Abstract: Embodiments of durable, scratch resistant articles are described. The articles have coatings that provide specific reflectance, transmission, and/or color properties, as well as high hardness. Some embodiments have low reflectance, and high color. Some embodiments have high reflectance and neutral color. Some embodiments have high reflectance and high color. In some embodiments, the articles may be sunglasses with an optical coating, a scratch resistant mirror with an optical coating, or a consumer electronic product with an optical coating.

Abstract: Embodiments of articles with optical coatings are described herein. According to one embodiment, an article may comprise a substrate having a major surface, and an optical coating disposed on the major surface and forming an anti-reflective surface, the optical coating comprising an anti-reflective coating. The article may exhibit a maximum hardness of about 12 GPa or greater as measured on the anti-reflective surface by a Berkovich Indenter Hardness Test along an indentation depth of about 100 nm or greater. The article may exhibit a single side average light reflectance measured at the anti-reflective surface of about 8% or less over an optical wavelength regime in the range from about 400 nm to about 800 nm. The article may exhibit an average light transmission of about 90% or greater over an optical wavelength regime in the range from about 400 nm to about 800 nm.

Abstract: An article includes a glass, glass-ceramic or ceramic substrate including a primary surface. A functional coating is disposed over the primary surface of the substrate. The coating includes a first portion disposed over the primary surface. One or more interrupting layers are disposed over the first portion. A second portion is disposed over the one or more interrupting layers. The one or more interrupting layers includes a microstructure different than one of the first and second portions and the coating has an average optical transmittance greater than about 10% over the visible wavelength range from about 450 nm to about 650 nm.

Abstract: An article includes a substrate including a glass, glass-ceramic, or ceramic composition and a primary surface. An optical film is disposed on the primary surface. The film includes a first plurality of layers which includes diamond or diamond-like carbon and a second plurality of layers. Each layer of the second plurality of layers is arranged in an alternating manner with each layer of the first plurality of layers. The optical film includes an average photopic light reflectance of about 2.0% or less and a transmittance of about 85% or greater from about 500 nm to about 800 nm.

Abstract: Embodiments of a filter for electromagnetic radiation are disclosed herein. The filter includes a first glass-ceramic substrate having a first refractive index, a second glass-ceramic substrate having the first refractive index, and a first region disposed between the first glass-ceramic substrate and the second glass-ceramic substrate. The first region has a second refractive index that is less than the first refractive index. Further, the second glass-ceramic substrate is arranged substantially parallel to and spatially disposed from the first glass-ceramic substrate. The filter transmits at least 70% of electromagnetic radiation within a band of frequencies and reflects at least 80% of electromagnetic radiation outside the band of frequencies. The band of frequencies is located within the frequency range of 20 GHz to 100 GHz.

Abstract: An article that includes: a glass-based substrate comprising opposing major surfaces; a crack mitigating composite over one of the major surfaces, the composite comprising an inorganic element and a polymeric element; and a hard film disposed on the crack mitigating composite comprising an elastic modulus greater than or equal to the elastic modulus of the glass-based substrate. The crack mitigating composite is characterized by an elastic modulus of greater than 30 GPa. Further, the hard film comprises at least one of a metal-containing oxide, a metal-containing oxynitride, a metal-containing nitride, a metal-containing carbide, a silicon-containing polymer, a carbon, a semiconductor, and combinations thereof.

Abstract: An article that includes: an inorganic oxide substrate having opposing major surfaces; and an optical film structure disposed on a first major surface of the substrate, the optical film structure comprising one or more of a silicon-containing oxide, a silicon-containing nitride and a silicon-containing oxynitride and a physical thickness from about 50 nm to less than 500 nm. The article exhibits a hardness of 8 GPa or greater measured at an indentation depth of about 100 nm or a maximum hardness of 9 GPa or greater measured over an indentation depth range from about 100 nm to about 500 nm, the hardness and the maximum hardness measured by a Berkovich Indenter Hardness Test. Further, the article exhibits a single-side photopic average reflectance that is less than 1%.

Abstract: A glass article is provided that includes: a glass substrate comprising a thickness and a primary surface; and a textured region defined by the primary surface. The textured region comprises a low spatial frequency region and a high spatial frequency region substantially superimposed within the low spatial frequency region. Further, the low spatial frequency region comprises an average lateral feature size that exceeds an average lateral feature size of the high spatial frequency region. In addition, the textured region comprises a surface roughness (Ra) from about 10 nm to about 1000 nm.

Abstract: An article is described herein that includes: a translucent substrate comprising opposing major surfaces; and an optical film structure disposed on a first major surface of the substrate, the optical film structure comprising an outer surface and a plurality of periods such that each period comprises an alternating low refractive index layer and high refractive index layer. The article exhibits a hardness of 10 GPa or greater measured at an indentation depth of about 100 nm by a Berkovich Indenter Hardness Test. Further, the article exhibits a single side average photopic light reflectance of at least 50% of non-polarized light as measured at the outer surface from near-normal incidence to an incident angle of 60 degrees over a portion of at least 10 nm within the visible spectrum. In addition, each low refractive index layer comprises SiO2 or doped-SiO2 and each high refractive index layer comprises AlOxNy, SiOxNy, SiuAlvOxNy, SiNx or ZrO2.

Abstract: Durable and scratch resistant articles including low-reflectance optical coating with gradient portion. In some embodiments, an article comprises: a substrate comprising a first major surface; and an optical coating disposed over the first major surface. The optical coating comprises: a second major surface; a thickness; and a first gradient portion. A refractive index of the optical coating varies along a thickness of the optical coating. The difference between the maximum refractive index of the first gradient portion and the minimum refractive index of the first gradient portion is 0.05 or greater. The absolute value of the slope of the refractive index of the first gradient portion is 0.1/nm or less everywhere along the thickness of the first gradient portion. The article exhibits a single side photopic average light reflectance of 3% or less, and a maximum hardness from 10 GPa to 30 GPa.

Abstract: According to one or more embodiments described herein, a coated article may comprise: a transparent substrate having a major surface, the major surface comprising a textured or rough surface inducing light scattering; and an optical coating disposed on the major surface of the transparent substrate and forming an air-side surface, the optical coating comprising one or more layers of material, the optical coating having a physical thickness of greater than 300 nm, wherein the coated article exhibits a maximum hardness of about 10 GPa or greater as measured on the air-side surface by a Berkovich Indenter Hardness Test along an indentation depth of about 50 nm or greater.

Abstract: According to one embodiment, there is an article including a glass-ceramic substrate having a major surface, an optical coating is disposed on the major surface and forms an appearance-enhancing surface, the optical coating including a appearance-enhancing coating, and a scratch-resistant layer. The article exhibits a hardness of 8 GPa or more, and a photopic average diffuse light reflectance measured at the appearance-enhancing surface of one of: (i) about 0.3% or less; (ii) about 0.2% or less; (iii) about 0.1% or less, over an optical wavelength regime in the range from about 400 nm to about 800 nm. Further, in the (L*, a*, b*) colorimetry system of the International Commission on Illumination, at near-normal incidence, the article comprises a diffuse reflectance dE* of one of: (i) about 3 or less; (ii) about 2 or less; or (iii) about 1 or less, where dE* is defined as dE*=sqrt(L*2+a*2+b*2).

Abstract: An article is described herein that includes: a translucent substrate having a major surface; and an anti-reflective coating disposed on the major surface and forming an anti-reflective surface. The article exhibits a single side average photopic light reflectance at the anti-reflective surface of less than 0.35%. Further, the article exhibits a single side color shift (?C) of less than 6 over an incident angle range from 0 degrees to 60 degrees incidence at the anti-reflective surface, wherein the anti-reflective coating comprises a physical thickness from about 50 nm to less than 500 nm. In addition, the anti-reflective coating comprises a plurality of layers that comprises at least one low refractive index layer and at least one high refractive index layer. Further, each high refractive index layer has a refractive index of greater than 2.0 and each low refractive index layer has a refractive index of less than 1.7.

Abstract: A coated article is described herein that may comprise a substrate and an optical coating. The substrate may have a major surface comprising a first portion and a second portion. A first direction that is normal to the first portion of the major surface may not be equal to a second direction that is normal to the second portion of the major surface. The optical coating may be disposed on at least the first portion and the second portion of the major surface. The coated article may exhibit at the first portion of the substrate and at the second portion of the substrate hardness of about 8 GPa or greater at an indentation depth of about 50 nm or greater as measured on the anti-reflective surface by a Berkovich Indenter Hardness Test.

Abstract: Embodiments of a color-neutral anti-reflective coating and articles including the same are described. In one or more embodiments, a substrate includes a first major surface and an anti-reflective coating disposed on the first major surface of the substrate and having a reflective surface opposite the first major surface. In one or more embodiments, a point on the reflective surface has a single-surface reflectance under a D65 illuminant with an angular color variation, ?E? that is less than 5, where ?E?=?{(a*?1?a*?2)2+(b*?1-b*?2)2}, and a*?1 and b*?1 are any two different viewing angles at least 5 degrees apart in a range from about 10° to about 60° relative to a normal vector of the reflective surface.

Abstract: A coated article may comprise a substrate and an optical coating. The substrate may have a major surface comprising a first portion and a second portion. A first direction that is normal to the first portion of the major surface may not be equal to a second direction that is normal to the second portion of the major surface. The optical coating may be disposed on at least the first portion and the second portion of the major surface. The coated article may exhibit at the first portion of the substrate and at the second portion of the substrate hardness of about 8 GPa or greater at an indentation depth of about 50 nm or greater as measured on the anti-reflective surface by a Berkovich Indenter Hardness Test.

Abstract: A coated article with a substrate having a major surface that comprises a first portion and a second portion that is curved or faceted; and an optical coating on the major surface that forms an anti-reflective surface. A first direction is normal to the first portion and is not equal to a plurality of second directions that are normal to the second portion, and the angle between the first direction and each of the second directions is from about 10 degrees to 60 degrees. Further, the coated article exhibits at the first and second portion a hardness of about 8 GPa or greater at an indentation depth of about 100 nm or greater. Further, the coated article exhibits a single side maximum reflectance of about 3% or less as the first and second portion, wherein the reflectance is measured in a range from about 425 nm to about 950 nm.

Abstract: Described herein are antimicrobial articles having improved antimicrobial efficacy and antireflective properties. Further described are methods of making and using the improved articles. The antimicrobial articles generally include an antimicrobial element and an antireflective element. The antireflective element, in some cases, can be disposed directly on a glass, glass-ceramic or ceramic substrate and the antimicrobial element is disposed on the antireflective element. The article can exhibit a reflectance of about 4% or less (and less than 1% in some cases) in the range of about 425 nm to about 725 nm. Further, the article can be characterized with an antimicrobial efficacy by exhibiting at least a 2 log reduction in a concentration of at least Staphylococcus aureus, Enterobacter aerogenes, and Pseudomonas aeruginosa bacteria under a Modified EPA Copper Test Protocol.

Abstract: Embodiments of articles including a low-contrast anti-reflection coating are disclosed. The coated surface of such articles exhibits a reduced difference in reflectance between a pristine state and when a surface defect is present. In one or more embodiments, the coated surface of such articles exhibits a first average reflectance in the range from about 0.6% to about 6.0% in a pristine condition and a second average reflectance of about 8% or less after removal of a surface thickness of the anti-reflection coating. In other embodiments, the coated substrate exhibits a second average reflectance of about 10% or less, when the coated surface comprises a contaminant. In some embodiments, the coated substrate exhibits a first color coordinate (a*1, b*1) in a pristine condition and a second color coordinate (a*2, b*2) after the presence of a surface defect such that ?a*b* is about 6 or less.

Abstract: A substrate with a textured surface is disclosed. The substrate may be, for example, a light emitter comprising a light guide, for example a backlight element for use in a display device, wherein a surface of the light guide, for example a glass substrate, is configured to have a textured surface with a predetermined RMS roughness and a predetermined correlation length of the texture. A plurality of light scatter suppressing features can be provided on the textured surface. Textured surfaces disclosed herein may be effective to reduce electrostatic charging of the substrate surface. Methods of producing the textured surface are also disclosed.