Abstract: A cement composition comprises free-flowing spray-dried unreacted cement particles and a liquid binder. The spray-dried particles may include a poly acid. A method for making a cement composition using spray dried cement particles comprises a) providing cement particles, b) milling or sieving said cement particles so as to produce cement particles having a desired average size, c) adding a liquid carrier to said particles before or after milling so as to form a slurry, d) adding a poly acid to said particles while maintaining the pH of the slurry above about 6, and e) spray-drying the slurry. The resulting particles can be used in conjunction with a liquid binder to form a monolith having a desired shape.

Abstract: A method for creating a three-dimensional solid freeform fabrication object includes spreading a reactive powder on a substrate, selectively dispensing a core binder in the reactive powder to form a core material, and selectively dispensing a shell binder in the reactive powder to form a shell on the core material.

Abstract: Systems and methods which utilize a plurality of reactive build compositions differing from one another in at least one material property and which may be applied, individually and/or in combination, layer upon layer to form solid three-dimensional objects having regions which vary in the at least one material property are provided. Further provided are systems and methods which utilize a plurality of reactive build compositions differing from one another in at least one material property and which may be applied, individually and/or in combination, layer upon layer to form a plurality of three-dimensional objects in a single solid freeform fabrication build, at least one object of the plurality of objects having a material property which differs from the same material property of at least one other object fabricated in the same build. Further provided are three-dimensional objects formed utilizing the disclosed systems and methods.

Abstract: A printing device is provided, wherein the printing device includes a printing fluid reservoir configured to hold a volume of a printing fluid, a print head assembly configured to transfer the printing fluid to a printing medium, a conduit fluidically connecting the printing fluid reservoir and the print head assembly, and a printing fluid detector. The printing fluid detector includes first and second electrodes configured to be in contact with the printing fluid, and is configured to distinguish printing fluid from printing fluid froth by taking an impedance measurement across the first and second electrodes and comparing the impedance measurement to a froth threshold impedance value that is calibrated to a measured printing fluid temperature.

Abstract: An apparatus for use with an ink supply system of a printer includes a housing having an inlet, an outlet and a longitudinal fluid conduit extending therebetween. A fluid sensing device extends from a first side of the fluid conduit to an opposite side of the fluid conduit. A monitoring device is electrically coupled to the fluid sensing device for detecting changes in the fluid sensing device.

Abstract: Chemical compositions are disclosed. One exemplary composition, among others, includes: a basic component, an acidic component, at least one acrylate component, oxidizing agent, reducing agent, and a binder. The binder includes a viscosity modifier and a surface tension modifier. The binder is capable of stimulating a reaction between the basic component and the acidic component. A portion of the binder is capable of undergoing a polymerization reaction between at least one acrylate component, the oxidizing agent, and the reducing agent. The polymerization reaction being initiated by the redox reaction between the oxidizing agent and the reducing agent.

Abstract: Compositions, methods of using the compositions, and solid freeform fabrication (SFF) systems for producing three-dimensional objects are disclosed. One exemplary composition, among others, includes a basic component, an acidic component, at least one monoacrylate component, a light sensitive initiator, and a polar binder. A polymerization reaction between the at least one monoacrylate component and the light sensitive initiator occurs upon exposure to optical energy. The polar binder includes a viscosity modifier and a surface tension modifier. The polar binder is capable of stimulating a crosslinking reaction between the basic component and the acidic component.

Abstract: A fluid supply is provided, which includes a body defining a storage space configured to contain a fluid, a first electrode and a second electrode contained within the storage space and configured to be in direct contact with the fluid, wherein the first electrode and second electrode are configured to be connected to external power supply circuitry for applying an alternating signal across the first and second electrodes, and a first electrical contact in electrical communication with the first electrode and a second electrical contact in electrical communication with the second electrode. The first electrical contact and second electrical contact are to be connected to the external power supply circuitry and to detector circuitry for determining a measured impedance value of the fluid.

Abstract: The present invention is drawn toward compositions, methods, and systems for solid free-form fabrication of three-dimensional objects. In one embodiment, a system for solid free-form fabrication of three-dimensional objects can comprise a particulate composition, a substrate configured for supporting at least a layer of the particulate composition in a defined region, and a liquid phase binder configured for being jetted in the defined region to polymerize at least a portion of the particulate composition to form a polymeric cement. Using this system in a layer by layer deposition process, three-dimensional objects can be formed. The particulate composition can include from 70 wt % to 99.9 wt % of polymeric particulates, and from 0.1 wt % to 10 wt % of a polymerization initiator. The liquid phase binder can include from 70 wt % to 90 wt % of polymerizable monomers and from 0.1 wt % to 10 wt % of a polymerization accelerator.

Abstract: Solid freeform fabrication (SFF) systems for producing a three-dimensional object and methods of producing three-dimensional objects are disclosed. The SFF system includes a dispensing system including an alginate-based material that includes an alginate-based powder and a binder. The dispensing system is adapted to dispense the alginate-based material.

Abstract: A method for solid free-form fabrication of a three-dimensional object includes depositing a particulate blend in a defined region, the particulate blend including a calcium phosphate source, a reaction retardant, and a layered double hydroxide, and selectively ink-jetting a solubilizing binder onto a predetermined volume of the particulate blend to form a pre-ceramic object in the predetermined volume, wherein the solubilizing binder includes wetting agents, humectants, pH modifiers, and surfactants.

Abstract: A method for solid free-form fabrication of a three-dimensional object includes depositing a particulate blend in a defined region, the particulate blend including radical source particulates, polyacid particulates, multivalent cation particulates, and a calcium phosphate source particulates, ink-jetting a liquid phase binder onto a predetermined area of the particulate blend to form hydrated cement in the predetermined area, wherein the liquid phase binder is acidic and includes reactive monomers, and hardening the hydrated cement.

Abstract: A method for solid free-form fabrication of a three-dimensional object includes depositing a particulate blend in a defined region, the particulate blend including reactive glass ionomer particulates, cross-linkable polyacid particulates including polyvinyl pyrrolidone-co-polyacrylic acid, and nanocomposites, ink-jetting an aqueous phase binder onto a predetermined area of the particulate blend to form hydrated cement in the predetermined area, and hardening the hydrated cement.

Abstract: A method for solid free-form fabrication of a three-dimensional metal object includes depositing a particulate blend in a defined region, the particulate blend including a number of metal or metal alloy particulates and a peroxide, and selectively ink-jetting a binder system onto a predetermined area of the particulate blend to form a green part, wherein the liquid phase binder includes a water soluble monofunctional acrylate-based monomer, a water soluble difunctional acrylate-based monomer, an amine, and water.

Abstract: The present invention is drawn to solid freeform fabrication systems and methods for producing three-dimensional objects. The system can include build material configured to be deposited in layers to form a three-dimensional object; and support material configured to be deposited adjacent to the build material for supporting the build material during formation of the three-dimensional object. The support material can also be configured to form a feature that imparts a predetermined property within the three-dimensional object.

Abstract: The present invention is drawn toward systems and methods for free-form fabrication of solid three-dimensional objects. In one embodiment, a solid free-form fabrication system for producing a three-dimensional object can comprise a dispensing system adapted to dispense a build material having nanofiller particulates dispersed therein; and a curing system adapted to harden the build material after being dispensed. In another embodiment, a method for producing a three-dimensional object can comprise steps of a) forming a jettable build composition including build material having nanofiller particulates dispersed therein; b) jetting a portion of the build composition to form a build layer; c) curing the build layer; and d) repeating steps b) and c), wherein multiple build layers are contacted and accrued to form a three-dimensional object.

Abstract: A printing device is provided, which is configured to print a printing fluid onto a printing medium. The printing device includes a printing fluid reservoir configured to hold a volume of the printing fluid, a print head assembly configured to transfer the printing fluid to the printing medium, a conduit fluidically connecting the printing fluid reservoir to the print head assembly, and a printing fluid detector associated with the conduit. The printing fluid detector includes a first electrode and a second electrode coupled with the conduit and configured to be in contact with printing fluid in the conduit, a power supply configured to apply an alternating supply signal to the first electrode, and detector circuitry configured to detect a measured impedance value related to the presence of printing fluid within the conduit by comparing the alternating supply signal with a detected signal that has been modified from the applied signal by an impedance characteristic of the printing fluid.

Abstract: The present invention is drawn toward materials, methods and systems for solid free-form fabrication of three dimensional objects. In one embodiment, a method for solid free-form fabrication of a three-dimensional object can comprise steps of a) depositing a particulate composition including inorganic phosphate particulates in a defined region; b) ink-jetting an aqueous liquid onto a predetermined area of the particulate composition to form hydrated cement in the predetermined area; c) hardening the hydrated cement; and repeating steps a) through c) such that multiple layers of the cement are formed that are bound to one another, thereby forming the three dimensional object.

Abstract: Solid freeform fabrication (SFF) systems for producing a three-dimensional object and methods of producing three-dimensional objects are disclosed. One exemplary SFF system, among others, includes a dispensing system and a curing system. The dispensing system includes a norbornene based curable material and is adapted to dispense the norbornene based curable material. The curing system is operative to cure the norbornene based curable material.

Abstract: A system for separating materials of differing melting points includes an ultrasonic bath with a solution configured to remove a meltable material by cavitation, and an emulsifier disposed in the solution, wherein the emulsifier is configured to solubilize the meltable material thereby extending a useable life of the solution.