Patents by Inventor Kunihiko Ishizaki

Kunihiko Ishizaki has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9976001
    Abstract: Provided is a process for producing a water-absorbing resin powder which contains a given amount of water added thereto, has a low dust content, and has high material properties. When a water-absorbing resin powder which has undergone surface crosslinking is produced on an industrial scale, various problems concerning production are eliminated and a long-term stable operation is possible without causing a deterioration in the material properties of the resin. Even when the process is continued over a long period, the material properties are stabilized (decrease in standard deviation) or improved (improvement in AAP). The process for producing a water-absorbing resin comprises, in the following order, a first classification step for classifying a water-absorbing resin, a surface crosslinking step after the classification, a water addition step for adding water to the water-absorbing resin powder after or during the surface crosslinking, a second classification step, and a conveying step.
    Type: Grant
    Filed: February 10, 2011
    Date of Patent: May 22, 2018
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Sumio Okuda, Kunihiko Ishizaki, Katsuyuki Wada
  • Patent number: 9962680
    Abstract: Provided is a method for producing a polyacrylic acid (salt)-based water absorbent resin, which is a convenient production method for a water absorbent resin for an absorbent suitable for practical use, the water absorbent resin having a reduced amount of residual monomers.
    Type: Grant
    Filed: December 16, 2011
    Date of Patent: May 8, 2018
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Satoshi Matsumoto, Kunihiko Ishizaki, Kanako Tsuru
  • Publication number: 20180071714
    Abstract: Provided is a method for producing a particulate water absorbing agent, the method including the steps of: a polymerization step of polymerizing an acrylic acid (salt)-based aqueous monomer solution so as to obtain a crosslinked hydrogel polymer; a drying step of drying the crosslinked hydrogel polymer so as to obtain a dried polymer; a classification step of classifying a polymer subjected to classification so as to obtain a water-absorbing resin powder having a specific particle size; and a surface-crosslinking step of surface-crosslinking the water-absorbing resin powder that is not surface crosslinked, wherein the classification step is carried out at least either or both of before and/or after the surface-crosslinking step but after said drying step, and wherein a hole shape of a classification sieve used in the classification step is an irregular polygonal or non-circular.
    Type: Application
    Filed: March 30, 2016
    Publication date: March 15, 2018
    Applicant: NIPPON SHOKUBAI CO., LTD.
    Inventors: Kazushi TORII, Kunihiko ISHIZAKI, Shinichi FUJINO, Ryota WAKABAYASHI, Motohiro IMURA
  • Patent number: 9896529
    Abstract: The present invention provides a method for producing, by adding an additive and/or gas bubbles to a monomer with high efficiency, a polyacrylic acid (salt)-based water-absorbing resin having high physical properties while high productivity is maintained. The step of preparing an aqueous monomer solution includes the steps of: preparing an aqueous solution; and adding a water-insoluble additive and/or gas bubbles. A retention time from when the water-insoluble additive and/or the gas bubbles is/are added to when polymerization starts is 1 second to 60 seconds.
    Type: Grant
    Filed: March 2, 2015
    Date of Patent: February 20, 2018
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Satoshi Matsumoto, Kunihiko Ishizaki, Shinichi Fujino
  • Patent number: 9873104
    Abstract: To provide a method for producing a water-absorbing resin by which problems caused by addition of a particulate additive or water-absorbing resin fine powder can be prevented and a water-absorbing resin having high physical properties can be stably and efficiently obtained. A method for producing a polyacrylic acid (salt)-based water-absorbing resin, the method including: an aqueous monomer solution preparation step for preparing an aqueous solution containing a monomer having an acrylic acid (salt) as a main component; a polymerization step for polymerizing the monomer to obtain a hydrogel-forming crosslinked polymer; and a drying step for drying the hydrogel-forming crosslinked polymer to obtain a dry polymer, wherein the method further includes an adding step for adding a particulate additive to the aqueous monomer solution and/or the hydrogel-forming crosslinked polymer, and in the adding step, an oxygen concentration in an ambient atmosphere of the particulate additive is set to 5% by volume or less.
    Type: Grant
    Filed: March 3, 2015
    Date of Patent: January 23, 2018
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Satoshi Matsumoto, Shinichi Fujino, Kunihiko Ishizaki
  • Patent number: 9868800
    Abstract: A method for producing polyacrylic acid (salt)-based water-absorbing resin includes a step of polymerizing an acrylic acid (salt)-based aqueous monomer solution, the polymerization step involving use of a polymerization reaction apparatus including a polymerization reaction unit covered with a casing, the polymerization step involving a polymerization reaction under internal pressure of the polymerization reaction unit, the internal pressure being slightly reduced and having a pressure reduction level of more than 0 kPa and not more than 10 kPa relative to the ambient pressure at the periphery of the polymerization reaction unit.
    Type: Grant
    Filed: April 24, 2015
    Date of Patent: January 16, 2018
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Shinichi Fujino, Kunihiko Ishizaki, Satoshi Matsumoto
  • Publication number: 20170216816
    Abstract: To provide a method for producing a water-absorbing resin by which problems caused by addition of a particulate additive or water-absorbing resin fine powder can be prevented and a water-absorbing resin having high physical properties can be stably and efficiently obtained. A method for producing a polyacrylic acid (salt)-based water-absorbing resin, the method including: an aqueous monomer solution preparation step for preparing an aqueous solution containing a monomer having an acrylic acid (salt) as a main component; a polymerization step for polymerizing the monomer to obtain a hydrogel-forming crosslinked polymer; and a drying step for drying the hydrogel-forming crosslinked polymer to obtain a dry polymer, wherein the method further includes an adding step for adding a particulate additive to the aqueous monomer solution and/or the hydrogel-forming crosslinked polymer, and in the adding step, an oxygen concentration in an ambient atmosphere of the particulate additive is set to 5% by volume or less.
    Type: Application
    Filed: March 3, 2015
    Publication date: August 3, 2017
    Inventors: Satoshi MATSUMOTO, Shinichi FUJINO, Kunihiko ISHIZAKI
  • Patent number: 9682362
    Abstract: The purpose of the present invention is to provide a process for stably and continuously producing a water-absorbing resin, specifically, a process for stably and continuously producing a water-absorbing resin, the process including a gas absorbing step in which a gas discharged from a step of producing a water-absorbing resin is efficiently and persistently absorbed. A main point of this process for producing a water-absorbing polyacrylic acid (salt) resin further including a step of absorbing a gas discharged from a production step of the water-absorbing polyacrylic acid (salt) resin in water having a pH of 7 to 11 and a polyvalent metal ion content of 100 ppm or less or a step of absorbing the gas in water having a pH of 7 to 11, the pH of the water having been adjusted by mixing a water having an electric conductivity of 500 (?S/cm) or less at 25° C. with an alkali compound.
    Type: Grant
    Filed: November 14, 2014
    Date of Patent: June 20, 2017
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Makoto Nagasawa, Jiro Sano, Yoshiki Katada, Kunihiko Ishizaki
  • Publication number: 20170166670
    Abstract: A polyacrylic acid (salt), or a polyacrylic acid (salt)-based water-absorbing resin, contains a tracer for detecting various troubles in the water-absorbing resin during the period from the production of the water-absorbing resin to the use and discard thereof by a consumer. The polyacrylic acid (salt)-based water-absorbing resin has a stable carbon isotope ratio, as determined by accelerator mass spectrometry, of less than ?20‰ and a radioactive carbon content of 1.0×10?14 or more. The polyacrylic acid (salt)-based water-absorbing resin has: a CRC of 10 [g/g] or more; an AAP of 20 [g/g] or more; an Ext of 35 wt. % or less; a content of residual monomers of 1,000 ppm or less; a PSD in which the proportion of particles having a particle diameter of 150 ?m or larger but less than 850 ?m is 90 wt. % or more; and an FSR of 0.15 [g/g/s] or more.
    Type: Application
    Filed: February 24, 2017
    Publication date: June 15, 2017
    Inventors: Satoshi MATSUMOTO, Yuki MIURA, Kunihiko ISHIZAKI, Yoshifumi ADACHI
  • Publication number: 20170158791
    Abstract: Disclosed are a polyacrylate (salt) and a polyacrylate (salt) water-absorbent resin containing a tracer which can be verified back to the manufacturing process of the water-absorbent resin when dealing with various problems with the water-absorbent resin which can occur from the manufacturing process of the water-resistant resin, during the use thereof by a consumer, up until the disposal thereof. The disclosed polyacrylate (salt) and the polyacrylate (salt) water-absorbent resin have a carbon stable isotope ratio (?13C) of at least ?20‰ when measured by accelerator mass spectrometry.
    Type: Application
    Filed: February 23, 2017
    Publication date: June 8, 2017
    Inventors: Satoshi MATSUMOTO, Yuki MIURA, Kunihiko ISHIZAKI, Shigeru SAKAMOTO
  • Patent number: 9624322
    Abstract: A method for producing a water absorbent resin, the method including a polymerization step, a drying step, a classification step, and a surface crosslinking step. The classification step carried out before or after the surface crosslinking step requires use of a tapping material and a metal sieve mesh, in which the tapping material being heated at 40° C. to 100° C. is installed below the metal sieve mesh, and the metal sieve mesh has an area of 1 to 10 m2/sheet. The classification step further requires introducing a classification aid particle, which has a specific gravity different from that of the water absorbent resin, to the metal sieve mesh; and monitoring the presence or absence of damage to the metal sieve mesh.
    Type: Grant
    Filed: March 17, 2011
    Date of Patent: April 18, 2017
    Assignee: Nippon Shukubai Co., Ltd.
    Inventors: Sumio Okuda, Syuji Kanzaki, Kunihiko Ishizaki, Shinichi Fujino, Kozo Nogi
  • Patent number: 9593212
    Abstract: The present invention provides a method for producing a water absorbent resin particle, in high productivity, not only in a controlled manner of particle size but also enhancing fundamental property (absorption capacity or absorption capacity against pressure) of a water absorbent resin.
    Type: Grant
    Filed: September 28, 2007
    Date of Patent: March 14, 2017
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Shigeru Sakamoto, Yoshio Irie, Hiroyuki Ikeuchi, Makoto Nagasawa, Kunihiko Ishizaki, Sayaka Machida
  • Publication number: 20170066862
    Abstract: The present invention provides a method for producing, by adding an additive and/or gas bubbles to a monomer with high efficiency, a polyacrylic acid (salt)-based water-absorbing resin having high physical properties while high productivity is maintained. The step of preparing an aqueous monomer solution includes the steps of: preparing an aqueous solution; and adding a water-insoluble additive and/or gas bubbles. A retention time from when the water-insoluble additive and/or the gas bubbles is/are added to when polymerization starts is 1 second to 60 seconds.
    Type: Application
    Filed: March 2, 2015
    Publication date: March 9, 2017
    Inventors: Satoshi MATSUMOTO, Kunihiko ISHIZAKI, Shinichi FUJINO
  • Patent number: 9580519
    Abstract: The purpose of the present invention is to provide a method for producing a water absorbent resin in which a water absorbent resin having excellent properties can be obtained effectively.
    Type: Grant
    Filed: April 20, 2012
    Date of Patent: February 28, 2017
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kozo Nogi, Syuji Kanzaki, Kunihiko Ishizaki, Shinichi Fujino, Satoshi Matsumoto
  • Publication number: 20170044281
    Abstract: A method for producing polyacrylic acid (salt)-based water-absorbing resin includes a step of polymerizing an acrylic acid (salt)-based aqueous monomer solution, the polymerization step involving use of a polymerization reaction apparatus including a polymerization reaction unit covered with a casing, the polymerization step involving a polymerization reaction under internal pressure of the polymerization reaction unit, the internal pressure being slightly reduced and having a pressure reduction level of more than 0 kPa and not more than 10 kPa relative to the ambient pressure at the periphery of the polymerization reaction unit.
    Type: Application
    Filed: April 24, 2015
    Publication date: February 16, 2017
    Inventors: Shinichi FUJINO, Kunihiko ISHIZAKI, Satoshi MATSUMOTO
  • Patent number: 9567414
    Abstract: From a view point of reduction in an out of spec product after surface crosslinking, particularly, when an alkylene carbonate compound is used as a surface crosslinking agent, influence by an air temperature is great, and it is necessary to reduce ethylene glycol which is produced as a byproduct, and there is provided a process for producing a polyacrylic acid (salt)-based water absorbent resin powder, comprising a step of polymerizing an aqueous acrylic acid (salt)-based monomer solution, a step of drying the resulting polymer, an optional grinding•classifying step, and a surface crosslinking step, wherein in the surface crosslinking step, (1) a surface crosslinking agent containing an alkylene carbonate compound and a polyhydric alcohol compound is mixed into a water absorbent resin powder, the mixture is heat-reacted and, further, simultaneously with, or separately from the mixing, an ion reactive surface crosslinking agent is mixed, and/or (2) mixing treatment of mixing a surface crosslinking agent sol
    Type: Grant
    Filed: January 30, 2012
    Date of Patent: February 14, 2017
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kozo Nogi, Masatoshi Nakamura, Hirofumi Shibata, Koji Honda, Yusuke Watanabe, Satoshi Matsumoto, Reiko Nakatsuru, Kunihiko Ishizaki, Kazuki Kimura, Sayaka Machida
  • Patent number: 9518133
    Abstract: The physical properties of a water-absorbing resin with low residual monomer content are improved or stabilized, without sacrifices in productivity, production cost, stability, etc. Provided is a water-absorbing resin with low residual monomer content and excellent whiteness, wherein a water-absorbing resin consumed in large quantities in disposable diapers, etc., is preferably a sustainable and renewable water-absorbing resin that does not require excessive purification of the acrylic acid, particularly acrylic acids derived from non-fossil sources, that is the starting material of the water-absorbing resin. Disclosed is a method of manufacturing a hydrophilic polyacrylic acid (salt) resin, which is a method of manufacturing a water-absorbing polyacrylic acid resin that comprises a step in which a monomer is prepared from acrylic acid, a step in which said monomer is polymerized, and a step in which the resulting hydrous gel is dried.
    Type: Grant
    Filed: February 8, 2010
    Date of Patent: December 13, 2016
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Shinichi Fujino, Satoshi Matsumoto, Kunihiko Ishizaki
  • Publication number: 20160279602
    Abstract: The purpose of the present invention is to provide a process for stably and continuously producing a water-absorbing resin, specifically, a process for stably and continuously producing a water-absorbing resin, the process including a gas absorbing step in which a gas discharged from a step of producing a water-absorbing resin is efficiently and persistently absorbed. A main point of this process for producing a water-absorbing polyacrylic acid (salt) resin further including a step of absorbing a gas discharged from a production step of the water-absorbing polyacrylic acid (salt) resin in water having a pH of 7 to 11 and a polyvalent metal ion content of 100 ppm or less or a step of absorbing the gas in water having a pH of 7 to 11, the pH of the water having been adjusted by mixing a water having an electric conductivity of 500 (?S/cm) or less at 25° C. with an alkali compound.
    Type: Application
    Filed: November 14, 2014
    Publication date: September 29, 2016
    Inventors: Makoto NAGASAWA, Jiro SANO, Yoshiki KATADA, Kunihiko ISHIZAKI
  • Patent number: 9453091
    Abstract: A method for producing a water absorbent resin, the method including a polymerization step, a drying step, a classification step, and a surface crosslinking step. The classification step carried out before or after the surface crosslinking step requires use of a metal sieve mesh having stretch tension from 35 to 100 N/cm, in which an air jet cleaner or an air jet brush cleaner and plural tapping balls or tapping blocks are installed below the metal sieve mesh, a classification aid particle having specific gravity different from that of the water absorbent resin powder is added, and a fine powder of the water absorbent resin and the classification aid particle are removed.
    Type: Grant
    Filed: March 17, 2011
    Date of Patent: September 27, 2016
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Sumio Okuda, Syuji Kanzaki, Kunihiko Ishizaki, Shinichi Fujino, Kozo Nogi
  • Patent number: 9382390
    Abstract: There is disclosed a process for continuous production of a water-absorbent resin product by which the water-absorbent resin product having high properties can continuously be produced easily and inexpensively with stable constant quality. In addition, there is disclosed a water-absorbent resin product having high properties and being stable in quality.
    Type: Grant
    Filed: February 21, 2007
    Date of Patent: July 5, 2016
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kunihiko Ishizaki, Katsuhiro Kajikawa