Patents by Inventor Kunihiko Ishizaki

Kunihiko Ishizaki has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9320822
    Abstract: The present invention provides a method for manufacturing a water-absorbing resin which (i) is made of acrylic acid that is suitable for mass production of water-absorbing resin and (ii) has an excellent water-absorbing property. In the method, a polyacrylic acid (salt)-based water-absorbing resin is manufactured by sequentially carrying out predetermined monomer preparing step, polymerization step, drying step, and surface crosslinking step. An acetic acid concentration in acrylic acid or the like supplied in the monomer preparing step is in a range of 300 ppm to 10000 ppm on the acrylic acid basis, and an acetic acid concentration lowering rate defined by a predetermined formula is 35% or higher.
    Type: Grant
    Filed: February 18, 2013
    Date of Patent: April 26, 2016
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Satoshi Matsumoto, Takashi Miyamoto, Toyofumi Sakai, Yoshitake Ishii, Kunihiko Ishizaki
  • Patent number: 9308290
    Abstract: To improve the heat retention by diapers and other absorbents, a heat retention indicator 1 of a water-absorbing resin which is defined in the present invention needs be 3.0° C./min or less and also that particular requirements need be met to satisfy this condition. If the requirements are met, a water-absorbing resin, absorbent, and absorbent article can be provided which has a heat retention indicator 1 of 0 to 3.0° C./min or less and which exhibits excellent heat retention and absorption.
    Type: Grant
    Filed: September 18, 2013
    Date of Patent: April 12, 2016
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Katsuyuki Wada, Makoto Nagasawa, Kunihiko Ishizaki
  • Patent number: 9272068
    Abstract: The disclosed process for producing a water-absorbing resin comprising: a polymerization step of polymerizing an aqueous unsaturated monomer; and a drying step of drying a particulated water-containing gel-liked crosslinked polymer, obtained in a finely crushing step during the polymerization or after the polymerization. In the process, the drying step is interrupted with a dryer kept in a heated state and thereafter the drying step is restarted.
    Type: Grant
    Filed: March 14, 2011
    Date of Patent: March 1, 2016
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Syuji Kanzaki, Sumio Okuda, Kunihiko Ishizaki, Satoshi Matsumoto
  • Patent number: 9243079
    Abstract: A method for producing a polyacrylic water-absorbent resin powder includes the steps of: producing an acrylic monomer solution in which gas is dissolved and/or dispersed; polymerizing the monomer solution in the absence of a surface active agent or in the presence of not more than 300 ppm of a surface active agent; during or after polymerizing, fragmenting the resulting hydrated gel crosslinked polymer; and drying the fragmented hydrated gel crosslinked polymer. The gas is dissolved and/or dispersed in the monomer solution by (a) applying pressure to the acrylic monomer solution and the gas; (b) creating swirling flows of the acrylic monomer solution and the gas; or (c) introducing the gas with the acrylic monomer solution via fine holes. The production method efficiently produces a water-absorbent resin having an excellent water-absorption rate without deteriorating a liquid-absorbent property of a sanitary product or the like.
    Type: Grant
    Filed: June 11, 2014
    Date of Patent: January 26, 2016
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Shigeru Sakamoto, Yoshio Irie, Kozo Nogi, Kunihiko Ishizaki
  • Patent number: 9233186
    Abstract: The disclosed process for producing a water-absorbing resin comprising: a polymerization step of polymerizing an aqueous unsaturated monomer; a drying step of drying a particulated water-containing gel-liked crosslinked polymer, obtained in a finely crushing step during the polymerization or after the polymerization; a pulverizing step after the drying, a classification step after the drying, and a surface treatment step after the classification. In the process is, the surface-treatment step is interrupted with a heating treatment apparatus kept in a heated state and thereafter the surface treatment step is restarted.
    Type: Grant
    Filed: March 14, 2011
    Date of Patent: January 12, 2016
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Syuji Kanzaki, Sumio Okuda, Kunihiko Ishizaki, Satoshi Matsumoto
  • Patent number: 9138505
    Abstract: Disclosed is a method for producing a water absorbent resin, by which a surface-crosslinked water absorbent resin having excellent physical properties can be efficiently obtained at low cost, while assuring high productivity. When the production scale is increased to a continuous production on a huge scale (for example, 1 t/hr or more), the physical properties are improved and stabilized (for example, standard deviation of the physical properties is reduced) by a surface-crosslinking treatment, and the absorption against pressure (AAP) and liquid permeability (SFC) are further improved.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: September 22, 2015
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Kozo Nogi, Kunihiko Ishizaki, Katsuyuki Wada
  • Patent number: 9062140
    Abstract: An embodiment of the present invention allows for the production, with a high productivity, of a water-absorbent resin having an improved relationship between absorption capacity and water-soluble polymer, which are conflicting properties of the water-absorbent resin, being easily controlled for polymerization reaction, being of no odor, being less colored, and being of high absorption properties (high absorption capacity under load and high PPUP).
    Type: Grant
    Filed: April 6, 2006
    Date of Patent: June 23, 2015
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Hirotama Fujimaru, Kunihiko Ishizaki, Sei Nakahara
  • Patent number: 9044525
    Abstract: Provided is a water absorbent resin having excellent liquid permeability, water absorbent speed, anti-impact stability, and weather resistance. Provided is a polyacrylic acid (salt)-based water absorbent resin powder in which the water absorption capacity without load (CRC) is 30 to 45 [g/g], the water absorption capacity under load (AAP 0.3) is 20 to 35 [g/g], the water absorption capacity under load (AAP 0.7) is 10 to 28 [g/g], and the weight average particle diameter (D50) is 300 to 500 ?m, characterized by including p-methoxyphenol; having a degradable soluble component (0.05% L-A (saline) for 2 hours/60° C., one hour extraction rinse/room temperature) of 40% by weight or less; and having a internal gas bubbles ratio of 0.1 to 2.5%, as specified by the following equation.
    Type: Grant
    Filed: June 29, 2012
    Date of Patent: June 2, 2015
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Kazushi Torii, Reiko Nakatsuru, Yasuhisa Nakashima, Katsuyuki Wada, Kunihiko Ishizaki
  • Patent number: 9023951
    Abstract: Disclosed is a method for producing a water absorbent resin, by which a surface-crosslinked water absorbent resin having excellent physical properties can be efficiently obtained at low cost, while assuring high productivity. When the production scale is increased to a continuous production on a huge scale (for example, 1 t/hr or more), the physical properties are improved and stabilized (for example, standard deviation of the physical properties is reduced) by a surface-crosslinking treatment, and the absorption against pressure (AAP) and liquid permeability (SFC) are further improved.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: May 5, 2015
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kozo Nogi, Kunihiko Ishizaki, Syuji Kanzaki
  • Publication number: 20150011388
    Abstract: The present invention provides a method for manufacturing a water-absorbing resin which (i) is made of acrylic acid that is suitable for mass production of water-absorbing resin and (ii) has an excellent water-absorbing property. In the method, a polyacrylic acid (salt)-based water-absorbing resin is manufactured by sequentially carrying out predetermined monomer preparing step, polymerization step, drying step, and surface crosslinking step. An acetic acid concentration in acrylic acid or the like supplied in the monomer preparing step is in a range of 300 ppm to 10000 ppm on the acrylic acid basis, and an acetic acid concentration lowering rate defined by a predetermined formula is 35% or higher.
    Type: Application
    Filed: February 18, 2013
    Publication date: January 8, 2015
    Inventors: Satoshi Matsumoto, Takashi Miyamoto, Toyofumi Sakai, Yoshitake Ishii, Kunihiko Ishizaki
  • Patent number: 8907021
    Abstract: Disclosed is a method for producing a water absorbent resin, by which a surface-crosslinked water absorbent resin having excellent physical properties can be efficiently obtained at low cost, while assuring high productivity. When the production scale is increased to a continuous production at 1 t/hr or more, the physical properties are improved and stabilized (for example, standard deviation of the physical properties is reduced) by a surface-crosslinking treatment, and the absorption against pressure (AAP) and liquid permeability (SFC) are further improved.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: December 9, 2014
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Takahiro Kitano, Kozo Nogi, Kunihiko Ishizaki
  • Patent number: 8859685
    Abstract: A process for producing a water absorbent resin is provided with which it is possible to efficiently and inexpensively obtain a surface-crosslinked water-absorbing resin having excellent material properties, while ensuring high productivity. In continuous production scaled up to a large scale (in particular, 1 t/hr or more), the physical properties are improved and stabilized (for example, a reduction in standard deviation of the physical properties) by a surface crosslinking treatment to further improve absorption against pressure (AAP) and saline flow conductivity (SFC).
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: October 14, 2014
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kozo Nogi, Kunihiko Ishizaki, Kazumasa Konishi
  • Publication number: 20140296465
    Abstract: A method for producing a polyacrylic water-absorbent resin powder includes the steps of: producing an acrylic monomer solution in which gas is dissolved and/or dispersed; polymerizing the monomer solution in the absence of a surface active agent or in the presence of not more than 300 ppm of a surface active agent; during or after polymerizing, fragmenting the resulting hydrated gel crosslinked polymer; and drying the fragmented hydrated gel crosslinked polymer, the gas being dissolved and/or dispersed in the monomer solution by (a) applying pressure to the acrylic monomer solution and the gas; (b) creating swirling flows of the acrylic monomer solution and the gas; or (c) introducing the gas with the acrylic monomer solution via fine holes. The production method efficiently produces a water-absorbent resin having an excellent water-absorption rate without deteriorating a liquid-absorbent property of a sanitary product or the like.
    Type: Application
    Filed: June 11, 2014
    Publication date: October 2, 2014
    Inventors: Shigeru SAKAMOTO, Yoshio IRIE, Kozo NOGI, Kunihiko ISHIZAKI
  • Patent number: 8809475
    Abstract: A production method for a water-absorbent resin, comprising a polymerization step for obtaining hydrogel by subjecting a monomer aqueous solution to a polymerization reaction, and a drying step for drying the hydrogel, wherein drying in the drying step is performed using a continuous through-flow belt-type drying machine, the solid content of the hydrogel supplied to the drying step is 35% by weight or more, and thickness variation rate (1) represented by the following EXPRESSION 1 of the hydrogel loaded onto through-flow belt in the continuous through-flow belt, is 1.05 to 5: [MATH. 1] Thickness variation rate (1)=(Maximum thickness of hydrogel in a width direction of the through-flow belt)/(Average thickness of hydrogel in a width direction of the through-flow belt).
    Type: Grant
    Filed: August 30, 2010
    Date of Patent: August 19, 2014
    Assignee: Nippon Shokubai, Co., Ltd.
    Inventors: Koji Matsumoto, Kozo Nogi, Shinichi Fujino, Yorimichi Dairoku, Kunihiko Ishizaki
  • Patent number: 8802800
    Abstract: A production method for a water-absorbent resin, comprising a polymerization step for obtaining hydrogel by subjecting a monomer aqueous solution to a polymerization reaction, and a drying step for drying the hydrogel, wherein drying in the drying step is performed using a continuous through-flow belt-type drying machine, the pore opening rate of the through-flow belt in the continuous through-flow belt-type drying machine is 20 to 50%, the solid content of the hydrogel supplied to the drying step is 35% by weight or more, and the area occupancy rate of the hydrogel is 85 to 100% relative to the through-flow belt.
    Type: Grant
    Filed: August 30, 2010
    Date of Patent: August 12, 2014
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Shinichi Fujino, Kozo Nogi, Kunihiko Ishizaki
  • Patent number: 8791210
    Abstract: A method for producing a polyacrylic water-absorbent resin powder includes the steps of: producing an acrylic monomer solution in which gas is dissolved and/or dispersed; polymerizing the monomer solution in the absence of a surface active agent or in the presence of not more than 300 ppm of a surface active agent; during or after polymerizing, fragmenting the resulting hydrated gel crosslinked polymer; and drying the fragmented hydrated gel crosslinked polymer, the gas being dissolved and/or dispersed in the monomer solution by (a) applying pressure to the acrylic monomer solution and the gas; (b) creating swirling flows of the acrylic monomer solution and the gas; or (c) introducing the gas with the acrylic monomer solution via fine holes. The production method efficiently produces a water-absorbent resin having an excellent water-absorption rate without deteriorating a liquid-absorbent property of a sanitary product or the like.
    Type: Grant
    Filed: February 17, 2010
    Date of Patent: July 29, 2014
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Shigeru Sakamoto, Yoshio Irie, Kozo Nogi, Kunihiko Ishizaki
  • Publication number: 20140193641
    Abstract: Provided is a water absorbent resin having excellent liquid permeability, water absorbent speed, anti-impact stability, and weather resistance. Provided is a polyacrylic acid (salt)-based water absorbent resin powder in which the water absorption capacity without load (CRC) is 30 to 45 [g/g], the water absorption capacity under load (AAP 0.3) is 20 to 35 [g/g], the water absorption capacity under load (AAP 0.7) is 10 to 28 [g/g], and the weight average particle diameter (D50) is 300 to 500 ?m, characterized by including p-methoxyphenol; having a degradable soluble component (0.05% L-A (saline) for 2 hours/60° C., one hour extraction rinse/room temperature) of 40% by weight or less; and having a internal gas bubbles ratio of 0.1 to 2.5%, as specified by the following equation.
    Type: Application
    Filed: June 29, 2012
    Publication date: July 10, 2014
    Applicant: NIPPON SHOKUBAI CO., LTD.
    Inventors: Kazushi Torii, Reiko Nakatsuru, Yasuhisa Nakashima, Katsuyuki Wada, Kunihiko Ishizaki
  • Patent number: 8772413
    Abstract: Disclosed is a method for producing a water absorbent resin, by which a surface-crosslinked water absorbent resin having excellent physical properties can be efficiently obtained at low cost, while assuring high productivity. When the production scale is increased to a continuous production at 1 t/hr or more, the physical properties are improved and stabilized (for example, standard deviation of the physical properties is reduced) by a surface-crosslinking treatment, and the absorption against pressure (AAP) and liquid permeability (SFC) are further improved.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: July 8, 2014
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Takahiro Kitano, Kozo Nogi, Kunihiko Ishizaki
  • Patent number: 8765906
    Abstract: A water absorbent resin having less fine powder or powdery dust and a controlled particle size is provided, and the water absorption rate of the water absorbent resin is increased by a simple method at low cost, while maintaining or improving other physical properties such as liquid permeability.
    Type: Grant
    Filed: April 27, 2011
    Date of Patent: July 1, 2014
    Assignee: Nippon Shokubai, Co., Ltd.
    Inventors: Yusuke Watanabe, Kazushi Torii, Kozo Nogi, Kunihiko Ishizaki, Reiko Nakatsuru, Shigeru Sakamoto
  • Patent number: 8765857
    Abstract: A particulate water retaining material for cultivating plant comprising (A) a carboxyl group-containing water-insoluble water absorbent resin and (B) a polyvalent metal compound, by having the compound (B) deposited on the rerin (A), it is made possible to possess an outstanding water absorbing property without impairing the growth of a plant.
    Type: Grant
    Filed: December 6, 2004
    Date of Patent: July 1, 2014
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Hirotama Fujimaru, Yorimichi Dairoku, Kunihiko Ishizaki, Yoshifumi Adachi, Nobuyuki Harada