Abstract: An electrochemical fuel cell stack with improved reactant manifolding and sealing includes a pair of separator plates interposed between adjacent membrane electrode assemblies. Passageways fluidly interconnecting the anodes to a fuel manifold and interconnecting the cathodes to an oxidant manifold are formed between adjoining non-active surfaces of the pairs of separator plates. The passageways extend through one or more ports penetrating the thickness of one of the plates thereby fluidly connecting the manifold to the opposite active surface of that plate, and the contacted electrode. The non-active surfaces of adjoining separator plates in a fuel cell stack cooperate to provide passageways for directing both reactants from respective stack fuel and oxidant supply manifolds to the appropriate electrodes. The fuel and oxidant reactant streams passageways are fluidly isolated from each other, although they both traverse adjoining non-active surfaces of the same pair of plates.

Abstract: Reactant gas supply streams for solid polymer fuel cells may be heated and humidified using heat generated by the fuel cell and water vapor from the fuel cell exhaust. The heat and water vapor in the oxidant exhaust stream are sufficient to heat and humidify a reactant gas supply stream, preferably the oxidant supply stream. The heating and humidifying can be accomplished by flowing a reactant gas supply stream and a fuel cell exhaust gas stream on opposite sides of a water permeable membrane in a combined heat and humidity exchange apparatus. The method and apparatus are particularly suitable for use with air-cooled fuel cell systems and systems which employ near ambient pressure air as the oxidant gas supply.

Abstract: An electrochemical fuel cell stack with improved reactant man folding and sealing includes a pair of separator plates interposed between adjacent membrane electrode assemblies. Passageways fluidly interconnecting the anodes to a fuel manifold and interconnecting the cathodes to an oxidant manifold are formed between adjoining non-active surfaces of the pairs of separator plates. The passageways extend through one or more ports penetrating the thickness of one of the plates thereby fluidly connecting the manifold to the opposite active surface of that plate, and the contacted electrode. The non-active surfaces of adjoining separator plates in a fuel cell stack cooperate to provide passageways for directing both reactants from respective stack fuel and oxidant supply manifolds to the appropriate electrodes. The fuel and oxidant reactant streams passageways are fluidly isolated from each other, although they both traverse adjoining non-active surfaces of the same pair of plates.

Abstract: Certain fuel cells (e.g., solid polymer electrolyte fuel cells) may temporarily exhibit below normal performance after initial manufacture or after prolonged storage. While normal performance levels may be obtained after operating such fuel cells for a suitable time period, this process can take of order of days to fully complete. However, various conditioning and/or maintenance techniques are disclosed that provide for normal performance levels without the need for a lengthy initial operating period.

Abstract: An electrochemical fuel cell stack with improved reactant man folding and sealing includes a pair of separator plates interposed between adjacent membrane electrode assemblies. Passageways fluidly interconnecting the anodes to a fuel manifold and interconnecting the cathodes to an oxidant manifold are formed between adjoining non-active surfaces of the pairs of separator plates. The passageways extend through one or more ports penetrating the thickness of one of the plates thereby fluidly connecting the manifold to the opposite active surface of that plate, and the contacted electrode. The non-active surfaces of adjoining separator plates in a fuel cell stack cooperate to provide passageways for directing both reactants from respective stack fuel and oxidant supply manifolds to the appropriate electrodes. The fuel and oxidant reactant streams passageways are fluidly isolated from each other, although they both traverse adjoining non-active surfaces of the same pair of plates.

Abstract: A vehicle includes a traction unit capable of delivering mechanical power for driving the vehicle; electric loads; and a fuel cell system for supplying the electric loads with electric power. The fuel cell system includes a fuel cell stack with an anode input line, an anode exhaust line, a cathode input line, and an cathode exhaust line. A compression/expansion loop is employed in the cathode exhaust line. The expansion side of the compression/expansion loop is in thermal contact with the cathode exhaust to cool the cathode exhaust and to transfer the heat of the exhaust to the compression side of the compression/expansion loop at a higher temperature level. A water separator is arranged in the cathode exhaust line for collecting water vapor of product water that is carried in the cathode exhaust and is recycled to the fuel cell system.

Abstract: A vehicle includes a traction unit capable of delivering mechanical power for driving the vehicle; electric loads; and a fuel cell system for supplying the electric loads with electric power. The fuel cell system includes a fuel cell stack with an anode input line, an anode exhaust line, a cathode input line, and an cathode exhaust line. A compression/expansion loop is employed in the cathode exhaust line. The expansion side of the compression/expansion loop is in thermal contact with the cathode exhaust to cool the cathode exhaust and to transfer the heat of the exhaust to the compression side of the compression/expansion loop at a higher temperature level. A water separator is arranged in the cathode exhaust line for collecting water vapor of product water that is carried in the cathode exhaust and is recycled to the fuel cell system.

Abstract: An improved membrane electrode assembly (“MEA”) comprises coextensive ion exchange membrane and electrode layers and a resilient fluid impermeable integral seal comprising a sealant material impregnated into the porous electrode layers in the sealing regions. The integral seal preferably circumscribes the electrochemically active area of the MEA. The integral seal preferably also extends laterally beyond the edge of the MEA. An integral seal may also be provided around any openings, such as external manifold openings formed outside the MEA. Preferably, the uncured sealant material is a flow processable elastomer applied using an injection molding process. In preferred embodiments the seal has a plurality of spaced, parallel raised ribs with cross-ribs extending therebetween at spaced intervals. The raised ribs and cross-ribs provide compartmentalized seals that provide improved protection against fluid leaks.

Abstract: Reactant gas supply streams for solid polymer fuel cells may be heated and humidified using heat generated by the fuel cell and water vapor from the fuel cell exhaust. The heat and water vapor in the oxidant exhaust stream are sufficient to heat and humidify a reactant gas supply stream, preferably the oxidant supply stream. The heating and humidifying can be accomplished by flowing a reactant gas supply stream and a fuel cell exhaust gas stream on opposite sides of a water permeable membrane in a combined heat and humidity exchange apparatus. The method and apparatus are particularly suitable for use with air-cooled fuel cell systems and systems which employ near ambient pressure air as the oxidant gas supply.

Abstract: Reactant gas supply streams for solid polymer fuel cells may be heated and humidified using heat generated by the fuel cell and water vapor from the fuel cell exhaust. The heat and water vapor in the oxidant exhaust stream are sufficient to heat and humidify a reactant gas supply stream, preferably the oxidant supply stream. The heating and humidifying can be accomplished by flowing a reactant gas supply stream and a fuel cell exhaust gas stream on opposite sides of a water permeable membrane in a combined heat and humidity exchange apparatus. The method and apparatus are particularly suitable for use with air-cooled fuel cell systems and systems which employ near ambient pressure air as the oxidant gas supply.

Abstract: An electrochemical fuel cell stack with an improved compression assembly comprises a tension member which is electrically non-conductive and preferably non-metallic. The tension member can be made from a composite material which has similar expansion and contraction properties as the stack materials, thereby reducing undesirable fluctuations in the compressive force applied to the stack. An improved apparatus for securing the improved tension member to the rest of the compression assembly is also provided. Preferred embodiments of an improved compression assembly employ a collet and wedges to grip the tension member and compress a resilient member which imparts a tensile force to the tension member and a compressive force to the fuel cell assemblies. In other embodiments, an improved compression assembly employs a unitary resilient member and fastener in combination with a tension member.

Abstract: Reactant gas supply streams for solid polymer fuel cells may be heated and humidified using heat generated by the fuel cell and water vapor from the fuel cell exhaust. The heat and water vapor in the oxidant exhaust stream are sufficient to heat and humidify a reactant gas supply stream, preferably the oxidant supply stream. The heating and humidifying can be accomplished by flowing a reactant gas supply stream and a fuel cell exhaust gas stream on opposite sides of a water permeable membrane in a combined heat and humidity exchange apparatus. The method and apparatus are particularly suitable for use with air-cooled fuel cell systems and systems which employ near ambient pressure air as the oxidant gas supply.

Abstract: An electrochemical fuel cell stack with improved reactant manifolding and sealing includes a pair of separator plates interposed between adjacent membrane electrode assemblies. Passageways fluidly interconnecting the anodes to a fuel manifold and interconnecting the cathodes to an oxidant manifold are formed between adjoining non-active surfaces of the pairs of separator plates. The passageways extend through one or more ports penetrating the thickness of one of the plates thereby fluidly connecting the manifold to the opposite active surface of that plate, and the contacted electrode. The non-active surfaces of adjoining separator plates in a fuel cell stack cooperate to provide passageways for directing both reactants from respective stack fuel and oxidant supply manifolds to the appropriate electrodes. The fuel and oxidant reactant streams passageways are fluidly isolated from each other, although they both traverse adjoining non-active surfaces of the same pair of plates.

Abstract: An improved membrane electrode assembly ("MEA") comprises coextensive ion exchange membrane and electrode layers and a resilient fluid impermeable integral seal made by impregnating a sealing material into the porous electrode layers in the sealing regions. The integral seal preferably circumscribes the electrochemically active area of the MEA. In addition, the integral seal preferably extends laterally beyond the edge of the MEA, enveloping the peripheral region including the side edge of the MEA. The uncured sealant material is preferably a flow processable elastomer that is applied to the MEA using a vacuum injection molding process. In preferred embodiments, the seal has a plurality of spaced, parallel raised ribs with cross-ribs extending therebetween at spaced intervals. The parallel raised ribs and cross-ribs provide compartmentalized seals that provide improved protection against fluid leaks.

Abstract: An electrode comprises a first catalytic component active at gas-phase reaction sites and a second catalytic component active at electrochemical reaction sites wherein each catalytic component is present either as a separate layer, or a single mixed layer or a combination of a separate layer and a single mixed layer. The electrode has an improved tolerance to poisons such as carbon monoxide and carbon dioxide.

Abstract: A fuel cell assembly within an electrochemical fuel cell stack has an anode layer and a cathode layer. A cooling layer is disposed adjacent the fuel cell assembly. Each layer comprises channels for directing a fluid stream from an inlet to a an outlet. The coolant stream channels extend such that, in operation, the coolest region of the cooling layer coincides with the region of the cathode layer having the highest concentration of oxygen (and/or the lowest water content), and the warmest region of the cooling layer coincides with the region of the cathode layer having the lowest concentration of oxygen (and/or the highest water content).

Abstract: An electrochemical fuel cell assembly with compliant compression mechanism includes a first plate, a second plate, and at least one membrane electrode assembly disposed between the first and second plates. Compliant compression members, such as twisted wire springs or ribbon springs, extend between the first and second plates such that the compression members urge the first plate toward said second plate to compress each membrane electrode assembly interposed between the plates. In operation, compressive force is applied by the compression members to each membrane electrode assembly to maintain electrical conductivity.

Abstract: A fuel cell assembly within an electrochemical fuel cell stack has a cooling jacket disposed adjacent the cathode layer. The cooling layer comprises a coolant stream inlet, a coolant stream outlet, and at least one channel for directing a coolant stream from the coolant stream inlet to the coolant stream outlet. The coolant stream channels extend such that the coolest region of the cooling layer substantially coincides with the region of the adjacent cathode layer having the highest concentration of oxygen (and also the lowest water content), and the warmest region of the cooling layer substantially coincides with the region of the adjacent cathode layer having the lowest concentration of oxygen (and also the highest water content).

Abstract: An embossed fluid flow field plate for electrochemical cells comprises two sheets of compressible, electrically conductive material. Each sheet has two oppositely facing major surfaces. At least one of the major surfaces has an embossed surface which has a fluid inlet formed therein. The embossed surface has at least one open-faced channel embossed therein extending from the fluid inlet for conducting pressurized fluid introduced at the fluid inlet. A metal sheet is interposed between each of the compressible sheets. The compressible, electrically conductive sheet preferably comprises graphite foil. A method of fabricating an embossed separator plate for use in conjunction with an electrochemical fuel cell comprises (1) providing two sheets of compressible, electrically conductive sheet material, (2) interposing a metal sheet between each of the compressible sheets, and (3) embossing an open-faced channel in at least one of the surfaces of the sheets facing away from the metal sheet.

Abstract: An embossed fluid flow field plate for electrochemical cells comprises two sheets of compressible, electrically conductive material. Each sheet has two oppositely facing major surfaces. At least one of the major surfaces has an embossed surface which has a fluid inlet formed therein. The embossed surface has at least one open-faced channel embossed therein extending from the fluid inlet for conducting pressurized fluid introduced at the fluid inlet. A metal sheet is interposed between each of the compressible sheets. The compressible, electrically conductive sheet preferably comprises graphite foil.