of the tantalum metal complex include carbon; and thermally decomposing the tantalum metal complex to form a tantalum carbon nitride layer on the substrate. In some embodiments, the tantalum metal complex includes Ta(NR1)(NR2R3)3, wherein R1, R2 and R3 are each independently H or a C1-C6 alkyl group. In some embodiments, the tantalum metal complex may be [Ta(?NC(CH3)2C2H5)(N(CH3)2)3]. Methods of forming a gate structure, methods of manufacturing dual gate electrodes and methods of manufacturing a capacitor including tantalum carbon nitride are also provided herein.

Abstract: In a gate structure and a method of forming the same, a first conductive pattern is formed on a substrate and comprises a metal-containing material. A second conductive pattern is formed on the first conductive pattern, and the second conductive pattern comprises metal and silicon. A third conductive pattern is formed on the second conductive pattern, and the third conductive pattern comprises polysilicon. A gate conductive pattern of an n-type metal-oxide semiconductor (NMOS) transistor, a p-type MOS (PMOS) transistor and a complementary MOS (CMOS) transistor includes the gate structure.

Abstract: Provided herein is a non-volatile semiconductor device that includes a tunnel insulation layer pattern formed on a semiconductor substrate, a charge trapping layer pattern formed on the tunnel insulation layer pattern, a blocking dielectric layer pattern formed on the charge trapping layer pattern and a tantalum carbon nitride layer pattern formed on the blocking dielectric layer pattern. The tantalum carbon nitride layer pattern may be formed by a CVD process using a source gas including a tantalum metal complex, wherein one or more of ligands of the tantalum metal complex include nitrogen and carbon. Since the non-volatile semiconductor device includes the tantalum carbon nitride layer pattern as an electrode, the non-volatile semiconductor device according to embodiments of the invention may have improved response speed and require relatively low driving voltage.

Abstract: A semiconductor device has two transistors of different structure from each other. One of transistors is P-type and the other is N-type. One of the transistors includes a gate structure in which a polysilicon layer contacts a gate insulation film while the other transistor includes a gate structure in which a metal layer contacts a gate insulation film.

Abstract: A semiconductor device comprising a semiconductor substrate having a first impurity region and a second impurity region, a first gate pattern formed on the first impurity region, and a second gate pattern formed on the second impurity region is disclosed. The first gate pattern comprises a first gate insulation layer pattern, a metal layer pattern having a first thickness, and a first polysilicon layer pattern. The second gate pattern comprises a second gate insulation layer pattern, a metal silicide layer pattern having a second thickness smaller than the first thickness, and a second polysilicon layer pattern. The metal silicide layer pattern is formed from a material substantially the same as the material from which the metal layer pattern is formed. A method for manufacturing the semiconductor device is also disclosed.

Abstract: Methods of forming a composite layer, a gate structure and a capacitor are disclosed. In the methods, a first dielectric layer is atomic layer deposited on a substrate by using an oxidation gas and a first precursor gas that includes hafnium precursors. A second dielectric layer is then atomic layer deposited on the first dielectric layer by using a nitriding gas and a second precursor gas that includes hafnium precursors.

Abstract: A dielectric region, such as a ferroelectric dielectric region of an integrated circuit capacitor, is protected by a multi-layer insulation structure including a first relatively thin insulation layer, e.g., an aluminum oxide or other metal oxide layer, and a second, thicker insulating layer, e.g., a second aluminum oxide or other metal oxide layer. Before formation of the second insulation layer, the first insulation layer and the dielectric preferably annealed, which can increase a remnant polarization of the dielectric region. The first insulation layer can serve as a hydrogen diffusion barrier during formation of the second insulation layer and other overlying structures. In this manner, degradation of the dielectric can be reduced. Devices and fabrication methods are discussed.

Abstract: A method of forming transistor gate structures in an integrated circuit device can include forming a high-k gate insulating layer on a substrate including a first region to include PMOS transistors and a second region to include NMOS transistors. A polysilicon gate layer can be formed on the high-k gate insulating layer in the first and second regions. A metal silicide gate layer can be formed directly on the high-k gate insulating layer in the first region and avoiding forming the metal-silicide in the second region. Related gate structures are also disclosed.

Abstract: Some methods that are provided form a composite dielectric structure on a substrate. A first dielectric layer that includes metal and oxygen is formed on a substrate. A preliminary dielectric layer that includes silicon is formed on the first dielectric layer. A plasma nitriding treatment is performed on the preliminary dielectric layer to change it into a second dielectric layer. The composite dielectric structure includes the second dielectric layer and the first dielectric layer. Other methods form a semiconductor device that includes the composite dielectric structure.

Abstract: Integrated circuit devices are manufactured by exposing at least a portion of an insulation layer that comprises oxygen to a metal precursor that is reactive with oxygen so as to form a metal oxide layer on the portion of the insulation layer. The metal oxide layer may reduce the diffusion of impurities, such as hydrogen, into the insulation layer, which may degrade the electrical characteristics of the insulation layer.

Abstract: Integrated circuit devices are manufactured by exposing at least a portion of an insulation layer that comprises oxygen to a metal precursor that is reactive with oxygen so as to form a metal oxide layer on the portion of the insulation layer. The metal oxide layer may reduce the diffusion of impurities, such as hydrogen, into the insulation layer, which may degrade the electrical characteristics of the insulation layer.

Abstract: A dielectric region, such as a ferroelectric dielectric region of an integrated circuit capacitor, is protected by a multi-layer insulation structure including a first relatively thin insulation layer, e.g.,. an aluminum oxide or other metal oxide layer, and a second, thicker insulating layer, e.g., a second aluminum oxide or other metal oxide layer. Before formation of the second insulation layer, the first insulation layer and the dielectric preferably annealed, which can increase a remnant polarization of the dielectric region. The first insulation layer can serve as a hydrogen diffusion barrier during formation of the second insulation layer and other overlying structures. In this manner, degradation of the dielectric can be reduced. Devices and fabrication methods are discussed.

Abstract: A dielectric region, such as a ferroelectric dielectric region of an integrated circuit capacitor, is protected by a multi-layer insulation structure including a first relatively thin insulation layer, e.g., an aluminum oxide or other metal oxide layer, and a second, thicker insulating layer, e.g., a second aluminum oxide or other metal oxide layer. Before formation of the second insulation layer, the first insulation layer and the dielectric preferably annealed, which can increase a remnant polarization of the dielectric region. The first insulation layer can serve as a hydrogen diffusion barrier during formation of the second insulation layer and other overlying structures. In this manner, degradation of the dielectric can be reduced. Devices and fabrication methods are discussed.

Abstract: A semiconductor memory device having a capacitor protection layer and a method for manufacturing the same. A capacitor of the semiconductor memory device is entirely covered with an encapsulating layer having a multi-layered structure. The encapsulating layer comprises at least a blocking layer and a capacitor protection layer, each of which is formed of different materials. The blocking is formed of a material capable of preventing a capacitor dielectric layer from volatilizing and/or capable of preventing a reaction between a material layer under the blocking layer and the capacitor protection layer. The capacitor protection layer is formed of a material layer capable of preventing diffusion of hydrogen into the capacitor dielectric layer. In addition, the semiconductor memory device may has a hydrogen barrier layer as another capacitor protection layer, between the capacitor and a passivation layer.

Abstract: A dielectric region, such as a ferroelectric dielectric region of an integrated circuit capacitor, is protected by a multi-layer insulation structure including a first relatively thin insulation layer, e.g., an aluminum oxide or other metal oxide layer, and a second, thicker insulating layer, e.g., a second aluminum oxide or other metal oxide layer. Before formation of the second insulation layer, the first insulation layer and the dielectric preferably annealed, which can increase a remnant polarization of the dielectric region. The first insulation layer can serve as a hydrogen diffusion barrier during formation of the second insulation layer and other overlying structures. In this manner, degradation of the dielectric can be reduced. Devices and fabrication methods are discussed.

Abstract: Integrated circuit devices are manufactured by exposing at least a portion of an insulation layer that comprises oxygen to a metal precursor that is reactive with oxygen so as to form a metal oxide layer on the portion of the insulation layer. The metal oxide layer may reduce the diffusion of impurities, such as hydrogen, into the insulation layer, which may degrade the electrical characteristics of the insulation layer.

Abstract: Methods of forming integrated circuit capacitors include the steps of forming a capacitor comprising first and second electrodes and a dielectric layer between the first and second electrodes, on a substrate. A step is then performed to expose at least one of the dielectric layer and the second electrode to an ECR plasma for a duration of sufficient length to improve charge leakage characteristics of the integrated circuit capacitor. The dielectric layer may comprise STO, BST, PZT, SBT PLZT and BTO, for example. This exposing step may include the step of selectively exposing the second electrode, but not the ferroelectric dielectric layer, to the ECR plasma. The exposing step also preferably includes simultaneously maintaining the substrate at a temperature below about 700.degree. C.