Patents by Inventor John T. Loper
John T. Loper has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20150024984Abstract: An engine oil comprising a major amount of a base oil and a minor amount of an additive package, wherein the additive package comprises at least one friction modifier represented by the formula: wherein R is selected from a hydrocarbyl group having 12 to 28 carbon atoms, a heteroatom containing hydrocarbyl having 12 to 32 carbon atoms, or a group represented by the formula: wherein R1 and R2 are independently selected from hydrocarbyl carbonyl moieties having 12 to 28 carbon atoms, or R1 and R2 form a hydrocarbon dicarbonyl containing ring with 12 to 32 carbon atoms, and R3 and R4 are independently selected from alkyl groups having 1 to 18 carbon atoms. Methods of using the engine oil to improve thin film and/or boundary layer friction in an engine are also provided.Type: ApplicationFiled: July 18, 2013Publication date: January 22, 2015Inventor: John T. Loper
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Publication number: 20150024985Abstract: A lubricating oil comprising a major amount of a base oil and a minor amount of an additive package, and the additive package comprises at least one friction modifier selected from compounds of the formulae II, III and IV, and carboxylate salts thereof: wherein R is a linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl having about 8 to about 28 carbon atoms, n is 0 or 1; and the carboxylate salts have a cation that is an alkali metal, alkaline earth metal, group IIB metal, or ammonium cation; and a dispersant and/or a detergent wherein said lubricating oil comprises at total of at least 5 wt. % of the dispersant and/or the detergent. Methods of using the engine oil to improve thin film and/or boundary layer friction in an engine are also provided.Type: ApplicationFiled: June 18, 2014Publication date: January 22, 2015Inventor: John T. Loper
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Publication number: 20150024986Abstract: A lubricating oil comprises a major amount of a base oil and a minor amount of an additive package, wherein the additive package comprises one or more friction modifiers including a reaction product of a hydroxy acid represented by HOCH2CO2H and an amine represented by the formula II: wherein R is a linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl having about 8 to about 22 carbon atoms; X is oxygen or —NH; and m is an integer from about 1 to about 4. The friction modifiers may include one or more compounds of the Formula I: wherein X is selected from oxygen, —NR1, and a glycolic amide moiety; and R and each R1 are independently selected from linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl having about 8 to about 22 carbon atoms and one but not both of R and R1 can be hydrogen; and m is an integer from about 1 to about 4. Methods of improving thin film and/or boundary layer friction are also provided.Type: ApplicationFiled: July 18, 2013Publication date: January 22, 2015Inventor: John T. Loper
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Patent number: 8927471Abstract: An engine oil comprising a major amount of a base oil and a minor amount of an additive package, wherein the additive package comprises at least one friction modifier represented by the formula: wherein R is selected from a hydrocarbyl group having 12 to 28 carbon atoms, a heteroatom containing hydrocarbyl having 12 to 32 carbon atoms, or a group represented by the formula: wherein R1 and R2 are independently selected from hydrocarbyl carbonyl moieties having 12 to 28 carbon atoms, or R1 and R2 form a hydrocarbon dicarbonyl containing ring with 12 to 32 carbon atoms, and R3 and R4 are independently selected from alkyl groups having 1 to 18 carbon atoms. Methods of using the engine oil to improve thin film and/or boundary layer friction in an engine are also provided.Type: GrantFiled: July 18, 2013Date of Patent: January 6, 2015Assignee: Afton Chemical CorporationInventor: John T. Loper
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Patent number: 8822392Abstract: A lubricating oil comprising a major amount of a base oil and a minor amount of an additive package, and the additive package comprises at least one friction modifier selected from compounds of the formulae II, III and IV, and carboxylate salts thereof: wherein R is a linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl having about 8 to about 28 carbon atoms, n is 0 or 1; and the carboxylate salts have a cation that is an alkali metal, alkaline earth metal, group IIB metal, or ammonium cation. Methods of using the engine oil to improve thin film and/or boundary layer friction in an engine are also provided.Type: GrantFiled: July 18, 2013Date of Patent: September 2, 2014Assignee: Afton Chemical CorporationInventor: John T. Loper
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Publication number: 20140179572Abstract: A lubricating oil comprising a major amount of base oil and a minor amount of an additive package, wherein the additive package comprises: (A) a friction modifier component selected from: (a) one or more a reaction products of an alcohol with a compound of the formula IV: and (b) one or more compounds of the Formulae II-III: wherein R is a linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl having about 8 to about 22 carbon atoms, R2 and R3 are independently selected from hydrogen C1-C18 hydrocarbyl groups, and C1-C18 hydrocarbyl groups containing one or more heteroatoms; X is an alkali metal, alkaline earth metal or ammonium cation and n is the valence of cation X, and reaction products of amines, amino alcohols, alkali or alkaline earth metal hydroxides, alkali or alkaline earth metal oxides and mixtures thereof with compounds of the Formula IV: wherein R is as defined above; and (B) at least one friction modifier that is different from the one or mType: ApplicationFiled: December 21, 2012Publication date: June 26, 2014Applicant: AFTON CHEMICAL CORPORATIONInventors: John T. Loper, Jeremy P. Styer
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Publication number: 20140179571Abstract: A lubricating oil comprises a major amount of a base oil and a minor amount of an additive package, and the additive package comprises at least one friction modifier of formula I: where R is a linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl having about 8 to about 22 carbon atoms or R is represented by: and R1 is a linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl having about 8 to about 22 carbon atoms and R2 is hydrogen or a hydrocarbyl having about 1 to about 2 carbon atoms. Methods of using the lubricating oil to improve thin film and/or boundary layer friction in an engine are also disclosed.Type: ApplicationFiled: December 21, 2012Publication date: June 26, 2014Applicant: AFTON CHEMICAL CORPORATIONInventors: John T. Loper, Jeremy P. Styer
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Publication number: 20140179577Abstract: A lubricating composition comprising a major amount of base oil and a minor amount of an additive package, wherein the additive package comprises (A) a friction modifier component selected from: (a) one or more a reaction products of an alcohol with a compound of the formula IV: and (b) one or more compounds of the Formulae II-III: wherein R is a linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl having about 8 to about 22 carbon atoms; R2 and R3 are independently selected from hydrogen, C1-C18 hydrocarbyl groups, and C1-C18 hydrocarbyl groups containing one or more heteroatoms; and X is an alkali metal, alkaline earth metal or ammonium cation and n is the valence of cation X; and (B) at least one detergent.Type: ApplicationFiled: December 21, 2012Publication date: June 26, 2014Applicant: Alton Chemical CorporationInventors: John T. Loper, Jeremy P. Styer
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Publication number: 20140179579Abstract: A lubricating oil comprising a major amount of base oil and a minor amount of an additive package comprising a friction modifier component selected from: (A) one or more friction modifiers of the formulae I and II: (B) two or more friction modifiers independently selected from the formulae III and IV: and (C) at least one friction modifier of the formulae III and IV in combination with at least one friction modifier of the formulae I and II, and R, R1, R2, R3, X and n are as defined in the specification.Type: ApplicationFiled: December 21, 2012Publication date: June 26, 2014Applicant: AFTON CHEMICAL CORPORATIONInventors: Jeremy P. Styer, John T. Loper
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Publication number: 20140179570Abstract: A lubricating composition comprising a major amount of base oil and a minor amount of an additive package, wherein the additive package comprises (A) a friction modifier component selected from: (a) one or more a reaction products of an alcohol with a compound of the formula IV: wherein R is a linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl group having about 8 to about 22 carbon atoms; and (b) one or more compounds of the Formulae II-III: wherein R is as defined above and R2 and R3 are independently selected from hydrogen, C1-C18hydrocarbyl groups, and C1-C18hydrocarbyl groups containing one or more heteroatoms; and wherein R is as defined above; and X is an alkali metal, alkaline earth metal or ammonium cation and n is the valence of cation X; and (B) at least one dispersant.Type: ApplicationFiled: December 21, 2012Publication date: June 26, 2014Applicant: AFTON CHEMICAL CORPORATIONInventors: John T. Loper, Jeremy P. Styer
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Publication number: 20140179576Abstract: A lubricating composition comprising a major amount of base oil and a minor amount of an additive package, wherein the additive package comprises: (A) a friction modifier component selected from: (a) one or more a reaction products of an alcohol with a compound of the formula IV: and (b) one or more compounds of the Formulae II-III: wherein R is a linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl having about 8 to about 22 carbon atoms; R2 and R3 are independently selected from hydrogen, C1-C18 hydrocarbyl groups, and C1-C18 hydrocarbyl groups containing one or more heteroatoms; and X is an alkali metal, alkaline earth metal, or ammonium cation and n is the valence of cation X; and (B) at least one metal dialkyl dithio phosphate salt.Type: ApplicationFiled: December 21, 2012Publication date: June 26, 2014Applicant: AFTON CHEMICAL CORPORATIONInventors: John T. Loper, Jeremy P. Styer
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Patent number: 8728995Abstract: A polyalkenyl succinic anhydride is prepared with low amounts of resinous or chlorinated byproducts in a two-step process whereby a polyalkene is first reacted with an unsaturated organic acid in a thermal ene reaction, followed with exposure to a gaseous halogen in presence of an additional amount of the unsaturated organic acidic reagent. The foregoing process produces a polyisobutenyl succinic anhydride having a high ratio of succinic anhydride functional groups to polyisobutenyl backbone groups. Such a polyisobutenyl succinic anhydride is particular suitable for the production of oil-soluble hydrocarbyl succinimides that have good dispersant properties when added to lubricating oil compositions.Type: GrantFiled: January 19, 2011Date of Patent: May 20, 2014Assignee: Afton Chemical CorporationInventors: Chente Huang, John T. Loper
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Patent number: 8709985Abstract: There is disclosed a lubricant composition comprising a base oil comprising a reduced total amount of cyclobenzene as compared to another base oil. Methods of using the lubricant composition for preventing and/or reducing the deposit formation in an engine are also disclosed.Type: GrantFiled: November 17, 2006Date of Patent: April 29, 2014Assignee: Afton Chemical CorporationInventors: Mark T. Devlin, John T. Loper, Roger M. Sheets, Todd M. Dvorak
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Publication number: 20140020645Abstract: A lubricant additive, an crankcase lubricant composition and a method for reducing intake valve deposits in a spark ignition direct injection (SIDI) engine. The lubricant additive includes an aromatic compound having a boiling point under standard atmospheric conditions of from about 190° to about 270° C. The aromatic compound is effective to reduce intake valve deposits in a SIDI engine when used in an amount ranging from about 0.1 to about 5.0 percent by weight based on a total weight of a lubricant composition containing the additive.Type: ApplicationFiled: July 18, 2012Publication date: January 23, 2014Applicant: AFTON CHEMICAL CORPORATIONInventors: Gregory H. GUINTHER, John T. LOPER
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Patent number: 8575390Abstract: In accordance with the disclosure, one aspect of the present application is directed to a dispersant compound comprising the reaction product of (i) a hydrocarbyl carbonyl compound, (ii) a polycarbonyl compound having at least three carbonyl acylating functions, and (iii) a primary amine moiety of a polyamine. Methods of making and methods of using the dispersant compound are also disclosed.Type: GrantFiled: December 21, 2010Date of Patent: November 5, 2013Assignee: Afton Chemical CorporationInventor: John T. Loper
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Patent number: 8349778Abstract: The present invention provides an additive composition comprising (a) at least one ash-containing phosphorus compound prepared by a primary or secondary alcohol or mixtures thereof, and (b) a salt of at least one hydrocarbylamine and at least one hydrocarbyl acid phosphate. Further, the present invention provides a lubricating composition comprising (a) at least one ash-containing phosphorus compound prepared by a primary or secondary alcohol or mixtures thereof, and (b) a salt of at least one hydrocarbylamine and at least one hydrocarbyl acid phosphate, and methods of use thereof.Type: GrantFiled: August 16, 2007Date of Patent: January 8, 2013Assignee: Afton Chemical CorporationInventors: Gregory H. Guinther, John T. Loper, Roger M. Sheets
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Publication number: 20120291737Abstract: An ashless additive for lubricating oil compositions, lubricating oil compositions and methods for lubricating that are effective to improve the total base number (TBN) of a lubricant composition.Type: ApplicationFiled: March 2, 2012Publication date: November 22, 2012Applicant: AFTON CHEMICAL CORPORATIONInventors: Naresh MATHUR, Jason A. LAGONA, John T. LOPER
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Patent number: 8299003Abstract: There is disclosed herein an additive composition including a compound of formula (III): wherein R1, R2, R3, R4, R5, R6 , R7, R8, and R9are independently selected from the group consisting of hydrogen, cyano, and hydrocarbyl groups comprising from about 1 to about 30 carbon atoms.Type: GrantFiled: March 9, 2006Date of Patent: October 30, 2012Assignee: Afton Chemical CorporationInventors: David J. DeGonia, Chip Hewette, Roger M. Sheets, Ronald L. Phillips, John T. Loper
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Patent number: 8211840Abstract: Lubricated surfaces and lubricant compositions for lubricating a surface. The lubricated surface is provided by a lubricant composition including a base oil of lubricating viscosity, at least one metal salt of phosphorothioic acid, and an ashless, sulfur-free organophosphorus compound providing a metal to phosphorus weight ratio ranging from about 0.25:1 to about 1.0:1 by weight. The lubricant composition is substantially devoid of molybdenum.Type: GrantFiled: December 9, 2008Date of Patent: July 3, 2012Assignee: Afton Chemical CorporationInventors: Mark T. Devlin, John T. Loper, Roger M. Sheets, Gregory H. Guinther, Jeffrey M. Guevremont
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Patent number: 8207099Abstract: A crankcase lubricant, an additive concentrate and a method for improving water tolerance of a lubricant. The lubricant includes a) a major amount of a base oil; b) an alkali or alkaline earth metal-containing detergent; c) a phosphorus-based wear preventative; and d) a surfactant agent other than (b). The lubricant has a weight ratio of alkali or alkaline earth metal content to phosphorus content, based on a total mass of lubricant, ranging from about 1.6 to about 5.0.Type: GrantFiled: September 22, 2009Date of Patent: June 26, 2012Assignee: Afton Chemical CorporationInventor: John T. Loper