Patents by Inventor Lawrence N. Kremer
Lawrence N. Kremer has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20180216015Abstract: A multi-component scavenging system containing at least one ester and at least one electron-deficient organic compound, together with or without one or more optional components such as an aldehyde having from 4 to 20 carbon atoms, a ketone having from 4 to 20 carbon atoms, an ether, a solvent, an alkali metal salt of an alkyl or dialkyl phenol, an epoxide, an alkyl anhydride, and mixtures thereof, may be used to scavenge contaminants from hydrocarbon and/or aqueous streams. The contaminants scavenged or otherwise removed may include, but are not necessarily limited to, ammonia, primary amines, secondary or tertiary amines, H2S, mercaptans, sulfide cyanides, and combinations thereof.Type: ApplicationFiled: March 29, 2018Publication date: August 2, 2018Applicant: Baker Hughes IncorporatedInventors: Jianzhong Yang, Bradley G. Harrell, Lawrence N. Kremer
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Patent number: 9963642Abstract: It has been discovered that metals and/or amines can be removed or transferred from a hydrocarbon phase to a water phase in an emulsion breaking process by using a composition that contains water-soluble hydroxyacids. Suitable water-soluble hydroxyacids include, but are not necessarily limited to glycolic acid, gluconic acid, C2-C4 alpha-hydroxy acids, poly-hydroxy carboxylic acids, thioglycolic acid, chloroacetic acid, polymeric forms of the above hydroxyacids, poly-glycolic esters, glycolate ethers, and ammonium salt and alkali metal salts of these hydroxyacids, and mixtures thereof. The composition may also include at least one mineral acid to reduce the pH of the desalter wash water. A solvent may be optionally included in the composition. The invention permits transfer of metals and/or amines into the aqueous phase with little or no hydrocarbon phase undercarry into the aqueous phase.Type: GrantFiled: April 15, 2016Date of Patent: May 8, 2018Assignee: BAKER PETROLITE LLCInventors: Tran M. Nguyen, Lawrence N. Kremer, Jerry J. Weers
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Patent number: 9938470Abstract: A multi-component scavenging system containing at least one ester and at least one electron-deficient organic compound, together with or without one or more optional components such as an aldehyde having from 4 to 20 carbon atoms, a ketone having from 4 to 20 carbon atoms, an ether, a solvent, an alkali metal salt of an alkyl or dialkyl phenol, an epoxide, an alkyl anhydride, and mixtures thereof, may be used to scavenge contaminants from hydrocarbon and/or aqueous streams. The contaminants scavenged or otherwise removed may include, but are not necessarily limited to, ammonia, primary amines, secondary or tertiary amines, H2S, mercaptans, sulfide cyanides, and combinations thereof.Type: GrantFiled: May 10, 2012Date of Patent: April 10, 2018Assignee: Baker Hughes, a GE company, LLCInventors: Jianzhong Yang, Bradley G. Harrell, Lawrence N. Kremer
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Patent number: 9921177Abstract: Monitoring of conductivity within a steam generating system may proceed in real time and without interruption of the steam generating system by use of a boron doped diamond based electrochemical band sensor placed within the steam generating system. The boron doped diamond based electrochemical band sensor has a diamond body and a plurality of boron doped diamond band electrodes disposed within the diamond body. At least a portion of each of the plurality of boron doped diamond band electrodes is doped with boron to provide metallic conduction.Type: GrantFiled: May 29, 2015Date of Patent: March 20, 2018Assignee: Baker Hughes, a GE company, LLCInventors: Lawrence N. Kremer, Sidney A. Dunn, David N. Fulmer, Regis R. Rumpf
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Patent number: 9845434Abstract: Biological source oils, including, but not limited to, algae oil, stabilize the presence of asphaltenes in petroleum feedstocks, such as crude oil, to help avoid or prevent fouling and/or corrosion in the production, transferring and processing of the petroleum feedstocks. Chemical additives such as phenol-based resins, and reaction products or combinations of long chain alpha-olefins and/or small chain aldehydes and/or long chain alkyl phenate sulfides and/or metal oxide-based colloidal hydrocarbon-based nanodispersions, may also stabilize the presence of asphaltenes in petroleum feedstocks. By “stabilizing” is meant keeping the asphaltenes in solution in the petroleum feedstocks.Type: GrantFiled: December 19, 2016Date of Patent: December 19, 2017Assignee: Baker Hughes, a GE company, LLCInventors: Sai Reddy Pinappu, Lawrence N. Kremer, Corina L. Sandu
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Patent number: 9790251Abstract: Cellulose may be converted into simple sugars such as glucose by contacting the cellulose with a compound effective to catalytically cleave the ether bonds of the cellulose. The compound may be a vitamin, a porphyrin, flavins, pyridoxal-containing molecules, and/or a compound containing at least one ylide functional group. The cellulose may be carboxymethyl cellulose (CMC), which may be made by reacting cellulose with chloroacetic acid and a base such as NaOH. The compound may be vitamins (B1, B2, B6, or B12), phosphonium ylides, sulfonium ylides, sulfoxonium ylides, carbonyl ylides, oxonium ylides, asomethine ylides, iminium ylides, halonium ylides, and combinations thereof. The free glucose may be used for fermentation, converted to a biofuel and for other applications.Type: GrantFiled: July 24, 2014Date of Patent: October 17, 2017Assignee: Baker Hughes IncorporatedInventors: Charles David Armstrong, Stanley Gunawan, Lawrence N. Kremer
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Publication number: 20170096606Abstract: Biological source oils, including, but not limited to, algae oil, stabilize the presence of asphaltenes in petroleum feedstocks, such as crude oil, to help avoid or prevent fouling and/or corrosion in the production, transferring and processing of the petroleum feedstocks. Chemical additives such as phenol-based resins, and reaction products or combinations of long chain alpha-olefins and/or small chain aldehydes and/or long chain alkyl phenate sulfides and/or metal oxide-based colloidal hydrocarbon-based nanodispersions, may also stabilize the presence of asphaltenes in petroleum feedstocks. By “stabilizing” is meant keeping the asphaltenes in solution in the petroleum feedstocks.Type: ApplicationFiled: December 19, 2016Publication date: April 6, 2017Applicant: BAKER HUGHES INCORPORATEDInventors: SAI REDDY PINAPPU, LAWRENCE N. KREMER, CORINA L. SANDU
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Publication number: 20170066975Abstract: It has been discovered that metals and/or amines can be removed or transferred from a hydrocarbon phase to a water phase in an emulsion breaking process by using a composition that contains water-soluble hydroxyacids. Suitable water-soluble hydroxyacids include, but are not necessarily limited to glycolic acid, gluconic acid, C2-C4 alpha-hydroxy acids, poly-hydroxy carboxylic acids, thioglycolic acid, chloroacetic acid, polymeric forms of the above hydroxyacids, poly-glycolic esters, glycolate ethers, and ammonium salt and alkali metal salts of these hydroxyacids, and mixtures thereof. The composition may also include at least one mineral acid to reduce the pH of the desalter wash water. A solvent may be optionally included in the composition. The invention permits transfer of metals and/or amines into the aqueous phase with little or no hydrocarbon phase undercarry into the aqueous phase.Type: ApplicationFiled: April 15, 2016Publication date: March 9, 2017Applicant: Baker Petrolite LLCInventors: Tran M. Nguyen, Lawrence N. Kremer, Jerry J. Weers
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Patent number: 9523054Abstract: Biological source oils, including, but not limited to, algae oil, stabilize the presence of asphaltenes in petroleum feedstocks, such as crude oil, to help avoid or prevent problematic issues caused by the asphaltenes, such as sludges, plugging, deposits, fouling and/or corrosion in the production, transferring and processing of the petroleum feedstocks. Chemical additives such as phenol-based resins, and reaction products or combinations of long chain alpha-olefins and/or small chain aldehydes and/or long chain alkyl phenate sulfides and/or metal oxide-based colloidal hydrocarbon-based nanodispersions, may also stabilize the presence of asphaltenes in petroleum feedstocks. By “stabilizing” is meant keeping the asphaltenes in solution in the petroleum feedstocks.Type: GrantFiled: August 20, 2014Date of Patent: December 20, 2016Assignee: Baker Hughes IncorporatedInventors: Sai Reddy Pinappu, Lawrence N. Kremer, Corina L. Sandu
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Patent number: 9434890Abstract: It has been discovered that metals and/or amines can be removed or transferred from a hydrocarbon phase to a water phase in an emulsion breaking process by using a composition that contains water-soluble hydroxyacids. Suitable water-soluble hydroxyacids include, but are not necessarily limited to glycolic acid, gluconic acid, C2-C4 alpha-hydroxy acids, poly-hydroxy carboxylic acids, thioglycolic acid, chloroacetic acid, polymeric forms of the above hydroxyacids, poly-glycolic esters, glycolate ethers, and ammonium salt and alkali metal salts of these hydroxyacids, and mixtures thereof. The composition may also include at least one mineral acid to reduce the pH of the desalter wash water. A solvent may be optionally included in the composition. The invention permits transfer of metals and/or amines into the aqueous phase with little or no hydrocarbon phase undercarry into the aqueous phase.Type: GrantFiled: January 18, 2011Date of Patent: September 6, 2016Assignee: BAKER HUGHES INCORPORATEDInventors: Tran M. Nguyen, Lawrence N. Kremer, Jerry J. Weers
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Publication number: 20160230101Abstract: It has been discovered that metals and/or amines can be removed or transferred from a hydrocarbon phase to a water phase in an emulsion breaking process by using a composition that contains water-soluble hydroxyacids. Suitable water-soluble hydroxyacids include, but are not necessarily limited to glycolic acid, gluconic acid, C2-C4 alpha-hydroxy acids, poly-hydroxy carboxylic acids, thioglycolic acid, chloroacetic acid, polymeric forms of the above hydroxyacids, poly-glycolic esters, glycolate ethers, and ammonium salt and alkali metal salts of these hydroxyacids, and mixtures thereof. The composition may also include at least one mineral acid to reduce the pH of the desalter wash water. A solvent may be optionally included in the composition. The invention permits transfer of metals and/or amines into the aqueous phase with little or no hydrocarbon phase undercarry into the aqueous phase.Type: ApplicationFiled: April 15, 2016Publication date: August 11, 2016Applicant: Baker Petrolite LLCInventors: Tran M. Nguyen, Lawrence N. Kremer, Jerry J. Weers
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Publication number: 20160230068Abstract: Anionic polysaccharide polymers, derived from kelp may be used in additive compositions, and fluid compositions for viscosifying a base fluid, such as an aqueous-based fluid, a non-aqueous based fluid, and combinations thereof. In a non-limiting embodiment, a breaker additive may be used to break the viscosity of the viscosified fluid composition, which may have or include a breaker agent to break the viscosified fluid composition.Type: ApplicationFiled: April 20, 2016Publication date: August 11, 2016Applicant: BAKER HUGHES INCORPORATEDInventors: Lawrence N. Kremer, Charles D. Armstrong, Stanley Gunawan
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Publication number: 20150362452Abstract: Monitoring of conductivity within a steam generating system may proceed in real time and without interruption of the steam generating system by use of a boron doped diamond based electrochemical band sensor placed within the steam generating system. The boron doped diamond based electrochemical band sensor has a diamond body and a plurality of boron doped diamond band electrodes disposed within the diamond body. At least a portion of each of the plurality of boron doped diamond band electrodes is doped with boron to provide metallic conduction.Type: ApplicationFiled: May 29, 2015Publication date: December 17, 2015Inventors: Lawrence N. Kremer, Sidney A. Dunn, David N. Fulmer, Regis R. Rumpf
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Patent number: 9200213Abstract: Total acid number and/or corrosiveness of a crude or refined hydrocarbon, where the total acid number and/or corrosiveness is due to the presence of acid compounds such as carboxylic acid (naphthenic acid), may be reduced by treating the hydrocarbon with a metallic overbase. The effect of this treatment may be substantially enhanced by the presence of a hydrogen transfer agent.Type: GrantFiled: March 23, 2009Date of Patent: December 1, 2015Assignee: Baker Hughes IncorporatedInventors: Ksenija Babic-Samardzija, Joseph L. Stark, Michael J. Zetlmeisl, Bradley G. Harrell, Lawrence N. Kremer
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Publication number: 20150267105Abstract: Anionic polysaccharide polymers, derived from kelp may be used in additive compositions, and fluid compositions for viscosifying a base fluid, such as an aqueous-based fluid, a non-aqueous based fluid, and combinations thereof. In a non-limiting embodiment, a breaker additive may be used to break the viscosity of the viscosified fluid composition, which may have or include a breaker agent to break the viscosified fluid composition.Type: ApplicationFiled: March 18, 2014Publication date: September 24, 2015Applicant: BAKER HUGHES INCORPORATEDInventors: Lawrence N. Kremer, Charles D. Armstrong, Stanley Gunawan
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Publication number: 20150052802Abstract: Biological source oils, including, but not limited to, algae oil, stabilize the presence of asphaltenes in petroleum feedstocks, such as crude oil, to help avoid or prevent problematic issues caused by the asphaltenes, such as sludges, plugging, deposits, fouling and/or corrosion in the production, transferring and processing of the petroleum feedstocks. Chemical additives such as phenol-based resins, and reaction products or combinations of long chain alpha-olefins and/or small chain aldehydes and/or long chain alkyl phenate sulfides and/or metal oxide-based colloidal hydrocarbon-based nanodispersions, may also stabilize the presence of asphaltenes in petroleum feedstocks. By “stabilizing” is meant keeping the asphaltenes in solution in the petroleum feedstocks.Type: ApplicationFiled: August 20, 2014Publication date: February 26, 2015Applicant: BAKER HUGHES INCORPORATEDInventors: SAI REDDY PINAPPU, Lawrence N. Kremer, Corina L. Sandu
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Publication number: 20150051391Abstract: Cellulose may be converted into simple sugars such as glucose by contacting the cellulose with a compound effective to catalytically cleave the ether bonds of the cellulose. The compound may be a vitamin, a porphyrin, flavins, pyridoxal-containing molecules, and/or a compound containing at least one ylide functional group. The cellulose may be carboxymethyl cellulose (CMC), which may be made by reacting cellulose with chloroacetic acid and a base such as NaOH. The compound may be vitamins (B1, B2, B6, or B12), phosphonium ylides, sulfonium ylides, sulfoxonium ylides, carbonyl ylides, oxonium ylides, asomethine ylides, iminium ylides, halonium ylides, and combinations thereof. The free glucose may be used for fermentation, converted to a biofuel and for other applications.Type: ApplicationFiled: July 24, 2014Publication date: February 19, 2015Applicant: BAKER HUGHES INCORPORATEDInventors: Charles David ARMSTRONG, Stanley GUNAWAN, Lawrence N. KREMER
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Publication number: 20140378718Abstract: Introducing an additive into a crude oil may result in the crude oil having comparatively lower acid levels as compared to an otherwise identical crude oil absent the additive. The additive may include nanoparticles of metal oxides, oil soluble hydrogen donors, and/or heavy amines. The oil soluble hydrogen donors may be or include 1,2,3,4-tetrahydronaphthalene; 1,2,3,4-tetrahydrdroquinoline; 9,10-dihydroanthracene; 9,10-dihydrophenanthrene; and combinations thereof. The heavy amines may be or include alkyl amines, alkanolamines, polyethylene amines, polypropylene amines, and combinations thereof.Type: ApplicationFiled: June 23, 2014Publication date: December 25, 2014Applicant: BAKER HUGHES INCORPORATEDInventors: Zhenning Gu, Jerry M. Basconi, Corina L. Sandu, Lawrence N. Kremer, Jerry J. Weers
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Publication number: 20140202923Abstract: A demulsifying agent may be added to a hydrocarbon stream in an effective amount where the hydrocarbon stream includes a plurality of phosphorous-containing solids. The demulsifying agent may be added to the hydrocarbon stream at a location that is upstream from a desalter. The demulsifying agent may water-wet at least a portion of the phosphorous-containing solids for subsequent separation of the phosphorous-containing solids from the hydrocarbon stream. The demulsifying agent may be or include but is not limited to at least one maleic acid derivative, such as di-lauryl succinate, dioctyl succinate, di-hexyl succinate, octyl pheno succinate, dodecyl diphenyl succinate, ditridecyl succinate, dioctyl sulfosuccinate, disodium laureth sulfosuccinate, diammonium 1-icosyl 2 sulfosuccinate, ammonium 1,4 didecyl sulfosuccinate, dihexyl sodium sulfosuccinate, sodium dinonyl sulfosuccinate, sodium lauryl sulfoacetate, salts thereof, and combinations thereof.Type: ApplicationFiled: March 25, 2014Publication date: July 24, 2014Applicant: BAKER HUGHES INCORPORATEDInventors: Lawrence N. Kremer, Gerald O. Hoffman, Jerry J. Weers
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Patent number: 8765020Abstract: Mitigating or preventing corrosion of metal may be achieved in systems that are alkaline, such as carbon dioxide capture systems. The method may include adding an additive to a system wherein the system is at an alkaline pH; the system has both O2 and CO2 present; or the system is at an alkaline pH and has both O2 and CO2 present. The additive may be selected from the group consisting of: quaternary aromatic amines; quaternary alkyl substituted aromatic amines; and combinations thereof. The corrosion inhibiting properties of the additives may be increased by use of synergistic combinants. The abstract is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.Type: GrantFiled: May 17, 2010Date of Patent: July 1, 2014Assignee: Baker Hughes IncorporatedInventors: Ksenija Babić-Samard{hacek over (z)}ija, Lawrence N. Kremer, David J. Poelker, Vladimir Jovancicevic, Sunder Ramachandran