Patents by Inventor Karl William Koch, III

Karl William Koch, III has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11597674
    Abstract: A colored glass article includes from 40 mol % to 70 mol % SiO2; from 8 mol % to 20 mol % Al2O3; from 1 mol % to 10 mol % B2O3; from 1 mol % to 20 mol % Li2O; from 1 mol % to 15 mol % Na2O; from 0 mol % to 8 mol % MgO; from 0 mol % to 5 mol % ZnO; and from 0.0005 mol % to 1 mol % Au. MgO+ZnO is from 0.1 mol % to 6 mol %.
    Type: Grant
    Filed: February 22, 2022
    Date of Patent: March 7, 2023
    Assignee: Corning Incorporated
    Inventors: Xiaoju Guo, Jill Marie Hall, Karl William Koch, III, Jesse Kohl, Liping Xiong Smith, Nicole Taylor Wiles
  • Publication number: 20230034541
    Abstract: A coated article is described herein with a substrate having a major surface that comprises a first portion and a second portion that is curved or faceted; and an optical coating on the major surface that forms an anti-reflective surface. A first direction is normal to the first portion and is not equal to a plurality of second directions that are normal to the second portion, and the angle between the first direction and each of the second directions is from about 10 degrees to 60 degrees. Further, the coated article exhibits at the first and second portion a hardness of about 8 GPa or greater at an indentation depth of about 100 nm or greater. Further, the coated article exhibits a single side maximum reflectance of about 3% or less as the first and second portion, wherein the reflectance is measured in a range from about 425 nm to about 950 nm.
    Type: Application
    Filed: September 29, 2022
    Publication date: February 2, 2023
    Inventors: Shandon Dee Hart, Karl William Koch, III, Carlo Anthony Kosik Williams, Lin Lin, Thien An Thi Nguyen, Charles Andrew Paulson, James Joseph Price
  • Patent number: 11567237
    Abstract: An article that includes: an inorganic oxide substrate having opposing major surfaces; and an optical film structure disposed on a first major surface of the substrate, the optical film structure comprising one or more of a silicon-containing oxide, a silicon-containing nitride and a silicon-containing oxynitride and a physical thickness from about 50 nm to less than 500 nm. The article exhibits a hardness of 8 GPa or greater measured at an indentation depth of about 100 nm or a maximum hardness of 9 GPa or greater measured over an indentation depth range from about 100 nm to about 500 nm, the hardness and the maximum hardness measured by a Berkovich Indenter Hardness Test. Further, the article exhibits a single-side photopic average reflectance that is less than 1%.
    Type: Grant
    Filed: August 15, 2019
    Date of Patent: January 31, 2023
    Assignee: Corning Incorporated
    Inventors: Shandon Dee Hart, Karl William Koch, III, Lin Lin, James Joseph Price, Alexandre Michel Mayolet, Carlo Anthony Kosik Williams
  • Publication number: 20230028863
    Abstract: A substrate for a display article is described herein including (a) a primary surface; and (b) a textured region disposed at the primary surface, the textured region comprising: (i) one or more higher surfaces residing at a higher mean elevation parallel to a base-plane disposed below the textured region extending through the substrate; (ii) one or more lower surfaces residing at a lower mean elevation parallel to the base-plane; and (iii) surface features providing at a least a portion of either or both of (i) the one or more higher surfaces and (ii) the one or more lower surfaces. The surface features can include larger surface features and smaller surface features, either or both providing one or more surfaces of the substrate that reside at one or more intermediate mean elevations parallel to the base-plane between the higher mean elevation and the lower mean elevation.
    Type: Application
    Filed: June 29, 2022
    Publication date: January 26, 2023
    Inventors: Jiangwei Feng, Corinne Elizabeth Isaac, Karl William Koch, III, Shenping Li, Wageesha Senaratne, William Allen Wood
  • Patent number: 11560329
    Abstract: A colored glass article includes greater than or equal to 50 mol % and less than or equal to 80 mol % SiO2; greater than or equal to 7 mol % and less than or equal to 25 mol % Al2O3; greater than or equal to 1 mol % and less than or equal to 15 mol % B2O3; greater than or equal to 5 mol % and less than or equal to 20 mol % Li2O; greater than or equal to 0.5 mol % and less than or equal to 15 mol % Na2O; greater than 0 mol % and less than or equal to 1 mol % K2O; and greater than or equal to 1×10?6 mol % and less than or equal to 1 mol % Au. R2O—Al2O3 is greater than or equal to ?5 mol % and less than or equal to 7 mol %, R2O being the sum of Li2O, Na2O, and K2O.
    Type: Grant
    Filed: February 22, 2022
    Date of Patent: January 24, 2023
    Assignee: Corning Incorporated
    Inventors: Xiaoju Guo, Jill Marie Hall, Karl William Koch, III, Jesse Kohl, Jian Luo, Liping Xiong Smith, Nicole Taylor Wiles
  • Publication number: 20230010461
    Abstract: An article is described that includes: a substrate having opposing major surfaces; and an optical film structure in direct contact with a first major surface and comprising a physical thickness from ˜50 nm to less than 500 nm, high refractive index (RI) and low RI layers with a first low RI layer directly on the first major surface, and a capping low RI layer. The high and low RI layers total three (3) layers to nine (9) layers, wherein each low RI layer and the capping low RI layer comprises a silicon-containing oxide and each high RI layer comprises a silicon-containing nitride or oxynitride. The article exhibits a Berkovich maximum hardness of 8 GPa or greater measured over an indentation depth ?˜50 nm. The article exhibits a two-side average transmittance >85% at infrared wavelengths from 840 to 860 nm and from 930 to 950 nm at 0° incidence.
    Type: Application
    Filed: June 29, 2022
    Publication date: January 12, 2023
    Inventors: Shandon Dee Hart, Karl William Koch, III, Carlo Anthony Kosik Williams, Lin Lin, James Joseph Price
  • Patent number: 11535555
    Abstract: Glass articles with infrared reflectivity and methods for making the same are disclosed herein. In one embodiment, glass article having infrared reflectivity includes a first surface, a second surface and a body extending between the first and second surfaces. A plurality of discrete layers of metallic silver are formed in the body creating at least one optical cavity in the body. Each discrete layer may have a thickness T such that 100 nm?T?250 nm and may be spaced apart from adjacent layers of metallic silver by a spacing S?500. The glass article reflects at least a portion of electromagnetic radiation incident on the glass article having a wavelength from 800 nm to 2500 nm and transmits at least a portion of electromagnetic radiation incident on the glass article having a wavelength from 390 nm to 750 nm.
    Type: Grant
    Filed: April 17, 2018
    Date of Patent: December 27, 2022
    Assignee: Corning Incorporated
    Inventors: Nicholas Francis Borrelli, Karl William Koch, III, Joseph Francis Schroeder, III
  • Publication number: 20220402808
    Abstract: A glass composition includes greater than or equal to 50 mol % and less than or equal to 70 mol % SiO2; greater than or equal to 10 mol % and less than or equal to 20 mol % Al2O3; greater than or equal to 1 mol % and less than or equal to 10 mol % B2O3; greater than or equal to 7 mol % and less than or equal to 14 mol % Li2O; greater than 0 mol % and less than or equal to 8 mol % Na2O; greater than 0 mol % and less than or equal to 1 mol % K2O; greater than or equal to 0 mol % and less than or equal to 7 mol % CaO; greater than or equal to 0 mol % and less than or equal to 8 mol % MgO; and greater than or equal to 0 mol % and less than or equal to 8 mol % ZnO. R2O+R?O is less than or equal to 25 mol %, wherein R2O is the sum of Li2O, Na2O, and K2O and R?O is the sum of CaO, MgO, and ZnO. The glass composition includes at least one of NiO+CO3O4+Cr2O3+CuO is greater than or equal to 0.001 mol %, CeO2 is greater than or equal to 0.1 mol %, and TiO2 is greater than or equal to 0.1 mol %.
    Type: Application
    Filed: June 17, 2022
    Publication date: December 22, 2022
    Inventors: Xiaoju Guo, Karl William Koch, III, Liping Xiong Smith, Nicole Taylor Wiles
  • Publication number: 20220402806
    Abstract: A colored glass article includes greater than or equal to 50 mol % and less than or equal to 70 mol % SiO2, greater than or equal to 10 mol % and less than or equal to 17.5 mol % Al2O3, greater than or equal to 3 mol % and less than or equal to 10 mol % B2O3, greater than or equal to 8.8 mol % and less than or equal to 14 mol % Li2O, greater than or equal to 1.5 mol % and less than or equal to 8 mol % Na2O, and greater than 0 mol % and less than or equal to 2 mol % Cr2O3. R2O+RO?Al2O3 is greater than or equal to 0.5 mol % and less than or equal to 6 mol %. Al2O3+MgO+ZnO is greater than or equal to 12 mol % and less than or equal to 22 mol %.
    Type: Application
    Filed: June 16, 2022
    Publication date: December 22, 2022
    Inventors: Xiaoju Guo, Karl William Koch, III, Liping Xiong Smith
  • Publication number: 20220402805
    Abstract: A colored glass article includes from 40 mol % to 70 mol % SiO2; from 8 mol % to 20 mol % Al2O3; from 1 mol % to 10 mol % B2O3; from 1 mol % to 20 mol % Li2O; from 1 mol % to 15 mol % Na2O; from 0 mol % to 8 mol % MgO; from 0 mol % to 5 mol % ZnO; and from 0.0005 mol % to 1 mol % Au. MgO+ZnO is from 0.1 mol % to 6 mol %.
    Type: Application
    Filed: February 22, 2022
    Publication date: December 22, 2022
    Inventors: Xiaoju Guo, Jill Marie Hall, Karl William Koch, III, Jesse Kohl, Liping Xiong Smith, Nicole Taylor Wiles
  • Patent number: 11531141
    Abstract: Embodiments of articles including a low-contrast anti-reflection coating are disclosed. The coated surface of such articles exhibits a reduced difference in reflectance between a pristine state and when a surface defect is present. In one or more embodiments, the coated surface of such articles exhibits a first average reflectance in the range from about 0.6% to about 6.0% in a pristine condition and a second average reflectance of about 8% or less after removal of a surface thickness of the anti-reflection coating. In other embodiments, the coated substrate exhibits a second average reflectance of about 10% or less, when the coated surface comprises a contaminant. In some embodiments, the coated substrate exhibits a first color coordinate (a*1, b*1) in a pristine condition and a second color coordinate (a*2, b*2) after the presence of a surface defect such that ?a*b* is about 6 or less.
    Type: Grant
    Filed: March 17, 2020
    Date of Patent: December 20, 2022
    Assignee: Corning Incorporated
    Inventors: Shandon Dee Hart, Karl William Koch, III, Charles Andrew Paulson
  • Patent number: 11520082
    Abstract: Durable and scratch resistant articles including an optical coating with a gradient. An article comprises: a substrate; and an optical coating having a thickness and a first gradient portion. A refractive index of the optical coating varies along a thickness of the optical coating. The difference between the maximum refractive index of the first gradient portion and the minimum refractive index of the first gradient portion is 0.1 or greater. The absolute value of the slope of the refractive index of the first gradient portion is 0.1/nm or less everywhere along the thickness of the first gradient portion. The article exhibits an average single-surface reflectance of 15% to 98% over the wavelength range 400 nm-700 nm. The article also exhibits a maximum hardness in the range from about 10 GPa to about 30 GPa.
    Type: Grant
    Filed: August 31, 2018
    Date of Patent: December 6, 2022
    Assignee: Corning Incorporated
    Inventors: Robert Alan Bellman, Shandon Dee Hart, Karl William Koch, III, Carlo Anthony Kosik Williams, Charles Andrew Paulson, James Joseph Price
  • Patent number: 11500130
    Abstract: A coated article with a substrate having a major surface that comprises a first portion and a second portion that is curved or faceted; and an optical coating on the major surface that forms an anti-reflective surface. A first direction is normal to the first portion and is not equal to a plurality of second directions that are normal to the second portion, and the angle between the first direction and each of the second directions is from about 10 degrees to 60 degrees. Further, the coated article exhibits at the first and second portion a hardness of about 8 GPa or greater at an indentation depth of about 100 nm or greater. Further, the coated article exhibits a single side maximum reflectance of about 3% or less as the first and second portion, wherein the reflectance is measured in a range from about 425 nm to about 950 nm.
    Type: Grant
    Filed: March 26, 2020
    Date of Patent: November 15, 2022
    Assignee: Corning Incorporated
    Inventors: Shandon Dee Hart, Karl William Koch, III, Carlo Anthony Kosik Williams, Lin Lin, Thien An Thi Nguyen, Charles Andrew Paulson, James Joseph Price
  • Publication number: 20220340483
    Abstract: An article is described herein that includes: a glass-based substrate comprising opposing major surfaces; a crack mitigating composite over one of the major surfaces, the composite comprising an inorganic element and a polymeric element; and a hard film disposed on the crack mitigating composite comprising an elastic modulus greater than or equal to the elastic modulus of the glass-based substrate. The crack mitigating composite is characterized by an elastic modulus of greater than 30 GPa. Further, the hard film comprises at least one of a metal-containing oxide, a metal-containing oxynitride, a metal-containing nitride, a metal-containing carbide, a silicon-containing polymer, a carbon, a semiconductor, and combinations thereof.
    Type: Application
    Filed: July 7, 2022
    Publication date: October 27, 2022
    Inventors: Robert Alan Bellman, Shandon Dee Hart, Jenny Kim, Karl William Koch, III, James Joseph Price, Hannah Shenouda
  • Publication number: 20220317353
    Abstract: A window for a sensing system is provided. The window includes a substrate having a predetermined thickness and an index of refraction for electromagnetic radiation having a wavelength of 905 nm and a layered film disposed on the substrate, the layered film including alternating layers of a high refractive index material and a lower refractive index material, the high refractive index material having a higher refractive index than the lower refractive index material, wherein each layer of the alternating layers of the layered film has a thickness, and the thicknesses of the alternating layers are configured so that the window has a transmittance of at least 80% for electromagnetic radiation having a wavelength within the range of 850 nm to 950 nm. The window further includes a hardness of at least 10 GPa, at the layered film, as measured by the Berkovich Indenter Hardness Test.
    Type: Application
    Filed: May 29, 2020
    Publication date: October 6, 2022
    Inventors: Shandon Dee Hart, Karl William Koch, III, Carlo Anthony Kosik Williams, Charles Andrew Paulson, James Joseph Price
  • Publication number: 20220317340
    Abstract: A transparent article is described herein that includes: a glass-ceramic substrate comprising first and second primary surfaces opposing one another and a crystallinity of at least 40% by weight; and an optical film structure disposed on the first primary surface. The optical film structure comprises a plurality of alternating high refractive index (RI) and low RI layers and a scratch-resistant layer. The article also exhibits an average photopic transmittance of greater than 80% and a maximum hardness of greater than 10 GPa, as measured by a Berkovich Hardness Test over an indentation depth range from about 100 nm to about 500 nm. The glass-ceramic substrate comprises an elastic modulus of greater than 85 GPa and a fracture toughness of greater than 0.8 MPa·?m. Further, the optical film structure exhibits a residual compressive stress of ?700 MPa and an elastic modulus of ?140 GPa.
    Type: Application
    Filed: March 30, 2022
    Publication date: October 6, 2022
    Inventors: Jaymin Amin, Jason Thomas Harris, Shandon Dee Hart, Chang-gyu Kim, Karl William Koch, III, Carlo Anthony Kosik Williams, Lin Lin, Dong-gun Moon, Jeonghong Oh, James Joseph Price, Charlene Marie Smith, Ljerka Ukrainczyk, Tingge Xu
  • Publication number: 20220299606
    Abstract: A window for a sensing system is provided. The window includes a substrate, a layered film disposed on a first surface of the substrate, the layered film including alternating layers of higher refractive index materials and lower refractive index materials, wherein the refractive index of the higher refractive index materials is greater than the refractive index of the lower refractive index materials, and a maximum hardness, measured at the layered film and by the Berkovich Indenter Hardness Test, of at least 8 GPa. The window has: an average percentage transmittance of greater than 75% for electromagnetic radiation having a wavelength of 1550 nm at normal or near normal incidence; and an average percentage reflectance of less than 10% for electromagnetic radiation having a wavelength of 1550 nm at any angle of incidence within the range of 0° to 8°.
    Type: Application
    Filed: June 1, 2020
    Publication date: September 22, 2022
    Inventors: Shandon Dee Hart, Karl William Koch, III, Carlo Anthony Kosik Williams, Charles Andrew Paulson, James Joseph Price
  • Publication number: 20220251396
    Abstract: Embodiments of durable, anti-reflective articles are described. In one or more embodiments, the article includes a substrate and an anti-reflective coating disposed on the major surface. The article exhibits an average light transmittance of about 94% or greater over an optical wavelength regime and/or an average light reflectance of about 2% or less over the optical wavelength regime, as measured from an anti-reflective surface. In some embodiments, the article exhibits a maximum hardness of about 8 GPa or greater as measured by a Berkovich Indenter Hardness Test along an indentation depth of about 50 nm or greater and a b* value, in reflectance, in the range from about ?5 to about 1 as measured on the anti-reflective surface only at all incidence illumination angles in the range from about 0 degrees to about 60 degrees under an International Commission on Illumination illuminant.
    Type: Application
    Filed: February 25, 2022
    Publication date: August 11, 2022
    Inventors: Jaymin Amin, Shandon Dee Hart, Karl William Koch, III, Eric Louis Null, Xu Ouyang, Charles Andrew Paulson, James Joseph Price
  • Patent number: 11407681
    Abstract: An article that includes: a glass-based substrate comprising opposing major surfaces; a crack mitigating composite over one of the major surfaces, the composite comprising an inorganic element and a polymeric element; and a hard film disposed on the crack mitigating composite comprising an elastic modulus greater than or equal to the elastic modulus of the glass-based substrate. The crack mitigating composite is characterized by an elastic modulus of greater than 30 GPa. Further, the hard film comprises at least one of a metal-containing oxide, a metal-containing oxynitride, a metal-containing nitride, a metal-containing carbide, a silicon-containing polymer, a carbon, a semiconductor, and combinations thereof.
    Type: Grant
    Filed: March 23, 2018
    Date of Patent: August 9, 2022
    Assignee: Corning Incorporated
    Inventors: Robert Alan Bellman, Shandon Dee Hart, Jenny Kim, Karl William Koch, III, James Joseph Price, Hannah Shenouda
  • Patent number: 11391869
    Abstract: According to one or more embodiments described herein, a coated article may comprise a transparent substrate and an optical coating. The transparent substrate may have a major surface, and the optical coating may be disposed on the major surface of the transparent substrate and form an air-side surface. The optical coating may comprise one or more layers of deposited material and one or more light-altering features which may reduce oscillations in the reflectance spectrum of the coated article. The coated article may exhibit a maximum hardness of about 8 GPa or greater, have an average photopic transmittance of about 50% or greater, and exhibit an angular color shift of less than about 10 from a reference illumination angle in a range of 0-10 degrees to an incident illumination angle in a range of 30-60 degrees relative to the air-side surface.
    Type: Grant
    Filed: July 17, 2019
    Date of Patent: July 19, 2022
    Assignee: Corning Incorporated
    Inventors: Robert Alan Bellman, Shandon Dee Hart, Karl William Koch, III